scholarly journals Atmospheric carbonyl sulfide (OCS) measured remotely by FTIR solar absorption spectrometry

2018 ◽  
Vol 18 (3) ◽  
pp. 1923-1944 ◽  
Author(s):  
Geoffrey C. Toon ◽  
Jean-Francois L. Blavier ◽  
Keeyoon Sung

Abstract. Atmospheric OCS abundances have been retrieved from infrared spectra measured by the Jet Propulsion Laboratory (JPL) MkIV Fourier transform infra-red (FTIR) spectrometer during 24 balloon flights and during nearly 1100 days of ground-based observations since 1985. Our spectral fitting approach uses broad windows to enhance the precision and robustness of the retrievals. Since OCS has a vertical profile similar in shape to that of N2O, and since tropospheric N2O is very stable, we reference the OCS observations to those of N2O, measured simultaneously in the same air mass, to remove the effects of stratospheric transport, allowing a clearer assessment of secular changes in OCS. Balloon measurements reveal less than 5 % change in stratospheric OCS amounts over the past 25 years. Ground-based measurements reveal a springtime peak of tropospheric OCS, followed by a rapid early-summer decrease, similar to the behavior of CO2. This results in a peak-to-peak seasonal cycle of 5–6 % of the total OCS column at northern mid-latitudes. In the long-term tropospheric OCS record, a 5 % decrease is seen from 1990 to 2002, followed by a 5 % increase from 2003 to 2012.

2017 ◽  
Author(s):  
Geoffrey C. Toon ◽  
Jean-Francois L. Blavier ◽  
Keeyoon Sung

Abstract. Atmospheric OCS abundances have been retrieved from spectra measured by the JPL MkIV Fourier Transform Infra-Red (FTIR) spectrometer during 24 balloon flights and during nearly 1100 days of ground-based observations since 1985. Our spectral fitting approach uses broad windows to enhance the precision and robustness of the retrievals. Since OCS has a vertical profile similar in shape to that of N2O, and since tropospheric N2O is very stable, we reference the OCS observations to those of N2O, measured simultaneously in the same airmass, to remove the effects of stratospheric transport, allowing a clearer assessment of secular changes in OCS. Balloon measurements reveal less than 5 % change in stratospheric OCS amounts over the past 25 years. In the troposphere a springtime peak of tropospheric OCS is seen, followed by a rapid early summer decrease, similar to the behavior of CO2. This results in a peak-to-peak seasonal cycle of 5–6 % of the total OCS column at Northern mid-latitudes. In the long-term tropospheric OCS record, a 5 % decrease is seen during 1990–2002, followed by a 5 % increase from 2003 to 2012.


2014 ◽  
Vol 7 (3) ◽  
pp. 2071-2106
Author(s):  
O. E. García ◽  
M. Schneider ◽  
F. Hase ◽  
T. Blumenstock ◽  
E. Sepúlveda ◽  
...  

Abstract. This study examines the possibility of ground-based remote sensing ozone total column amounts (OTC) from spectral signatures at 3040 and 4030 cm−1. These spectral regions are routinely measured by the NDACC (Network for the Detection of Atmospheric Composition Change) ground-based FTIR (Fourier Transform InfraRed) experiments. In addition, they are potentially detectable by the TCCON (Total Carbon Column Observing Network) FTIR instruments. The ozone retrieval strategy presented here estimates the OTC from NDACC FTIR high resolution spectra with a theoretical precision of about 2% and 5% in the 3040 cm−1 and 4030 cm−1 regions, respectively. Empirically, these OTC products are validated by inter-comparison to FTIR OTC reference retrievals in the 1000 cm−1 spectral region (standard reference for NDACC ozone products), using a 8 year FTIR time series (2005–2012) taken at the subtropical ozone super-site of the Izaña Observatory (Tenerife, Spain). Associated with the weaker ozone signatures at the higher wavenumber regions, the 3040 cm−1 and 4030 cm−1 retrievals show lower vertical sensitivity than the 1000 cm−1 retrievals. Nevertheless, we observe that the rather consistent variations are detected: the variances of the 3040 cm−1 and the 4030 cm−1 retrievals agree within 90% and 75%, respectively, with the variance of the 1000 cm−1 standard retrieval. Furthermore, all three retrievals show very similar annual cycles. However, we observe a large systematic difference of about 7% between the OTC obtained at 1000 cm−1 and 3040 cm−1, indicating a significant inconsistency between the spectroscopic ozone parameters (HITRAN 2012) of both regions. Between the 1000 cm−1 and the 4030 cm−1 retrieval the systematic difference is only 2–3%. Finally, the long-term stability of the OTC retrievals has also been examined, observing that both near infrared retrievals can monitor the long-term OTC evolution in consistency to the 1000 cm−1reference data.


2015 ◽  
Vol 8 (10) ◽  
pp. 10523-10548 ◽  
Author(s):  
M. Buschmann ◽  
N. M. Deutscher ◽  
V. Sherlock ◽  
M. Palm ◽  
T. Warneke ◽  
...  

