Experimental Research of the 2-Ethylhexyl Nitrate with Micro-Channel Reaction Production Technology

2014 ◽  
Vol 997 ◽  
pp. 16-19
Author(s):  
Xi Chao Chen ◽  
Yan Yang ◽  
Fang Hua Yin ◽  
Ran Xu ◽  
Long Yao Wang
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Raw Materials ◽  
Space Velocity ◽  
Micro Channel ◽  
Channel Reactor ◽  
Mild Conditions ◽  
Liquid Hourly Space Velocity ◽  
Low Energy Consumption ◽  
Yield And Purity

The paper is about synthesizing the 2-ethylhexyl nitrate (2-EHN) with nitric acid and 2-Ethyl hexanol as raw materials and sulfuric acid as catalyst in a micro-channel reactor. The best synthetic conditions were determined under experiments: 1:2 for the mole ratio of nitric acid and sulfuric acid; 1:1 for the mole ratio of nitric acid and 2-Ethyl hexanol, the optimal liquid hourly space velocity is obtain as 4000h-1. In this condition, The yield and purity of EHN are Relatively high. This method is simple in process, mild conditions, safe, reliable and low energy consumption, providing the theory basis for industrialized production.

TIMETAL 35A

Alloy Digest ◽  
2001 ◽  
Vol 50 (11) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
High Temperature ◽  
Nitric Acid ◽  
Physical Properties ◽  
Chlorine Dioxide ◽  
Heat Treating ◽  
Bend Strength ◽  
Temperature Performance ◽  
Sodium And Potassium

Abstract Titanium shows outstanding resistance to seawater and marine atmospheres. It is also resistant to attack by hot metallic chloride solutions, sodium and potassium hypochlorite, and chlorine dioxide. The metal is resistant to attack by hot nitric acid at concentrations up to 80% and is not attacked by sulfuric acid. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and bend strength as well as fatigue. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: TI-122. Producer or source: Timet.

Gallium Arsenide Integrated Circuits Decapsulation Technique Using Mixed Acid Chemistry For Die-Level Failure Analysis

2018 ◽  
Author(s):  
Harold Jeffrey M. Consigo ◽  
Ricardo S. Calanog ◽  
Melissa O. Caseria
Keyword(s):  
Gallium Arsenide ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Integrated Circuits ◽  
Failure Analysis ◽  
Mixed Acid ◽  
Optimum Parameters ◽  
Plastic Package ◽  
Fuming Nitric Acid ◽  
Concentrated Sulfuric Acid

Abstract Gallium Arsenide (GaAs) integrated circuits have become popular these days with superior speed/power products that permit the development of systems that otherwise would have made it impossible or impractical to construct using silicon semiconductors. However, failure analysis remains to be very challenging as GaAs material is easily dissolved when it is reacted with fuming nitric acid used during standard decapsulation process. By utilizing enhanced chemical decapsulation technique with mixture of fuming nitric acid and concentrated sulfuric acid at a low temperature backed with statistical analysis, successful plastic package decapsulation happens to be reproducible mainly for die level failure analysis purposes. The paper aims to develop a chemical decapsulation process with optimum parameters needed to successfully decapsulate plastic molded GaAs integrated circuits for die level failure analysis.

Dimethyldisulphide Hydrodesulphurization on NiCoMo / Al2O3 Catalyst

2017 ◽  
Vol 68 (7) ◽  
pp. 1496-1500
Author(s):  
Rami Doukeh ◽  
Mihaela Bombos ◽  
Ancuta Trifoi ◽  
Minodora Pasare ◽  
Ionut Banu ◽  
...  
Keyword(s):  
Good Accuracy ◽  
Fixed Bed ◽  
Continuous System ◽  
Space Velocity ◽  
Molar Ratio ◽  
Catalytic Reactor ◽  
Liquid Hourly Space Velocity ◽  
Hydrodesulfurization Process ◽  
Al2o3 Catalyst ◽  
Simplified Kinetic Model

Hydrodesulphurization of dimethyldisulphide was performed on Ni-Co-Mo /�-Al2O3 catalyst. The catalyst was characterized by determining the adsorption isotherms, the pore size distribution and the acid strength. Experiments were carried out on a laboratory echipament in continuous system using a fixed bed catalytic reactor at 50-100�C, pressure from 10 barr to 50 barr, the liquid hourly space velocity from 1h-1 to 4h-1 and the molar ratio H2 / dimethyldisulphide 60/1. A simplified kinetic model based on the Langmuir�Hinshelwood theory, for the dimethyldisulphide hydrodesulfurization process of dimethyldisulphide has been proposed. The results show the good accuracy of the model.

