Dynamics and chemistry of vortex remnants in late Arctic spring 1997 and 2000: Simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS)

Abstract. High-resolution simulations of the chemical composition of the Arctic stratosphere during late spring 1997 and 2000 were performed with the Chemical Lagrangian Model of the Stratosphere (CLaMS). The simulations were performed for the entire northern hemisphere on two isentropic levels 450 K (~18 km) and 585 K (~24 km). The spatial distribution and the lifetime of the vortex remnants formed after the vortex breakup in May 1997 display different behavior above and below 20 km. Above 20 km, vortex remnants propagate southward (up to 40°N) and are "frozen in'' in the summer circulation without significant mixing. Below 20 km the southward propagation of the remnants is bounded by the subtropical jet. Their lifetime is shorter by a factor of 2 than that above 20 km, owing to significant stirring below this altitude. The behavior of vortex remnants formed in March 2000 is similar but, due to an earlier vortex breakup, dominated during the first 6 weeks after the vortex breakup by westerly winds, even above 20 km. Vortex remnants formed in May 1997 are characterized by large mixing ratios of HCl indicating negligible, halogen-induced ozone loss. In contrast, mid-latitude ozone loss in late boreal spring 2000 is dominated, until mid-April, by halogen-induced ozone destruction within the vortex remnants, and subsequent transport of the ozone-depleted polar air masses (dilution) into the mid-latitudes. By varying the intensity of mixing in CLaMS, the impact of mixing on the formation of ClONO2 and ozone depletion is investigated. We find that the photochemical decomposition of HNO3 and not mixing with NOx-rich mid-latitude air is the main source of NOx within the vortex remnants in March and April 2000. Ozone depletion in the remnants is driven by ClOx photolytically formed from ClONO2. At the end of May 1997, the halogen-induced ozone deficit at 450 K poleward of 30°N amounts to ~12% with ~10% in the polar vortex and ~2% in well-isolated vortex remnants after the vortex breakup.

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Dynamics and chemistry of vortex remnants in late Arctic spring 1997 and 2000: Simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS)

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-3-1051-2003 ◽

2003 ◽

Vol 3 (1) ◽

pp. 1051-1080 ◽

Cited By ~ 1

Author(s):

P. Konopka ◽

J.-U. Grooß ◽

S. Bausch ◽

R. Müller ◽

D. S. McKenna ◽

...

Keyword(s):

Ozone Depletion ◽

Effective Diffusivity ◽

Lagrangian Model ◽

The Arctic ◽

Summer Circulation ◽

Air Masses ◽

Ozone Loss ◽

Mixing Ratios ◽

Photochemical Decomposition ◽

The Impact

Abstract. High resolution simulations of the chemical composition of the Arctic stratosphere during late spring 1997 and 2000 have been conducted with the Chemical Lagrangian Model of the Stratosphere (CLaMS). The simulations were performed for the entire northern hemisphere on two isentropic levels 450 K (~18 km) and 585 K (~24 km). The spatial distribution and the lifetime of the vortex remnants formed after the vortex breakup in May 1997 show a completely different behavior above and below 20 km. Above 20 km, vortex remnants effectively propagate southward (up to 40° N) and are "frozen'' in the summer circulation without significant mixing. Below 20 km the southward propagation of the remnants is bounded by the subtropical jet near 55° N. Their lifetime is shorter by a factor of 2 than above 20 km, owing to significant stirring below this altitude. The behavior of vortex remnants formed in March 2000 is similar but, due to an earlier vortex breakup, dominated until mid of May by westerly winds, even above 20 km. Vortex remnants formed in May 1997 are characterized by large mixing ratios of HCl indicating a negligible contribution of the halogen-induced ozone loss. In contrast, mid-latitude ozone loss in late boreal spring 2000 is dominated by an irreversible transport of the ozone-depleted polar air masses (dilution) and, until mid of April, by halogen-induced ozone destruction within the vortex remnants. By varying the effective diffusivity of CLaMS, the impact of mixing on the formation of ClONO2 and ozone depletion is considered. In particular, the photochemical decomposition of HNO3 and not mixing with NOx-rich mid-latitude air is the main source of NOx within the vortex remnants in March and April 2000. Ozone depletion in the remnants is driven by ClOx photolytically formed from ClONO2 and can be properly resolved for CLaMS spatial resolution better then 100\\,km. At 450 K, ozone loss in the vortex remnants contributes by ~2% to the ozone deficit poleward of 30° N.

