Relationship between Microscopic Structures and Compressive Strength of Alkali-Activated Fly Ash Mortar

2010 ◽  
Vol 452-453 ◽  
pp. 737-740
Author(s):  
Hyun Jin Kang ◽  
Gum Sung Ryu ◽  
Gyung Taek Koh ◽  
Su Tae Kang ◽  
Jung Jun Park

This paper evaluates the relationship between the compressive strength and microscopic structure of geopolymer mortar using 100% of fly ash instead of cement. The experimental variable is the curing temperature, which may influence the compressive strength of the geopolymer. The compressive strength, porosity, XRD, SEM and EDS are examined after 48 hours of curing at 30, 60 and 90°C. The resulting compressive strength at 60°C appeared to be the largest. In order to evaluate the voids produced during the polymerization, the porosity was measured and showed also the largest value after curing at 60°C during 48 hours. Furthermore, SEM and EDS analyses verified clear improvement of the microstructure after 48 hours of curing at 60°C. Such result can be explained by the variation of the Si-Al ratio according to the curing conditions, which revealed to be lower for curing at 30 and 90°C than at 60°C and demonstrated that the curing temperature has significantly effect on the compressive strength of the geopolymer.

2011 ◽  
Vol 328-330 ◽  
pp. 1475-1482 ◽  
Author(s):  
M. M. A. Abdullah ◽  
H. Kamarudin ◽  
M. Bnhussain ◽  
I. Khairul Nizar ◽  
A.R. Rafiza ◽  
...  

Geopolymer, produced by the reaction of fly ash with an alkaline activator (mixture of Na2SiO3 and NaOH solutions), is an alternative to the use of ordinary Portland cement (OPC) in the construction industry. However, there are salient parameters that affecting the compressive strength of geopolymer. In this research, the effects of various NaOH molarities, Na2SiO3/NaOH ratios, fly ash/alkaline activator, and curing temperature to the strength of geopolymer paste fly ash were studied. Tests were carried out on 50 x 50 x 50 mm cube geopolymer specimens. Compression tests were conducted on the seventh day of testing for all samples. The test results revealed that a 12 M NaOH solution produced the highest compressive strength for the geopolymer. The combination mass ratios of fly ash/alkaline activator and Na2SiO3/NaOH of 2.0 and 2.5, respectively, produced the highest compressive strength after seven days. Geopolymer samples cured at 60 °C produced compressive strength as high as 70 MPa.


Author(s):  
Anıl Niş ◽  
İlhan Altındal

This study investigated the influence of different curing conditions on the compressive strength (CS) of the different alkali activated concrete (AAC) specimens at the ages of 2, 28, and 90 days for the structural utilization and standardization process of AAC instead of OPC concrete. For this aim, 100% slag (S100), 75% slag and 25% fly ash (S75FA25), and 50% slag and 50% fly ash based (S50FA50) AAC specimens were produced. Based on the oven-curing (O), water-curing (W), and ambient-curing (A) methods, the influence of 2O for 2 days, 26A2O, 2O26A, 28A, 28W, 26W2O, and 2O26W for 28 days, and 88A2O, 2O88A, 90A, 88W2O, 2O88W, 90W for 90 days on the CS of the AAC were examined in details. In addition, the influence of delayed oven-curing conditions on CS development was also investigated. The results indicated that curing conditions significantly affected on the CS and the water-curing condition could provide a better CS for those of AAC at 90 days. Although, the oven-curing enhanced CS of the S100 specimens at initial ages (first oven-curing applied), delayed oven-curing (oven-curing applied later) was found significant for S75FA25 and S50FA50 specimens. The delayed oven-curing affected more on the CS of the AAC when fly ash content increased. The most of AAC specimens with oven-curing had significantly enhanced the CS at 28 days, but S50FA50 at the age of 90 days decreased. Different curing regimes were proposed for the superior compressive strength values for each AAC specimens at the ages of 28 and 90 days.


2011 ◽  
Vol 33 (6) ◽  
pp. 653-660 ◽  
Author(s):  
Alexandre Silva de Vargas ◽  
Denise C.C. Dal Molin ◽  
Antônio C.F. Vilela ◽  
Felipe José da Silva ◽  
Bruno Pavão ◽  
...  

2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.


2011 ◽  
Vol 99-100 ◽  
pp. 960-964 ◽  
Author(s):  
Xue Ying Li ◽  
En Zu Zheng ◽  
Chun Long Ma

The compressive strength of geopolymer prepared from a class C fly ash (CFA) at different curing conditions and mass ratio of water to fly ash were investigated. The geopolymer was activated with a mixed solution of sodium hydroxide (NaOH) and sodium silicate. The results revealed that the obtained compressive strength was in the range of 11.7~61.9MPa and the compressive strength decreased with the increment of the mass ratio of water to CFA (W/F). The geopolymer samples with the highest strength were obtained when W/F was 0.30 with proper delay time 1d before being demoulded and then followed by curing at 60°C for 24h. For geopolymer with lower W/F (0.30), its optimum curing temperature was better not higher than 60°C, however, for the higher W/F, the curing temperature was suit to more than 70°C.


