Degassing Behavior and Solid State Reaction of Nano-Ti(CN) Base Cermets in Sintering

2008 ◽  
Vol 368-372 ◽  
pp. 1104-1106 ◽  
Author(s):  
Shu Zhu Zhou ◽  
Ye Xia Qin ◽  
Chun Lei Wan ◽  
Kai Qi Liu ◽  
Long Hao Qi ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Solid State ◽  
Liquid Phase ◽  
Nitrogen Content ◽  
Oxygen Content ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Total Carbon ◽  
Two Phases

The chemical composition and solid state reaction of the nano-Ti(CN) base cermets in different sintering temperature were studied. The total carbon and oxygen content in compact were declined gradually with the increasing of sintering temperature, the nitrogen content in compact began to decline above 1100°C, the peak of de-gassing of N2 was formed before the emergence of liquid phase, the decomposition of N2 was arisen acutely above 1500°C. Mo2C and TaC diffused and took part in solid state reaction with Ti(CN) above 900°C, the solid state reaction was finished below 1200°C. WC diffused and took part in solid state reaction with Ti(CN) above 1100°C, it was dissolved below 1250°C, there were only two phases, Ti(CN) and Ni(Ni+Co), in the alloy.

scholarly journals Synthesis and Na+ Ion Conductivity of Stoichiometric Na3Zr2Si2PO12 by Liquid-Phase Sintering with NaPO3 Glass

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3790
Author(s):  
Yongzheng Ji ◽  
Tsuyoshi Honma ◽  
Takayuki Komatsu
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Sintering Temperature ◽  
Liquid Phase Sintering ◽  
Ion Conductivity ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Sintering Time ◽  
Lower Activation

Sodium super ionic conductor (NASICON)-type Na3Zr2Si2PO12 (NZSP) with the advantages of the high ionic conductivity, stability and safety is one of the most famous solid-state electrolytes. NZSP, however, requires the high sintering temperature about 1200 °C and long sintering time in the conventional solid-state reaction (SSR) method. In this study, the liquid-phase sintering (LPS) method was applied to synthesize NZSP with the use of NaPO3 glass with a low glass transition temperature of 292 °C. The formation of NZSP was confirmed by X-ray diffraction analyses in the samples obtained by the LPS method for the mixture of Na2ZrSi2O7, ZrO2, and NaPO3 glass. The sample sintered at 1000 °C for 10 h exhibited a higher Na+ ion conductivity of 1.81 mS/cm at 100 °C and a lower activation energy of 0.18 eV compared with the samples prepared by the SSR method. It is proposed that a new LPE method is effective for the synthesis of NZSP and the NaPO3 glass has a great contribution to the Na+ diffusion at the grain boundaries.

Effect of Sintering Temperature on Electrical Properties of SFN Ceramics Doped with Al Prepared by a Solid-State Reaction Technique

2016 ◽  
Vol 675-676 ◽  
pp. 527-530
Author(s):  
Thanatep Phatungthane ◽  
Kachaporn Sanjoom ◽  
Denis Russell Sweatman ◽  
Buagun Samran ◽  
Chamnan Randorn ◽  
...  
Keyword(s):  
Solid State ◽  
Electrical Properties ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Perovskite Phase ◽  
Dielectric Behavior ◽  
Orthorhombic Symmetry ◽  
X Ray Diffraction ◽  
Solid State Reaction Technique ◽  
Pure Perovskite Phase

In the present work, strontium iron niobate SrFe0.5Nb0.5O3 ceramics doped with aluminum were synthesized by a solid-state reaction technique. Phase formation investigation by X-ray diffraction technique (XRD) revealed that all ceramics exhibited pure perovskite phase with orthorhombic symmetry. Grain size observed by electron microscopy (SEM) was found to increase with increasing sintering temperature. The electrical properties and related parameters of the ceramics were also measured. The ceramics exhibit very good dielectric behavior and have a significant potential for dielectric applications.

