Effect of Heat Treatment on Properties of Portland Cement Pastes: Determination through Ultra-Microhardness Test

2015 ◽  
Vol 820 ◽  
pp. 492-496
Author(s):  
D.C.S. Garcia ◽  
Roberto Braga Figueiredo ◽  
Maria Teresa Paulino Aguilar
Keyword(s):  
Heat Treatment ◽  
Portland Cement ◽  
Optical Microscopy ◽  
Silica Fume ◽  
Ordinary Portland Cement ◽  
Cement Pastes ◽  
Microhardness Test ◽  
Material Hardness ◽  
Binder Ratio ◽  
Water Binder Ratio

The aim of this paper was to investigate the influence of heat treatment on hardness evolution of cement pastes containing silica fume. The specimens were prepared with Ordinary Portland Cement, water/binder ratio of 0,40 and 25% wt. silica fume. The specimens were cast at room temperatures and after 24 hours, they were placed in a furnace for 24 hours, with heat regimes of 100°C, 200°C and 300°C and then submitted to the ultra-microhardness test. The microstructure was analyzed using optical microscopy. The results showed that the silica fume prevents the production of calcium hydroxide and the heat treatment increases the material hardness.

scholarly journals Effect of the water/binder ratio on the hydration process of Portland cement pastes with silica fume and metakaolin

2022 ◽  
Vol 15 (1) ◽  
Author(s):  
Mara Monaliza Linhares Pereira ◽  
Ana Luiza Rocha de Souza ◽  
Valdirene Maria Silva Capuzzo ◽  
Rodrigo de Melo Lameiras
Keyword(s):  
Portland Cement ◽  
Silica Fume ◽  
Cementitious Materials ◽  
Hydration Process ◽  
X Ray Diffraction ◽  
Cement Pastes ◽  
X Ray ◽  
Binder Ratio ◽  
Water Binder Ratio ◽  
Mineralogical Phases

abstract: The microstructure of cement pastes is important to understand the effect of some parameters in the hydration process. In this context, this study had as objective to evaluate the effect of different water/binder (w/b) ratios in the hydration process of cementitious pastes produced with and without incorporation of silica fume and metakaolin. The pastes were obtained with water/binder ratios of 0.3, 0.4 e 0.5, with replacement, by weight, of Portland cement for silica fume and metakaolin, in the contents of 10% and 20%, respectively. It was performed the X-ray diffraction test of the pastes in the ages of 1, 3, 7, and 28 days, to evaluate the hydration evolution of the cementitious materials. According to the results obtained, it was observed that the cementitious pastes presented similar mineralogical phases, except for the pastes containing metakaolin due to the formation of new aluminate phases. With the increase of the water/binder ratio, the pozzolanic reactions and hydration occurred in greater proportion, standing out the metakaolin with greater reactivity.

High Performance Concrete with Ternary Binders

2018 ◽  
Vol 761 ◽  
pp. 120-123 ◽  
Author(s):  
Vlastimil Bílek ◽  
David Pytlík ◽  
Marketa Bambuchova
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume ◽  
High Performance ◽  
Ordinary Portland Cement ◽  
High Performance Concrete ◽  
Fresh Concrete ◽  
Binder Ratio ◽  
Water To Binder Ratio ◽  
Condensed Silica Fume

Use a ternary binder for production of a high performance concrete with a compressive strengths between 120 and 170 MPa is presented. The water to binder ratio of the concrete is 0.225 and the binder is composed of Ordinary Portland Cement (OPC), condensed silica fume (CSF), ground limestone (L), fly ash (FA) and metakaoline (MK). The dosage of (M + CSF) is kept at a constant level for a better workability of fresh concrete. Different workability, flexural and compressive strengths were obtained for concretes with a constant cement and a metakaoline dosage, and for a constant dosage (FA + L) but a different ratio FA / L. An optimum composition was found and concretes for other tests were designed using this composition.

