Adsorption Removal of Copper and Nickel Ions from Wastewater by Ammonia Modified Cotton Stalks

2014 ◽  
Vol 955-959 ◽  
pp. 2440-2443 ◽  
Author(s):  
Jing Li ◽  
Dong Mei Jia ◽  
Chang Hai Li ◽  
Bao Qing Yu
Keyword(s):  
Copper Ions ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Optimum Conditions ◽  
Nickel Ions ◽  
Adsorption Removal ◽  
Cotton Stalks ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Adsorbent Dose

The ammonia modified cotton stalks (CS) were utilized to adsorb the Ni2+and Cu2+ions from wastewaters, and the effect parameters (i.e. pH, contact time, adsorbent dose, and temperature) were also investigated by batch adsorption experiments. The maximum uptake was attained, i.e., 99.4% and 98.8%, respectively, for nickel and copper ions, under the optimum conditions (adsorbent dose: 10 g/L; pH: 6.0 (Ni2+), 5.0 (Cu2+); t: 75min; T: 20 °C) when the initial concentration of heavy metal ions was 20 mg/L. The adsorption process of nickel and copper ions on ammonia modified CS was well described by the pseudo-second-order kinetic model.

scholarly journals Removal of Cu(II) Ions byLeucaena Leucocephala(Subabul) Seed Pods from Aqueous Solutions

2010 ◽  
Vol 7 (s1) ◽  
pp. S377-S385 ◽  
Author(s):  
A. K. Patil ◽  
V. S. Shrivastava
Keyword(s):  
Leucaena Leucocephala ◽  
Contact Time ◽  
Unit Weight ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorption Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Isotherm Equations ◽  
Adsorbent Dose

In this method,Leucaena leucocephalaseed pods (LLSP) have been used for removal of Cu(II) ions from aqueous solution. Batch adsorption experiments were conducted to study the effect of process parameters like pH, contact time initial Cu(II) ions concentration and adsorbent dose. The maximum adsorption of Cu(II) ions onLeucaena leucocephalaseed pods was 94.17% at pH 5. The amount of metal adsorbed per unit weight of adsorbent increases with time and reach equilibrium after 30 minutes of shaking time for the different initial metal concentrations. The Freundlich and Langmuir isotherm equations were applied for the equilibrium adsorption data and the various isotherm parameters were evaluated. The obtained plots were linear as evident fromR2values close to unity. The data agreed very well with the pseudo second-order kinetic model.

scholarly journals Modified Cenospheres as an Adsorbent for the Removal of Disperse Dyes

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Markandeya Tiwari ◽  
S. P. Shukla ◽  
D. Mohan ◽  
D. S. Bhargava ◽  
G. C. Kisku
Keyword(s):  
Adsorption Process ◽  
Low Cost ◽  
Agitation Speed ◽  
Disperse Dyes ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorbate Concentration ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Adsorbent Dose

The main objective of this investigation was to use modified cenospheres for the removal of disperse blue 79:1 (DB) and disperse orange 25 (DO) dyes from aqueous solution by batch adsorption process under different conditions (pH, adsorbent dose, adsorbate concentration, agitation speed, contact time, and temperature). Modified cenosphere was capable of removing up to 78% of DB and 81% of DO dyes from aqueous solutions of 40 mg/L dyes concentration. The investigated data was explained by the Langmuir isotherm. The experimental data were found to follow the pseudo-second-order kinetic model. The results of this study suggested that modified cenospheres could be used as a low-cost alternative to expensive adsorbents like activated carbon in wastewater treatment for the removal of disperse dyes.

scholarly journals Removal of Copper (II) from Aqueous Solutions Using Cuttlebone as Bio-adsorbent

2016 ◽  
pp. 39-48
Author(s):  
Pathompong Vibhatabandhu ◽  
Sarawut Srithongouthai
Keyword(s):  
Aqueous Solutions ◽  
Low Cost ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Optimal Conditions ◽  
Optimum Conditions ◽  
Adsorption Data ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Biosorptionis an effective process for removal and recovery of heavy metal ions from aqueous solutions. In the present study, batch adsorption experiments were carried out for the removal of copper (Cu II) from aqueous solutions using cuttlebone powder (<100 μm)as a bio-adsorbent. The effects of initial pH, adsorbent dosage, initial concentration, and contact time on adsorption efficiency and capacity were studied to evaluate the optimum conditions for copper removal.The results found optimal conditions at initial pH of 5.0, 10 g L-1cuttlebone, 500 mg L-1initial concentration of Cu II in solution, and 150 min of equilibrium time.The Langmuir isotherm and pseudo-second order kinetic model were fitted to the experimental adsorption data. The maxi-mum adsorption capacity calculated from theLangmuir isotherm was 54.05 mg g-1. This result shows that cuttlebone is an effective bio-adsorbent, constituting a promising, efficient, low-cost, and eco-friendly technology bio-sorbent for reducing copper pollution during wastewater treatment.