The dichotomy between nitration of substituted 1,4-dimethoxybenzenes and formation of corresponding 1,4-benzoquinones by using nitric and sulfuric acid

2000 ◽  
Vol 2000 (3) ◽  
pp. 106-107 ◽  
Author(s):  
C. Waterlot ◽  
B. Haskiak ◽  
D. Couturier
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Oxidative Demethylation

Various alkyl-substituted p-dimethoxybenzenes (ArH) react readily with nitric acid and sulfuric to form nitro-products (ArNO2). When the nitric acid is used in excess, the nitro-product react via either nitration to dinitro-compound (Ar(NO2)2) or via oxidative demethylation to nitro- p-quinone (Q). As such, the competition between the nitration, polynitration and oxidative dealkylation is effectively modulated by the added nitric acid and the alkyl-substituted p-dimethoxybenzenes.

scholarly journals Electrochemical multicomponent synthesis of 4-selanylpyrazoles under catalyst- and chemical-oxidant-free conditions

2021 ◽  
Author(s):  
Yan Wu ◽  
Jin-Yang Chen ◽  
Jing Ning ◽  
Xue Jiang ◽  
Jie Deng ◽  
...  
Keyword(s):  
Multicomponent Reaction ◽  
Raw Materials ◽  
Multicomponent Synthesis ◽  
Mild Conditions ◽  
Simple Protocol ◽  
High Yields

An electrochemical multicomponent reaction was established under catalyst-, chemical-oxidant-free and mild conditions, which provides an eco-friendly and simple protocol for constructing 4-selanylpyrazoles from easily available raw materials with high yields.

Parametric study of methane catalytic combustion in a micro-channel reactor: Effects of porous washcoat properties

Fuel ◽  
2021 ◽  
Vol 290 ◽  
pp. 120099
Author(s):  
Weiqiang Liu ◽  
John Wen ◽  
Jinke Gong ◽  
Guanlin Liu ◽  
Chao Zhong ◽  
...  
Keyword(s):  
Parametric Study ◽  
Catalytic Combustion ◽  
Micro Channel ◽  
Channel Reactor ◽  
Methane Catalytic Combustion

scholarly journals Nitrile Synthesis with Aldoxime Dehydratases: A Biocatalytic Platform with Applications in Asymmetric Synthesis, Bulk Chemicals, and Biorefineries

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4466
Author(s):  
Pablo Domínguez de María
Keyword(s):  
Asymmetric Synthesis ◽  
Organic Solvents ◽  
Raw Materials ◽  
Aqueous Media ◽  
Industrial Processes ◽  
Polymer Chemistry ◽  
Fine Chemicals ◽  
Mild Conditions ◽  
Bulk Chemicals ◽  
Recent Developments

Nitriles comprise a broad group of chemicals that are currently being industrially produced and used in fine chemicals and pharmaceuticals, as well as in bulk applications, polymer chemistry, solvents, etc. Aldoxime dehydratases catalyze the cyanide-free synthesis of nitriles starting from aldoximes under mild conditions, holding potential to become sustainable alternatives for industrial processes. Different aldoxime dehydratases accept a broad range of aldoximes with impressive high substrate loadings of up to >1 Kg L−1 and can efficiently catalyze the reaction in aqueous media as well as in non-aqueous systems, such as organic solvents and solvent-free (neat substrates). This paper provides an overview of the recent developments in this field with emphasis on strategies that may be of relevance for industry and sustainability. When possible, potential links to biorefineries and to the use of biogenic raw materials are discussed.

scholarly journals A Multi-Function Compact Micro-Channel Reactor Coated with Sulphur Tolerant Catalyst for LPG Steam Reforming

Fuel Cells ◽  
2015 ◽  
Vol 15 (3) ◽  
pp. 516-522 ◽  
Author(s):  
J. Reed ◽  
R. Chen ◽  
C. Dudfield ◽  
P. Adcock
Keyword(s):  
Steam Reforming ◽  
Micro Channel ◽  
Channel Reactor

Activation and catalytic transformation of methane under mild conditions

2022 ◽  
Author(s):  
Yu Tang ◽  
Yuting Li ◽  
Franklin (Feng) Tao
Keyword(s):  
Energy Consumption ◽  
Low Energy ◽  
Catalytic Transformation ◽  
Mild Conditions ◽  
Low Energy Consumption ◽  
Fundamental Understanding

In the last few decades, scientists have been motivated by promising production of chemicals from methane under mild conditions for low energy consumption and climate remediation; significant fundamental understanding on this topic has been achieved.

Sign in / Sign up

Export Citation Format

Share Document