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The impact of mid-latitude intrusions into the polar vortex on ozone loss estimates

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-2-2489-2002 ◽

2002 ◽

Vol 2 (6) ◽

pp. 2489-2506

Author(s):

J.-U. Grooß ◽

R. Müller

Keyword(s):

Loss Rate ◽

Polar Vortex ◽

Lagrangian Model ◽

The Arctic ◽

Mixing Ratio ◽

Match Method ◽

Air Masses ◽

Model Simulations ◽

Ozone Loss ◽

The Impact

Abstract. Current stratospheric chemical model simulations underestimate substantially the large ozone loss rates that are derived for the Arctic from ozone sondes for January of some years. Until now, no explanation for this discrepancy has been found. Here, we examine the influence of intrusions of mid-latitude air into the polar vortex on these ozone loss estimates. This study focuses on the winter 1991/92. It is based on simulations performed with the Chemical Lagrangian Model of the Stratosphere (CLaMS). The simulations for January 1992 show that the intrusions induce a reduction of vortex average ozone mixing ratio corresponding to a systematic offset of the ozone loss rate of about 12 ppb per day. Further, the results of the Match method are influenced by the intrusions, since the intruded air masses are deformed and reach dimensions below the Match radius. From our calculations we deduce a systematic offset of the Match ozone loss rate by about 10 ppb/day, which may explain about 28% of the published discrepancy between Match and box model simulations for the winter 1991/92.

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The impact of mid-latitude intrusions into the polar vortex on ozone loss estimates

Atmospheric Chemistry and Physics ◽

10.5194/acp-3-395-2003 ◽

2003 ◽

Vol 3 (2) ◽

pp. 395-402 ◽

Cited By ~ 9

Author(s):

J.-U. Grooß ◽

R. Müller

Keyword(s):

Large Scale ◽

Loss Rate ◽

Polar Vortex ◽

Control Measures ◽

Lagrangian Model ◽

The Arctic ◽

Match Method ◽

Ozone Loss ◽

The Impact ◽

Loss Rates

Abstract. Current stratospheric chemical model simulations underestimate substantially the large ozone loss rates that are derived for the Arctic from ozone sondes for January of some years. Until now, no explanation for this discrepancy has been found. Here, we examine the influence of intrusions of mid-latitude air into the polar vortex on these ozone loss estimates. This study focuses on the winter 1991/92, because during this winter the discrepancy between simulated and experimentally derived ozone loss rates is reported to be the largest. Also during the considered period the vortex was disturbed by a strong warming event with large-scale intrusions of mid-latitude air into the polar vortex, which is quite unusual for this time of the year. The study is based on simulations performed with the Chemical Lagrangian Model of the Stratosphere (CLaMS). Two methods for determination the ozone loss are investigated, the so-called vortex average approach and the Match method. The simulations for January 1992 show that the intrusions induce a reduction of vortex average ozone mixing ratio corresponding to a systematic offset of the ozone loss rate of about 12 ppb per day. This should be corrected for in the vortex average method. The simulations further suggest, that these intrusions do not cause a significant bias for the Match method due to effective quality control measures in the Match technique.

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Record springtime stratospheric ozone depletion at 80°N in 2020

10.5194/egusphere-egu21-8892 ◽

2021 ◽

Author(s):

Ramina Alwarda ◽

Kristof Bognar ◽

Kimberly Strong ◽

Martyn Chipperfield ◽

Sandip Dhomse ◽

...

Keyword(s):

Ozone Depletion ◽

Transport Model ◽

Stratospheric Ozone ◽

Polar Vortex ◽

The Arctic ◽

Optical Absorption Spectroscopy ◽

Chemical Transport Model ◽

Polar Stratospheric Clouds ◽

Ozone Loss ◽

Stratospheric Clouds

The Arctic winter of 2019-2020 was characterized by an unusually persistent polar vortex and temperatures in the lower stratosphere that were consistently below the threshold for the formation of polar stratospheric clouds (PSCs). These conditions led to ozone loss that is comparable to the Antarctic ozone hole. Ground-based measurements from a suite of instruments at the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Canada (80.05&#176;N, 86.42&#176;W) were used to investigate chemical ozone depletion. The vortex was located above Eureka longer than in any previous year in the 20-year dataset and lidar measurements provided evidence of polar stratospheric clouds (PSCs) above Eureka. Additionally, UV-visible zenith-sky Differential Optical Absorption Spectroscopy (DOAS) measurements showed record ozone loss in the 20-year dataset, evidence of denitrification along with the slowest increase of NO2 during spring, as well as enhanced reactive halogen species (OClO and BrO). Complementary measurements of HCl and ClONO2 (chlorine reservoir species) from a Fourier transform infrared (FTIR) spectrometer showed unusually low columns that were comparable to 2011, the previous year with significant chemical ozone depletion. Record low values of HNO3 in the FTIR dataset are in accordance with the evidence of PSCs and a denitrified atmosphere. Estimates of chemical ozone loss were derived using passive ozone from the SLIMCAT offline chemical transport model to account for dynamical contributions to the stratospheric ozone budget.

