scholarly journals STUDY OF THE CHEMICAL COMPOSITION OF VOLUME-SURFACE CONCENTRIC-ZONE COLOR SPECTRA IN ZOLOCERAMIC MATERIALS

2020 ◽  
Vol 71 (3) ◽  
pp. 123-127
Author(s):  
V. Kulbek ◽  
◽  
D. Baimolda ◽  
N. Aytan ◽  
◽  
...  
Keyword(s):  
Chemical Composition ◽  
Experimental Studies ◽  
Ceramic Materials ◽  
X Ray ◽  
Xrf Analysis ◽  
Laboratory Setup ◽  
Scientific World ◽  
Concentric Zone ◽  
Cylindrical Samples

The article presents the results of a study of the chemical composition of new volumetric-surface concentric-zonal color spectra in ash-ceramic materials associated with a well-known phenomenon in the scientific world called "Kulbek's Rings". One of the variants of the "Kulbek's Ring" was used as an object of research, which takes place in samples made on the basis of ash generated from the combustion of Ekibastuz coal. The experimental studies were carried out by the method of X-ray fluorescence (XRF) analysis on a special laboratory setup. Concentric-zonal color spectra in the phenomenon of "Kulbek's Ring" in ash-ceramic cylindrical samples are located strictly symmetrically relative to the center of the surface. The research focused on this provision. An analysis of the XRF spectra showed that symmetry, i.e., uniformity, is observed concentrically located in the color bands of the sample

The determination of the crystallinity in glass-ceramic materials by the method of Ruland

1983 ◽  
Vol 16 (2) ◽  
pp. 274-276 ◽  
Author(s):  
C. G. Vonk ◽  
G. Fagherazzi
Keyword(s):  
Chemical Composition ◽  
Glass Ceramic ◽  
Ceramic Materials ◽  
Acta Cryst ◽  
X Ray ◽  
Glass Ceramic Materials ◽  
Two Samples ◽  
Ray Methods

The method of Ruland [Acta Cryst. (1961). 14, 1180–1185] for the determination of crystallinity has been modified in order to take account of a difference in chemical composition of the crystallized and non-crystallized fractions, such as occurs in glass-ceramic materials. Application to two samples leads to higher crystallinities than found by other X-ray methods, and shows a large increase of disorder with decreasing crystallinity.

Воздействиеультразвуковогополянадинамическуювязкостьводы

2019 ◽  
pp. 27-29
Author(s):  
P. Vikulin ◽  
K. Khlopov ◽  
M. Cherkashin
Keyword(s):  
Dynamic Viscosity ◽  
Experimental Studies ◽  
Ultrasonic Field ◽  
Maximum Effect ◽  
Ultrasonic Frequency ◽  
Ultrasonic Vibrations ◽  
Wastewater Disposal ◽  
Laboratory Setup ◽  
Sonic Treatment ◽  
The Impact

Enhancing water purification processes is provided by various methods including physical ones, in particular, exposure to ultrasonic vibrations. The change in the dynamic viscosity of water affects the rate of deposition of particles in the aquatic environment which can be used in natural and wastewater treatment. At the Department Water Supply and Wastewater Disposal of the National Research Moscow State University of Civil Engineering experimental studies were conducted under laboratory conditions to study the effect of ultrasound on the change in the dynamic viscosity of water. A laboratory setup has been designed consisting of an ultrasonic frequency generator of the relative intensity, a transducer (concentrator) that transmits ultrasonic vibrations to the source water, and sonic treatment tanks. Experimental studies on the impact of the ultrasonic field in the cavitation mode on the dynamic viscosity of the aqueous medium were carried out the exposure time was obtained to achieve the maximum effect.Интенсификация процессов очистки воды осуществляется с помощью различных методов, в том числе и физических, в частности воздействием ультразвуковых колебаний. Изменение динамической вязкости воды влияет на скорость осаждения частиц в водной среде, что может быть использовано в процессах очистки природных и сточных вод. На кафедре Водоснабжение и водоотведение Национального исследовательского Московского государственного строительного университета в лабораторных условиях проведены экспериментальные исследования по изучению влияния ультразвука на изменение динамической вязкости воды. Разработана схема лабораторной установки, состоящая из генератора ультразвуковых частот с соответствующей интенсивностью, преобразователя (концентратора), передающего ультразвуковые колебания в исходную воду, и емкости для озвучивания. Выполнены экспериментальные исследования по влиянию ультразвукового поля в режиме кавитации на динамическую вязкость водной среды, получено время экспозиции для достижения максимального эффекта.