PENGARUH JENIS SEMEN DAN PENAMBAHAN SILICA FUME TERHADAP KEKUATAN DAN DURABILITAS BETON

2012 ◽  
Vol 2 (1) ◽  
pp. 25
Author(s):  
Ariyadi Basuki ◽  
Maulana Ikhwan Sadikin
Keyword(s):  
Portland Cement ◽  
Silica Fume ◽  
Ordinary Portland Cement ◽  
Composite Cement

Dalam penelitian ini dilakukan serangkaian pengujian untuk mengetahui sifat fisik dari material penyusun (agregat), yang kemudian dirancang komposisi rencana beton dengan mutu K250 (normal/kontrol) dan K250 dengan aditif Silica Fume 10% dari berat semen. Variasi campuran menggunakan tiga tipe semen yang berbeda yaitu Ordinary Portland Cement (OPC)/ Semen Tipe I, Portland Composite Cement (PCC) dan Semen Tipe II. Proses dilanjutkan dengan pembuatan sampel uji silinder berukuran 15 cm x 30 cm (karakteristik kuat tekan, ketahanan sulfat), sampel uji prisma berukuran 20 cm x 20 cm x 12 cm (karakteristik permeabilitas) dan sampel uji kubus berukuran 15 cm x 15 cm x 15 cm (untuk penetrasi klorida). Pengamatan dilakukan untuk melihat karakteristik beton K250 dengan penambahan silica fume 10%, dibandingkan dengan beton normal sebagai acuan, serta aplikasinya dalam lingkungan normal maupun asam (Sulfat, Klor). Hasil kuat tekan memperlihatkan, bahwa campuran dengan menggunakan semen PCC memiliki nilai kuat tekan rata-rata diatas semen OPC. Penambahan silica fume pada campuran semen PCC akan menaikkan nilai kuat tekan sebesar 4,2% dibandingkan beton normal dengan produk semen yang sama, meskipun nilai rasio air-semen nya membesar menjadi 0,71 karena penambahan air. Nilai kuat tekan terbesar diperoleh untuk campuran beton dengan semen Tipe II. Campuran dengan semen PCC (2) menunjukkan nilai penetrasi yang lebih kecil dibandingkan campuran lainnya, hal ini mengindikasikan produk beton yang terbentuk memiliki kepadatan yang lebih baik dari produk campuran lainnya dan tidak porous, sehingga dapat dikatakan memiliki tingkat durabilitas yang cukup baik. Untuk ketahanan terhadap serangan sulfat, beton dengan menggunakan campuran semen tipe II mengalami tingkat pelapukan/penggerusan penampang (scaling) yang lebih besar dibandingkan campuran beton lainnya, meskipun begitu hal ini tidak mempengaruhi nilai kuat tekannya. Untuk produk dengan semen PCC, serangan sulfat tidak mempengaruhi nilai kuat tekannya, bahkan cenderung naik bila dibandingkan pada usia 28 hari.Kata kunci: aspek durabilitas, tipe semen, pemanfaatan silica fume

Mechanical Performance of Steam-Cured Self-Compacting Concrete Incorporating Silica Fume and Limestone Powder

2021 ◽  
Vol 56 ◽  
pp. 111-122
Author(s):  
Youcef Ghernouti ◽  
Bahia Rabehi ◽  
Sabria Malika Mansour
Keyword(s):  
Heat Treatment ◽  
Silica Fume ◽  
Mechanical Performance ◽  
Limestone Powder ◽  
Maximum Temperature ◽  
Self Compacting Concrete ◽  
Curing Period ◽  
Heat Treated ◽  
Binder Ratio ◽  
Mechanical Strengths

In this paper, influence of heat treatment on evolution of mechanical strengths at early age, less than 24hours of self-compacting concretes containing limestone powder and silica fume as fine materials was investigated experimentally. Two compositions of self-compacting concrete have been studied; the first is elaborated with silica fume addition and the second with limestone powder, each mixture were prepared with a constant water/binder ratio of 0.39. Concrete samples were either cured in water at (23±1°C), or steam cured at 65°C maximum temperature over six hours (6h) curing period. Tests of mechanical strengths were performed on specimens cooled down slowly to room temperature after heating.The obtained results show that all self-compacting mixtures exhibited satisfying fresh properties and check EFNARC specifications of self-compacting concrete (slump flow diameter higher than 650mm, L-box ratio higher than 80% and sieve stability less than 17%).Mechanical strengths of concrete containing limestone addition are slightly lower than those of concrete based on silica fume at all ages. Moreover, heat treatment generates an improvement of compressive and flexural strength. Interesting compressive strengths are obtained. At 24 hours, after heat treatment, the strengths are already greater than 35 MPa. The values ​​are 37 MPa and 40 MPa for self-compacting concrete containing limestone powder and silica fume respectively compared to 40 MPa and 46 MPa obtained at 7 days for the corresponding non-heat treated concretes. Compressive strength gain of SCCs mixtures with limestone powder and with silica fume, undergoing heat treatment at the age of 24hours is 85% and 75% respectively compared to SCCs mixtures cured in water.

