Anodic Polarization Characteristics Of Gold and Silver In Chloride and Sulfate Media

CORROSION ◽  
1963 ◽  
Vol 19 (4) ◽  
pp. 115t-119t ◽  
Author(s):  
F. P. A. ROBINSON ◽  
F. A. FROST
Keyword(s):  
Anodic Polarization ◽  
Current System ◽  
Anodic Polarization Curve ◽  
Chloride Ions ◽  
Passive State ◽  
Anode Reaction ◽  
Polarization Characteristics ◽  
Impressed Current ◽  
The Stability ◽  
A Current

Abstract The anodic polarization characteristics of gold and silver in chloride and sulfate media have been studied, employing potentiostatic techniques. It was found that gold produces an active-passive S-shaped curve, the form of which is not seriously affected by the presence of oxygen in the electrolyte. The stability of the passive state was greater in the sulfate than in the chloride media. Silver does not give a typical anodic polarization curve in NaCl solution, because formation of an AgCl film is the primary anode reaction. This film thickens and exfoliates at a current density of 2 a/sq ft. For this reason, silver could not be used as an inexpendable anode in an impressed current system containing chloride ions.

Effect of Nitrite Ions on Polarization Behavior of Steel Immersed in Simulated Concrete Pore Environments

2013 ◽  
Vol 368-370 ◽  
pp. 919-924
Author(s):  
Zhong Lu Cao ◽  
Makoto Hibino ◽  
Hiroki Goda
Keyword(s):  
Polarization Curve ◽  
Current Density ◽  
Linear Polarization ◽  
Anodic Polarization ◽  
Cathodic Polarization ◽  
Corrosion Current ◽  
Anodic Polarization Curve ◽  
Polarization Curves ◽  
Passive State ◽  
Nitrite Concentration

The influence of nitrite concentration on the linear polarization curves of steel, Tafel slope and Stern-Geary constant B have been investigated in three different pH environments simulating the highly alkaline environment, carbonated environment and neutral environment that really existed on the surface of steel in concrete. The results indicate that when the steel is in passive state, the presence of nitrite has little influence on anodic/cathodic polarization curves and Stern-Geary constant B; but when the steel is corroded, the presence of nitrite not only reduces the current density of anodic polarization curve but also decreases the value of Stern-Geary constant B. If this influence is not considered in practical corrosion measurement, the corrosion current will be overestimated.

CURRENT ISSUES OF INTERBUDGETARY EQUALIZATION

2020 ◽  
Vol 1 (12) ◽  
pp. 74-78
Author(s):  
A. A. BISULTANOVA ◽  
Keyword(s):  
Economic Policy ◽  
Economic Development ◽  
Russian Federation ◽  
Current System ◽  
Federal Budget ◽  
Financial Resources ◽  
Socio Economic Development ◽  
Interregional Differentiation ◽  
The Russian Federation ◽  
The Stability

The author touched upon topical issues of inter-budget alignment, budget provision of regions with financial resources, focusing on factors that directly affect the stability of the budget system, as well as highlighting problems in the budget sphere that require urgent attention from the authorities. It is concluded that the level of interregional differentiation continues to increase, and the modern mechanism of budget equalization requires urgent amendments and adjustments. It is emphasized that the main goals of socio-economic development of the Russian Federation related to the transition to an innovative type of development, changes in the structure of the national economy, set out in strategic documents and messages of the President of the Russian Federation and declared since 2009, are not being implemented, and the effectiveness of state economic policy and Federal budget expenditures for its implementation remains low. This indicates the need to review the current system.

scholarly journals Review of claudin proteins as potential biomarkers for necrotizing enterocolitis

2021 ◽  
Author(s):  
Victoria Griffiths ◽  
Niazy Al Assaf ◽  
Rizwan Khan
Keyword(s):  
Necrotizing Enterocolitis ◽  
Intestinal Permeability ◽  
Central Feature ◽  
Search Terms ◽  
Area Of Interest ◽  
Noninvasive Biomarker ◽  
Current Area ◽  
The Stability ◽  
Human Neonates ◽  
A Current

