Correlation of Blooming and Tensile Properties in Surfactant-Loaded Natural Rubber Vulcanizates

2016 ◽  
Vol 705 ◽  
pp. 35-39 ◽  
Author(s):  
Bryan B. Pajarito ◽  
Jimyl Arabit
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Tensile Strain ◽  
Tensile Modulus ◽  
Adhesive Tape ◽  
Taguchi Design Of Experiment ◽  
Convection Oven ◽  
Maximum Tensile Strain ◽  
Natural Rubber Vulcanizates

Tensile properties of surfactant-loaded natural rubber (NR) vulcanizates are investigated in correlation with blooming. Rubber sheets are compounded using an L12 orthogonal array of Taguchi design of experiment, where ingredients are treated as factors varied at low and high loadings. Blooming experiments are carried out by placing NR sheets in a natural convection oven set at 50 °C for 20 days. The amount of bloom on the surface is removed using adhesive tape and is monitored with time. Tensile properties of rubber dogbone samples are also measured with time. Results show that 5 out of 12 formulations show blooming to be significantly related to tensile modulus (0.005 < p < 0.039). It is observed that the tensile modulus increases with blooming (0.898 < r < 0.973). Three formulations indicate significant correlation of blooming with tensile strength (0.022 < p < 0.047). As observed, tensile strength decreases with blooming (-0.884 < r < -0.930). Five formulations signify blooming to have significant correlation with maximum tensile strain (0.000 < p < 0.011), which decreases with blooming (-0.957 < r < -0.995). Two formulations imply significant negative (-0.960 < r < -0.963) correlation between blooming and tensile set (p= 0.009).

Effect of Ingredient Loading and Temperature on Tensile Properties of Surfactant-Loaded Natural Rubber Vulcanizates

2019 ◽  
Vol 803 ◽  
pp. 356-360
Author(s):  
J. Arabit-Cruz ◽  
Bryan Pajarito
Keyword(s):  
Tensile Strength ◽  
Elastic Modulus ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Tensile Strain ◽  
High Loading ◽  
Glycerol Monostearate ◽  
Taguchi Design Of Experiment ◽  
Used Oil ◽  
Natural Rubber Vulcanizates

Tensile properties are among the measures that give rubber products value. In this study, the effect of ingredient loading and temperature on the tensile properties of surfactant-loaded natural rubber vulcanizates (NRV) are investigated. Rubber dogbone samples are compounded using an L12 orthogonal array of Taguchi design of experiment, where ingredients are treated as factors varied at low and high loadings. Rubber specimens for each formulation are thermally aged for 20 days in ovens with temperatures of 40, 50, and 60 °C. Results show that zinc oxide (ZnO), paraffin wax, sulfur, mercaptobenzothiazole (MBT), and diphenylguanidine (DPG) significantly have the highest effect on increasing the elastic modulus while decreasing the tensile strength, tensile strain, and tensile set. Used oil has the highest effect on decreasing the elastic modulus but has the highest effect on increasing tensile strength, tensile strain, and tensile set. High loading of cocamide diethanolamide (coca DEA) significantly increases tensile strength at 60 °C. High loading of glycerol monostearate (GMS) significantly decreases tensile strength and strain at 40 °C. Highest elastic modulus, tensile strength, strain, and set are achieved when NRV are thermally aged at 50 °C.

scholarly journals The effects of alkanolamide addition on cure characteristics, swelling behaviour and tensile properties of silica-filled natural rubber (NR) / chloroprene rubber (CR) blends

2018 ◽  
Vol 34 ◽  
pp. 01030 ◽  
Author(s):  
Indra Surya ◽  
Syahrul Fauzi Siregar ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Tensile Modulus ◽  
Palm Stearin ◽  
Swelling Behaviour ◽  
Elongation At Break ◽  
Cure Characteristics ◽  
Chloroprene Rubber