Sintering behavior and ionic conductivity of Li1.5Al0.5Ti1.5(PO4)3 synthesized with different precursors

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Bambar Davaasuren ◽  
Qianli Ma ◽  
Alexandra von der Heiden ◽  
Frank Tietz
Keyword(s):  
Grain Size ◽  
Solid State ◽  
Ionic Conductivity ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Sintering Behavior ◽  
Homogeneous Microstructure ◽  
Micro Cracks ◽  
Primary Particles ◽  
Total Ionic Conductivity

Abstract Li1.5Al0.5Ti1.5(PO4)3 (LATP) powders were prepared from different NO x -free precursors using an aqueous-based solution-assisted solid-state reaction (SA-SSR). The sintering behavior, phase formation, microstructure and ionic conductivity of the powders were explored as a function of sintering temperature. The powders showed a relatively narrow temperature windows in which shrinkage occurred. Relative densities of 95% were reached upon heating between 900 and 960 °C. Depending on the morphological features of the primary particles, either homogeneous and intact microstructures with fine grains of about <2 µm in size or a broad grain size distribution, micro-cracks and grain cleavages were obtained, indicating the instability of the microstructure. Consequently, the ceramics with a homogeneous microstructure possessed a maximum total ionic conductivity of 0.67 mS cm−1, whereas other ceramics reached only 0.58 mS cm−1 and 0.21 mS cm−1.

Effect of Temperature on the Structural and Magnetic Properties of Co0.7Zn0.3Fe2O4 Ceramic Prepared from Solid State Reaction

2015 ◽  
Vol 804 ◽  
pp. 38-41
Author(s):  
Pattarinee Klumdoung ◽  
Piyapong Pankaew
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
Magnetic Properties ◽  
Solid State ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Effect Of Temperature ◽  
Dense Structure ◽  
Paramagnetic Behavior ◽  
Structural And Magnetic Properties

In present study, the Co0.7Zn0.3Fe2O4 ceramic was prepared using solid state reaction. The crystal structure of prepared ceramic indicated as solid solution. The SEM result indicated the dense structure of prepared ceramic as increased sintering temperature. For VSM result of Co0.7Zn0.3Fe2O4 ceramic indicated the super paramagnetic behavior with high magnetization. These results could lead us to the development of Co0.7Zn0.3Fe2O4 ceramic preparation optimized for specific applications.

Effect of Ag2O Doping on Some Physical Properties Y145 Superconductor

2016 ◽  
Vol 851 ◽  
pp. 57-60 ◽  
Author(s):  
Theerathawan Panklang ◽  
Rattanasuda Supadanaison ◽  
Chalit Wanichayanan ◽  
Adullawich Kaewkao ◽  
Tunyanop Nilkamjon ◽  
...  
Keyword(s):  
Critical Temperature ◽  
Solid State ◽  
Physical Properties ◽  
Porous Structure ◽  
Solid State Reaction ◽  
Annealing Temperature ◽  
Sintering Temperature

In this paper, the Y145 superconductor doped Ag2O were synthesized by solid state reaction. The calcinations and sintering temperature were at 920 °C and annealing temperature was at 550 °C. The highest critical temperature was in Y145+0.1Ag sample with Tc onset at 96 K and the lowest was found in pure Y145 at 95 K. We found that the surface of Y145 superconductor was improved by Ag adding on the porous structure.

Effects of Mg2SiO4 Addition on the Microstructure and Dielectric Properties of MgTiO3-CaTiO3 Ceramics

2013 ◽  
Vol 675 ◽  
pp. 200-204
Author(s):  
Fei Shi ◽  
Peng Cheng Du ◽  
Jing Xiao Liu ◽  
Ji Wei Wu ◽  
De Qing Chen ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Solid State ◽  
Dielectric Loss ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Solid State Reaction Method ◽  
Composite Ceramics ◽  
Reaction Method ◽  
Dielectric Ceramics

The Mg2SiO4-MgTiO3-CaTiO3 composite dielectric ceramics with different Mg2SiO4 addition amounts were prepared by solid state reaction method. The effects of Mg2SiO4 addition amounts on the microstructure and dielectric properties as well as sintering temperature of xMg2SiO4-(0.95-x)MgTiO3-0.05CaTiO3 (abbreviated as xMSTC, 0.25≦x≦0.75) composite ceramics were investigated. The results indicated that the sintering temperature of MgTiO3-CaTiO3 based ceramics with Mg2SiO4 addition could be lowered effectively to 1320~1340°C, and the dielectric constant decreased and dielectric loss increased gradually with the increase of Mg2SiO4 content. The 0.45MSTC ceramics containing 45 wt% Mg2SiO4 and sintered at 1340°C showed desirable dielectric properties with dielectric constant εr=13.3，dielectric loss tanδ=4.5×10-4 and temperature coefficient of relative permittivity τε =10 ppm/°C.