Abstract Background Claudin proteins are a component of tight junctions found in cell-cell adhesion complexes. A central feature of necrotizing enterocolitis (NEC) is intestinal permeability, with changes to claudin proteins potentially contributing to intestinal instability, inflammation, and the progression of NEC. A current area of interest is the development of a novel, noninvasive biomarker for the detection of NEC in neonates at risk of developing this disease, in order to reduce morbidity and mortality through earlier intervention. Aims This review aims to explore the relevance of claudin proteins in the pathophysiology of NEC and their potential usefulness as a biomarker. Methods This review was conducted using the search terms “claudin” + “necrotizing enterocolitis”, with 27 papers selected for review. Results Claudin proteins appear to have a role in the stability of the gut epithelium through the regulation of intestinal permeability, maturity, and inflammation. Formula feeding has been shown to promote inflammation and result in changes to claudin proteins, while breastfeeding and certain nutritional supplements lead to reduced inflammation and improved intestinal stability as demonstrated through changes to claudin protein expression. Preliminary studies in human neonates suggest that urinary claudin measurements may be used to predict the development of NEC. Conclusions Alterations to claudin proteins may reflect changes seen to intestinal permeability and inflammation in the context of NEC. Further research is necessary to understand the relevance of claudin proteins in the pathophysiology of NEC and their use as a biomarker.

Effects of Stress and Plastic Deformation on the Corrosion of Steel

CORROSION ◽  
1970 ◽  
Vol 26 (5) ◽  
pp. 189-199 ◽  
Author(s):  
W. D. FRANCE
Keyword(s):  
Plastic Deformation ◽  
Electrochemical Techniques ◽  
Chloride Ions ◽  
Localized Corrosion ◽  
Dissolution Behavior ◽  
Potential Range ◽  
Chemical Corrosion ◽  
Effects Of Ph ◽  
Current Densities ◽  
The Stability

Abstract The rate and type of corrosion exhibited by mild steel in the annealed, stressed, and plastically deformed state have been investigated. Precise electrochemical techniques provided potential and polarization data to supplement the results of chemical corrosion tests. Experiments were conducted in 0.6M NH4NO3 solutions in which steel exhibits active-passive dissolution behavior as well as localized corrosion. At active potentials, the anodic polarization curves for annealed and deformed specimens were nearly identical, with only slight increases in current densities for the deformed steel. Results at passive potentials demonstrated that increased plastic deformation can markedly decrease the passive potential range, the stability of passivity, and the ability to passivate. At certain passive potentials, the deformed steel exhibited current densities that were 400 times greater than those for annealed steel. The effects of pH, chloride ions, and crevices on the corrosion of deformed steel were examined in detail. The differences between the dissolution behavior of annealed and deformed steel were most distinctive in the approximate pH range of 3 to 6. This work is relevant to the understanding of the initiation of localized corrosion and to anodic protection.

scholarly journals Layered Double Hydroxides Precursor as Chloride Inhibitor: Synthesis, Characterization, Assessment of Chloride Adsorption Performance

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2537 ◽  
Author(s):  
Lin Chi ◽  
Zheng Wang ◽  
Youfang Zhou ◽  
Shuang Lu ◽  
Yan Yao
Keyword(s):  
Removal Rate ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Chloride Ions ◽  
Ion Removal ◽  
Hydraulic Concrete ◽  
Adsorption Behaviors ◽  
The Stability ◽  
Inhibition Performance ◽  
Double Hydroxides

In this study, the chloride adsorption behaviors of CaAl-Cl LDH precursors with various Ca:Al ratios were investigated. The optimal chloride ion removal rate was 87.06% due to the formation of hydrocalumite. The chloride adsorption products of CaAl-Cl LDH precursors were further characterized by X-ray diffraction analysis and atomic structure analysis, the adsorption mechanism was considered to be co-precipitate process. The chloride adsorption behaviors of cementitious materials blended with CaAl-Cl LDH precursors were further investigated. Leaching test according to Test Code for Hydraulic Concrete (SL352-2006) was performed to testify the stability of chloride ions in the mortar. The results show that more than 98.3% chloride ions were immobilized in cement mortar blended with CaAl-Cl LDH precursor and cannot be easily released again. The inhibition performance of steel in the electrolytes with/without CaAl LDH precursor was investigated by using electrochemical measurements. The results indicate that CaAl LDH precursor can effectively protect the passive film on steel surface by chloride adsorption. Considering the high anion exchange capacities of the LDHs, synthesized chloride adsorbent precursor can be applied as new inhibitors blended in cementitious materials to prevent the chloride-induced deterioration. Moreover, the application of chloride adsorption on CaAl-Cl LDH could also be of interest for the application of seawater blended concrete.

scholarly journals Dynamics and stability of skyrmions in a bended nano-beam

2021 ◽  
Author(s):  
Anruo Zhong ◽  
Xiaoming Lan ◽  
Yangfan Hu ◽  
Biao Wang
Keyword(s):  
Energy Cost ◽  
High Mobility ◽  
Bending Moment ◽  
Elastic Fields ◽  
Spintronic Devices ◽  
Bulk Stress ◽  
The Stability ◽  
Magnetic Skyrmions ◽  
Nontrivial Topology ◽  
A Current

