Nondestructive Microscopy Test on Damage of Waterproof Material in Underground Engineering

2015 ◽  
Vol 645-646 ◽  
pp. 900-905
Author(s):  
Qing Guo Wang ◽  
Qi Xin Yang ◽  
Ya Jun Jiang ◽  
Juan Yang

The microstructure changes of acrylate spray-on waterproof material in alkaline groundwater environment were tentatively studied with X-ray microscopy (XRM), and the validity of deciding the failure of the material was explored in paper. Regarded NaOH solution with pH=12 as corrosive medium, after the immersion in the alkaline solution, spray-on waterproof material was scanned with XRM, and the structure was characterized with some indexes such as porosity and pore connectivity. The results show that when the waterproof material is immersed in alkaline solution for some time, the surface of the material becomes uneven, the overall porosity falls and the pore connectivity rises. It is feasible to study on the failure of waterproof material in underground engineering with XRM.

2013 ◽  
Vol 78 (4) ◽  
pp. 549-554 ◽  
Author(s):  
Uros Lacnjevac

Composite Ni-MoO2 coatings were prepared and characterized with respect to their possible application as electrocatalysts for the hydrogen evolution reaction (HER) in alkaline solution. The composites were electrodeposited onto Ni meshes from an ammonium chloride Ni solution with suspended MoO2 particles in simulated industrial conditions for production of commercial cathodes. The influence of the concentration of MoO2 particles in the solution and deposition current density on the morphology, chemical and phase composition of obtained coatings was investigated by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). Catalytic activity for the HER of the coatings was examined by polarization measurements in a 32 wt. % NaOH solution at 90?C and compared to the activity of the commercial De Nora?s cathode (DN). It was shown that the most active Ni-MoO2 coating exhibits better polarization characteristics for the HER than the DN cathode. The mechanism of the HER on the specified Ni-MoO2 coating was investigated in 8 mol dm-3 NaOH at 30?C by means of steady-state polarization measurements and an electrochemical impedance spectroscopy (EIS) method. Based on the theoretical interpretation of the experimental data, rate constants of the three individual steps of the HER were determined and the source of catalytic activity of the coating was elucidated.


2014 ◽  
Vol 595 ◽  
pp. 8-13 ◽  
Author(s):  
Shan Lin Gu ◽  
Xing Li Zou ◽  
Xiong Gang Lu

Electroreduction of Fe2O3to Fe in sodium hydroxide solutions has been investigated. It is found that pure iron powder with uniform crystal particles can be obtained by electrolysis of Fe2O3in alkaline solution. The porosity of the iron oxide (Fe2O3) pellet and the concentration of NaOH solution have significant influences on the electrolysis process. The deoxidation rate increases with increasing the concentration of NaOH solution, the grain size of iron products decreases with increasing the concentration of NaOH. The optimum NaOH concentration and pressure load used to fabricate Fe2O3pellet are 60 wt% and 6 MPa, respectively. X-ray powder diffraction (XRD) analysis indicates that Fe3O4was produced as the intermediate product during the electroreduction process.


Author(s):  
Kristof Dorau ◽  
Daniel Uteau ◽  
Maren Hövels ◽  
Stephan Peth ◽  
Tim Mansfeldt

Soil Research ◽  
2012 ◽  
Vol 50 (8) ◽  
pp. 638 ◽  
Author(s):  
Alla Marchuk ◽  
Pichu Rengasamy ◽  
Ann McNeill ◽  
Anupama Kumar

Non-destructive X-ray computed tomography (µCT) scanning was used to characterise changes in pore architecture as influenced by the proportion of cations (Na, K, Mg, or Ca) bonded to soil particles. These observed changes were correlated with measured saturated hydraulic conductivity, clay dispersion, and zeta potential, as well as cation ratio of structural stability (CROSS) and exchangeable cation ratio. Pore architectural parameters such as total porosity, closed porosity, and pore connectivity, as characterised from µCT scans, were influenced by the valence of the cation and the extent it dominated in the soil. Soils with a dominance of Ca or Mg exhibited a well-developed pore structure and pore interconnectedness, whereas in soil dominated by Na or K there were a large number of isolated pore clusters surrounded by solid matrix where the pores were filled with dispersed clay particles. Saturated hydraulic conductivities of cationic soils dominated by a single cation were dependent on the observed pore structural parameters, and were significantly correlated with active porosity (R2 = 0.76) and pore connectivity (R2 = 0.97). Hydraulic conductivity of cation-treated soils decreased in the order Ca > Mg > K > Na, while clay dispersion, as measured by turbidity and the negative charge of the dispersed clays from these soils, measured as zeta potential, decreased in the order Na > K > Mg > Ca. The results of the study confirm that structural changes during soil–water interaction depend on the ionicity of clay–cation bonding. All of the structural parameters studied were highly correlated with the ionicity indices of dominant cations. The degree of ionicity of an individual cation also explains the different effects caused by cations within a monovalent or divalent category. While sodium adsorption ratio as a measure of soil structural stability is only applicable to sodium-dominant soils, CROSS derived from the ionicity of clay–cation bonds is better suited to soils containing multiple cations in various proportions.


