Mechanical Properties of Mortars Prepared by Alkali Activated Fly Ash Coming from Different Production Batches

2015 ◽  
Vol 244 ◽  
pp. 140-145 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Fly ash is a well utilizable secondary raw material for the production of alkali activated construction materials. It is a significant alumina-silicates source suitable for the chemical reaction resulting in hardened composites. Physical and chemical properties of fly ashes as a co-product of coal burning mainly depend on characteristics of coal, burning temperature and combustion conditions. High variability of the properties of fly ash causes an uncertainty in the properties of alkali activated mortars. Time behaviour of the composition of the fly ash produced in a heating plant located in Košice, Slovakia as well as leaching behaviour of both alumina and silica from particular batches during one-year period was documented. Leaching tests were carried out using the distilled water and alkali solutions with three different concentrations. Both compressive and tensile strengths of alkali activated mortars were measured, and the correlation between the mechanical properties of hardened mortars and the chemical composition of fly ashes as well as their leaching characteristics was investigated.

2021 ◽  

Concrete is the most versatile, durable and reliable material and is the most used building material. It requires large amounts of Portland cement which has environmental problems associated with its production. Hence, an alternative concrete – geopolymer concrete is needed. The general aim of this book is to make significant contributions in understanding and deciphering the mechanisms of the realization of the alkali-activated fly ash-based geopolymer concrete and, at the same time, to present the main characteristics of the materials, components, as well as the influence that they have on the performance of the mechanical properties of the concrete. The book deals with in-depth research of the potential recovery of fly ash and using it as a raw material for the development of new construction materials, offering sustainable solutions to the construction industry.


2018 ◽  
Vol 761 ◽  
pp. 73-78 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Alkali-activated materials based on fly ash are widely developed and also produced on the present. Some of fly ashes are not suitable for production of alkali-activated materials because of their inconvenient chemical composition. Alumina-silicates are the most important components that are needed to accomplish the successful reaction. The proper content of amorphous phase of alumina-silicates and its proportion as well should be provided for the final composition of alkali-activated materials. The influence of pure aluminum oxide powder as well as raw milled natural perlite on mechanical properties and durability of alkali-activated mortars was investigated. These minerals were used as partial replacement of fly ash coming from black coal combustion. In addition, the mortars were prepared by using different alkali activators.


2012 ◽  
Vol 18 (3) ◽  
pp. 373-383 ◽  
Author(s):  
Anja Terzic ◽  
Zagorka Radojevic ◽  
Ljiljana Milicic ◽  
Ljubica Pavlovic ◽  
Zagorka Acimovic

The disposal of the fly ash generated in coal based power-plants may pose a significant risk to the environment due to the possible leaching of hazardous pollutants, such as toxic metals. Also, there is a risk of leaching even when fly ash is built-in the construction composites. Fly ashes from various landfills were applied in several composite samples (mortar, concrete and brick) without any physical or thermal pre-treatment. The leachability of the potentially toxic pollutants from the fly ash based products was investigated. The leaching behavior and potential environmental impact of the 11 potentially hazardous elements was tracked: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb and Se. A detailed study of physico-chemical characteristics of the fly ash, with accent on trace elements and the chemical composition investigation is included. Physico/chemical properties of fly ash were investigated by means of X-ray fluorescence, differential thermal analysis and X-ray diffraction methods. Scanning electron microscope was used in microstructural analysis. The results show that most of the elements are more easily leachable from the fly ash in comparison with the fly ash based composites. The leaching of investigated pollutants is within allowed range thus investigated fly ashes can be reused in construction materials production.


2019 ◽  
Vol 4 (2) ◽  
pp. 20 ◽  
Author(s):  
Ramamohana Reddy Bellum ◽  
Ruben Nerella ◽  
Sri Rama Chand Madduru ◽  
Chandra Sekhar Reddy Indukuri

Cement is one of the construction materials widely used around the world in order to develop infrastructure and it is also one of the factors affecting economies. The production of cement consumes a lot of raw materials like limestone, which releases CO2 into the atmosphere and thus leads to global warming. Many investigations are underway in this area, essentially focusing on the eco-accommodating environment. In the research, an alternative material to cement binder is geopolymer binder, with the same efficiency. This paper presents scanning electron microscope (SEM) and X-ray diffraction (XRD) analysis of factory byproducts (i.e., fly ash and ground granulated blast furnace slag (GGBFS)). The mix design process for the manufacture of alkali-activated geopolymer binders synthesized by fly ash and GGBFS is presented. The mechanical properties (compression, split tensile and flexural strength, bond strength) of geopolymer concrete at different mix proportions and at dissimilar curing conditions were also investigated. Geopolymer concrete synthesized with 30% fly ash and 70% GGBFS has better properties at 14 M of NaOH and cured in an oven for 24 h at 70 °C.


