Durability of Red Mud Based Geopolymer Paste in Acid Solutions

2016 ◽  
Vol 866 ◽  
pp. 99-105 ◽  
Author(s):  
Smita Singh ◽  
M.U. Aswath ◽  
R.V. Ranganath

The present investigation is on the effect of red mud on the mechanical properties and durability of the geopolymer paste in sulphuric and acetic acid solution. Red mud and fly ash were used to form the geopolymer paste along with the alkalies. The variation of red mud in the paste composition was from 0% to 90%. Cylindrical shaped specimens of 1 inch diameter and 1 inch height were prepared. The specimens were immersed in 5% sulphuric acid and 5% acetic acid for 1, 7, 14, 28, 56 and 84 days and tested for weight loss, visual deformation, strength loss and colour of the solvent, based on the procedure specified by ASTM C 267 – 01. SEM/EDX Tests were performed on the geopolymer specimens. Test results show that initially, the strength of the geopolymer increased upon the addition of red mud. The strength was maximum when the percentage of red mud was 30%. The maximum strength obtained was 38 MPa for the paste containing 30% red mud using 10M alkali solution as against 31.69 MPa, when only fly ash was used. Geopolymer paste containing 30% and 50% red mud showed better resistance to acid attack. The strength loss was minimum for the samples containing 30% red mud in both inorganic and organic acid i.e. sulphuric and acetic acid.

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Sheng-quan Zhou ◽  
Da-wei Zhou ◽  
Yong-fei Zhang ◽  
Wei-jian Wang ◽  
Dongwei Li

To probe into the dynamic mechanical properties of expansive soil stabilized by fly ash and lime under impact load, the split-Hopkinson pressure bar (SHPB) test was carried out in this study. An analysis was made on the dynamic mechanical property and final fracture morphology of stabilized soil, and the failure mechanism was also explored from the perspective of energy dissipation. According to the test results, under the impact pressure of 0.2 MPa, plain soil and pure fly ash-stabilized soil exhibit strong plasticity. After the addition of lime, the stabilized soil shows obvious brittle failure. The dynamic compressive strength and absorbed energy of stabilized soil first increase and then decrease with the change of mix proportions. Both the dynamic compressive strength and the absorbed energy reach the peak value at the content of 20% fly ash and 5% lime (20% F + 5% L). In the process of the test, most of the incident energy is reflected back to the incident bar. The absorbed energy of stabilized soil increases linearly with the rise of dynamic compressive strength, while the absorbed energy is negatively correlated with the fractal dimension. The fractal dimension of pore morphology of the plain soil is lower than that of the fly ash-lime combined stabilized soil when it comes to the two different magnification ratios. The test results indicate that the modifier content of 20% F + 5% L can significantly improve the dynamic mechanical properties of the expansive soil.


2015 ◽  
Vol 77 (12) ◽  
Author(s):  
Nuria S. Mohammed ◽  
Ahmad Baharuddin Abdul Rahman ◽  
Nur Hafizah A. Khalid

This paper presents the mechanical properties and performance of polyester grout as infill material for grouted connection in precast concrete. The mix proportions of polyester grout was properly designed and manufactured. The polymer binder with polymer additive was added together with filing materials of sand and fly ash. The binder to filler ratio was 0.43. Properties such as flowing ability and compression strength were studied by varying the level of fly ash in the mixtures. Also, to assess the efficacy of polyester grouted connections, three grouted connections were tested in direct tension. The test results show that, polyester resin grout with binder to filler ratio 0.43% and 16% fly ash perform satisfactorily. The polyester grout is suitable for use in the steel pipe splice connections.


2010 ◽  
Vol 168-170 ◽  
pp. 1426-1431
Author(s):  
Zhi Qing Li ◽  
Zhen Dong Cui ◽  
Yan Ping Wang ◽  
Li Chao Wang ◽  
Duo Zhong

According to the typical loess in Shuozhou in Shanxi province, tests involved in compaction characteristics, shearing strength characteristics and disintegration are carried out by using loess and three kinds of improved loess, namely lime and fly-ash, lime and cement, cement and fly-ash. The best improved soil method is selected. The test results indicate that the compact hybrid structure is formed by fly ash and loess. The activity of fly ash is activated as a result of the lime mixing. A series of hydration reaction prompt the intensity of modified loess. And the physical and mechanical properties of improved loess are improved noticeably.


2015 ◽  
Vol 49 (3) ◽  
pp. 259-265 ◽  
Author(s):  
Falk Schwendicke ◽  
Kerrin Eggers ◽  
Hendrik Meyer-Lueckel ◽  
Christof Dörfer ◽  
Alexander Kovalev ◽  
...  

Artificially inducing dentinal lesions mimicking those remaining after selective excavation should allow to investigate the effects and limits of such selective excavation, for example regarding the mechanical properties of treated teeth or the remineralisation of sealed residual lesions. Such analyses might otherwise be limited by the variability of natural lesions or ethical and practical concerns. This study compared different demineralisation protocols for their suitability to induce lesions similar to natural residual caries. Twelve natural deep lesions were excavated until leathery dentin remained, and analysed for their mineral loss (ΔZ), lesion depth (LD), mineral loss ratio (R), the slope of the mineral gradient and their nano-hardness profile. Artificial lesions were induced using four different demineralisation protocols (acetic acid pH = 4.95; 0.1 M lactic acid gel pH = 5.0; 0.5 M ethylenediaminetetraacetic acid pH = 7.2; Streptococcus mutans biofilms) and their depths monitored over different demineralisation times. Lesions with depths most according to those of natural lesions were analysed using transversal microradiography. Lesions induced by acetic acid solution did not significantly differ with regards to LD, ΔZ, R and mineral profile. Seven dentin specimens were subsequently submitted to a moderately acidic (pH = 5.3) methylhydroxydiphosphonate-buffered acetate solution for 12 weeks. Natural and artificial residual lesions were similarly deep (mean ± SD: LD = 626 ± 212 and 563 ± 88 µm), demineralised (R = 19.5 ± 4.7 and 29.8 ± 4.1%), showed a flat and continuous mineral gradient (slope = 0.10 ± 0.05 and 0.13 ± 0.06 vol%/µm) and did not significantly differ regarding their nano-hardness profile. The described protocol induces lesions with mineral content and mechanical properties similar to natural residual lesions.