Perspective Biomass Carrier for Anaerobic Processing Systems of Organic Waste AIC

2020 ◽  
Vol 67 (1) ◽  
pp. 148-155
Author(s):  
Anatoliy V. Fedotov ◽  
Viktor S. Grigoriev ◽  
Dmitriy A. Kovalev ◽  
Andrey A. Kovalev
Keyword(s):  
Wastewater Treatment ◽  
Anaerobic Digestion ◽  
Specific Surface ◽  
Organic Waste ◽  
Porous Ceramic ◽  
Experimental Studies ◽  
Ceramic Materials ◽  
Porous Ceramics ◽  
Developed Surface ◽  
Highly Porous

To speed up the wastewater treatment under aerobic conditions and to optimize the processes of anaerobic wastewater treatment in digesters, immobilization technologies of microorganisms and enzymes on solid carriers are used. Ceramic carriers based on aluminosilicates and alumina are one of the promising inorganic biomass carriers. (Research purpose) To study the structure of porous ceramic biomass carriers for anaerobic processing of organic waste and evaluate the prospects for their use. (Materials and methods) The substrate for anaerobic digestion was a mixture of sediments of the primary and secondary sewage sumps of the Lyubertsy treatment facilities. K-65 cattle feed was used to ensure the constancy of the composition of organic substances in substrates as a cosubstrate. The authors used the method of low-temperature nitrogen adsorption of Bruner-Emmett-Teller to study the pore structure and specific surface of solid carriers on a specific surface analyzer Quntachrome Autosorb-1. (Results and discussion) The main characteristics (specific surface, volume of micro- and mesopores, predominant pore radius, water absorption and others) of chamotte foam lightweight and highly porous corundum ceramics were determined. It was revealed that ceramic materials with a developed surface and electrically conductive material provided an increase in biogas yield by 3.8-3.9 percent with an increase in methane content by an average of 5 percent. (Conclusions) The results of anaerobic digestion showed a positive effect of both a conductive carrier and highly porous ceramic materials on the process of anaerobic bioconversion of organic waste into biogas. It is advisable to expand experimental studies on the use of a conductive carrier with a developed surface based on highly porous ceramics.

Preparation and properties of green rust type substances

1987 ◽  
Vol 52 (1) ◽  
pp. 93-102 ◽  
Author(s):  
Jaroslav Vinš ◽  
Jan Šubrt ◽  
Vladimír Zapletal ◽  
František Hanousek
Keyword(s):  
Chemical Composition ◽  
Electron Diffraction ◽  
Green Rust ◽  
X Ray ◽  
Synthesis Conditions ◽  
Diffraction Patterns

A method has been worked out for the reproducible preparation of Green Rust substances involving SO42-, Cl-, Br-, and I- anions. The chemical composition of the substances prepared has been followed in dependence on the synthesis conditions. The powder X-ray and electron diffraction patterns and infrared and Moessbauer spectra have been measured and discussed.

scholarly journals Surface Analysis of Chamber Coating Materials Exposed to CF4/O2 Plasma

Coatings ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 105
Author(s):  
Seung Hyun Park ◽  
Kyung Eon Kim ◽  
Sang Jeen Hong
Keyword(s):  
Photoelectron Spectroscopy ◽  
Yttrium Aluminum Garnet ◽  
Silicon Oxide ◽  
Ceramic Materials ◽  
High Plasma ◽  
Coating Materials ◽  
Continuous Increase ◽  
X Ray ◽  
Bonding Structure ◽  
Manufacturing Environments

Coating the inner surfaces of high-powered plasma processing equipment has become crucial for reducing maintenance costs, process drift, and contaminants. The conventionally preferred alumina (Al2O3) coating has been replaced with yttria (Y2O3) due to the long-standing endurance achieved by fluorine-based etching; however, the continuous increase in radio frequency (RF) power necessitates the use of alternative coating materials to reduce process shift in a series of high-powered semiconductor manufacturing environments. In this study, we investigated the fluorine-based etching resistance of atmospheric pressure-sprayed alumina, yttria, yttrium aluminum garnet (YAG), and yttrium oxyfluoride (YOF). The prepared ceramic-coated samples were directly exposed to silicon oxide etching, and the surfaces of the plasma-exposed samples were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. We found that an ideal coating material must demonstrate high plasma-induced structure distortion by the fluorine atom from the radical. For endurance to fluorine-based plasma exposure, the bonding structure with fluoride was shown to be more effective than oxide-based ceramics. Thus, fluoride-based ceramic materials can be promising candidates for chamber coating materials.

scholarly journals Evaluation of Fe-Mg Binary Oxide for As (III) Adsorption—Synthesis, Characterization and Kinetic Modelling

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 805
Author(s):  
Saif Ullah Khan ◽  
Rumman Zaidi ◽  
Feroz Shaik ◽  
Izharul Haq Farooqi ◽  
Ameer Azam ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Kinetic Modelling ◽  
Arsenic Concentration ◽  
Experimental Studies ◽  
Precipitation Method ◽  
Arsenic Adsorption ◽  
Adsorbent Dosage ◽  
X Ray ◽  
Co Precipitation ◽  
Contaminated Waters