Interaction Between Naphthalene Sulfonate and Silica Fume in Portland Cement Pastes

1987 ◽  
Vol 114 ◽  
Author(s):  
Sidney Diamond ◽  
Leslie J. Struble
Keyword(s):  
Portland Cement ◽  
Silica Fume ◽  
Cement Paste ◽  
Uv Spectrophotometry ◽  
Residual Concentration ◽  
Cement Pastes ◽  
High Ph ◽  
Substantial Concentration ◽  
Low Dosage

ABSTRACTPortland cement pastes were mixed with predissolved naphthalene sulfonate superplasticizer at normal water:cement ratios. Solutions were separated from the fresh pastes at intervals and the residual concentration of the superplasticizer determined by UV spectrophotometry. At low dosage levels essentially all of the superplasticizer was found to be removed from solution within a few minutes; at high dosage levels a substantial concentration was maintained in solution at least to approximately the time of set. In pastes in which silica fume replaced 10% by weight of the cement, it was found that the incorporation of silica fume significantly increased the uptake of superplasticizer. In separate trials it was found that the silica fume by itself adsorbed little superplasticizer, even from high pH solution simulating that of cement paste.

scholarly journals Effect of Some Acrylate—Poly(Ethylene Glycol) Copolymers as Superplasticizers on the Mechanical and Surface Properties of Portland Cement Pastes

2005 ◽  
Vol 23 (3) ◽  
pp. 245-254 ◽  
Author(s):  
S.A. Abo-El-Enein ◽  
S. Hanafi ◽  
F.I. El-Hosiny ◽  
El-Said H.M. El-Mosallamy ◽  
M.S. Amin
Keyword(s):  
Ethylene Glycol ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Mechanical Characteristics ◽  
Hardened Cement ◽  
Poly Ethylene Glycol ◽  
Cement Pastes ◽  
Surface Areas ◽  
Poly Ethylene ◽  
Hardened Cement Pastes

Ordinary Portland cement (OPC) pastes with added superplasticizer were made using water/cement weight ratios of standard consistency. Three types of superplasticizer based on acrylate—poly(ethylene glycol) copolymers were used. The pastes were hydrated for various time lengths and the mechanical characteristics of the hardened cement pastes were studied and related to their pore structures. It was found that the addition of the superplasticizers to OPC improved the mechanical properties of the hardened pastes for all hydration lengths. The addition of such superplasticizers to OPC resulted in a decrease in the specific surface areas and total pore volumes of the hardened superplasticized cement pastes relative to the corresponding hardened neat cement pastes.

scholarly journals Physical Properties of Concrete Containing Graphene Oxide Nanosheets

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1707 ◽  
Author(s):  
Yu-You Wu ◽  
Longxin Que ◽  
Zhaoyang Cui ◽  
Paul Lambert
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Graphene Oxide ◽  
Flexural Strength ◽  
Portland Cement ◽  
Physical Properties ◽  
Ordinary Portland Cement ◽  
Construction Materials ◽  
Split Tensile Strength ◽  
Cement Pastes

Concrete made from ordinary Portland cement is one of the most widely used construction materials due to its excellent compressive strength. However, concrete lacks ductility resulting in low tensile strength and flexural strength, and poor resistance to crack formation. Studies have demonstrated that the addition of graphene oxide (GO) nanosheet can effectively enhance the compressive and flexural properties of ordinary Portland cement paste, confirming GO nanosheet as an excellent candidate for using as nano-reinforcement in cement-based composites. To date, the majority of studies have focused on cement pastes and mortars. Only limited investigations into concretes incorporating GO nanosheets have been reported. This paper presents an experimental investigation on the slump and physical properties of concrete reinforced with GO nanosheets at additions from 0.00% to 0.08% by weight of cement and a water–cement ratio of 0.5. The study demonstrates that the addition of GO nanosheets improves the compressive strength, flexural strength, and split tensile strength of concrete, whereas the slump of concrete decreases with increasing GO nanosheet content. The results also demonstrate that 0.03% by weight of cement is the optimum value of GO nanosheet dosage for improving the split tensile strength of concrete.

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