Effect of Yttrium on Morphologies of Precipitation Phases along Grain Boundaries of As-Cast ZK60 Magnesium Alloy

2005 ◽  
Vol 488-489 ◽  
pp. 245-248 ◽  
Author(s):  
Yan Long Ma ◽  
Ru Lin Zuo ◽  
Ai Tao Tang ◽  
Wen Ming Wang ◽  
Jing Zhang ◽  
...  
Keyword(s):  
Magnesium Alloy ◽  
Grain Boundary ◽  
Grain Boundaries ◽  
Ternary Compound ◽  
Binary Compound ◽  
Fish Bone ◽  
Experimental Results ◽  
The Other ◽  
Zk60 Magnesium Alloy ◽  
Precipitation Phase

Morphologies of precipitation phases along grain boundaries of the as-cast Mg-6.0Zn-0.45Zr, Mg-6.0Zn-1.2Y and Mg-6.0Zn-0.6Zr-1.0Y alloys were investigated. The experimental results indicated that the main precipitation phase along grain boundary of the as-cast Mg-6.0Zn-0.45Zr was a Mg-Zn binary compound. There were two kinds of precipitation phases along grain boundaries for Mg-6.0Zn-1.2Y and Mg-6.0Zn-0.6Zr-1.0Y alloys. One grew at triangular grain boundary, which was fish-bone -like in shape and a Mg-Zn binary compound. The other distributed mainly around the grain, which was net-like in shape and a Mg-Zn-Y ternary compound. In addition, there were lots of granular phases, extending to the interior of the grain, at the rim of grain boundary phases. Y was found to affect obviously morphology of precipitation phases along grain boundary of the as-cast Mg-Zn-Zr (ZK60) alloys.

Investigation on the Alloy Phases in As-Aged ZK60 Magnesium Alloy

2005 ◽  
Vol 488-489 ◽  
pp. 181-184 ◽  
Author(s):  
Fu Sheng Pan ◽  
Wen Ming Wang ◽  
Yan Long Ma ◽  
Ru Lin Zuo ◽  
Ai Tao Tang ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Magnesium Alloy ◽  
Experimental Results ◽  
Solution Treated ◽  
Secondary Compound ◽  
Zk60 Alloy ◽  
Zk60 Magnesium Alloy ◽  
Precipitation Phase

Alloy phases in the as-aged (T6) ZK60 magnesium alloy were investigated. More attentions were paid to types and morphologies of main alloy phases in the as-aged ZK60 magnesium alloy. The experimental results indicated that there was an abundant flower-shaped segregation in the solution-treated ZK60 magnesium alloy. A small quantity of undissolved compounds, MgZn2, was also found. They distributed irregularly in the form of similar parallelogram, with a dimension of 200nm~500nm and not sensitive to heat-treatment. Mg2Zn3 was found to be a main secondary compound in the as-aged ZK60 alloy, which precipitated during aging. Another precipitation phase, MgZn, in the as-aged ZK60 magnesium alloy was also found in the form of long and thin rods with a dimension of 500nm.

Measurement of the Displacement Across a Coincidence Grain Boundary

1977 ◽  
Vol 35 ◽  
pp. 124-125
Author(s):  
J. W. Matthews ◽  
W. M. Stobbs
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Stacking Fault ◽  
The Other ◽  
Measuring Technique ◽  
High Angle ◽  
Twin Boundaries ◽  
Rigid Displacement ◽  
Cubic Crystals ◽  
Lattice Displacement

Many high-angle grain boundaries in cubic crystals are thought to be either coincidence boundaries (1) or coincidence boundaries to which grain boundary dislocations have been added (1,2). Calculations of the arrangement of atoms inside coincidence boundaries suggest that the coincidence lattice will usually not be continuous across a coincidence boundary (3). There will usually be a rigid displacement of the lattice on one side of the boundary relative to that on the other. This displacement gives rise to a stacking fault in the coincidence lattice.Recently, Pond (4) and Smith (5) have measured the lattice displacement at coincidence boundaries in aluminum. We have developed (6) an alternative to the measuring technique used by them, and have used it to find two of the three components of the displacement at {112} lateral twin boundaries in gold. This paper describes our method and presents a brief account of the results we have obtained.

Effect of Manganese Addition on Strength and Fracture Toughness in Mg-6Al-1Zn Alloy

2006 ◽  
Vol 306-308 ◽  
pp. 857-862 ◽  
Author(s):  
Taisuke Sasaki ◽  
Tokuteru Uesugi ◽  
Yorinobu Takigawa ◽  
Kenji Higashi
Keyword(s):  
Fracture Toughness ◽  
Magnesium Alloy ◽  
Yield Strength ◽  
Ductile Fracture ◽  
Manganese Content ◽  
Experimental Results ◽  
The Other ◽  
Excessive Amount ◽  
Void Coalescence ◽  
Other Hand

The effect of manganese on strength and fracture toughness was investigated using five kinds of Mg-6Al-1Zn alloys. From the experimental results, the yield strength increased with increasing in manganese content until manganese content reached 0.14 wt. %. On the other hand, further increase in yield strength was not observed in case larger than 0.14 % of manganese was added. In addition, fracture toughness decreases with increasing manganese content. Fracture of magnesium alloy was ductile fracture by void coalescence. Adding excessive amount of manganese caused the increase in the presence of inclusions. This kind of particle easily became the nucleus of microvoid. As a conclusion, manganese should be added so that coarse manganese-bearing particle is not formed. Thus, 0.14 wt. % of manganese should be added to Mg-6Al-1Zn alloy in order to develop the alloy with well-balanced relationship between strength and fracture toughness.

