Supplementary material to "Time-resolved emission reductions for atmospheric chemistry modelling in Europe during the COVID-19 lockdowns"

Author(s):  
Marc Guevara ◽  
Oriol Jorba ◽  
Albert Soret ◽  
Hervé Petetin ◽  
Dene Bowdalo ◽  
...  
2020 ◽  
Author(s):  
Marc Guevara ◽  
Oriol Jorba ◽  
Albert Soret ◽  
Hervé Petetin ◽  
Dene Bowdalo ◽  
...  

Abstract. We quantify the reductions in primary emissions due to the COVID-19 lockdowns in Europe. Our estimates are provided in the form of a dataset of reduction factors varying per country and day that will allow modelling and identifying the associated impacts upon air quality. The country- and daily-resolved reduction factors are provided for each of the following source categories: energy industry (power plants), manufacturing industry, road traffic and aviation (landing and take-off cycle). We computed the reduction factors based on open access and near-real time measured activity data from a wide range of information sources. We also trained a machine learning model with meteorological data to derive weather-normalised electricity consumption reductions. The time period covered is from 21 February, when the first European localised lockdown was implemented in the region of Lombardy (Italy), until 26 April 2020. This period includes five weeks (23 March until 26 April) with the most severe and relatively unchanged restrictions upon mobility and socio-economic activities across Europe. The computed reduction factors were combined with the Copernicus Atmosphere Monitoring Service's European emission inventory using adjusted emission temporal profiles in order to derive time-resolved emission reductions per country and pollutant sector. During the most severe lockdown period, we estimate the average emission reductions to be −33 % for NOx, −8 % for NMVOC, −7 % for SOx and −7 % for PM2.5 at the EU-30 level (EU-28 plus Norway and Switzerland). For all pollutants more than 85 % of the total reduction is attributable to road transport, except SOx. The reductions reached −50 % (NOx), −14 % (NMVOC), −12 % (SOx) and −15 % (PM2.5) in countries where the lockdown restrictions were more severe such as Italy, France or Spain. To show the potential for air quality modelling we simulated and evaluated NO2 concentration decreases in rural and urban background regions across Europe (Italy, Spain, France, Germany, United-Kingdom and Sweden). We found the lockdown measures to be responsible for NO2 reductions of up to −58 % at urban background locations (Madrid, Spain) and −44 % at rural background areas (France), with an average contribution of the traffic sector to total reductions of 86 % and 93 %, respectively. A clear improvement of the modelled results was found when considering the emission reduction factors, especially in Madrid, Paris and London where the bias is reduced with more than 90 %. Future updates will include the extension of the COVID-19 lockdown period covered, the addition of other pollutant sectors potentially affected by the restrictions (commercial/residential combustion and shipping) and the evaluation of other air quality pollutants such as O3 and PM2.5. All the emission reduction factors are provided in the supplementary material.


2021 ◽  
Vol 21 (2) ◽  
pp. 773-797
Author(s):  
Marc Guevara ◽  
Oriol Jorba ◽  
Albert Soret ◽  
Hervé Petetin ◽  
Dene Bowdalo ◽  
...  

Abstract. We quantify the reductions in primary emissions due to the COVID-19 lockdowns in Europe. Our estimates are provided in the form of a dataset of reduction factors varying per country and day that will allow the modelling and identification of the associated impacts upon air quality. The country- and daily-resolved reduction factors are provided for each of the following source categories: energy industry (power plants), manufacturing industry, road traffic and aviation (landing and take-off cycle). We computed the reduction factors based on open-access and near-real-time measured activity data from a wide range of information sources. We also trained a machine learning model with meteorological data to derive weather-normalized electricity consumption reductions. The time period covered is from 21 February, when the first European localized lockdown was implemented in the region of Lombardy (Italy), until 26 April 2020. This period includes 5 weeks (23 March until 26 April) with the most severe and relatively unchanged restrictions upon mobility and socio-economic activities across Europe. The computed reduction factors were combined with the Copernicus Atmosphere Monitoring Service's European emission inventory using adjusted temporal emission profiles in order to derive time-resolved emission reductions per country and pollutant sector. During the most severe lockdown period, we estimate the average emission reductions to be −33 % for NOx, −8 % for non-methane volatile organic compounds (NMVOCs), −7 % for SOx and −7 % for PM2.5 at the EU-30 level (EU-28 plus Norway and Switzerland). For all pollutants more than 85 % of the total reduction is attributable to road transport, except SOx. The reductions reached −50 % (NOx), −14 % (NMVOCs), −12 % (SOx) and −15 % (PM2.5) in countries where the lockdown restrictions were more severe such as Italy, France or Spain. To show the potential for air quality modelling, we simulated and evaluated NO2 concentration decreases in rural and urban background regions across Europe (Italy, Spain, France, Germany, United-Kingdom and Sweden). We found the lockdown measures to be responsible for NO2 reductions of up to −58 % at urban background locations (Madrid, Spain) and −44 % at rural background areas (France), with an average contribution of the traffic sector to total reductions of 86 % and 93 %, respectively. A clear improvement of the modelled results was found when considering the emission reduction factors, especially in Madrid, Paris and London where the bias is reduced by more than 90 %. Future updates will include the extension of the COVID-19 lockdown period covered, the addition of other pollutant sectors potentially affected by the restrictions (commercial and residential combustion and shipping) and the evaluation of other air quality pollutants such as O3 and PM2.5. All the emission reduction factors are provided in the Supplement.


