scholarly journals The Elbrus (Caucasus, Russia) ice core glaciochemistry to reconstruct anthropogenic emissions in central Europe: The case of sulfate

2019 ◽  
Author(s):  
Susanne Preunkert ◽  
Michel Legrand ◽  
Stanislav Kutuzov ◽  
Patrick Ginot ◽  
Vladimir Mikhalenko ◽  
...  

Abstract. This study reports on the glaciochemistry of a deep ice core (182 m long) drilled in 2009 at Mount Elbrus (43°21′ N, 42°26′ E; 5115 m above sea level) in the Caucasus, Russia. Radiocarbon dating of the particulate organic carbon fraction in the ice suggests a basal ice age of ~ 1670 ± 400 cal yr BP. Based on chemical stratigraphy, the upper 168.6 m of the core were dated by counting annual layers. The seasonally resolved chemical records cover the years 1774–2009 (Common Era), thus, being useful to reconstruct many aspects of atmospheric pollution in central Europe from pre-industrial times to present-day. After having examined the extent to which the arrival of large dust plumes originating from Sahara and Middle East modifies the chemical composition of the Elbrus (ELB) snow and ice layers, we focus on the sulfur pollution. The ELB sulfate levels indicate a four- and six-fold increase from 1774–1900 to 1980–1995 in winter and summer, respectively. Remaining close to 116 ± 28 ppb during the nineteen century, the summer sulfate levels started to rise at a mean rate of ~ 6 ppb per year from 1920 to 1950. The summer sulfate increase accelerated between 1950 and 1975 (11 ppb per year), levels reaching a maximum between 1980 and 1990 (730 ± 152 ppb) and subsequently decreasing to 630 ± 130 ppb at the beginning of the twenty first century. Long-term sulfate trends observed in the ELB ice cores are compared with those previously obtained in Alpine ice, the most important difference consists in a more pronounced decrease of the sulfur pollution over the three last decades in western than central Europe.

2019 ◽  
Vol 19 (22) ◽  
pp. 14119-14132 ◽  
Author(s):  
Susanne Preunkert ◽  
Michel Legrand ◽  
Stanislav Kutuzov ◽  
Patrick Ginot ◽  
Vladimir Mikhalenko ◽  
...  

Abstract. This study reports on the glaciochemistry of a deep ice core (182 m long) drilled in 2009 at Mount Elbrus in the Caucasus, Russia. Radiocarbon dating of the particulate organic carbon fraction in the ice suggests that the basal ice dates to 280±400 CE (Common Era). Based on chemical stratigraphy, the upper 168.6 m of the core was dated by counting annual layers. The seasonally resolved chemical records cover the years 1774–2009 CE, thus being useful to reconstruct many aspects of atmospheric pollution in south-eastern Europe from pre-industrial times to the present day. After having examined the extent to which the arrival of large dust plumes originating from the Sahara and Middle East modifies the chemical composition of the Elbrus (ELB) snow and ice layers, we focus on the dust-free sulfur pollution. The ELB dust-free sulfate levels indicate a 6- and 7-fold increase from 1774–1900 to 1980–1995 in winter and summer, respectively. Remaining close to 55±10 ppb during the 19th century, the annual dust-free sulfate levels started to rise at a mean rate of ∼3 ppb per year from 1920 to 1950. The annual increase accelerated between 1950 and 1975 (8 ppb per year), with levels reaching a maximum between 1980 and 1990 (376±10 ppb) and subsequently decreasing to 270±18 ppb at the beginning of the 21st century. Long-term dust-free sulfate trends observed in the ELB ice cores are compared with those previously obtained in Alpine and Altai (Siberia) ice, with the most important differences consisting in a much earlier onset and a more pronounced decrease in the sulfur pollution over the last 3 decades in western Europe than south-eastern Europe and Siberia.


2017 ◽  
Author(s):  
Pascal Bohleber ◽  
Tobias Erhardt ◽  
Nicole Spaulding ◽  
Helene Hoffmann ◽  
Hubertus Fischer ◽  
...  

