Optical Properties of Sputtered Silver Granular Films

2005 ◽  
Vol 480-481 ◽  
pp. 287-292 ◽  
Author(s):  
S.E. Paje ◽  
F. Teran ◽  
J.M. Riveiro ◽  
J. Llopis ◽  
M.A. García ◽  
...  

In this research we study optical absorption and morphology of silver films prepared with a sputtering method. Silver granular films are obtained on a glass substrate for films with thickness smaller than about 60 Å. Superficial silver clusters of around 100 nm in diameter are clearly seen in the atomic force micrographs. The absorption of these samples are characterized by plasmon excitation in the 450-650 nm spectral range, which differs from the known excitation of silver nanoparticles fabricated by different techniques. The optical absorption of silver granular films depend on sputtering conditions like substrate temperature or deposition rate and correlates with the surface morphology.

2014 ◽  
Vol 3 (1) ◽  
Author(s):  
Paul Johannes Jobst ◽  
Olaf Stenzel ◽  
Mark Schürmann ◽  
Norbert Modsching ◽  
Sergiy Yulin ◽  
...  

AbstractThe optical properties of opaque sputtered silver films are investigated and related to their surface morphology. As reference, an evaporated sample produced by thermal flash evaporation has been studied, too. Standard optical and electrical characterizations as well as scanning electron microscopy (SEM) and X-ray reflectometry have been carried out with unprotected silver films directly after deposition and reveal strong correlations between the corresponding characterization results. The aging behavior of the normal incidence reflectance has been studied over a time period of 36 weeks. Protected silver mirrors have been prepared by sputtering using silica and alumina as the protective coating. It is shown by model calculations that the main spectral features occurring in the reflectance spectra of as-deposited unprotected coatings, unprotected coatings after aging, and protected coatings can be reproduced assuming a rough silver surface covered by a corresponding ultrathin absorbing interface layer or overlayer.


1991 ◽  
Vol 220 ◽  
Author(s):  
J. R. Jimenez ◽  
L. J. Schowalter ◽  
R. W. Fathauer

ABSTRACTAn analysis of optical absorption and internal photoemission in epitaxial CoSi2 particles buried in silicon is carried out. The optical absorption is dominated by the well-known surface plasma resonance, and calculations of the surface plasma frequencies, using the previously measured dielectric constant of CoSi2, agree well with experiment. A model for the photoemission yield is presented which includes the effects of the surface plasmon excitation and decay. The model can reproduce the observed features of the yield in photoresponse experiments. A model for the replenishment of photoemitted carriers is also presented, in which the metal particles acquire a small steady-state charge under illumination.


2021 ◽  
Vol 2103 (1) ◽  
pp. 012109
Author(s):  
V A Kazakov ◽  
A G Razina ◽  
A V Smirnov ◽  
A I Vasilev

Abstract The kinetics of the formation of silver clusters Ag from nanoscale continuous films of Ag on the surface of silicate glass and composite structures from films of Ag with carbon in the form of a continuous film and individual nanoparticles upon annealing in air at temperatures up to 670K is investigated. In the course of the work, the dependences of the surface morphology of silver clusters and absorption spectra in the visible wavelength range were obtained by the methods of atomic force microscopy and optical spectrophotometry.


Author(s):  
KwangHyok Jong ◽  
Yavar T. Azar ◽  
Luca Grisanti ◽  
Amberley D. Stephens ◽  
Saul T.E. Jones ◽  
...  

<div>We combine absorption and fluorscence spectroscopy experiments and theoretical modeling to specifically examine the role of termini interactions on the optical properties.</div><div><div>Optical absorption and fluorescence is measured for a six-chain amino acid 2Y3J (AIIGLM) which forms a segment of the full amyloid beta 1-40. In order to explore the sensitivity of the optical properties to the termini interactions, the experiments were repeated by acetylating the N-terminus.</div><div>Although atomic force microscopy experiments indicate the formation of some form of fibrilar or crystal aggregates in both systems, the optical properties are strikingly different - acetylation significantly reduces optical activity between 280-350 nm.</div></div>


2018 ◽  
Author(s):  
KwangHyok Jong ◽  
Yavar T. Azar ◽  
Luca Grisanti ◽  
Amberley D. Stephens ◽  
Saul T.E. Jones ◽  
...  

