High Temperature Capacitors Based on [0001] and [1120] Sapphire Dielectrics

2010 ◽  
Vol 2010 (HITEC) ◽  
pp. 000182-000187
Author(s):  
Liang-Yu Chen

The test results of the dielectric properties of [0001] (C-plane) and [1120] (A-plane) sapphire (single crystalline Al2O3) at high temperatures indicate that these materials have very stable dielectric constants and low dielectric losses (compared with polycrystalline alumina) at low frequencies in the temperature range from room temperature to 550°C. Therefore, sapphire materials have become likely candidate dielectric materials for high temperature capacitors. This paper reports prototype low-volume (∼100pF) capacitors based on sapphire dielectrics for high temperature and low frequency applications. Low-volume parallel-plate capacitors using C-plane and A-plane sapphire as dielectric material were fabricated by stacking metallized sapphire substrates. These prototype capacitors were characterized in the temperature range from room temperature to 550°C by measuring the capacitance and parallel resistance of these devices at 120Hz, 1kHz, 10kHz, 100kHz, and 1MHz. The capacitance and equivalent parallel resistance of these capacitors were all directly measured by an AC LCZ impedance meter in controlled temperature environments. These prototype devices demonstrate stable capacitances over a wide temperature range, and therefore, have the potential to be integrated with silicon carbide (SiC) devices to enable high temperature electronics. The needs of thin-film metallization and encapsulation for these sapphire substrates are also discussed.

2009 ◽  
Vol 23 (17) ◽  
pp. 3649-3654 ◽  
Author(s):  
MOHAN V. JACOB

The microwave properties of some of the low cost materials which can be used in high frequency applications with low transmission losses are investigated in this paper. One of the most accurate microwave characterization techniques, Split Post Dielectric Resonator technique (SPDR) is used for the experimental investigation. The dielectric constants of the 3 materials scrutinized at room temperature and at 10K are 3.65, 2.42, 3.61 and 3.58, 2.48, 3.59 respectively. The corresponding loss tangent values are 0.00370, 0.0015, 0.0042 and 0.0025, 0.0009, 0.0025. The high frequency transmission losses are comparable with many of the conventional materials used in low temperature electronics and hence these materials could be implemented in such applications.


2016 ◽  
Vol 680 ◽  
pp. 179-183 ◽  
Author(s):  
Ming Chao Wang ◽  
Meng Meng Zhuang ◽  
Xin Tao ◽  
Xi Qing Xu ◽  
Hai Tao Geng ◽  
...  

A heat-resistant phosphate adhesive was developed for joining and repairing of C/C composites. The high-temperature bonding effect for both cured adhesive and 1300°C-calcined adhesive had been evaluated through testing high-temperature shear strength of corresponding joints. The results showed that the bonding strength of cured adhesive decreased from 7.9 MPa at RT to 0.9 MPa at 1300°C, while that of 1300°C-calcined adhesive could maintain about 4 MPa at temperature range from RT to 700°C and then decreased to 1.7 MPa at 1300°C. Besides, with the increasing thermal cycling times at 1300°C, the high-temperature bonding strength at this temperature could maintain at about 2.3 MPa.


RSC Advances ◽  
2015 ◽  
Vol 5 (96) ◽  
pp. 78414-78421 ◽  
Author(s):  
G. Murugesan ◽  
R. Nithya ◽  
S. Kalainathan ◽  
Shamima Hussain

We herein report dielectric studies on Ca0.9Nd0.1Ti0.9Al0.1O3−δ single crystals grown by the optical floating zone technique in the temperature range from room temperature to 660 K.


1988 ◽  
Vol 124 ◽  
Author(s):  
W. W. Ho

ABSTRACTExperimental methods for determining the high-temperature millimeter-wave dielectric properties of solids are described and the data obtained on a wide variety of polycrystalline ceramics are reviewed. In general, the observed increase in dielectric constants with temperature can be modeled with a macroscopic dielectric virial expansion and shown to be primarily caused by an increase in polarizability due to volume expansion. The room-temperature loss tangents in low-absorption ceramics are probably caused by impurity doping of the primary and secondary crystalline phases at grain junctions and along grain boundaries. The rapid increase in loss tangent at high temperatures commonly observed in polycrystalline ceramics is associated with softening of intergranular amorphous phases resulting in an increase in localized electrical conductivity.