Abstract. Among ice core drilling sites in the European Alps, the Colle Gnifetti (CG) glacier saddle is the only one to offer climate records back to at least 1000 years. This unique long-term archive is the result of an exceptionally low net accumulation driven by wind erosion and rapid annual layer thinning. To-date, however, the full exploitation of the CG time series has been hampered by considerable dating uncertainties and the seasonal summer bias in snow preservation. Using a new core drilled in 2013 we extend annual layer counting, for the first time at CG, over the last 1000 years and add additional constraints to the resulting age scale from radiocarbon dating. Based on this improved age scale, and using a multi-core approach with a neighboring ice core, we explore the potential for reconstructing long-term temperature variability from the stable water isotope and mineral dust proxy time series. A high and potentially non-stationary isotope/temperature sensitivity limits the quantitative use of the stable isotope variability thus far. However, we find substantial agreement comparing the mineral dust proxy Ca2+ with instrumental temperature. The temperature-related variability in the Ca2+ record is explained based on the temperature-dependent snow preservation bias combined with the advection of dust-rich air masses coinciding with warm temperatures. We show that using the Ca2+ trends for a quantitative temperature reconstruction results in good agreement with instrumental temperature and the latest summer temperature reconstruction derived from other archives covering the last 1000 years. This includes a Little Ice Age cold period as well as a medieval climate anomaly. In particular, part of the medieval climate period around 1100–1200 AD stands out through an increased occurrence of dust events, potentially resulting from a relative increase in meridional flow and dry conditions over the Mediterranean.


2021 ◽  
Vol 34 (10) ◽  
pp. 3839-3852
Author(s):  
Stacy E. Porter ◽  
Ellen Mosley-Thompson ◽  
Lonnie G. Thompson ◽  
Aaron B. Wilson

AbstractUsing an assemblage of four ice cores collected around the Pacific basin, one of the first basinwide histories of Pacific climate variability has been created. This ice core–derived index of the interdecadal Pacific oscillation (IPO) incorporates ice core records from South America, the Himalayas, the Antarctic Peninsula, and northwestern North America. The reconstructed IPO is annually resolved and dates to 1450 CE. The IPO index compares well with observations during the instrumental period and with paleo-proxy assimilated datasets throughout the entire record, which indicates a robust and temporally stationary IPO signal for the last ~550 years. Paleoclimate reconstructions from the tropical Pacific region vary greatly during the Little Ice Age (LIA), although the reconstructed IPO index in this study suggests that the LIA was primarily defined by a weak, negative IPO phase and hence more La Niña–like conditions. Although the mean state of the tropical Pacific Ocean during the LIA remains uncertain, the reconstructed IPO reveals some interesting dynamical relationships with the intertropical convergence zone (ITCZ). In the current warm period, a positive (negative) IPO coincides with an expansion (contraction) of the seasonal latitudinal range of the ITCZ. This relationship is not stationary, however, and is virtually absent throughout the LIA, suggesting that external forcing, such as that from volcanoes and/or reduced solar irradiance, could be driving either the ITCZ shifts or the climate dominating the ice core sites used in the IPO reconstruction.


2006 ◽  
Vol 2 (2) ◽  
pp. 145-165 ◽  
Author(s):  
V. Masson-Delmotte ◽  
G. Dreyfus ◽  
P. Braconnot ◽  
S. Johnsen ◽  
J. Jouzel ◽  
...  

Abstract. Ice cores provide unique archives of past climate and environmental changes based only on physical processes. Quantitative temperature reconstructions are essential for the comparison between ice core records and climate models. We give an overview of the methods that have been developed to reconstruct past local temperatures from deep ice cores and highlight several points that are relevant for future climate change. We first analyse the long term fluctuations of temperature as depicted in the long Antarctic record from EPICA Dome C. The long term imprint of obliquity changes in the EPICA Dome C record is highlighted and compared to simulations conducted with the ECBILT-CLIO intermediate complexity climate model. We discuss the comparison between the current interglacial period and the long interglacial corresponding to marine isotopic stage 11, ~400 kyr BP. Previous studies had focused on the role of precession and the thresholds required to induce glacial inceptions. We suggest that, due to the low eccentricity configuration of MIS 11 and the Holocene, the effect of precession on the incoming solar radiation is damped and that changes in obliquity must be taken into account. The EPICA Dome C alignment of terminations I and VI published in 2004 corresponds to a phasing of the obliquity signals. A conjunction of low obliquity and minimum northern hemisphere summer insolation is not found in the next tens of thousand years, supporting the idea of an unusually long interglacial ahead. As a second point relevant for future climate change, we discuss the magnitude and rate of change of past temperatures reconstructed from Greenland (NorthGRIP) and Antarctic (Dome C) ice cores. Past episodes of temperatures above the present-day values by up to 5°C are recorded at both locations during the penultimate interglacial period. The rate of polar warming simulated by coupled climate models forced by a CO2 increase of 1% per year is compared to ice-core-based temperature reconstructions. In Antarctica, the CO2-induced warming lies clearly beyond the natural rhythm of temperature fluctuations. In Greenland, the CO2-induced warming is as fast or faster than the most rapid temperature shifts of the last ice age. The magnitude of polar temperature change in response to a quadrupling of atmospheric CO2 is comparable to the magnitude of the polar temperature change from the Last Glacial Maximum to present-day. When forced by prescribed changes in ice sheet reconstructions and CO2 changes, climate models systematically underestimate the glacial-interglacial polar temperature change.