2007 ◽  
Vol 352 ◽  
pp. 297-300
Author(s):  
Toshikazu Akahori ◽  
Mitsuo Niinomi ◽  
Masaaki Nakai

Titanium and its alloys have been widely used as biomaterials for hard tissue replacements because of their excellent mechanical properties and biocompatibility. However, the bonding between their surfaces and bone is not enough after implantation. The bioactive surface modification such as a hydroxyapatite (HAp) coating on their surfaces has been investigated. Recently, a simple method for forming HAp layer on the surfaces of titanium and its alloys has been developed. This method is called as alkaline treatment process. In this method, HAp deposits on the surfaces of titanium and its alloys by dipping into simulated body fluid (SBF) after an alkaline solution treatment that is followed by a baking treatment (alkaline treatment). This process is applicable to newly developed beta-type Ti-29Nb-13Ta-4.6Zr alloy (TNTZ) for biomedical applications achieving bioactive HAp modification. In this study, the morphology of the HAp layer formed on the surface of TNTZ was investigated after various alkaline treatments followed by dipping in SBF. The formability of HAp on the surface of TNTZ was then discussed. The formability of HAp on TNTZ is much lower than that of commercially pure Ti, Ti-6Al-4V ELI and Ti-15Mo-5Zr-3Al alloys, which are representative metallic biomaterials. The formability of HAp on TNTZ is improved by increasing the amount of Na in the sodium titanate gels formed during an alkaline solution treatment where the NaOH concentrations and the dipping time are over 5 M and 172.8 ks, respectively. The formability of HAp on TNTZ is considerably improved by dipping in a 5 M NaOH solution for 172.8 ks. This condition for alkaline solution treatment process is the most suitable for TNTZ.


2021 ◽  
Vol 21 (11) ◽  
pp. 5592-5602
Author(s):  
Samira Almasi ◽  
Ali Mohammad Rashidi

The effect of the yttria-stabilized zirconia (YSZ) nanoparticle loading in an electro-less bath was considered as one of the vital synthesis variables for control Ni content and microstructure of prepared nanocomposite particles, which are two crucial factors to achieving high-performance SOFC anode. Nanocomposite particles were prepared using a simple electroless method without any expensive pretreatment of sensitizing by Sn2+ ions as well as activating by Pd2+ ions that are usually used to apply nickel coating on the surface of a non-conductive substrate. The process was performed by adding YSZ nanoparticles into NaOH solution, separating them from the solution by the centrifugal method, then providing several water-based nanofluids with different concentrations of activated YSZ nanoparticles, mixing them with NiCI2 solution, followed by adding the hydrazine and then NaOH solution. X-ray diffraction and scanning electron microscopy coupled with energy dispersive X-ray analysis were used to analyze the prepared nanocomposite particles. It is observed that after adding YSZ nanoparticles into the NaOH solution, the pH of the solution varied gradually from a starting pH of 10.2 to 9. Also, by increasing the YSZ nanoparticles loading in the electroless bath from 76 mg/l to 126 mg/l, the grain size of Ni deposits, the Ni content and the average size of the prepared nanocomposite particles decreased. The electrochemical mechanism previously proposed for the nickel ion reduction was modified, and a novel analytical model was proposed for variation of the efficiency of Ni deposition with YSZ nanoparticles loading.


2011 ◽  
Vol 675-677 ◽  
pp. 33-36
Author(s):  
Chuan Wu ◽  
Ying Bai ◽  
Feng Wu ◽  
Dan Xian Liu

Amorphous Ni-Co-B catalyst was synthesized by a chemical reduction method, and followed by a heat-treating at 100°C, then characterized by X-ray diffraction (XRD), Scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmetr-Teller (BET) analysis, and adopted to help accelerating hydrolysis reaction of NaBH4 alkaline solution. It is proved that the amorphous Ni-Co-B catalyst is not a simple combination of elemental Ni, Co and B, but a multiplex metal boride. It exhibits an maximum hydrogen generation rate of 210 ml/min/(g catalyst) at 100% H2 utilization, which is potentially to give a successive H2 supply for proton exchange membrane fuel cells.


