Study on the Rheological Properties of LLDPE/CaCO3 Plasticized with the Fatty Acid Extracted from Hogwash Oil

2012 ◽  
Vol 724 ◽  
pp. 468-471
Author(s):  
Chao Le Yun ◽  
Xue Gang Luo ◽  
Xiao Yan Lin ◽  
Hong Ping Zhang ◽  
Ji Wei Li ◽  
...  

The reaction in linear low density polyethylene/Calcium carbonate (LLDPE/CaCO3) melting blend system with the presence of fatty acid extracted from Hogwash oil (HWOFA) was investigated by means of a Torque Rheometer during compounding. The characteristics of the products were evaluated by DSC and Universal Testing machine. The results showed that the maximum torque and equilibrium torque of the LLDPE/CaCO3 blends with addition of 15wt% HWOFA decreased respectively by 23.83% and 27.55% which were lower than that without HWOFA. The tensile strength decreased by 23.94%and the elongation at break increased by 16.88%. The compatibility became poor with addition of more than 15wt% HWOFA. The above results indicated that the fatty acid extracted from Hogwash oil can be used as a lower-cost plasticizer, which provides a new method of utilization of Hogwash oil.

2014 ◽  
Vol 803 ◽  
pp. 348-352
Author(s):  
A. Ainatun Nadhirah ◽  
S.T. Sam ◽  
N.Z. Noriman ◽  
C.H. Voon ◽  
S.S. Samera

Polyethylene (PE) has found well-known use as a packaging material. The effect of rambutan peels flour (RPF) content on the tensile properties of linear low density polyethylene filled with rambutan peel flour was studied. RPF was melt blended with linear low–density polyethylene (LLDPE). LLDPE/RPF blends were prepared by using internal mixer (brabender) at 160 °C with the flour content ranged from 0 to 15 wt%. The tensile properties were tested by using a universal testing machine (UTM) according to ASTM D638. The tensile strength of LLDPE/RPF decreased gradually with the addition of rambutan peels flour content from 0% to 15%. The Young’s modulus of LLDPE/RPF increased with increasing the RPF size and content.


2013 ◽  
Vol 795 ◽  
pp. 429-432
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
H. Ismail

Linear low-density polyethylene (LLDPE)/soya spent powder blends with different blends ratio were prepared by using internal mixer. Soya spent powder was varied from 5 to 40 wt. The thermal degradability was assessed by subjecting the dumbbell sample to oven aging. Thermal aging was carried out for 5 weeks. The degradability was measured by the periodic change in tensile properties of the blend samples. The tensile strength and elongation at break of the blends reduced as increasing the aging time. The effect of degradation was obvious in higher soya spent powder blends.


2016 ◽  
Vol 1133 ◽  
pp. 226-230
Author(s):  
M.A. Nuradibah ◽  
Sung Ting Sam ◽  
N.Z. Noriman ◽  
Santiagoo Ragunathan ◽  
H. Ismail

The effect of natural weathering on tensile properties of low density polyethylene/ thermoplastic soya spent powder (TSSP) was studied. TSSP was produced by mixing the soya spent powder (SSP) with glycerol. Both blends were prepared by using internal mixer (brabender) at 150 °C with the SSP/TSSP content ranged from 0 to 25 wt%. Then, all the dumb-bell samples were exposed to Perlis environment located at Kubang Gajah, Perlis for 6 months period. The tensile properties were tested by using a universal testing machine (UTM) according to ASTM D638. LDPE/SSP blends presented lower strength and elongation at break (Eb) than LDPE/ TSSP blends meanwhile there were no Young’s Modulus values for 20 wt% onwards of both blends due to the brittle samples after 6 months of weathering.


2016 ◽  
Vol 673 ◽  
pp. 171-179 ◽  
Author(s):  
A. Ainatun Nadhirah ◽  
S.T. Sam ◽  
N.Z. Noriman ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Mohd Firdaus Omar ◽  
...  

The effect of rambutan peels flour (RPF) content on the tensile properties of linear low density polyethylene filled with rambutan peel flour was studied. RPF was melt blended with linear low–density polyethylene (LLDPE). LLDPE/RPF blends were prepared by using twin screw extruder at 150°C with the flour content ranged from 0 to 25 wt%. The tensile properties were tested by using a universal testing machine (UTM) according to ASTM D638. The highest tensile strength was pure LLDPE meanwhile the tensile strength LLDPE/RPF decreased gradually with the addition of rambutan peels flour. Young’s modulus of rambutan peels flour filled LLDPE increased with increasing fiber loading. The crystallinity of the blends was significantly reduced with increasing RPF content. Instead, the water absorption increased with the addition of RPF content.


2016 ◽  
Vol 29 (12) ◽  
pp. 1641-1655 ◽  
Author(s):  
Koay Seong Chun ◽  
Salmah Husseinsyah ◽  
Nurul Fatin Syazwani

This research focuses on utilization of kapok husk (KH) as a natural filler in linear low-density polyethylene (LLDPE) ecocomposites. The effect of KH content and coupling agent on tensile properties, thermal properties, water absorption behavior, and morphology of ecocomposites were studied. The addition of KH had increased tensile modulus and water absorption of ecocomposites, whereas tensile strength and elongation at break decreased. However, the polyethylene-grafted acrylic acid (PEAA) was used as a polymeric-coupling agent to enhance the properties of LLDPE/KH ecocomposites. The incorporation of PEAA improved the tensile strength, tensile modulus, crystallinity, and thermal stability as well as reduced the water absorption of LLDPE/KH ecocomposites. The improvement of those properties was caused by the enhanced interfacial bonding, which was evidenced by scanning electron microscopy. The Fourier transmission infrared spectra also confirmed the presence of ester linkage between PEAA and KH.