Effects of alkanolamide (ALK) addition on cure characteristics, swelling behaviour and tensile properties of silica-filled natural rubber (NR)/chloroprene rubber (CR) blends were investigated. The ALK was synthesized from Refined Bleached Deodorized Palm Stearin (RBDPS) and diethanolamine, and incorporated into the silica-filled NR/CR blends as a non-toxic rubber additive. The ALK loadings were 0.0, 1.0, 3.0, 5.0 and 7.0 phr. It was found that the ALK exhibited shorter scorch and cure times and higher elongation at break of the silica-filled NR/CR blends. The ALK also exhibited higher torque differences, tensile modulus and tensile strength at a 1.0 phr of ALK loading and then decreased with further increases in the ALK loading. The swelling measurement proved that the 1.0 phr loading of ALK caused the highest degree in crosslink density of the silica-filled NR/CR blends.

Improving the Tensile Properties of Curcuma Mangga Val Extract (CMVE)/PVA Nanofiber Mats by Using a Type of Non-Commercial CMVE

2021 ◽  
Vol 880 ◽  
pp. 117-124
Author(s):  
Harini Sosiati ◽  
Angga Ardinista ◽  
M. Dirga Rianto ◽  
Ardhia Revarti ◽  
Sinin Hamdan ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Tensile Strain ◽  
Fiber Diameter ◽  
Tensile Modulus ◽  
Poly Vinyl Alcohol ◽  
Liquid Extract ◽  
The Mean ◽  
Nanofiber Mats ◽  
Very High

The commercially available Curcuma mangga Val extract (CMVE) and poly (vinyl alcohol) (PVA) blends were studied by electrospinning. The result showed inadequate tensile properties of commercial CMVE/PVA nanofiber mats with very high modulus (220.0 MPa) and low strain (50%). The commercial CMVE was then replaced by a type of non-commercial CMVE to compare them with those of the commercial bandage. A non-commercial CMVE was prepared by simply extracting of the fresh Curcuma mangga Val (CMV) produced in a liquid extract. This non-commercial CMVE was then blended with 10% (w/w) PVA at various concentrations of CMVE (0, 2, 5, 10 and 15%) (w/w). The morphology and tensile properties of the mats were investigated. The findings indicated that the tensile strength and modulus increased with CMVE concentrations, decreased of the mean fiber diameter. In this study, a nanofiber mat with a concentration of 2% CMVE was selected and compared to others. This mat had lower average fiber diameter (187.50 nm), tensile strength (8.93 ± 0.36 MPa) and modulus (31.37 ± 4.91MPa), and higher tensile strain (90%) than the commercial CMVE/PVA. Compared to the tensile properties of the Hansaplast bandage, the current tensile strength was higher, the tensile modulus was equivalent and lower tensile strain.

scholarly journals PENGARUH PENAMBAHAN LAURIL ALKOHOL TERHADAP SIFAT-SIFAT UJI TARIK KOMPOSIT KARET ALAM TERISI SILIKA

2018 ◽  
Vol 7 (1) ◽  
pp. 48-53
Author(s):  
Rieska Wulandari Sianturi ◽  
Indra Surya
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Fatty Alcohol ◽  
Crosslink Density ◽  
Palm Kernel ◽  
Tensile Modulus ◽  
Lauryl Alcohol ◽  
Kernel Oil ◽  
Silica Filler

By using a semi-efficient vulcanisation system; the effects of lauryl alcohol (LA) as a new rubber additive on tensile properties of silica-filled natural rubber (NR) composites were investigated. The NR composites were filled by silica filler with a fixed loading, 30.0 phr (part per hundred rubber). The LA is a fatty alcohol based on palm kernel oil and incorporated into the silica-filled NR composites. The LA loadings were 1.0 phr, 2.0 phr, 3.0 phr and 4.0 phr. It was found that LA functioned as an internal plasticiser. As an internal plasticiser, LA decreased the tensile modulus and increased elongations at break of silica-filled NR composites. It was also found that LA increased the crosslink density and tensile strength up to 3.0 phr of LA loading. The 3.0 phr of LA was the optimum loading.