1988 ◽  
Vol 11 ◽  
pp. 204-204
Author(s):  
L. Mounier ◽  
J. R. Petit ◽  
J. Jouzel ◽  
C. Lorius ◽  
Ye. S. Korotkevich ◽  
...  

The 2083 m Vostok Antarctic ice core provides a unique opportunity for access to many paleoclimatic and paleo-environmental proxy data. This core, which has been dated by using a glaciological model, fully covers the last glacial-interglacial cycle, and goes back to the ice age which preceded the last interglaciai (−160 ka B P ).A continuous deuterium record is now available and we have interpreted it in terms of local temperature changes. This record is dominated by the large 100 ka glacial-inter-glacial oscillation, with a maximum temperature amplitude of about 11°C; the long Last Glacial period is very well documented and it is confirmed that the warmest part of the Last Interglaciai period was about 2°C warmer than the Holocene. Comparison with the ice-volume marine record shows that the Vostok climate record is of relatively large geographical significance, which makes it possible to establish, over the last 160 ka, the link between worldwide climatic changes and the Vostok dust record that we present here.This dust content corresponds to the non-soluble microparticles. It was obtained on a discontinuous basis (1 sample = about ∼10 m). Due to the very low concentration of some samples (down to 20 x 10−9gg−1) and cracks in the ice from the first 1000 m depth, we used stringent decontamination procedures. Size distribution and total concentration were measured, using a Coulter counter and an optical microscope; the results were tested against chemical measurements (aluminium concentration). In previous studies, it has been shown that the main proportion of insoluble microparticles is of terrigenous origin and represents the small-sized (radius <2 μm) dust produced on the continents.The Vostok record displays an increase in dust concentration of up to 20 times during the coldest climatic periods, coupled with the presence of larger particles. It confirms, on a much longer time-scale, a characteristic previously noted in Antarctic and Greenland ice cores over the Last Glacial Maximum. This large increase is attributed to a greater areal extent of global tropical aridity during the cold periods, coupled with higher efficiency of atmospheric circulation in respect of dust production and transport. Beyond this, the relationship between the dust input and the successive stages during the Last Glacial is now very well documented and will be discussed with a view to correlating the Vostok climatic record with other marine and terrestrial paleodata.


2007 ◽  
Vol 3 (3) ◽  
pp. 527-540 ◽  
Author(s):  
L. Loulergue ◽  
F. Parrenin ◽  
T. Blunier ◽  
J.-M. Barnola ◽  
R. Spahni ◽  
...  

Abstract. Gas is trapped in polar ice sheets at ~50–120 m below the surface and is therefore younger than the surrounding ice. Firn densification models are used to evaluate this ice age-gas age difference (Δage) in the past. However, such models need to be validated by data, in particular for periods colder than present day on the East Antarctic plateau. Here we bring new constraints to test a firn densification model applied to the EPICA Dome C (EDC) site for the last 50 kyr, by linking the EDC ice core to the EPICA Dronning Maud Land (EDML) ice core, both in the ice phase (using volcanic horizons) and in the gas phase (using rapid methane variations). We also use the structured 10Be peak, occurring 41 kyr before present (BP) and due to the low geomagnetic field associated with the Laschamp event, to experimentally estimate the Δage during this event. Our results seem to reveal an overestimate of the Δage by the firn densification model during the last glacial period at EDC. Tests with different accumulation rates and temperature scenarios do not entirely resolve this discrepancy. Although the exact reasons for the Δage overestimate at the two EPICA sites remain unknown at this stage, we conclude that current densification model simulations have deficits under glacial climatic conditions. Whatever the cause of the Δage overestimate, our finding suggests that the phase relationship between CO2 and EDC temperature previously inferred for the start of the last deglaciation (lag of CO2 by 800±600 yr) seems to be overestimated.


2018 ◽  
Vol 14 (1) ◽  
pp. 21-37 ◽  
Author(s):  
Pascal Bohleber ◽  
Tobias Erhardt ◽  
Nicole Spaulding ◽  
Helene Hoffmann ◽  
Hubertus Fischer ◽  
...  