Adsorption Removal of Phosphorus from Aqueous Solution by the Activated Carbon Prepared from Sugarcane Bagasse

2011 ◽  
Vol 183-185 ◽  
pp. 1046-1050
Author(s):  
Mei Na Liang ◽  
Hong Hu Zeng ◽  
Yi Nian Zhu ◽  
Ze Long Xu ◽  
Hui Li Liu
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Sugarcane Bagasse ◽  
Activated Carbons ◽  
Phosphorus Concentration ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorption Removal ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The activated carbon was prepared firstly by soaking sugarcane bagasse in 0.39% AlCl3 solution, and then by carbonization in a charcoal kiln at 400oC for 2 days and activation in a muffle furnace at 900°C for 100 minutes. The adsorption removal of phosphorus from aqueous solution by the prepared activated carbons was studied in a batch adsorption system. The amount of phosphorus adsorbed per unit mass of adsorbent decreased from 1.13 to 0.33 mg/g and the removal percentage of phosphorus increased from 22.64 to 99.27% with increasing adsorbent dosages from 100 to 1500 mg in 50mL solution of the initial phosphorus concentration of 10mg/L. With increasing phosphorus concentrations from 1 to 30 mg/L, the amount of phosphorus adsorbed increased from 0.06 to 1.11 mg/g and the percent adsorption decreased from 91.93 to 57.34%. The dynamical data fit very well with the pseudo-second-order kinetic model (R2>0.9962) and the Langmuir model agreed well with the experimental data (R2>0.9648).

Adsorption of Zn(II) from Aqueous Solutions by Thiol-Functionalized MCM-48

2011 ◽  
Vol 413 ◽  
pp. 148-153 ◽  
Author(s):  
Xue Na Hu ◽  
Ya Han ◽  
Jia Yan Li ◽  
Jun Yan Wu ◽  
Jian Rong Chen ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Pluronic P123 ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Poly Ethylene Oxide ◽  
Ft Ir ◽  
Poly Ethylene ◽  
Poly Propylene

Thiol-functionalized MCM-48 (SH-MCM-48) was synthesized by co-condensation method, with co-templates of cetyltrimethylammonium bromide (CTAB) and nonionic poly (ethylene oxide)–poly (propylene oxide)–poly (ethylene oxide) triblock copolymer (Pluronic P123). The resulting material was characterized by XRD and FT-IR spectrum. The potential of SH-MCM-48 for adsorption Zn (II) from aqueous solution was examined. Batch adsorption studies were carried out to investigate the effect of experimental parameters including pH, metal ions concentration and adsorption time. The maximum adsorption capacities of Zn (II) onto SH-MCM-48 were 30.12, 34.01 and 38.02 mg g-1 at the temperature of 303, 313 and 323K, respectively. The adsorption kinetics data were found to follow the pseudo-second-order kinetic model, and adsorption isotherms were fitted well with Langmuir and Freundlich models. Moreover, the adsorption thermodynamic parameters (△G0, △H0 and △S0) were measured, and indicated that the adsorption was an exothermic and spontaneous process.

scholarly journals Efficient Congo Red Removal Using Porous Cellulose/Gelatin/Sepiolite Gel Beads: Assembly, Characterization, and Adsorption Mechanism

Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3890
Author(s):  
Chenlu Jiao ◽  
Die Liu ◽  
Nana Wei ◽  
Jiannan Gao ◽  
Fan Fu ◽  
...  
Keyword(s):  
Congo Red ◽  
Adsorption Mechanism ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Dye Wastewater ◽  
Step Method ◽  
Gel Beads ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Highly Porous