2018 ◽  
Vol 73 (11) ◽  
pp. 831-836 ◽  
Author(s):  
Gohil S. Thakur ◽  
Hans Reuter ◽  
Claudia Felser ◽  
Martin Jansen

AbstractA new stacking variant of sodium hexa-hydroxo platinate(IV), Na2Pt(OH)6, was synthesized and its structure elucidated through X-ray diffraction. The new polymorph was prepared by direct reaction of PtO2 with an excess of NaOH solution applying elevated oxygen pressure at 300°C. The structure consists of layers of edge sharing Pt(OH)6 and Na(OH)6 octahedra. These layers are separated by an edge-to-edge distance of ~2.4 Å. The packing of the hydroxide ions corresponds to the hcp sequence, the title compound thus may be regarded a cation ordered variant of the Brucite structure type. During heating above T~300°C all constitutional water is released, and anhydrous Na2PtO3 remains as the solid residue.


2019 ◽  
Vol 25 (2) ◽  
pp. 404-416 ◽  
Author(s):  
Tharmalingam Sivarupan ◽  
Mohamed El Mansori ◽  
Keith Daly ◽  
Mark Noel Mavrogordato ◽  
Fabrice Pierron

Purpose Micro-focus X-ray computed tomography (CT) can be used to quantitatively evaluate the packing density, pore connectivity and provide the basis for specimen derived simulations of gas permeability of sand mould. This non-destructive experiment or following simulations can be done on any section of any size sand mould just before casting to validate the required properties. This paper aims to describe the challenges of this method and use it to simulate the gas permeability of 3D printed sand moulds for a range of controlling parameters. The permeability simulations are compared against experimental results using traditional measurement techniques. It suggests that a minimum volume of only 700 × 700 × 700 µm3 is required to obtain, a reliable and most representative than the value obtained by the traditional measurement technique, the simulated permeability of a specimen. Design/methodology/approach X-ray tomography images were used to reconstruct 3D models to simulate them for gas permeability of the 3D printed sand mould specimens, and the results were compared with the experimental result of the same. Findings The influence of printing parameters, especially the re-coater speed, on the pore connectivity of the 3D printed sand mould and related permeability has been identified. Characterisation of these sand moulds using X-ray CT and its suitability, compared to the traditional means, are also studied. While density and 3PB strength are a measure of the quality of the moulds, the pore connectivity from the tomographic images precisely relates to the permeability. The main conclusions of the present study are provided below. A minimum required sample size of 700 × 700 × 700 µm3 is required to provide representative permeability results. This was obtained from sand specimens with an average sand grain size of 140 µm, using the tomographic volume images to define a 3D mesh to run permeability calculations. Z-direction permeability is always lower than that in the X-/Y-directions due to the lower values of X-(120/140 µm) and Y-(101.6 µm) resolutions of the furan droplets. The anisotropic permeability of the 3D printed sand mould is mainly due to, the only adjustable, X-directional resolution of the furan droplets; the Y-directional resolution is a fixed distance, 102.6 µm, between the printhead nozzles and the Z-directional one is usually, 280 µm, twice the size of an average sand grain.A non-destructive and most representative permeability value can be obtained, using the computer simulation, on the reconstructed 3D X-ray tomography images obtained on a specific location of a 3D printed sand mould. This saves time and effort on printing a separate specimen for the traditional test which may not be the most representative to the printed mould. Originality/value The experimental result is compared with the computer simulated results.


2021 ◽  
Author(s):  
Maik Lucas ◽  
Linh Nguyen ◽  
Andrey Guber ◽  
Alexandra Kravchenko

<p>Cover crops are known to increase macroporosity and pore connectivity, thus having a beneficial effect on soil hydraulic properties such as saturated hydraulic conductivity, However, cover crop species typically used encompass a variety of contrasting root architectures and their effects on small-scale pore properties are difficult to quantify.</p><p>Here we explore the influence of five different cover crops (annual ryegrass, Austrian winter pea, dwarf essex rapeseed, oats, and oilseed radish) on soil structure with X-ray µCT. Undisturbed samples were taken from an experiment with these cover crops on Kellogg Biological Station (Michigan, USA) in October 2019. Two soil columns with a diameter of 5 cm were taken in 5 - 10 cm depth from each of three replicated plots per plant species and scanned with X-ray µCT at a resolution of 18 µm.</p><p>These images will be used to characterize pore structure in terms of pore size distribution, pore connectivity. In addition, a new imaging protocol will be used, which combines existing ones with a random forest classifier to segment image features such as pores, biopores and roots simultaneously.</p><p>First, the results reveal that different cover crops indeed result in different pore characteristics.  The fibrous root system of oats leads to the highest volume of narrow macropores and increased their connectivity, while the tap root system of dwarf essex rapeseed mainly effected wide macropores.  The highly diverse root system of Australian winter pea increased a wide range of pore sizes and thus resulted in the highest visible porosity.</p><p>The current study is funded by a grant from USDA Organic Transition program</p>


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