scholarly journals PENGARUH PENAMBAHAN ALKANOLAMIDA TERHADAP SIFAT-SIFAT UJI TARIK VULKANISAT KARET ALAM BERPENGISI KAOLIN

2013 ◽  
Vol 2 (4) ◽  
pp. 1-5
Author(s):  
Yudha Widyanata ◽  
Indah M.S. Sitorus ◽  
Indra Surya
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Density Measurement ◽  
Tensile Modulus ◽  
Rubber Compound ◽  
Elongation At Break ◽  
Break Up

By using a semi-efficient vulcanization system, Alkanolamide (ALK) was incorporated into kaolin-filled natural rubber compound at 1.0; 3.0; 5.0 and 7.0 parts per hundred rubber (phr). An investigation was carried out to examine the effect of ALK on tensile properties of the kaolin filled-natural rubber compound. It was found that ALK exhibited higher tensile modulus, tensile strength, and elongation at break up to 5.0 phr of ALK loading and then decreased with further increasing of ALK loading. Crosslink density measurement proved that 5.0 phr loading of ALK in the kaolin-filled natural rubber system exhibited greatest tensile properties due to its highest crosslink density formation.

Tensile Properties of Polypropylene/Cocoa Pod Husk Biocomposites: Effect of Maleated Polypropylene

2013 ◽  
Vol 747 ◽  
pp. 645-648 ◽  
Author(s):  
Koay Seong Chun ◽  
Salmah Husseinsyah ◽  
Hakimah Osman
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Tensile Modulus ◽  
Melt Blending ◽  
Elongation At Break ◽  
Maleated Polypropylene ◽  
Matrix Interaction ◽  
Cocoa Pod Husk ◽  
Blending Process ◽  
Scanning Electron

Polypropylene/Cocoa Pod Husk (PP/CPH) biocomposites with different maleated polypropylene (MAPP) content were prepared via melt blending process using Brabender Plastrograph mixer. The tensile strength and tensile modulus of PP/CPH biocomposites increased with increasing of MAPP content. The PP/CPH biocomposites with 5 phr of MAPP showed the optimum improvement on tensile properties. However, the increased of MAPP content reduced the elongation at break of PP/CPH biocomposites. At 5 phr of MAPP content, PP/CPH biocomposites showed lowest elongation at break. Scanning electron microscope confirms the PP/CPH biocomposites with MAPP have better filler-matrix interaction and adhesion due to the effect of MAPP.

scholarly journals Kenaf Fibre Reinforced Polypropylene Composites: Effect of Cyclic Immersion on Tensile Properties

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
W. H. Haniffah ◽  
S. M. Sapuan ◽  
K. Abdan ◽  
M. Khalid ◽  
M. Hasan ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
Room Temperature ◽  
Tap Water ◽  
Tensile Modulus ◽  
Polypropylene Composites ◽  
Preliminary Results ◽  
Kenaf Fibre ◽  
The Difference ◽  
Number Of Cycles

This research studied the degradation of tensile properties of kenaf fibre reinforced polypropylene composites due to cyclic immersion into two different solutions, as well as comparison of the developed composites’ tensile properties under continuous and cyclic immersion. Composites with 40% and 60% fibre loadings were immersed in tap water and bleach for 4 cycles. Each cycle consisted of 3 days of immersion and 4 days of conditioning in room temperature (28°C and 55% humidity). The tensile strength and modulus of composites were affected by fibre composition, type of liquid of immersion, and number of cycles. The number of immersion cycles and conditioning caused degradation to tensile strength and modulus of kenaf fibre reinforced polypropylene composites. Continuous and cyclic immersion in bleach caused tensile strength of the composites to differ significantly whereas, for tensile modulus, the difference was insignificant in any immersion and fibre loadings. However, continuous immersion in the bleach reduced the tensile strength of composites more compared to cyclic immersion. These preliminary results suggest further evaluation of the suitability of kenaf fibre reinforced polypropylene composites for potential bathroom application where the composites will be exposed to water/liquid in cyclic manner due to discontinuous usage of bathroom.