Abstract Magnetic skyrmions are attracting much attention due to their nontrivial topology and high mobility to electric current. Nevertheless, suppression of the skyrmion Hall effect and maintaining high velocity of skyrmions with low energy cost are two major challenges concerning skyrmion-based spintronic devices. Here we show theoretically that in a nano-beam suffering appropriate bending moment, both Bloch-type and Néel-type skyrmions move with a vanishing Hall angle under a current density smaller than that required when the bending is absent. Moreover, bending alone can be used to move skyrmions, whose velocity is solved analytically from the Thiele equation. Generally speaking, inhomogeneous elastic fields affect the stability and dynamics of skyrmions, where the local stability is dominantly determined by the local bulk stress. These findings throw new light on how to drive skyrmions straightly with lower energy cost, which is vital for utilizing skyrmions as information carriers.

Study of Dynamic Modes of Current Stabilization Systems of Powerful Electromagnets with Pulse-Width Modulation

2021 ◽  
Vol 22 (6) ◽  
pp. 313-320
Author(s):  
M. S. Lur’e ◽  
O. M. Lur’e ◽  
A. S. Frolov
Keyword(s):  
Pulse Width ◽  
Pulse Width Modulation ◽  
Functional Differential Equations ◽  
Original System ◽  
Nyquist Stability ◽  
Detailed Assessment ◽  
Functional Differential ◽  
The Stability ◽  
Automatic Systems ◽  
A Current

This study is devoted to the consideration of a method for assessing the stability of systems with pulse-width modulation, based on the linearization of its equivalent system with pulse-width modulation. An approximate study of the dynamic modes of operation of systems with pulse-width modulation, taking into account the stability for the system of automatic control of the supply current of electromagnets under the conditions of external and internal interference, is carried out. Variants of execution of schemes of pulse-width regulators for the power supply of an electromagnet based on a unipolar and bipolar element with pulse-width modulation are presented. The possibility of linearization of systems with pulse-width modulation for the subsequent detailed assessment of the stability of such systems is shown. The prospects of using functional differential equations for stability analysis of automatic systems with pulse-width modulation are shown. The frequency characteristics of an equivalent pulse system are analyzed using the example of a current stabilization system of high-power electromagnets with a pulse-width regulator, taking into account the replacement of the latitude modulation by the amplitude one. Based on the analysis of the resulting transfer function, which is a stable linearized equivalent open system, the ways of evaluating the stability of the original system with pulse-width modulation using the Nyquist stability criterion are proposed. The conclusion is made about the advantage of a system with PWM, in relation to a system with AIM, in terms of stability, and recommendations are given for the use of the obtained data in the analysis oftransients in such systems.

The chemical stability of mendipite, diaboleïte, chloroxiphite, and cumengéite, and their relationships to other secondary lead(II) minerals

1980 ◽  
Vol 43 (331) ◽  
pp. 901-904 ◽  
Author(s):  
D. Alun Humphreys ◽  
John H. Thomas ◽  
Peter A. Williams ◽  
Robert F. Symes
Keyword(s):  
Chloride Ion ◽  
Stability Diagram ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Stability Field ◽  
Cupric Ion ◽  
Free Energy Of Formation ◽  
High Concentrations ◽  
The Stability ◽  
Ph Range

SummaryThe chemical stabilities of mendipite, Pb3O2Cl2, diaboleïte, Pb2CuCl2(OH)4, chloroxiphite, Pb3CuCl2O2(OH)2, and cumengéite, Pb19Cu24Cl42 (OH)44, have been determined in aqueous solution at 298.2 K. Values of standard Gibbs free energy of formation, ΔGf°, for the four minerals are −740, −1160, −1129, and −15163±20 kJ mol−1 respectively. These values have been used to construct the stability diagram shown in fig. I which illustrates their relationships to each other and to the minerals cotunnite, PbCl2, paralaurionite, PbOHCl, and litharge, PbO. This diagram shows that mendipite occupies a large stability field and should readily form from cold, aqueous, mineralizing solutions containing variable amounts of lead and chloride ions, and over a broad pH range. The formation of paralaurionite and of cotunnite requires a considerable increase in chloride ion concentration, although paralaurionite can crystallize under much less extreme conditions than cotunnite. The encroachment of the copper minerals on to the stability fields of those mineral phases containing lead(II) only is significant even at very low relative activities of cupric ion. Chloroxiphite has a large stability field, and at given concentrations of cupric ion, diaboleïte is stable at relatively high aCl−. Cumengéite will only form at high concentrations of chloride ion.

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