2015 ◽  
Vol 754-755 ◽  
pp. 210-214 ◽  
Author(s):  
Ragunathan Santiagoo ◽  
Sam Sung Ting ◽  
Hanafi Ismail ◽  
Mastura Jaafar

The compatibilizer effect of ENR-50 on the tensile properties and morphology of linear low density polyethylene (LLDPE)/ recycled acrylonitrile butadiene rubber (NBRr)/ rice husk powder (RHP) composites has been studied. The RHP size utilize in this work is 150 – 300 μm. LLDPE/NBRr/RHP composites were prepared by melt mixing technique at 180 °C for 9 minutes at 50 rpm rotor speed using heated two roll mill. The series of composites investigated were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. The composites were analysed by using tensile test and morphology examination. The result showed that the tensile strength of composite was decreased with the increasing of recycled acrylonitrile butadiene rubber (NBRr) content while elongation at break (Eb) were increased. However, the tensile strength and elongation at break result for composites with ENR-50 as compatibilizer showed higher values. The morphological finding supports the tensile properties which indicate better interaction between the RHP filler and LLDPE/NBRr matrix in the presence of ENR-50 compatibilizer.


2021 ◽  
Vol 1021 ◽  
pp. 290-298
Author(s):  
Abduati Elnaid ◽  
N.Z. Noriman

The effect of different content of steric acid (3, 6 and 9 wt.%) on the mechanical properies (tensile, flexural and impact properties) and morphology of linear low-density polyethylene / date seeds (LLDPE/DS) composites were evaulated in this research. The composites were produced by using extrusion followed by injuction molding process. Results presented that the addition of steric acid at 3 wt.% to the composite has shown highest tensile strength and elongation at break as compared to other treated samples. This is due to the improvement on the fiber surface in presence of SA. However, the tensile strength and elongation at break decreased thereafter treatment with 6% and 9% of SA. Furthermore, the flexural and impact properties have shown the same trend of the tensile properties, this was consistent with the results shown on SEM micrographs.


2011 ◽  
Vol 109 ◽  
pp. 46-50
Author(s):  
Yu Zhi Jiang ◽  
Li Li Zhang ◽  
Yan Bo Li

The magnesium hydroxide (MH) whiskers / ABS composites were prepared by melt-extrusion with modified whiskers as filler. The mechanical performances, including the tensile strength, elongation at break and elastic modulus, were tested by electronic universal testing machine. The results showed that with the increasing of the whisker dosage, the tensile strength and elongation at break reduced gradually, and the elastic modulus get maximum when it is 25%.The morphology on fracture of composites was analyzed by SEM. The conclusions are the whiskers of surface modifications can be evenly distributed in the composites and bond partly with ABS. that it is necessary to enhance the combine strength of interface on excellence performances of composites.


2017 ◽  
Vol 34 (1) ◽  
pp. 27-42 ◽  
Author(s):  
Suthakarn Auksornkul ◽  
Siriwat Soontaranon ◽  
Chonthicha Kaewhan ◽  
Pattarapan Prasassarakich

A series of linear low-density polyethylene films were produced using a three-layer co-extrusion machine. How the blow-up ratio and resin characteristics affected the final film morphology and engineering properties were studied. The crystalline morphology and orientation during the blown film process of the low-density polyethylene film were investigated using small-angle X-ray scattering, transmission electron microscopy and scanning electron microscopy. Increasing the blow-up ratio increased the transverse direction molecular orientation and decreased the machine direction orientation. The resulting low-density polyethylene morphology was a regular lamellar stacking parallel to the machine direction. The film morphology strongly influenced the mechanical properties. Increasing the blow-up ratio from 1.7 to 2.8 decreased the machine direction tensile strength by 14% and increased the transverse direction tensile strength up to 27% for both the low-density polyethylene/1-butene and low-density polyethylene/1-octene co-monomers, while the machine direction tear strength increased up to 36% and the transverse direction decreased by 16%. Moreover, the first and second heating characteristics from differential scanning calorimeter showed the inherent crystallinity change with increasing blow-up ratio for both the low-density polyethylene/1-octene and the low-density polyethylene/1-butene copolymer. The crystalline orientation changes induced with increasing blow-up ratio affected the film water vapor and oxygen permeability.


2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
Jong Won Kim ◽  
Joon Seok Lee

Polyethylene is one of the most commonly used polymer materials. Even though linear low density polyethylene (LLDPE) has better mechanical properties than other kinds of polyethylene, it is not used as a textile material because of its plastic behavior that is easy to break at the die during melt spinning. In this study, LLDPE fibers were successfully produced with a new approach using a dry-jet wet spinning and a heat drawing process. The fibers were filled with carbon nanotubes (CNTs) to improve the strength and reduce plastic deformation. The crystallinity, degree of orientation, mechanical properties (strength to yield, strength to break, elongation at break, and initial modulus), electrical conductivity, and thermal properties of LLDPE fibers were studied. The results show that the addition of CNTs improved the tensile strength and the degree of crystallinity. The heat drawing process resulted in a significant increase in the tensile strength and the orientation of the CNTs and polymer chains. In addition, this study demonstrates that the heat drawing process effectively decreases the plastic deformation of LLDPE.


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