Nanotechnology has received much attention in treating contaminated waters. In the present study, a facile co-precipitation method was employed to synthesize a novel iron and magnesium based binary metal oxide using a stoichiometrically fixed amount of FeNO3.9H2O and MgNO3.6H2O in a proportion of molar concentration 1:1 and was later evaluated in removing As (III) from contaminated waters. Characterization of the prepared nanomaterial was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX) and ultraviolet–visible spectrophotometry (UV-VIS). Experimental studies on batch scale were carried out, examining the effect of varying initial concentrations of metal, adsorbent dosage, application time and initial pH on removal efficiency. Arsenic removal increased on increasing adsorbent dosage (0.1–1 g/L) but trend reversed on increasing initial arsenic concentration attaining qmax of 263.20 mg/g. Adsorption was quite efficient in pH range 4–8. Freundlich fitted better for adsorption isotherm along with following Pseudo-2nd order kinetics. The reusability and effect of co-existing ions on arsenic adsorption, namely SO42−, CO32− and PO43− were also explored with reusability in 1st and 2nd cycles attained adsorptive removal up to 77% and 64% respectively. The prepared nano-adsorbent showed promising results in terms of high arsenic uptake (qmax of 263.20 mg/g) along with facile and cost-effective synthesis. Thus, the co-precipitation technique used in this work is a simple one step procedure without any use of any precursor as compared to most of the other procedures used for synthesis.

scholarly journals Sintering, Microstructure, and Dielectric Properties of Copper Borates for High Frequency LTCC Applications

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4017
Author(s):  
Dorota Szwagierczak ◽  
Beata Synkiewicz-Musialska ◽  
Jan Kulawik ◽  
Norbert Pałka
Keyword(s):  
Dielectric Properties ◽  
Dielectric Permittivity ◽  
High Frequency ◽  
Ceramic Materials ◽  
Sintering Behavior ◽  
Terahertz Time Domain Spectroscopy ◽  
Very High Frequency ◽  
X Ray ◽  
Low Dielectric ◽  
Very High

New ceramic materials based on two copper borates, CuB2O4 and Cu3B2O6, were prepared via solid state synthesis and sintering, and characterized as promising candidates for low dielectric permittivity substrates for very high frequency circuits. The sintering behavior, composition, microstructure, and dielectric properties of the ceramics were investigated using a heating microscope, X-ray diffractometry, scanning electron microscopy, energy dispersive spectroscopy, and terahertz time domain spectroscopy. The studies revealed a low dielectric permittivity of 5.1–6.7 and low dielectric loss in the frequency range 0.14–0.7 THz. The copper borate-based materials, owing to a low sintering temperature of 900–960 °C, are suitable for LTCC (low temperature cofired ceramics) applications.

scholarly journals Geochemistry and Mineralogy of Ice-Dammed Lake Sediments of the Lębork Deposit

2021 ◽  
Author(s):  
Radosław Rogoziński ◽  
Alina Maciejewska
Keyword(s):  
Chemical Composition ◽  
Lake Sediments ◽  
Inductively Coupled Plasma ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Element Analysis ◽  
X Ray ◽  
Dominant Component ◽  
Clay Deposits ◽  
Dammed Lake

AbstractVarved clay deposits from ice-dammed lakes are a particularly important and broadly applied raw material used for the production of high-quality ceramics (red bricks, roof tiles, etc.), but the mineralogy and geochemistry of these sediments are not fully understood. The aim of the present study was to determine the chemical and mineralogical composition of ice-dammed lake sediments of the Lębork deposit. Major-element analysis of the compositions of selected samples from the ice-dammed lake clays was performed by X-ray fluorescence (XRF) and trace elements were determined by inductively coupled plasma-mass spectrometry. The mineralogical composition of clay samples was determined by X-ray diffraction (XRD). Analyses of the chemical composition of the ice-dammed lake clays of the Lębork deposit showed that the dominant component was SiO2 with a mean content of 56.13 wt.%; the second most abundant component was Al2O3, with a mean content for the entire deposit of 11.61 wt.%. Analysis by ICP-MS indicated the presence of rare earth elements (REE), e.g. cerium, neodymium, lanthanum, and praseodymium; their mean contents are: 56.9, 27.0, 26.3, and 7.3 ppm, respectively. Mineralogical analysis of the varved clays identified quartz, muscovite, calcite, and clay minerals – illite, kaolinite, and montmorillonite. The material filling the Lębork basin is characterized by small lateral and vertical variability in chemical composition. The results of the present study may be of considerable importance in determining the parent igneous, metamorphic, and sedimentary rocks, the weathering products of which supplied material to the ice-dammed lake, as well as in determining the mechanisms and character of the sedimentation process itself.

Sign in / Sign up

Export Citation Format

Share Document