Multiphase Transport Processes of the Near-surface Concrete under Combined Carbonation-Chloride Exposures

2021 ◽  
Vol 2 (2) ◽  
pp. 2021-02108-2021-02108
Author(s):  
Muhammed Basheer
Keyword(s):  
Transport Processes ◽  
Multiphase Transport ◽  
Near Surface

Investigation of the Hydrogen Transport Processes in Crystalline Silicon of n-Type Conductivity

2007 ◽  
Vol 131-133 ◽  
pp. 425-430 ◽  
Author(s):  
Anis M. Saad ◽  
Oleg Velichko ◽  
Yu P. Shaman ◽  
Adam Barcz ◽  
Andrzej Misiuk ◽  
...  
Keyword(s):  
Hydrogen Concentration ◽  
Room Temperature ◽  
Crystalline Silicon ◽  
Transport Processes ◽  
Concentration Profiles ◽  
Hydrogen Transport ◽  
Hydrogen Atoms ◽  
Near Surface ◽  
Type Conductivity ◽  
Hydrogen Molecules

The silicon substrates were hydrogenated at approximately room temperature and hydrogen concentration profiles vs. depth have been measured by SIMS. Czochralski grown (CZ) wafers, both n- and p-type conductivity, were used in the experiments under consideration. For analysis of hydrogen transport processes and quasichemical reactions the model of hydrogen atoms diffusion and quasichemical reactions is proposed and the set of equations is obtained. The developed model takes into account the formation of bound hydrogen in the near surface region, hydrogen transport as a result of diffusion of hydrogen molecules 2 H , diffusion of metastable complexes * 2 H and diffusion of nonequilibrium hydrogen atoms. Interaction of 2 H with oxygen atoms and formation of immobile complexes “oxygen atom - hydrogen molecule” (O - H2 ) is also taken into account to explain the hydrogen concentration profiles in the substrates of n-type conductivity. The computer simulation based on the proposed equations has shown a good agreement of the calculated hydrogen profiles with the experimental data and has allowed receiving a value of the hydrogen molecules diffusivity at room temperature.

scholarly journals Sediment transport processes across the Tibetan Plateau inferred from robust grain-size end members in lake sediments

2014 ◽  
Vol 10 (1) ◽  
pp. 91-106 ◽  
Author(s):  
E. Dietze ◽  
F. Maussion ◽  
M. Ahlborn ◽  
B. Diekmann ◽  
K. Hartmann ◽  
...  
Keyword(s):  
Grain Size ◽  
Sediment Transport ◽  
Tibetan Plateau ◽  
Transport Processes ◽  
The Tibetan Plateau ◽  
Dust Deposition ◽  
Northerly Wind ◽  
Near Surface ◽  
Depositional Processes ◽  
End Members

Abstract. Grain-size distributions offer powerful proxies of past environmental conditions that are related to sediment sorting processes. However, they are often of multimodal character because sediments can get mixed during deposition. To facilitate the use of grain size as palaeoenvironmental proxy, this study aims to distinguish the main detrital processes that contribute to lacustrine sedimentation across the Tibetan Plateau using grain-size end-member modelling analysis. Between three and five robust grain-size end-member subpopulations were distinguished at different sites from similarly–likely end-member model runs. Their main modes were grouped and linked to common sediment transport and depositional processes that can be associated with contemporary Tibetan climate (precipitation patterns and lake ice phenology, gridded wind and shear stress data from the High Asia Reanalysis) and local catchment configurations. The coarse sands and clays with grain-size modes >250 μm and <2 μm were probably transported by fluvial processes. Aeolian sands (~200 μm) and coarse local dust (~60 μm), transported by saltation and in near-surface suspension clouds, are probably related to occasional westerly storms in winter and spring. Coarse regional dust with modes ~25 μm may derive from near-by sources that keep in longer term suspension. The continuous background dust is differentiated into two robust end members (modes: 5–10 and 2–5 μm) that may represent different sources, wind directions and/or sediment trapping dynamics from long-range, upper-level westerly and episodic northerly wind transport. According to this study grain-size end members of only fluvial origin contribute small amounts to mean Tibetan lake sedimentation (19± 5%), whereas local to regional aeolian transport and background dust deposition dominate the clastic sedimentation in Tibetan lakes (contributions: 42 ± 14% and 51 ± 11%). However, fluvial and alluvial reworking of aeolian material from nearby slopes during summer seems to limit end-member interpretation and should be crosschecked with other proxy information. If not considered as a stand-alone proxy, a high transferability to other regions and sediment archives allows helpful reconstructions of past sedimentation history.

scholarly journals Validation of farm-scale methane emissions using nocturnal boundary layer budgets

