Chemical Treatment and Characterization of Fiber of Babassu Coconut Epicarp (Orbignya phalerata) for Application in Polymeric Composite

2016 ◽  
Vol 869 ◽  
pp. 233-236
Author(s):  
Carlos Alberto Lopes Fonteles ◽  
Gustavo Figueiredo Brito ◽  
José Francisco Reis Sobrinho ◽  
Tatianny Soares Alves ◽  
Renata Barbosa

This set of mechanical properties of plant fibers allows its use as a reinforcement element in polymeric matrices and composites can be used in various sectors, and thus expanding the scope of use and the aggregate value of plant fibers. In this work, the choice by the use of alkali process to make the treatment of epicarp babassu fibers was decided in view of that it provides an effective, simple and low cost implementation process and also for being the most widely used method for modifying the surface of the fiber forming polymer composites. By SEM, it was observed the removal of wax layers, the impurities on the fiber surface and tyloses. With alkali treatment, it was also possible to notice the narrowing and closing of craters due to the packaging of denser material.

2016 ◽  
Vol 842 ◽  
pp. 61-66 ◽  
Author(s):  
Hendri Hestiawan ◽  
Jamasri ◽  
Kusmono

The aim of this research is to investigate the alkali treatment influence on tensile strength physical and mechanical properties of agel leaf fibers (ALF). The presence of surface impurities and the large amount of hydroxyl groups make plant fibers less attractive for polymeric materials reinforcement. ALF were subjected to alkali treatments with 2 and 4% NaOH solutions for different soaking times of 1, 12, and 24 hours at room temperature. The tensile test of single fiber was done according to ASTM D3379-75 standard. The chemical changes and the fiber surface after alkali treatment were investigated by using Fourier transform-infrared (FTIR) and scanning electron microscopy (SEM), respectively. Tensile tests showed the alkali treatment of ALF results in different tensile strength compared to untreated ALF. The highest tensile strength (1464 MPa) is found for ALF immersed in 4% NaOH for 1 hour. FTIR showed that the hemicellulose and lignin components in the ALF are removed by NaOH treatment. SEM observation of the treated ALF showed the removal of impurities and the increase of roughness on the ALF surface with alkalization. These results show that alkali treatment can increase the tensile strength of ALF.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2636
Author(s):  
Petr Valášek ◽  
Miroslav Müller ◽  
Vladimír Šleger ◽  
Viktor Kolář ◽  
Monika Hromasová ◽  
...  

Composite materials with natural fillers have been increasingly used as an alternative to synthetically produced materials. This trend is visible from a representation of polymeric composites with natural cellulose fibers in the automotive industry of the European Union. This trend is entirely logical, owing to a preference for renewable resources. The experimental program itself follows pronounced hypotheses and focuses on a description of the mechanical properties of untreated and alkali-treated natural vegetable fibers, coconut and abaca fibers. These fibers have great potential for use in composite materials. The results and discussion sections contribute to an introduction of an individual methodology for mechanical property assessment of cellulose fibers, and allows for a clear definition of an optimal process of alkalization dependent on the content of hemicellulose and lignin in vegetable fibers. The aim of this research was to investigate the influence of alkali treatment on the surface microstructure and tensile properties of coir and abaca fibers. These fibers were immersed into a 5% solution of NaOH at laboratory temperature for a time interval of 30 min, 1 h, 2 h, 3 h, 6 h, 12 h, 24 h, and 48 h, rinsed and dried. The fiber surface microstructures before and after the alkali treatment were evaluated by SEM (scanning electron microscopy). SEM analysis showed that the alkali treatment in the NaOH solution led to a gradual connective material removal from the fiber surface. The effect of the alkali is evident from the visible changes on the surface of the fibers.


2017 ◽  
Vol 37 (6) ◽  
pp. 547-557 ◽  
Author(s):  
Sekaran Sathees Kumar ◽  
Ganesan Kanagaraj

Abstract In this paper, the combined effect of different weight percentages of silicon carbide (SiC) and graphite (Gr) reinforcement on the mechanical properties of polyamide (PA6) composite is studied. Test specimens of pure PA6, 85 wt% PA6+10 wt% SiC+5 wt% Gr and 85 wt% PA6+5 wt% SiC+10 wt% Gr are prepared using an injection molding machine. The tensile, impact, hardness, morphology and thermal properties of the injection molded composites were investigated. The obtained results showed that mechanical properties, such as tensile and impact strength and modulus of the PA6 composites, were significantly higher than the pure PA6, and hybridization with silicon carbide and graphite further enhanced the performance properties, as well as the thermal resistance of the composites. The tensile fracture morphology and the characterization of PA6 polymer composites were observed by scanning electron microscope (SEM) and Fourier transform infrared spectroscopic methods. SEM observation of the fracture surfaces showed the fine dispersion of SiC and Gr for strong interfacial adhesion between fibers and matrix. The individual and combined reinforcing effects of silicon carbide and graphite on the mechanical properties of PA6 hybrid composites were compared and interpreted in this study. Improved mechanical properties were observed by the addition of small amount of SiC and Gr concurrently reinforced with the pure PA6. Finally, thermogravimetric analysis showed that the heat resistance of the composites tended to increase with increasing silicon carbide and graphite content simultaneously.