2012 ◽  
Vol 2012 (HITEC) ◽  
pp. 000278-000283 ◽  
Author(s):  
Kirk Slenes ◽  
Lew Bragg

Emerging power electronics in a broad range of military, aerospace, hybrid vehicle, renewable energy and drilling applications rely on advances in dielectric materials for capacitors. Compact capacitors possessing low dielectric loss and high operating temperature capability are needed for power conditioning in advanced converter and inverter designs for these applications. Wound film capacitors represent the preferred capacitor technology but are limited by low operating temperature capabilities, < 150°C, and low volumetric efficiency, capacitance per unit volume less than 1.0 μF/cc. TPL is developing processes and manufacturing techniques for fabrication of advanced capacitor films comprised of high temperature polymers modified with ceramic nanoparticles. The selected polymers enable high temperature operation and the ceramic nanoparticles enhance volumetric efficiency by increasing the dielectric constant. The fabricated films are directly adaptable to conventional wound film capacitor construction methodologies. This paper provides an overview of TPL's experience to-date with a film dielectric material system comprised of fluorenone polyester polymer and titanate nanoparticle filler. The fluorenone polyester polymer was selected to provide a stable operating temperature of at least 300°C, while the addition of the titanate powder increases the dielectric constant and, in turn, the volumetric efficiency of wound film capacitors constructed with this film system. The targeted device for the film is a 500 to 800 V filter capacitor for high temperature power conditioning applications.


2007 ◽  
Vol 336-338 ◽  
pp. 1429-1432 ◽  
Author(s):  
Jia Hu Ouyang ◽  
Takashi Murakami ◽  
Shinya Sasaki ◽  
Yu Zhou ◽  
De Chang Jia ◽  
...  

Spark plasma sintering is employed to synthesize a variety of self-lubricating ZrO2(Y2O3)- Al2O3 matrix nanocomposites by tailoring the chemical compositions and by adjusting the sintering parameters. Different additives are incorporated into the nanocrystalline ceramics of ZrO2(Y2O3)- 20wt.% Al2O3 to evaluate their potentials as effective high temperature solid lubricants from room temperature to 800oC by using a high temperature friction and wear tester in sliding against alumina ball in air. The density, microstructure, hardness and tribological properties of the sintered nanocomposites have been investigated, as contrasted with the unmodified ceramics, to obtain a better understanding of lubrication mechanisms over a wide temperature range. The ZrO2(Y2O3)-Al2O3-SrSO4 composite exhibits steady-state friction coefficients of less than 0.2 and wear rates in the order of 10-6 mm3/Nm over a broad temperature range from room temperature to 800oC.


2007 ◽  
Vol 539-543 ◽  
pp. 1200-1205
Author(s):  
Takashi Murakami ◽  
K. Umeda ◽  
Shinya Sasaki ◽  
Jia Hu Ouyang

In the present study, Al2O3, (ZrO2-3mol% Y2O3)-39.6mass% Al2O3, Si3N4 and MgO substrates coated with SrSO4 particles were prepared, and their high-temperature tribological properties were investigated. It was clarified that SrSO4 worked as solid lubricant efficiently against Al2O3 and (ZrO2-3mol% Y2O3)-39.6mass% Al2O3 substrates in the temperature range of room temperature to 1073K in air. In addition, thin SrSO4 films were observed on the wear scars formed on the Al2O3 and (ZrO2-3mol% Y2O3)-39.6mass% Al2O3 substrates.


2013 ◽  
Vol 738-739 ◽  
pp. 506-511 ◽  
Author(s):  
Gennady E. Monastyrsky ◽  
Patrick Ochin ◽  
Valery V. Odnosum ◽  
Alexander Yu. Pasko ◽  
Victor I. Kolomytsev ◽  
...  

In alloys Ni–39(41)Al–xPt (x = 5,10,15,20 at.%) the alloying by Pt strongly increases the Ms point. There is no direct proportionality between the Pt content and the Ms point increasing. No traces of Ni3Al were found in the alloys. The precipitation of Ni5Al3was observed in Ni–39Al–15Pt alloy after cycling through the temperature range between the room temperature and 800°C. The effect of Pt alloying on the martensitic transformation and high temperature martensitic transformation stability is governed by the competition between the martensitic transformation and formation of the Ni5Al3phase upon the cooling. Pt addition, instead of Ni, can resolve the problem of decomposition processes because the alloy composition is shifted out of the Ni3Al domain on the phase diagram and it reduces the influence of the Ni5Al3phase on the degradation of martensitic transformation.


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