2019 ◽  
Vol 23 (9) ◽  
pp. 3875-3888 ◽  
Author(s):  
Anant Lal Murmu ◽  
Anamika Jain ◽  
Anjan Patel

2016 ◽  
Vol 56 (4) ◽  
pp. 265-282 ◽  
Author(s):  
Usman Haider ◽  
Zdenek Bittnar ◽  
Lubomír Kopecky ◽  
Vít Šmilauer ◽  
Jaroslav Pokorny ◽  
...  

The properties of fly ashes vary because of the differences in the properties of their individual particles, and the determination of variation in these properties is of interest to the industries which use pulverized raw fly ash in applications, such as in cementitious materials and in the recovery of certain rare elements from raw fly ash. To investigate the differences in individual particles, four pulverized raw fly ashes from thermal power plants of the Czech Republic were used in this research. It was observed from FE-SEM that all four fly ashes consist of glassy hollow spherical, solid spherical, porous spherical, bright spherical, porous slaggy and compact slaggy particles. Box and whisker diagrams were plotted from the data of EDX individual particle analyses, which showed that the data of percentages for the Si, Al, and Fe elements is more scattered as compared to other elements. It was further observed from ternary phase diagrams and pseudo coloured images, that nature of fly ash particles changes from alumino silicate glassy to alumino silicate calcite metallic to pure ferro-metallic,where glassy particles showed high percentages and pure calcite particles were absent in fly ashes. Furthermore, a comparison between the XRF, the EDX total area analyses, showed that the EDX individual particle analysis gives more realistic and reliable data with median, mean, and the standard deviation for percentages of each element present in the fly ashes.


2014 ◽  
Vol 1000 ◽  
pp. 59-62
Author(s):  
Hana Kalousová ◽  
Eva Bartoníčková ◽  
Tomáš Opravil

The presented paper deals with the issue of influence of storage conditions on the quality of conventional fly ashes which are produced by combustion of lignite. These ashes were stockpiled for long time. A borehole for sampling was made in the fly ash stock-pile. Total depth of the borehole was 20 m. Samples of fly ashes taken from every single meter were analyzed and next mechanical properties and the volume stability of materials containing these fly ashes were tested. The quality of fly ashes especially with respect to the possibility to use them as components of pastes, mortars and concretes as pozzolanic admixture or fine filler was evaluated.


2018 ◽  
Vol 766 ◽  
pp. 305-310 ◽  
Author(s):  
Chayanee Tippayasam ◽  
Sarochapat Sutikulsombat ◽  
Jamjuree Paramee ◽  
Cristina Leonelli ◽  
Duangrudee Chaysuwan

Geopolymer is a greener alternative cement produced from the reaction of pozzolans and strong alkali solutions. Generally, the cement industry is one of largest producers of CO2that caused global warming. For geopolymer mortar usage, Portland cement is not utilized at all. In this research, geopolymer mortars were prepared by mixing metakaolin, various wastes (fly ash, bagasse ash and rice husk ash) varied as 80:20, 50:50 and 20:80, 15M NaOH, Na2SiO3and sand. The influence of various parameters such as metakaolin to ashes ratios and pozzolans to alkali ratios on engineering properties of metakaolin blended wastes geopolymer mortar were studied. Compressive strength tests were carried out on 25 x 25 x 25 mm3cube geopolymer mortar specimens at 7, 14, 21, 28 and 91 air curing days. Physical and chemical properties were also investigated at the same times. The test results revealed that the highest compressive strength was 20% metakaolin - 80% fly ash geopolymer mortar. When the curing times increases, the compressive strength of geopolymer mortar also increases. The mixing of metakaolin and bagasse ash/rice husk ash presented lower compressive strength but higher water absorption and porosity. For FTIR results, Si-O, Al-O and Si-O-Na+were found. Moreover, the geopolymer mortar could easily plastered on the wall.


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