<div>We combine absorption and fluorscence spectroscopy experiments and theoretical modeling to specifically examine the role of termini interactions on the optical properties.</div><div><div>Optical absorption and fluorescence is measured for a six-chain amino acid 2Y3J (AIIGLM) which forms a segment of the full amyloid beta 1-40. In order to explore the sensitivity of the optical properties to the termini interactions, the experiments were repeated by acetylating the N-terminus.</div><div>Although atomic force microscopy experiments indicate the formation of some form of fibrilar or crystal aggregates in both systems, the optical properties are strikingly different - acetylation significantly reduces optical activity between 280-350 nm.</div></div>


2016 ◽  
Vol 675-676 ◽  
pp. 73-76
Author(s):  
Thanut Jintakosol

Silver nanoparticles (Ag NPs) were synthesized by sparking process. The NPs were continuously deposited onto the substrate by varying the number of sparking cycles ranging from 100-200 and deposited on the glass substrate and annealing at 250-500 °C for 1 hr. The effect of Ag NPs on their structure and optical characteristics were investigated. The optical properties of the NPs have been studied from by Raman spectroscopy and UV-vis spectrophotometer. The morphology of Ag NP was characterized by Scanning Electron Microscope (SEM) and Atomic force microscope (AFM). The results have shown mainly spherical structure of Ag NPs in diameter ranging from 80-100 nm. This study demonstrated that the Ag NPs can be synthesized by sparking process and simply with low cost.


2006 ◽  
Vol 955 ◽  
Author(s):  
Gakuyo Fujimoto ◽  
Katsushi Fujii ◽  
Tsutomu Minegishi ◽  
Hiroki Goto ◽  
Takenari Goto ◽  
...  

ABSTRACTRemoving artificial oxide layer is important for fabrication process of semiconductor devices. We employed photoluminescence for optical, reflection high energy electron diffraction, atomic force microscope, and Nomarski microscope for surface analysis. We found that it is more difficult to remove the oxide layer made by O-plasma such as in O-plasma asher than that of native one. Our result reached that HF etching is effective for removal of the artificial oxide layer without changing surface morphology. In addition, (NH4)2Sx treatment after HF etching reduces donor bound exciton drastically which is dominant luminescence near the band edge at low temperature.


2015 ◽  
Vol 32 (7) ◽  
pp. 077802 ◽  
Author(s):  
Ming Zhou ◽  
Yao-Peng Li ◽  
Sheng Zhou ◽  
Ding-Quan Liu

2017 ◽  
Vol 18 (3) ◽  
pp. 302-308 ◽  
Author(s):  
I.D. Stolyarchuk ◽  
G.I. Kleto ◽  
A. Dziedzic

We have reported the effect of Co and Ni doping on structural and optical properties of ZnO thin films prepared by RF reactive sputtering technique. The composite targets were formed by mixing and pressing of ZnO, Mn3O4, CoO and NiO powders. The thin films were deposited on sapphire, quartz and glass substrates. The structure study confirms the formation of the hexagonal wurtzite ZnO without any secondary phase in transition metal (Co, Ni) - doped samples. Cross-sectional TEM images of all studied samples show a denseand uniformly textured structure composed of column-like structure along the growth direction. The surface morphology of the thin films was studied using atomic force microscopy (AFM). Different surface morphology (AFM) images were obtained depending on the film composition and growth conditions. Optical absorption spectra suggest of substitution Zn2+ ions in ZnO lattice by transition metal atoms. The shift of the absorption edge due to decrease the energy band gap with increasing cobalt content and complex dependence of the energy band gap on content of nickel was observed in optical absorption spectra of the studied films. The room temperature photoluminescence peaks are attributed to near band gap emission and vacancy or defect states.


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