2018 ◽  
Vol 55 (3) ◽  
pp. 405-409 ◽  
Author(s):  
Marinela Barbuta ◽  
Alexandru Timu ◽  
Liliana Bejan ◽  
Roxana Dana Bucur

The experimental results obtained by studying the influence of different types of fibers on the mechanical properties of fly ash polymer concrete are presented in the paper. The general demand of using wastes found applicability in building material industry because some of them are beneficial in improving concrete properties. The waste additions type fly ash and fibers were incorporated in polymer concrete. The study focused on fibers type glass, polyester, metallic and cellulose. The mechanical properties such as compressive strength, flexural strength and split tensile strength were investigated having in view the type, dosage and length of fibers. The results show that fibers improved mechanical properties in comparison with that of polymer concrete without fibers, the test results being differently influenced by the factors which were considered.


2019 ◽  
Vol 8 (2) ◽  
pp. 5761-5765

With an objective of saving the environment by providing crumb rubber as an alternative to natural fine aggregate this paper presents a study carried out to find the mechanical properties of rubberized concrete. Rubberized concrete is made up of waste rubber from vehicle tyres and other rubber waste which otherwise is left out polluting the environment. In this paper, 7.5% of crumb rubber (obtained by shredding the vehicle tyres) as an alternative to fine aggregate and 7.5% of fly-ash as an alternative to cement is added with other ingredients of concrete to produce an eco-friendly concrete which can be used economically and effectively for construction along the coastal areas. Various properties like workability, compressive strength, split tensile strength, and flexural strength was carried out on concrete specimens exposed to the natural marine environment along the coast of Visakhapatnam, Andhra Pradesh. The total exposure of concrete specimen was about 150 days, and various specimens were tested at 7, 28, 90, 120 and 150 days, respectively. The test results showed that with a slight compromise in strength, the workability of concrete and resistance to the effect of seawater on the strength of concrete significantly improved with the addition of crumb rubber and fly-ash.


2010 ◽  
Vol 113-116 ◽  
pp. 1293-1296
Author(s):  
Yu Zhu ◽  
Ying Zi Yang ◽  
Hong Wei Deng ◽  
Yan Yao

In order to investigate the mechanical properties of cementitious composites (ECC) cured at 60°C, four-point bending test and compressive strength test are employed to analyze the effect of fly ash on the properties of ECC. The replacement ratio of cement with fly ash is 50%, 70% and 80%, respectively. The test results indicate that ECC with high volume fly ash still remain the characteristic of pseudo-strain hardening and the deflection of ECC increases remarkably by adding more fly ash. The observations of ECC indicate that the crack width is relatively smaller for higher volume fly ash ECC. Meanwhile, compressive strength of ECC specimens with 80% fly ash can reach to 70MPa. This is helpful to produce precast ECC with high volume of fly ash.


2016 ◽  
Author(s):  
Puput Risdanareni ◽  
Poppy Puspitasari ◽  
Dessy Kartika ◽  
Boedya Djatmika

2013 ◽  
Vol 807-809 ◽  
pp. 1140-1146 ◽  
Author(s):  
Yi Xuan Chen ◽  
Xiu Li Sun ◽  
Zhi Hua Li

The objective of this work is to investigate the stimulation effect of the addition of alkali on the fly ash and slag for stabilizing dredged silt. Based on the test results, a viable alternative for the final disposal of dredged silt as subgrade construction materials were proposed. For this purpose, several mixtures of dredged silt-fly ash-slag and alkali were prepared and stabilized/solidified. In this system, fly ash and slag were used as hardening agents (solidified materials) of dredged silt and alkali was used as activator of fly ash and slag. The shear strength of the mixture was tested by several direct shear tests. Furthermore, X-Ray Diffraction (XRD) analysis was used to determine the hydration products of the system. The specimens were tested in order to determine the shear strength changes versus hydration time and the alkali content. It is indicated that mechanical properties of solidified silt are improved significantly by addition of fly ash and slag stimulated by alkali.


ISRN Ceramics ◽  
2012 ◽  
Vol 2012 ◽  
pp. 1-6
Author(s):  
Shuhua Liu ◽  
Lihua Li ◽  
Zhigang Wang ◽  
Jiafeng Wang ◽  
Meijuan Rao

Different cement pastes containing limestone powder were prepared and soaked, respectively, in flowing acetic acid solution with pH value of 4 and sulfuric acid solution with pH value of 2. The strength and microstructure of the pastes after different flowing acid attack periods were investigated by using strength test, X-ray diffraction (XRD), and scanning electron microscopy (SEM) techniques in this study, which reveals the effect of limestone powder on flowing acid resistance mechanism of cement paste. Testing results show that the strength of pastes suffered flowing acid attack decreases with the increase of water-binder ratio and the content of limestone powder. In flowing acetic acid solution, calcium hydroxide and calcium carbonate react with acetic acid, which therefore made deterioration of pastes proceed from the exterior to the interior. In flowing sulfuric acid solution, although calcium hydroxide and calcium carbonate could react with sulfuric acid and form gypsum, the flowing liquid would dissolve it out and thus the crystallization of gypsum was difficult which would somewhat inhibit the swell of pastes.


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