2015 ◽  
Vol 15 (15) ◽  
pp. 21765-21802 ◽  
Author(s):  
J. Stieger ◽  
I. Bamberger ◽  
N. Buchmann ◽  
W. Eugster
Keyword(s):  
Boundary Layer ◽  
Nocturnal Boundary Layer ◽  
Methane Emissions ◽  
Emission Factors ◽  
Transport Processes ◽  
Tethered Balloon ◽  
Near Surface ◽  
Time Space ◽  
Farm Scale ◽  
Balloon System

Abstract. This study provides the first experimental validation of Swiss agricultural methane emission estimates at the farm scale. We measured CH4 concentrations at a Swiss farmstead during two intensive field campaigns in August 2011 and July 2012 to (1) quantify the source strength of livestock methane emissions using a tethered balloon system, and (2) to validate inventory emission estimates via nocturnal boundary layer (NBL) budgets. Field measurements were performed at a distance of 150 m from the nearest farm buildings with a tethered balloon system in combination with gradient measurements at eight heights on a 10 m tower to better resolve the near-surface concentrations. Vertical profiles of air temperature, relative humidity, CH4 concentration, wind speed and wind direction showed that the NBL was strongly influenced by local transport processes and by the valley wind system. Methane concentrations showed a pronounced time course, with highest concentrations in the second half of the night. NBL budget flux estimates were obtained via a time–space kriging approach. Main uncertainties of NBL budget flux estimates were associated with instationary atmospheric conditions and the estimate of the inversion height zi (top of volume integration). The mean NBL budget fluxes of 1.60 ± 0.31 μg CH4 m-2 s-1 (1.40 ± 0.50 and 1.66 ± 0.20 μg CH4 m-2 s-1 in 2011 and 2012, respectively) were in good agreement with local inventory estimates based on current livestock number and default emission factors, with 1.29 ± 0.47 and 1.74 ± 0.63 μg CH4 m-2 s-1 for 2011 and 2012, respectively. This indicates that emission factors used for the national inventory reports are adequate, and we conclude that the NBL budget approach is a useful tool to validate emission inventory estimates.

scholarly journals Physical Transport Processes that Affect the Distribution of Oil in the Gulf of Mexico: Observations and Modeling

Oceanography ◽  
2021 ◽  
Vol 34 (1) ◽  
pp. 58-75
Author(s):  
Michel Boufadel ◽  
◽  
Annalisa Bracco ◽  
Eric Chassignet ◽  
Shuyi Chen ◽  
...  
Keyword(s):  
Gulf Of Mexico ◽  
Physical Environment ◽  
Large Scale ◽  
Transport Processes ◽  
Small Scale ◽  
Surface Mixed Layer ◽  
Physical Processes ◽  
Mixing Processes ◽  
Near Surface ◽  
Wide Range

Physical transport processes such as the circulation and mixing of waters largely determine the spatial distribution of materials in the ocean. They also establish the physical environment within which biogeochemical and other processes transform materials, including naturally occurring nutrients and human-made contaminants that may sustain or harm the region’s living resources. Thus, understanding and modeling the transport and distribution of materials provides a crucial substrate for determining the effects of biological, geological, and chemical processes. The wide range of scales in which these physical processes operate includes microscale droplets and bubbles; small-scale turbulence in buoyant plumes and the near-surface “mixed” layer; submesoscale fronts, convergent and divergent flows, and small eddies; larger mesoscale quasi-geostrophic eddies; and the overall large-scale circulation of the Gulf of Mexico and its interaction with the Atlantic Ocean and the Caribbean Sea; along with air-sea interaction on longer timescales. The circulation and mixing processes that operate near the Gulf of Mexico coasts, where most human activities occur, are strongly affected by wind- and river-induced currents and are further modified by the area’s complex topography. Gulf of Mexico physical processes are also characterized by strong linkages between coastal/shelf and deeper offshore waters that determine connectivity to the basin’s interior. This physical connectivity influences the transport of materials among different coastal areas within the Gulf of Mexico and can extend to adjacent basins. Major advances enabled by the Gulf of Mexico Research Initiative in the observation, understanding, and modeling of all of these aspects of the Gulf’s physical environment are summarized in this article, and key priorities for future work are also identified.

scholarly journals The impact of faults on the hydrogeological conditions in the Roer Valley Rift System: an overview

2003 ◽  
Vol 82 (1) ◽  
pp. 41-54 ◽  
Author(s):  
V.F. Bense ◽  
R.T. Van Balen ◽  
J.J. De Vries
Keyword(s):  
Groundwater Flow ◽  
Hydraulic Properties ◽  
Great Influence ◽  
Hydraulic Head ◽  
Transport Processes ◽  
Rift System ◽  
Near Surface ◽  
Mining Areas ◽  
Vertical Permeability ◽  
The Impact