Abstract. Among ice core drilling sites in the European Alps, Colle Gnifetti (CG) is the only non-temperate glacier to offer climate records dating back at least 1000 years. This unique long-term archive is the result of an exceptionally low net accumulation driven by wind erosion and rapid annual layer thinning. However, the full exploitation of the CG time series has been hampered by considerable dating uncertainties and the seasonal summer bias in snow preservation. Using a new core drilled in 2013 we extend annual layer counting, for the first time at CG, over the last 1000 years and add additional constraints to the resulting age scale from radiocarbon dating. Based on this improved age scale, and using a multi-core approach with a neighbouring ice core, we explore the time series of stable water isotopes and the mineral dust proxies Ca2+ and insoluble particles. Also in our latest ice core we face the already known limitation to the quantitative use of the stable isotope variability based on a high and potentially non-stationary isotope/temperature sensitivity at CG. Decadal trends in Ca2+ reveal substantial agreement with instrumental temperature and are explored here as a potential site-specific supplement to the isotope-based temperature reconstruction. The observed coupling between temperature and Ca2+ trends likely results from snow preservation effects and the advection of dust-rich air masses coinciding with warm temperatures. We find that if calibrated against instrumental data, the Ca2+-based temperature reconstruction is in robust agreement with the latest proxy-based summer temperature reconstruction, including a “Little Ice Age” cold period as well as a medieval climate anomaly. Part of the medieval climate period around AD 1100–1200 clearly stands out through an increased occurrence of dust events, potentially resulting from a relative increase in meridional flow and/or dry conditions over the Mediterranean.


2008 ◽  
Vol 4 (3) ◽  
pp. 175-180 ◽  
Author(s):  
T. Yao ◽  
K. Duan ◽  
B. Xu ◽  
N. Wang ◽  
X. Guo ◽  
...  

Abstract. Lack of reliable long-term precipitation record from the northern Tibetan Plateau has constrained our understanding of precipitation variations in this region. We drilled an ice core on the Puruogangri Ice Field in the central Tibetan Plateau in 2000 to reveal the precipitation variations. The well dated part of the core extends back to AD 1600, allowing us to construct a 400-year annual accumulation record. This record shows that the central Tibetan plateau experienced a drier period with an average annual precipitation of ~300 mm in the 19th century, compared to ~450 mm in the wetter periods during 1700–1780 and the 20th century. This pattern agrees with precipitation reconstructions from the Dunde and Guliya ice cores on the northern Plateau but differs from that found in the Dasuopu ice cores from the southern Plateau The north-south contrasts in precipitation reconstruction reveals difference in moisture origin between the south Tibetan Plateau dominated by the Asian monsoon and the north Tibetan Plateau dominated by the continental recycling and the westerlies.


2000 ◽  
Vol 54 (2) ◽  
pp. 284-294 ◽  
Author(s):  
Atte Korhola ◽  
Jan Weckström ◽  
Lasse Holmström ◽  
Panu Erästö

A diatom-based calibration model for predicting summer temperatures was developed using climatically sensitive subarctic lakes in northern Fennoscandia. The model was applied to a sediment core from a treeline lake to infer trends in Holocene climate. The record exhibits long-term variations, as well as a series of shorter-term fluctuations on a time scale of centuries. Summers were warmest in the area about 6200 cal yr B.P. and featured distinct cooling episodes around 8300, 7200, 4200, 3000, and 400 cal yr B.P., most of these coinciding with some known climate events (e.g., the 8200 cal yr B.P. event and the Little Ice Age). The similarity of the observed shifts with the pacings of climate events from marine and ice-core records represents evidence for coupled ocean–atmosphere forcing of the regional climate.


2007 ◽  
Vol 46 ◽  
pp. 362-366 ◽  
Author(s):  
Tandong Yao ◽  
Keqin Duan ◽  
L.G. Thompson ◽  
Ninglian Wang ◽  
Lide Tian ◽  
...  

AbstractTemperature variation on the Tibetan Plateau over the last 1000 years has been inferred using a composite δ18O record from four ice cores. Data from a new ice core recovered from the Puruogangri ice field in the central Tibetan Plateau are combined with those from three other cores (Dunde, Guliya and Dasuopu) recovered previously. The ice-core δ18O composite record indicates that the temperature change on the whole Tibetan Plateau is similar to that in the Northern Hemisphere on multi-decadal timescales except that there is no decreasing trend from AD 1000 to the late 19th century. The δ18O composite record from the northern Tibetan Plateau, however, indicates a cooling trend from AD 1000 to the late 19th century, which is more consistent with the Northern Hemisphere temperature reconstruction. The δ18O composite record reveals the existence of the Medieval Warm Period and the Little Ice Age (LIA) on the Tibetan Plateau. However, on the Tibetan Plateau the LIA is not the coldest period during the last millennium as in other regions in the Northern Hemisphere. The present study indicates that the 20th-century warming on the Tibetan Plateau is abrupt, and is warmer than at any time during the past 1000 years.


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