Dynamical Simulation of the Motion of Curved Grain Boundaries Composed of Pyramidal-Shaped Ledges

1990 ◽  
Vol 193 ◽  
Author(s):  
Re-Jhen Jhan ◽  
P. D. Bristowe
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Boundary Migration ◽  
Model System ◽  
The Other ◽  
Grain Boundary Migration ◽  
Dynamical Simulation ◽  
Atomic Mechanism ◽  
Or Groups

ABSTRACTA dynamical simulation of curved grain boundaries composed of pyramidal-shaped ledges has shown that the boundaries can move by local conservative shuffles of atoms or groups of atoms such that one adjoining crystal grows at the expense of the other. In the model system studied, the shuffles often take the form of correlated rotational displacements about the axis normal to the boundary. The simulations provide support for the atomic mechanism proposed by Babcock and Balluffi to explain their observation of grain boundary migration without the participation of SGBDs.

The Morphology of Grain Boundary Interactions with Twins in YBa2Cu3O7−δ

1993 ◽  
Vol 319 ◽  
Author(s):  
Jenn-Yue Wang ◽  
A. H. King
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Twin Boundary ◽  
Interfacial Energy ◽  
Coincidence Site Lattice ◽  
The Other ◽  
Twin Boundaries ◽  
Site Lattice ◽  
Dislocation Arrays

AbstractVarious morphologies are observed where twins meet grain boundaries in YBa2Cu3O7−δ. Twins may be “correlated” at the boundary (i.e. twin boundaries from one grain may meet a twin boundary from the other grain in a quadruple junction) and the twins may be narrowed or “constricted” at the boundary. These effects are determined by the interfacial energy. We estimate the energy of the various interfaces by determining the dislocation arrays they contain, using the constrained coincidence site lattice (CCSL) model and Bollmann's O2-lattice formalism. Our approach indicates that there are significant changes in the energy of the interfaces and is thus able to explain the variety of observed morphologies.

Influence of Cooling Rates on the Dentrite Morphology and Hardness of the Surface-Chilled Mg-10Gd-3Y Magnesium Alloy

2007 ◽  
Vol 546-549 ◽  
pp. 175-178 ◽  
Author(s):  
Yang Zhou ◽  
Li Ming Peng ◽  
Qu Dong Wang ◽  
Jin Bao Lin ◽  
Wen Jiang Ding
Keyword(s):  
Standard Deviation ◽  
Magnesium Alloy ◽  
Grain Boundary ◽  
Cast Alloy ◽  
The Other ◽  
Hardness Distribution ◽  
Cooling Rates

Mg-10wt%Gd-3wt%Y alloy was cast in a step-like mould, which provided five different cooling rates. The dentrite morphology and hardness of the as-cast alloy from the surface to the center was investigated and the influence of the cooling rates on these was analyzed. It was indicated that there were two different trends for the hardness distribution: in the section of the step castings with the two slowest cooling rates, the hardness decreased with the increase of depth; while in the other three step castings the hardness increased with the increase of depth. Also it was founded that the hardness could be influenced by the grain boundary, dentrite morphology and dentrite arm spacing (DAS) in the alloy. At last, according to the standard deviation curves of the hardness, the chilled depths were about 5mm in 1st step and 10mm in 2nd step. And the other steps were fully chilled.

Degradation of high-Tc superconductors by annealing in dry and moist atmospheres

1990 ◽  
Vol 5 (9) ◽  
pp. 1855-1859 ◽  
Author(s):  
W-K. Lee ◽  
A. S. Nowick
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Meissner Effect ◽  
Treatment Temperature ◽  
The Other ◽  
Boundary Phase ◽  
Maximum Effect ◽  
High Tc Superconductors ◽  
High Tc ◽  
Anneal Temperature

A study is made of the effects of annealing both La2−xSrxCuO4 (for x = 0, 0.1, and 0.15) and YBa2Cu3O7 in wet and dry O2 atmospheres at various temperatures between 200 and 930 °C. In the case of La2−xSrxSrCuO4, substantial degradation of resistive properties occurs during annealing in moist O2, the degradation being highest at 200 °C and decreasing as the treatment temperature increases. Since the Meissner effect remains unaffected, it is concluded that degradation is due to the formation of a hydroxide species at grain boundaries, which decomposes as the anneal temperature is increased to 930 °C. In the case of YBa2Cu3O7, on the other hand, moisture does not produce degradation for anneals at 200 °C and above, but severe degradation of resistive behavior does occur for dry O2 anneals, with a maximum effect at 500 °C. It is found that this effect results from a contaminant gas, possibly CO2, absorbed by the furnace when it is open to air. Again, the degradation is due to formation of a grain-boundary phase which decomposes by annealing at 930 °C.