Abstract. High resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change (NDACC) in the mid-infrared spectral region are used to infer partial or total column abundances of many gases. In this paper we present the retrieval of a column averaged mole fraction of carbon dioxide from NDACC-IRWG spectra taken with a Fourier-Transform-Infra-Red (FTIR) spectrometer at the site in Ny-Ålesund, Spitsbergen. The retrieved time series is compared to co-located standard TCCON measurements of total column CO2. Comparing the NDACC and TCCON retrievals we find that the sensitivity of the NDACC retrieval is lower in the troposphere (by a factor of two) and higher in the stratosphere, compared to TCCON. Thus, the NDACC retrieval is less sensitive to tropospheric changes (e.g. the seasonal cycle) in the column average.


Author(s):  
Robert Klinck ◽  
Ben Bradshaw ◽  
Ruby Sandy ◽  
Silas Nabinacaboo ◽  
Mannie Mameanskum ◽  
...  

The Naskapi Nation of Kawawachikamach is an Aboriginal community located in northern Quebec near the Labrador Border. Given the region’s rich iron deposits, the Naskapi Nation has considerable experience with major mineral development, first in the 1950s to the 1980s, and again in the past decade as companies implement plans for further extraction. This has raised concerns regarding a range of environmental and socio-economic impacts that may be caused by renewed development. These concerns have led to an interest among the Naskapi to develop a means to track community well-being over time using indicators of their own design. Exemplifying community-engaged research, this paper describes the beginning development of such a tool in fall 2012—the creation of a baseline of community well-being against which mining-induced change can be identified. Its development owes much to the remarkable and sustained contribution of many key members of the Naskapi Nation. If on-going surveying is completed based on the chosen indicators, the Nation will be better positioned to recognize shifts in its well-being and to communicate these shifts to its partners. In addition, long-term monitoring will allow the Naskapi Nation to contribute to more universal understanding of the impacts of mining for Indigenous peoples.


Author(s):  
Lindsey C Bohl

This paper examines a few of the numerous factors that may have led to increased youth turnout in 2008 Election. First, theories of voter behavior and turnout are related to courting the youth vote. Several variables that are perceived to affect youth turnout such as party polarization, perceived candidate difference, voter registration, effective campaigning and mobilization, and use of the Internet, are examined. Over the past 40 years, presidential elections have failed to engage the majority of young citizens (ages 18-29) to the point that they became inclined to participate. This trend began to reverse starting in 2000 Election and the youth turnout reached its peak in 2008. While both short and long-term factors played a significant role in recent elections, high turnout among youth voters in 2008 can be largely attributed to the Obama candidacy and campaign, which mobilized young citizens in unprecedented ways.


2016 ◽  
Vol 1 (1) ◽  
Author(s):  
Dr. Kamlesh Kumar Shukla

FIIs are companies registered outside India. In the past four years there has been more than $41 trillion worth of FII funds invested in India. This has been one of the major reasons on the bull market witnessing unprecedented growth with the BSE Sensex rising 221% in absolute terms in this span. The present downfall of the market too is influenced as these FIIs are taking out some of their invested money. Though there is a lot of value in this market and fundamentally there is a lot of upside in it. For long-term value investors, there’s little because for worry but short term traders are adversely getting affected by the role of FIIs are playing at the present. Investors should not panic and should remain invested in sectors where underlying earnings growth has little to do with financial markets or global economy.


2019 ◽  
Vol 20 (3) ◽  
pp. 251-264 ◽  
Author(s):  
Yinlu Feng ◽  
Zifei Yin ◽  
Daniel Zhang ◽  
Arun Srivastava ◽  
Chen Ling

The success of gene and cell therapy in clinic during the past two decades as well as our expanding ability to manipulate these biomaterials are leading to new therapeutic options for a wide range of inherited and acquired diseases. Combining conventional therapies with this emerging field is a promising strategy to treat those previously-thought untreatable diseases. Traditional Chinese medicine (TCM) has evolved for thousands of years in China and still plays an important role in human health. As part of the active ingredients of TCM, proteins and peptides have attracted long-term enthusiasm of researchers. More recently, they have been utilized in gene and cell therapy, resulting in promising novel strategies to treat both cancer and non-cancer diseases. This manuscript presents a critical review on this field, accompanied with perspectives on the challenges and new directions for future research in this emerging frontier.


Author(s):  
Nils Brunsson

This chapter argues that organizational reforms are driven by problems to be addressed, by solutions to be applied, and by forgetfulness. The greater the supply of any of these factors, the more likely it is that reforms will occur. Without problems, reforms are difficult to justify; without solutions they cannot be formulated; and without forgetfulness there is a risk that people will be discouraged by the fact that similar reforms have been tried and have failed in the past. In contemporary large organizations, problems tend to be easily found. Those interested in selling solutions often try to supply problems as well — problems that can be solved by their solutions. Forgetfulness can be promoted by the use of consultants with limited experience of the implementation and long-term effects of reforms. Reforms are also self-referential; they tend to cause new reforms. Thus, reforms can be considered as routines: they are likely to be repeated over and over again.


Author(s):  
Brad Partridge ◽  
Wayne Hall

Concussion management policies have become a major priority worldwide for sports that involve frequent collisions between participants because repeated head trauma has been associated with long-term cognitive impairments, mental health problems, and some forms of neurological degeneration. A number of concussion management policies have been developed by professional bodies and subsequently adopted by various sporting leagues. These have offered little guidance on how to navigate ethical issues in identifying and managing concussion. This chapter discusses ethical issues that arise in the diagnosis of concussion, debates about the longer-term consequences of repeated concussion injuries, and the design and implementation of policies that aim to prevent and manage concussion injuries in sporting matches.


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