AbstractThe hydrogeology of the Roer Valley Rift System is strongly influenced by the hydraulic properties of faults. The hydrogeological impact of faults is illustrated by examples from the SE Netherlands and the adjacent lignite mining areas within the Roer Valley Rift System, near Bonn in Germany. Hydraulic head discontinuities over the main faults in the latter area can be up to tens of meters as a result of extremely large groundwater extractions in combination with the relatively low conductivity of the main faults. Within the Netherlands, outside the mining areas, such large groundwater extractions do not take place, and groundwater fluxes are smaller. In this situation natural hydraulic head differences over the main faults are limited to several meters. Hydraulic head profiles over faults provide a first estimate of fault hydraulic properties that can be quantified using simple analytical solutions. The impact of faults on near surface processes is reflected in vegetation patterns and the structure of drainage networks, aquifer structure and hydraulic head patterns. Faults can thus be of great influence on transport processes in the subsurface as well as on water-related phenomena at the surface, and should accordingly be taken into consideration in studies related to water-management, contamination and environmental impact. Faults that have an enhanced vertical permeability are difficult to detect when horizontal groundwater flow is studied, which is probably the main reason why they are rarely described. Though, these faults may form important preferential paths to vertical groundwater flow.

scholarly journals A Drone-Based Bioaerosol Sampling System to Monitor Ice Nucleation Particles in the Lower Atmosphere

2020 ◽  
Vol 12 (3) ◽  
pp. 552 ◽  
Author(s):  
Paul Bieber ◽  
Teresa M. Seifried ◽  
Julia Burkart ◽  
Jürgen Gratzl ◽  
Anne Kasper-Giebl ◽  
...  
Keyword(s):  
Hydrological Cycle ◽  
Aerosol Particles ◽  
Sampling Site ◽  
Active Form ◽  
Ice Nucleation ◽  
Transport Processes ◽  
Polystyrene Latex ◽  
Raspberry Pi ◽  
Near Surface ◽  
Biological Particles

Terrestrial ecosystems can influence atmospheric processes by contributing a huge variety of biological aerosols (bioaerosols) to the environment. Several types of biological particles, such as pollen grains, fungal spores, and bacteria cells, trigger freezing processes in super-cooled cloud droplets, and as such can contribute to the hydrological cycle. Even though biogenic particles are known as the most active form of ice nucleation particles (INPs), the transport to high tropospheric altitudes, as well as the occurrence in clouds, remains understudied. Thus, transport processes from the land surface into the atmosphere need to be investigated to estimate weather phenomena and climate trends. To help fill this knowledge gap, we developed a drone-based aerosol particles sampling impinger/impactor (DAPSI) system for field studies to investigate sources and near surface transport of biological INPs. DAPSI was designed to attach to commercial rotary-wing drones to collect biological particles within about 100 m of the Earth’s surface. DAPSI provides information on particulate matter concentrations (PM10 & PM2.5), temperature, relative humidity, and air pressure at about 0.5 Hz, by controlling electrical sensors with an onboard computer (Raspberry Pi 3). Two remote-operated sampling systems (impinging and impacting) were integrated into DAPSI. Laboratory tests of the impinging system showed a 96% sampling efficiency for standardized aerosol particles (2 µm polystyrene latex spheres) and 84% for an aerosol containing biological INPs (Betula pendula). A series of sampling missions (12 flights) were performed using two Phantom 4 quadcopters with DAPSI onboard at a remote sampling site near Gosau, Austria. Fluorescence microscopy of impactor foils showed a significant number of auto-fluorescent particles < 0.5 µm at an excitation of 465–495 nm and an emission of 515–555 nm. A slight increase in ice nucleation activity (onset temperature between −27 °C and −31 °C) of sampled aerosol was measured by applying freezing experiments with a microscopic cooling technique. There are a number of unique opportunities for DAPSI to be used to study the transport of bioaerosols, particularly for investigations of biological INP emissions from natural sources such as birch or pine forests.

scholarly journals Nonlinear Wave Kinematics near the Ocean Surface

2017 ◽  
Vol 47 (7) ◽  
pp. 1657-1673 ◽  
Author(s):  
P. B. Smit ◽  
T. T. Janssen ◽  
T. H. C. Herbers
Keyword(s):  
Ocean Surface ◽  
Second Order ◽  
Transport Processes ◽  
Inviscid Fluid ◽  
Random Waves ◽  
Usual Practice ◽  
Near Surface ◽  
Wave Kinematics ◽  
Highly Nonlinear ◽  
Surface Kinematics