scholarly journals Effects of alkanolamide addition on cure characteristics, crosslink density and tensile properties of carbon-black-filled styrene-butadiene rubber compounds

2018 ◽  
Vol 197 ◽  
pp. 12006 ◽  
Author(s):  
Indra Surya ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Tensile Properties ◽  
Crosslink Density ◽  
Density Measurement ◽  
Tensile Modulus ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cure Characteristics ◽  
Styrene Butadiene

By using a semi-efficient sulphur vulcanisation system, the effects of alkanolamide (ALK) addition on cure characteristics, crosslink density and tensile properties of carbon black (CB)-filled styrene-butadiene rubber (SBR) compounds were investigated. The ALK was prepared from Refined Bleached Deodorized Palm Stearin and diethanolamine and added into the CB-filled SBR compounds. The ALK loadings were 1.0, 3.0, 5.0 and 7.0 phr. It was found that ALK decreased the scorch and cure times of the CB-filled SBR compounds. ALK also improved the tensile modulus and tensile strength; especially up to a 5.0 phr of loading. The crosslink density measurement proved that the 5.0 phr of ALK exhibited the highest degree of crosslink density which caused the highest in tensile modulus and tensile strength. Due to its plasticity effect, ALK increased the elongation at break of the CB-filled SBR vulcanisates.

The High-Temperature Tensile Test of Quartz Fiber Fabric- Reinforced Resin Composites

2021 ◽  
Vol 904 ◽  
pp. 188-195
Author(s):  
Hua Qiong Wang ◽  
Li Li Zhang ◽  
Da Cheng Jiao ◽  
Yan Ru Wang ◽  
Zeng Hua Gao
Keyword(s):  
Tensile Strength ◽  
High Temperature ◽  
Tensile Test ◽  
Tensile Properties ◽  
Tensile Modulus ◽  
National Standard ◽  
Resin Composites ◽  
Quartz Fiber ◽  
High Temperature Tensile ◽  
Fiber Fabric

The tensile properties of quartz fiber fabric-reinforced resin composites at high temperature were studied. The effects of specimen type and dimension, temperature loading procedure, holding time and loading rate on the tensile properties of the composites at high temperatures were analyzed through series of comparative experiments, the tensile test parameters were determined. Chinese national standard for high-temperature tensile property testing of the composites was compiled based on the data collected. According to the established standard, the tensile testing at 500°C was carried out. Compared with the tensile properties at room temperature, the tensile strength and tensile modulus of the composite at high temperature decreases significantly, with the tensile strength decreasing by about 42.32% and the tensile modulus decreasing by about 24.18%. This is mainly due to the high temperature which causes part of the resin matrix to pyrolyze and detach from around the fiber, thus losing the integrity of the material. In addition, this national standard for high-temperature tensile properties has some general applicability to different types of fiber-reinforced resin composites.

Effect of Short Banana Fiber on Hardness and Tensile Properties of Natural Rubber Composites

2021 ◽  
Vol 904 ◽  
pp. 232-236
Author(s):  
Thapanee Wongpreedee ◽  
Chana Prapruddivongs ◽  
Nanthaya Kengkhetkit
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Fiber Content ◽  
Rubber Composites ◽  
Banana Fiber ◽  
Roll Mill ◽  
Natural Rubber Composites ◽  
Reinforcing Filler

Banana fiber (BF) was utilized as a reinforcing filler for natural rubber (NR). BF/NR composites containing banana fiber contents of 5, 10, and 15 parts per hundred parts of rubber (phr) were mixed on a two-roll mill machine. The hardness, tensile properties of BF/NR composites were studied. It was found that the hardness and moduli of BF/NR composites are higher than that of NR. Despite tensile strength and strain at break of BF/NR composite lower than NR. Moreover, hardness and moduli of BF/NR composites increased, while tensile strength and strain at break decreased with the increase in banana fiber content. Thus, banana fiber exhibited improvement in the stiffness significantly of NR composites

Sign in / Sign up

Export Citation Format

Share Document