COMPARATIVE STUDY OF Bi-2223/Ag SUPERCONDUCTORS DERIVED FROM PARTICLES SIZE OF STARTING MATERIALS

2007 ◽  
Vol 21 (18n19) ◽  
pp. 3246-3249 ◽  
Author(s):  
D. SÝKOROVÁ ◽  
O. SMRČKOVÁ ◽  
K. RUBEŠOVÁ ◽  
P. VAŠEK
Keyword(s):  
Solid State ◽  
Comparative Study ◽  
Temperature Dependence ◽  
Solid State Reaction ◽  
Sintering Temperature ◽  
Sol Gel ◽  
Sol Gel Process ◽  
Current Densities ◽  
Size Of Particles ◽  
Micrometer Size

Series of the samples with nominal compositions Bi 3.2 Pb 0.8 Sr 4 Ca 5 Cu 7 O x and Bi 3.2 Pb 0.8 Sr 4 Ca 5 Cu 7 O x / Ag (10 wt%) were prepared by the standard solid state reaction at the same calcination and sintering temperature and time. Three starting mixtures were used, carbonates, oxides and silver i) with nanoparticles, ii) with micrometer size of particles and iii) powder obtained by modified sol-gel process. The main phase in all samples was Bi -2223 and silver formed the separate phase. The sol-gel process was found to be effective way in term of porosity, bulk density and connectivity of the grains. The effect of the microstructure on the transport properties were described by the temperature dependence of resistivity and critical current densities.

Low-Temperature Sintering and Microwave Dielectric Properties of CaWO4-Mg2SiO4 Ceramics

2014 ◽  
Vol 933 ◽  
pp. 12-16 ◽  
Author(s):  
Chung Long Pan ◽  
Ping Cheng Chen ◽  
Tsu Chung Tan ◽  
Wei Cheng Lin ◽  
Chun Hsu Shen ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Solid State ◽  
Liquid Phase ◽  
Sintering Temperature ◽  
Microwave Dielectric Properties ◽  
Liquid Phase Sintering ◽  
Low Temperature Sintering ◽  
Sintering Aids ◽  
Sintering Aid ◽  
Microwave Dielectric

The effect of V2O5addition on the microstructures and the microwave dielectric properties of 0.9CaWO4-0.1Mg2SiO4(9CWMS) ceramics prepared by conventional solid-state routes have been investigated. The V2O5were selected as liquid phase sintering aids to lower the sintering temperature of 9CWMS ceramics. A small amount of V2O5(0.25~1 wt%) were used for sintering aid and led to high densification at 1050°C. The dielectric properties of 9CWMS ceramics with V2O5additions are strongly dependent on the densification, the microstructure. As the amount of V2O5additives increased from 0.25 to 1.0 wt%, the dielectric constantsεrdecreased following the trend with density. The quality valuesQdecreased with the increase of V2O5amount for all sintering temperatures. The 0.25 wt% V2O5-doped 0.9CaWO4-0.1Mg2SiO4ceramicssintered at 1080°C for 2 h had the optimum dielectric properties: εr= 5.7;Q×f= 73000 (at 14 GHz).

Solid State Reaction Study of the System Li2CO3/Fe2O3

1998 ◽  
Vol 53 (12) ◽  
pp. 997-1003
Author(s):  
V. Berbenni ◽  
A. Marini ◽  
D. Capsoni
Keyword(s):  
Solid State ◽  
Detailed Analysis ◽  
Solid State Reaction ◽  
Reaction System ◽  
Reaction Model ◽  
Enthalpies Of Formation ◽  
Initial Composition ◽  
Xrd Study ◽  
Carbonate Decomposition ◽  
Two Phases

Abstract A thermoanalytical (TGA/DSC) and diffractometric (XRD) study has been performed on the solid state reaction system Li2CO3 -Fe2O3 in the x Li range 0.10±0.50. A detailed analysis of the results shows that the data are in agreement with a reaction model where the carbonate decomposition is regulated by the formation of both LiFeO2 and LiFe5O8 , and the relative amount of the two phases depends on the initial composition. The DSC evidence offers the possibility to directly quantify the LiFe5Ox phase. Furthermore it allows one to obtain the enthalpies of formation of both LiFeO2 and LiFe5O8 .

Sign in / Sign up

Export Citation Format

Share Document