AbstractEstimation of second-order, near-surface wave kinematics is important for interpretation of ocean surface remote sensing and surface-following instruments, determining loading on offshore structures, and understanding of upper-ocean transport processes. Unfortunately, conventional wave theories based on Stokes-type expansions do not consider fluid motions at levels above the unperturbed fluid level. The usual practice of extrapolating the fluid kinematics from the unperturbed free surface to higher points in the fluid is generally reasonable for narrowband waves, but for broadband ocean waves this results in dramatic (and nonphysical) overestimation of surface velocities. Consequently, practical approximations for random waves are at best empirical and are often only loosely constrained by physical principles. In the present work, the authors formulate the governing equations for water waves in an incompressible and inviscid fluid, using a boundary-fitted coordinate system (i.e., sigma or s coordinates) to derive expressions for near-surface kinematics in nonlinear random waves from first principles. Comparison to a numerical model valid for highly nonlinear waves shows that the new results 1) are consistent with second-order Stokes theory, 2) are similar to extrapolation methods in narrowband waves, and 3) greatly improve estimates of surface kinematics in random seas.

scholarly journals Development and evaluation of CO<sub>2</sub> transport in MPAS-A v6.3

2021 ◽  
Vol 14 (5) ◽  
pp. 3037-3066
Author(s):  
Tao Zheng ◽  
Sha Feng ◽  
Kenneth J. Davis ◽  
Sandip Pal ◽  
Josep-Anton Morguí
Keyword(s):  
Boundary Layer ◽  
High Resolution ◽  
Regional Scale ◽  
Global Scale ◽  
Transport Processes ◽  
Global Model ◽  
Total Carbon ◽  
Spatial Structures ◽  
Near Surface ◽  
Co2 Transport

Abstract. Chemistry transport models (CTMs) play an important role in understanding fluxes and atmospheric distribution of carbon dioxide (CO2). They have been widely used for modeling CO2 transport through forward simulations and inferring fluxes through inversion systems. With the increasing availability of high-resolution observations, it has been become possible to estimate CO2 fluxes at higher spatial resolution. In this work, we implemented CO2 transport in the Model for Prediction Across Scales – Atmosphere (MPAS-A). The objective is to use the variable-resolution capability of MPAS-A to enable a high-resolution CO2 simulation in a limited region with a global model. Treating CO2 as an inert tracer, we implemented in MPAS-A (v6.3) the CO2 transport processes, including advection, vertical mixing by boundary layer scheme, and convective transport. We first evaluated the newly implemented model's tracer mass conservation and then its CO2 simulation accuracy. A 1-year (2014) MPAS-A simulation is evaluated at the global scale using CO2 measurements from 50 near-surface stations and 18 Total Carbon Column Observing Network (TCCON) stations. The simulation is also compared with two global models: National Oceanic and Atmospheric Administration (NOAA) CarbonTracker v2019 (CT2019) and European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecasting System (IFS). A second set of simulation (2016–2018) is used to evaluate MPAS-A at regional scale using Atmospheric Carbon and Transport – America (ACT-America) aircraft CO2 measurements over the eastern United States. This simulation is also compared with CT2019 and a 27 km WRF-Chem simulation. The global-scale evaluations show that MPAS-A is capable of representing the spatial and temporal CO2 variation with a comparable level of accuracy as IFS of similar horizontal resolution. The regional-scale evaluations show that MPAS-A is capable of representing the observed atmospheric CO2 spatial structures related to the midlatitude synoptic weather system, including the warm versus cold sector distinction, boundary layer to free troposphere difference, and frontal boundary CO2 enhancement. MPAS-A's performance in representing these CO2 spatial structures is comparable to the global model CT2019 and regional model WRF-Chem.

scholarly journals Evaluating the potential of IASI ozone observations to constrain simulated surface ozone concentrations

2009 ◽  
Vol 9 (21) ◽  
pp. 8479-8491 ◽  
Author(s):  
G. Foret ◽  
L. Hamaoui ◽  
C. Schmechtig ◽  
M. Eremenko ◽  
C. Keim ◽  
...  
Keyword(s):  
Transport Model ◽  
Surface Ozone ◽  
High Sensitivity ◽  
Transport Processes ◽  
Free Troposphere ◽  
Tracer Study ◽  
Near Surface ◽  
European Model ◽  
Model Domain ◽  
Low Sensitivity

Abstract. A tracer study has been performed for two summers in 2003 and 2004 with a regional chemistry-transport model in order to evaluate the potential constraint that tropospheric ozone observations from nadir viewing infrared sounders like IASI or TES exert on modelled near surface ozone. As these instruments show high sensitivity in the free troposphere, but low sensitivity at ground, it is important to know how much of the information gained in the free troposphere is transferred to ground through vertical transport processes. Within the European model domain, and within a time span of 4 days, only ozone like tracers initialised in vertical layers above 500 hPa are transported to the surface. For a tracer initialised between 800 and 700 hPa, seven percent reaches the surface within one to three days, on the average over the European model domain but more than double over the Mediterranean Sea. For this region, trajectory analysis shows that this is related to strong subsident transport. These results are confirmed by a second tracer study taking into account averaging kernels related to IASI retrievals, indicating the potential of these measurements to efficiently constrain surface ozone values.

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