Porous sustainable cellulose/gelatin/sepiolite gel beads were fabricated via an efficient ‘hydrophilic assembly–floating droplet’ two-step method to remove Congo red (CR) from wastewater. The beads comprised microcrystalline cellulose and gelatin, forming a dual network framework, and sepiolite, which acted as a functional component to reinforce the network. The as-prepared gel beads were characterized using FTIR, SEM, XRD, and TGA, with the results indicating a highly porous structure that was also thermally stable. A batch adsorption experiment for CR was performed and evaluated as a function of pH, sepiolite addition, contact time, temperature, and initial concentration. The kinetics and isotherm data obtained were in agreement with the pseudo-second-order kinetic model and the Langmuir isotherm, with a maximum monolayer capacity of 279.3 mg·g−1 for CR at 303 K. Moreover, thermodynamic analysis demonstrated the spontaneous and endothermic nature of the dye uptake. Importantly, even when subjected to five regeneration cycles, the gel beads retained 87% of their original adsorption value, suggesting their suitability as an efficient and reusable material for dye wastewater treatments.

scholarly journals Karekterisasi, Kinetika, dan Isoterm Adsorpsi Limbah Ampas Kelapa sebagai Adsorben Ion Cu(II)

SAINTIFIK ◽  
2020 ◽  
Vol 6 (2) ◽  
pp. 104-115
Author(s):  
Agusriyadin Agusriyadin
Keyword(s):  
Adsorption Capacity ◽  
Ph Effect ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Optimum Conditions ◽  
Langmuir Adsorption ◽  
Adsorbent Surface ◽  
Adsorption Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Penelitian ini bertujuan untuk menguji kemampuan AK dan AKPM dalam mengadsorpsi ion Cu (II), pengaruh parameter adsorpsi dan mekanisme adsorpsi. AK dan AKP Madsorben dibuat dari residu ampas kelapa. Adsorben dikarakterisasi dengan FTIR, SEM dan EDS. Pengaruh parameter adsorpsi seperti pH awal, dosis adsorben, waktu kontak dan konsentrasi ion Cu (II) awal diperiksa untuk menentukan kondisi optimum serapan tembaga (II). Ion Cu (II) yang teradsorpsi diukur berdasarkan pada konsentrasi Ion Cu (II) sebelum dan sesudah adsorpsi menggunakan metode AAS. Hasil karakterisasi menunjukkan bahwa struktur pori dan gugus fungsi tersedia pada permukaan adsorben. Menurut percobaan efek pH, kapasitas adsorpsi maksimum dicapai pada pH 7. Waktu kontak optimal dan konsentrasi tembaga awal (II) ditemukan masing-masing pada 120 menit dan 100 mg L-1. Data eksperimental sesuai dengan model kinetik orde dua orde dua, dan Langmuir isoterm adsorpsi yang diperoleh paling sesuai dengan data adsorpsi. Kapasitas adsorpsi maksimum adsorben ditemukan menjadi 4,73 dan 6,46 mg g-1 pada kondisi optimal. The results of characterization showed that the pore structure and the functional groups were available on adsorbent surface. According to the pH effect experiments, the maximum adsorption capacity was achieved at pH 7. Optimum contact time and initial copper(II) concentration were found at 120 min and 100 mg L-1, respectively. The experimental data were comply with the pseudo-second-order kinetic model, and Langmuir adsorption isotherm obtained best fitted the adsorption data. The maximum adsorption capacity of the adsorbents was found to be 4.73 and 6.46 mg g-1 at optimum conditions.

scholarly journals Preparation of bio-absorbents by modifying licorice residue via chemical methods and removal of copper ions from wastewater

2021 ◽  
Author(s):  
Xiaochun Yin ◽  
Nadi Zhang ◽  
Meixia Du ◽  
Hai Zhu ◽  
Ting Ke
Keyword(s):  
Adsorption Capacity ◽  
Copper Ions ◽  
Order Kinetic ◽  
Solution Ph ◽  
Chemical Methods ◽  
Simple Strategy ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Surface Active ◽  
Adsorption Desorption