Author(s):  
Ênio Henrique Pires da Silva ◽  
Emiliano Barretto Almendro ◽  
Amanda Albertin Xavier da Silva ◽  
Guilherme Waldow ◽  
Flaminio CP Sales ◽  
...  

Composites using natural fibers as reinforcement and biodegradable polymers as matrix are considered environmentally friendly materials. This paper seeks the mechanical and morphological characterization of a biocomposite of polyurethane (PU) derived from a blend of vegetable oils doped with aluminatrihydrate (ATH) and reinforced with hydrated cotton fiber fabric (HCF). The comparison and study were performed based on the properties of the: (i) pure PU; (ii) PU doped with ATH containing 30% of the final mass (PU+30%ATH); (iii) composite of PU reinforced with 7 layers of cotton fiber fabric (PU+7CF); (iv) composite of PU+30%ATH reinforced with 7 layers of CF (PU+30%ATH+7CF); (v) composite of PU+30%ATH reinforced with 7 layers of hydrated cotton fiber fabric (PU+30%ATH+7HCF). The mechanical properties obtained according to the tensile test for the composite PU+30%ATH+CF with fibers oriented at 0° showed a significant increment in tensile strength (60 MPa) and the modulus of elasticity (4.7 GPa) when compared to pure PU (40 MPa) and (1.7 GPa) respectively. PU+30%ATH also presented a rising tensile strength (31 MPa) and Young modulus (2.6 GPa). For the composite with addition of water, results presented a significant decrease in strength (31.3 MPa) and stiffness (0.9 GPa) than the composite with no water. Electron microscopy (SEM) analyses exhibited that the samples with addition of water showed the presence of large amounts of pores and the lower interaction between matrix and fiber. These results may explain the lower mechanical properties of this material. DOI: http://dx.doi.org/10.30609/JETI.2019-7576


2021 ◽  
Vol 888 ◽  
pp. 15-21
Author(s):  
Ivelina Ivanova ◽  
Jules Assih ◽  
Dimitar Dontchev

This research aims at studying the mechanical properties of industrial hemp fibers and promoting their use as a reinforcing composite material for strengthening of civil engineering structures. Natural hemp fibers are of great interest due to the following advantages they have: low cost, high strength-to-weight ratio, low density and non-corrosive properties. The use of plant fiber composite materials has increased significantly in recent years because of the negative reduction impact on the environment. For example, the tendency to use renewable resources and their possibility for recycling. They cause fewer health and environmental problems than synthetic fibers. Natural fibers, in addition to environmental aspects, have advantages such as low densities, i.e. have low weight, interesting mechanical properties comparable to those of synthetic fiber materials, and last but not least, low cost. Composites based on natural plant fibers can be used to reinforce or repair reinforced concrete structures, as shown by research on flax fiber composites. These concretes specimens strengthened with biocomposite materials have very good resistance to bending and significantly increase the rigidity of the structure. The results show that the hemp fiber reinforcement has significant effects on the strengthening and increase in flexural strength from 8% to 35 %.


2020 ◽  
Vol 1002 ◽  
pp. 75-83
Author(s):  
Wafaa Mahdi Salih

Using PMMA Polymer reinforced by Natural Fiber (N.F.) materials have established much consideration because of several advantages for example low cost, non-abrasive, lightweight, non-toxic and the properties of bio-degradable. many kinds of research have been done in the recent usage of the natural reinforcing material to the preparation of different types of composites. Chemically treated jute fiber can enhance the surface of the fiber, decrease the absorption technique, and improve the roughness surface.in this research, pre-chemical treated in different lengths of jute- fibers in PMMA polymer-composites has been considered. Also, the effect of chemical treatment on mechanical properties of jute, jute reinforcing composite has been conferred. The results showed that the tensile strength T.S. of the treated in benzoylate solutions (4 mm) length fiber had good indicate to better interlocking between composite contents.Flexural-Strength F.S. of the-alkaline. solution treated (12 mm) length of fiber was obtained-better-results by increasing (16.5 %) compared with (2 mm) fiber-length. The fracture of the samples has discussed the relationship between composite adhesion. Impact Strength I.S. of the alkaline-treated (8,12 mm) fiber- a length that is due to to.better mechanical - interlocking between composite materials. The 2 mm fiber – length was not suitable-PMMA/ Jute composite in these tested for treated and untreated chemicals


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