2020 ◽  
Author(s):  
Natalia Paszek ◽  
Marcin Górski

ThispaperpresentsastudyintothemechanicalbehaviourofFluidizedBedCombustion (FBC)fly ash-based geopolymer.FBCflyashisaby-product of a burning of a solid fuel (hard coal in case of this study) in a furnace at a low temperature. FBC fly ash is a type of a waste which is more difficult to recycle than pulverized fly ash.UsingFBCflyashin geopolymers offers one possible way to recycle it. The main goals of the investigation were to determine the influence of curing temperature and curing conditions on the strength of FBC fly ash-based geopolymer; to determine the changes of strength over time and the changes of the temperature inside the geopolymer during the curing process. Tests have shown that the strength of the geopolymer generally increases in line with the increase of a curing temperature. The compressive strength stabilizes after 5 days of curing and yet continues to gain extra strength over the longer term. Theflexuralbehaviourisnotmonotonicandthereforehardtopredict.The temperature inside the geopolymer rises rapidly until reaching around 27.5°C and then decreases steadily. Keywords: geopolymer, Fluidized Bed Combustion Fly ash, temperature, strength


2021 ◽  
Vol 11 (11) ◽  
pp. 4754
Author(s):  
Assia Aboubakar Mahamat ◽  
Moussa Mahamat Boukar ◽  
Nurudeen Mahmud Ibrahim ◽  
Tido Tiwa Stanislas ◽  
Numfor Linda Bih ◽  
...  

Earth-based materials have shown promise in the development of ecofriendly and sustainable construction materials. However, their unconventional usage in the construction field makes the estimation of their properties difficult and inaccurate. Often, the determination of their properties is conducted based on a conventional materials procedure. Hence, there is inaccuracy in understanding the properties of the unconventional materials. To obtain more accurate properties, a support vector machine (SVM), artificial neural network (ANN) and linear regression (LR) were used to predict the compressive strength of the alkali-activated termite soil. In this study, factors such as activator concentration, Si/Al, initial curing temperature, water absorption, weight and curing regime were used as input parameters due to their significant effect in the compressive strength. The experimental results depict that SVM outperforms ANN and LR in terms of R2 score and root mean square error (RMSE).


Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 714 ◽  
Author(s):  
Evangelos Petrakis ◽  
Vasiliki Karmali ◽  
Georgios Bartzas ◽  
Konstantinos Komnitsas

This study aims to model grinding of a Polish ferronickel slag and evaluate the particle size distributions (PSDs) of the products obtained after different grinding times. Then, selected products were alkali activated in order to investigate the effect of particle size on the compressive strength of the produced alkali activated materials (AAMs). Other parameters affecting alkali activation, i.e., temperature, curing, and ageing time were also examined. Among the different mathematical models used to simulate the particle size distribution, Rosin–Rammler (RR) was found to be the most suitable. When piecewise regression analysis was applied to experimental data it was found that the particle size distribution of the slag products exhibits multifractal character. In addition, grinding of slag exhibits non-first-order behavior and the reduction rate of each size is time dependent. The grinding rate and consequently the grinding efficiency increases when the particle size increases, but drops sharply near zero after prolonged grinding periods. Regarding alkali activation, it is deduced that among the parameters studied, particle size (and the respective specific surface area) of the raw slag product and curing temperature have the most noticeable impact on the compressive strength of the produced AAMs.


2011 ◽  
Vol 261-263 ◽  
pp. 416-420 ◽  
Author(s):  
Fu Ping Jia ◽  
Heng Lin Lv ◽  
Yi Bing Sun ◽  
Bu Yu Cao ◽  
Shi Ning Ding

This paper presents the results of elevated temperatures on the compressive of high fly ash content concrete (HFCC). The specimens were prepared with three different replacements of cement by fly ash 30%, 40% and 50% by mass and the residual compressive strength was tested after exposure to elevated temperature 250, 450, 550 and 650°C and room temperature respectively. The results showed that the compressive strength apparently decreased with the elevated temperature increased. The presence of fly ash was effective for improvement of the relative strength, which was the ratio of residual compressive strength after exposure to elevated temperature and ordinary concrete. The relative compressive strength of fly ash concrete was higher than those of ordinary concrete. Based on the experiments results, the alternating simulation formula to determine the relationship among relative strength, elevated temperature and fly ash replacement is developed by using regression of results, which provides the theoretical basis for the evaluation and repair of HFCC after elevated temperature.


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