Abstract In this paper, a series of bio-adsorbents (LR-NaOH, LR-Na2CO3 and LR-CA) were successfully prepared by modifying Licorice Residue with NaOH, Na2CO3 and citric acid, which were used as the adsorbents to remove Cu2+ from wastewater. The morphology and structure of bio-adsorbents were characterized by Fourier Transform Infrared, SEM, TG and XRD. Using static adsorption experiments, the effects of the adsorbent dosage, the solution pH, the adsorption time, and the initial Cu2+ concentration on the adsorption performance of the adsorbents were investigated. The results showed that the adsorption process of Cu2+ by the bio-adsorbents can be described by pseudo-second order kinetic model and the Langmuir model. The surface structure of the LR-NaOH, LR-Na2CO3 and LR-CA changed obviously, and the surface-active groups increased. The adsorption capacity of raw LR was 21.56 mg/g, LR-NaOH, LR- Na2CO3 significantly enhanced this value up to 43.65 mg/g, 43.55 mg/g, respectively. After four adsorption-desorption processes, the adsorption capacity of LR-NaOH also maintained about 73%. Therefore, LR-NaOH would be a promising adsorbent for removing Cu2+ from wastewater, and the simple strategy towards preparation of adsorbent from the waste residue can be as a potential approach using in the water treatment.

Biosorption of hexavalent chromium from aqueous solution by polyethyleneimine-modified ultrasonic-assisted acid hydrochar from Sargassum horneri

2020 ◽  
Vol 81 (6) ◽  
pp. 1114-1129 ◽  
Author(s):  
Jun Wang ◽  
Qinglong Xie ◽  
Ao Li ◽  
Xuejun Liu ◽  
Fengwen Yu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photoelectron Spectroscopy ◽  
Batch Adsorption ◽  
Crosslinking Reaction ◽  
Order Kinetic ◽  
Adsorption Capacities ◽  
Initial Ph ◽  
Ultrasonic Assisted ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Abstract In this study, an efficient route to synthesizing polyethyleneimine-modified ultrasonic-assisted acid hydrochar (PEI-USAH) is developed and reported. Ultrasonic irradiation technique was used as surface modification method to shorten the crosslinking reaction for hydrochar and polyethyleneimine (PEI). The PEI-USAH showed an excellent adsorption capacity for Cr(VI) from aqueous solution. The physicochemical properties of this PEI-modified adsorbent were comparatively characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller analysis and CNHS analysis. The effects of contact time, initial pH, and biosorbent dose on adsorption capacities were investigated. The batch adsorption experiments showed that PEI-USAH possessed the maximum adsorption capacities of 94.38 mg/g and 330.84 mg/g for initial Cr(VI) concentration of 100 mg/L and 500 mg/L, respectively. Furthermore, this adsorption process could be fitted to Langmuir adsorption and described by the pseudo second order kinetic model. Based on the above findings, PEI-USAH could be used as a potential adsorbent for removal of Cr(VI) from wastewater.

scholarly journals Adsorption removal of Cr(VI) by isomeric FeOOH

2019 ◽  
Vol 80 (2) ◽  
pp. 300-307
Author(s):  
Di Zhang ◽  
Jiaxin Liu ◽  
Shibei Zhu ◽  
Huixin Xiong ◽  
Yiqun Xu
Keyword(s):  
Active Sites ◽  
Correlation Coefficients ◽  
Order Kinetic ◽  
Isothermal Adsorption ◽  
Adsorption Mechanisms ◽  
Ph Values ◽  
Adsorption Removal ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Theoretical Evidence

Abstract The aim of this work is to study the performances of isomeric α-, β-, and γ-FeOOH (goethite, akaganéite and lepidocrocite, including five samples named as Gth1 and Gth2, Aka1 and Aka2, and Lep, respectively) for removing hexavalent chromium (Cr(VI)) from aqueous solutions. The adsorption mechanisms were explored by kinetic and isothermal experiments. Adsorption efficiencies under the different pH values, anions, and the levels of adsorbate and adsorbent were also measured. Results showed that the Cr(VI) adsorption by isomeric FeOOH could be best described by pseudo-second-order kinetic model. The processes of Cr(VI) isothermal adsorption could be greatly fitted by the Langmuir and Freundlich equations with the high correlation coefficients of R2 (&gt;0.92). Also, there were the optimum pH values of 3.0–8.0 for FeOOH to adsorb Cr(VI), and their adsorption capacities were tightly related with the active sites of adsorbents. Cr(VI) adsorptions by these adsorbents were easily influenced by H2PO4–, and then SO42–, while there were little effects by Cl–, CO32– and NO3–. These obtained results could provide a potentially theoretical evidence for isomeric FeOOH materials applied in the engineering treatment of the polluted chromate-rich waters.

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