On {h,1,1}, the Recrystallisation Texture of Heavily Cold Rolled BCC Steel

2004 ◽  
Vol 467-470 ◽  
pp. 269-274 ◽  
Author(s):  
Hotaka Homma ◽  
Shuichi Nakamura ◽  
Naoki Yoshinaga
Keyword(s):  
Grain Boundary ◽  
Cold Rolling ◽  
Single Crystal ◽  
Grain Boundaries ◽  
Rolling Direction ◽  
Experimental Results ◽  
Rolled Steel ◽  
Fibre Structure ◽  
Pole Figures ◽  
Cold Rolled

Heavily cold rolled BCC steel has been indicated to generate {411}<148> recrystallisation texture and its family orientations which might be represented as {h,1,1}<1/h,1,2>. As a-fibre structure, or RD//<011> texture is significantly developed during the cold rolling, it is naturally speculated to be the recrystallisation site of {h,1,1}<1/h,1,2> fibre. The present paper prompts to demonstrate the recrystallisation procedure by utilising EBSP-OIM analysis. The first demonstration was carried out with OIM analysis on partially recrystallised cold rolled steel. At the stage of 50% recrystallisation, only ND//<111> texture has appeared for the recrystallised area. {100}<011> - {211}<011> a-fibre remains as deformed structure, and several {h,1,1}<1/h,1,2> grains could be found at the grain boundaries. Therefore, a bi-crystal of {100}<011> was employed to simulate the irregular deformation at the grain boundary. After cold rolling, a warp toward the grain boundary was observed. Although the interior of the {100}<011> single crystal was hardly recrystallised, sharp {411}<148> texture was created along the grain boundary. In order to confirm the phenomenon, another experiment was carried out that a cold rolled {100}<011> single crystal was bent along the rolling direction and annealed. Very sharp {411}<148> recrystallisation texture was formed again at the bent perimeter. These experimental results lead us to conclude that the irregular strain was sufficiently piled at the grain boundary after the heavy deformation and generates {h,1,1}<1/h,1,2> texture. On {100} pole figures, the recrystallisation textures were equivalently scattered around three <100> poles, therefore the rotation relationship around <111> axes with the original orientation was suggested.

Grain Boundaries in Nanophase Materials and Conventional Polycrystals – Are They Distinct?

1994 ◽  
Vol 351 ◽  
Author(s):  
S. C. Mehta ◽  
D. A. Smith ◽  
U. Erb
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
The Other ◽  
Boundary Structure ◽  
Triple Junctions ◽  
Grain Sizes ◽  
Grain Boundary Structure ◽  
Nanophase Materials ◽  
20 Nm ◽  
Boundary Diffusivity

ABSTRACTNanograined materials, with grain sizes in the range of 1–20 nm, exhibit significant enhancement of grain boundary dependent properties such as yield strength, intergranular fracture toughness, grain boundary diffusivity, specific heat and thermal expansion coefficient. Measurements by indirect techniques suggest that the grain boundaries in nanophase materials are structurally different from the boundaries in their conventional polycrystal counterparts. Exploratory HRTEM observations, on the other hand, indicate that the grain boundary structure in nanophase materials is the same as that found in grain boundaries in conventional polycrystals. This paper reports an HRTEM investigation of the microstructure in electrodeposited nanocrystalline (nc) Ni1wt.%P alloy. These observations reveal the presence of about 8-10 vol. % porosity in the microstructure. There is also evidence for the presence of an amorphous phase at some grain boundaries and triple junctions. A comparison of grain boundary structures with boundaries in conventional materials suggests that grain boundaries in the nc Ni-P alloy are, for the most part, normal.

scholarly journals Improving mechanical properties of ZK60 magnesium alloy by cryogenic treatment before hot extrusion

2020 ◽  
Vol 39 (1) ◽  
pp. 200-208
Author(s):  
Tao Lin ◽  
Ji-Xue Zhou ◽  
Cai-Nian Jing ◽  
Yun-Teng Liu ◽  
Lin-Lin Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Magnesium Alloy ◽  
Grain Boundaries ◽  
Cryogenic Treatment ◽  
Hot Extrusion ◽  
Microstructure And Mechanical Properties ◽  
Zk60 Alloy ◽  
Nonferrous Alloys ◽  
Zk60 Magnesium Alloy

AbstractFew studies of cryogenic treatment were focused on nonferrous alloys, such as magnesium alloy. In this work, the effect of cryogenic treatment (77 K) before extrusion on microstructure and mechanical properties of ZK60 alloy was investigated. The results showed that many fine G.P. zones were formed during the cryogenic treatment and then grew to short fine {\beta }_{1}^{^{\prime} } precipitates when heating before extrusion. These precipitates pinned dynamic recrystallized grain boundaries in the subsequent extrusion, resulting in fine gains and dispersed spherical precipitates. By the cryogenic treatment before extrusion, the extruded ZK60 alloy showed good tensile strength and elongation balance. Especially, elongation was improved by 29%.

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