2020 ◽  
Author(s):  
Thomas R. Lewis ◽  
Juan Carlos Gómez Martin ◽  
Mark A. Blitz ◽  
Carlos A. Cuevas ◽  
John M. C. Plane ◽  
...  

Abstract. Iodine oxides (IxOy) play an important role in the atmospheric chemistry of iodine. They are initiators of new particle formation events in the coastal and polar boundary layer and act as iodine reservoirs in tropospheric ozone-depleting chemical cycles. Despite the importance of the aforementioned processes, the photochemistry of these molecules has not been studied in detail previously. Here, we report the first determination of the absorption cross sections of IxOy, x = 2, 3, 5, y = 1–12 at λ = 355 nm by combining pulsed laser photolysis of I2/O3 gas mixtures in air with time-resolved photo-ionization time-of-flight mass spectrometry, using NO2 actinometry for signal calibration. The oxides selected for absorption cross section determinations are those presenting the strongest signals in the mass spectra, where signals containing 4 iodine atoms are absent. The method is validated by measuring the absorption cross section of IO at 355 nm, σ355 nm, IO = (1.2 ± 0.1) ×  10–18 cm2, which is found to be in good agreement with the most recent literature. The results obtained are: σ355 nm, I2O3 


2018 ◽  
Author(s):  
Shahzad Gani ◽  
Sahil Bhandari ◽  
Sarah Seraj ◽  
Dongyu S. Wang ◽  
Kanan Patel ◽  
...  

Abstract. Delhi, India routinely experiences some of the world's highest urban particulate matter concentrations. We established the Delhi Aerosol Supersite campaign to provide long-term characterization of the ambient submicron aerosol composition in Delhi. Here we report on 1.25 years of highly time resolved speciated submicron particulate matter (PM1) data, including black carbon (BC) and non-refractory PM1 (NR-PM1), which we combine to develop a composition-based estimate of PM1 (“C-PM1” = BC + NR-PM1) concentrations. We observed marked seasonal and diurnal variability in the concentration and composition of PM1 owing to the interactions of sources and atmospheric processes. Winter was the most polluted period of the year with average C-PM1 mass concentrations of ~210 μg m−3. Monsoon was hot and rainy, consequently making it the least polluted (C-PM1 ~50 μg m−3) period. Organics constituted more than half of the C-PM1 for all seasons and times of day. While ammonium, chloride and nitrate each were ~10% of the C-PM1 for the cooler months, BC and sulfate contributed ~5% each. For the warmer periods, the fractional contribution of BC and sulfate to C-PM1 increased and the chloride contribution decreased to less than 2%. The seasonal and diurnal variation in absolute mass loadings were generally consistent with changes in ventilation coefficients, with higher concentrations for periods with unfavorable meteorology—low planetary boundary layer height and low wind speeds. However, the variation in C-PM1 composition was influenced by temporally varying sources, photochemistry and gas-particle partitioning. During cool periods when wind was from the northwest, episodic hourly averaged chloride concentrations reached 50–100 μg m−3, ranking among the highest chloride concentrations reported anywhere in the world. We estimated the contribution of primary emissions and secondary processes to Delhi's submicron aerosol. Secondary species contributed almost 50–70% of Delhi's C-PM1 mass for the winter and spring months, and up to 60–80% for the warmer summer and monsoon months. For the cooler months that had the highest C-PM1 concentrations, the nighttime sources were skewed towards primary sources, while the daytime C-PM1 was dominated by secondary species. Overall, these findings point to the important effects of both primary emissions and more regional atmospheric chemistry on influencing the extreme particle concentrations that impact the Delhi megacity region. Future air quality strategies considering Delhi's situation in both a regional and local context will be more effective than policies targeting only local, primary air pollutants.


2018 ◽  
Author(s):  
Zacharias Marinou Nikolaou ◽  
Jyh-Yuan Chen ◽  
Yiannis Proestos ◽  
Johannes Lelieveld ◽  
Rolph Sander

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