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Nitrification of the lowermost stratosphere during the exceptionally cold Arctic winter 2015–2016

Atmospheric Chemistry and Physics ◽

10.5194/acp-19-13681-2019 ◽

2019 ◽

Vol 19 (21) ◽

pp. 13681-13699 ◽

Cited By ~ 1

Author(s):

Marleen Braun ◽

Jens-Uwe Grooß ◽

Wolfgang Woiwode ◽

Sören Johansson ◽

Michael Höpfner ◽

...

Keyword(s):

Nitric Acid ◽

Cross Sections ◽

Large Scale ◽

Potential Temperature ◽

Lagrangian Model ◽

The Arctic ◽

Small Scale ◽

Mixing Ratios ◽

Fine Structures ◽

The Impact

Abstract. The Arctic winter 2015–2016 was characterized by exceptionally low stratospheric temperatures, favouring the formation of polar stratospheric clouds (PSCs) from mid-December until the end of February down to low stratospheric altitudes. Observations by GLORIA (Gimballed Limb Observer for Radiance Imaging of the Atmosphere) on HALO (High Altitude and LOng range research aircraft) during the PGS (POLSTRACC–GW-LCYCLE II–SALSA) campaign from December 2015 to March 2016 allow the investigation of the influence of denitrification on the lowermost stratosphere (LMS) with a high spatial resolution. Two-dimensional vertical cross sections of nitric acid (HNO3) along the flight track and tracer–tracer correlations derived from the GLORIA observations document detailed pictures of wide-spread nitrification of the Arctic LMS during the course of an entire winter. GLORIA observations show large-scale structures and local fine structures with enhanced absolute HNO3 volume mixing ratios reaching up to 11 ppbv at altitudes of 13 km in January and nitrified filaments persisting until the middle of March. Narrow coherent structures tilted with altitude of enhanced HNO3, observed in mid-January, are interpreted as regions recently nitrified by sublimating HNO3-containing particles. Overall, extensive nitrification of the LMS between 5.0 and 7.0 ppbv at potential temperature levels between 350 and 380 K is estimated. The GLORIA observations are compared with CLaMS (Chemical Lagrangian Model of the Stratosphere) simulations. The fundamental structures observed by GLORIA are well reproduced, but differences in the fine structures are diagnosed. Further, CLaMS predominantly underestimates the spatial extent of HNO3 maxima derived from the GLORIA observations as well as the overall nitrification of the LMS. Sensitivity simulations with CLaMS including (i) enhanced sedimentation rates in case of ice supersaturation (to resemble ice nucleation on nitric acid trihydrate (NAT)), (ii) a global temperature offset, (iii) modified growth rates (to resemble aspherical particles with larger surfaces) and (iv) temperature fluctuations (to resemble the impact of small-scale mountain waves) slightly improved the agreement with the GLORIA observations of individual flights. However, no parameter could be isolated which resulted in a general improvement for all flights. Still, the sensitivity simulations suggest that details of particle microphysics play a significant role for simulated LMS nitrification in January, while air subsidence, transport and mixing become increasingly important for the simulated HNO3 distributions towards the end of the winter.

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Linking the uncertainty in simulated arctic ozone losses to modelling of tropical stratospheric water vapour

10.5194/acp-2018-310 ◽

2018 ◽

Author(s):

Laura Thölix ◽

Alexey Karpechko ◽

Leif Backman ◽

Rigel Kivi

Keyword(s):

Water Vapour ◽

Climate Models ◽

Polar Vortex ◽

The Arctic ◽

Ozone Loss ◽

Tropical Tropopause ◽

Water Vapour Concentration ◽

Vapour Concentration ◽

The Impact ◽

Stratospheric Water Vapour

Abstract. Stratospheric water vapor plays a key role in radiative and chemical processes, it e.g. influences the chemical ozone loss via controlling the polar stratospheric cloud formation in the polar stratosphere. The amount of water entering the stratosphere through the tropical tropopause differs substantially between chemistry-climate models. This is because the present-day models have difficulties in capturing the whole complexity of processes that control the water transport across the tropopause. As a result there are large differences in the stratospheric water vapour between the models. In this study we investigate the sensitivity of simulated Arctic ozone loss to the amount of water, which enters the stratosphere through the tropical tropopause. We used a chemical transport model, FinROSE-CTM, forced by ERA-Interim meteorology. The water vapour concentration in the tropical tropopause was varied between 0.5 and 1.6 times the concentration in ERA-Interim, which is similar to the range seen in chemistry climate models. The water vapour changes in the tropical tropopause led to about 1.5 and 2 ppm more water vapour in the Arctic polar vortex compared to the ERA-Interim, respectively. We found that the impact of water vapour changes on ozone loss in the Arctic polar vortex depend on the meteorological conditions. Polar stratospheric clouds form in the cold conditions within the Arctic vortex, and chlorine activation on their surface lead to ozone loss. If the cold conditions persist long enough (e.g. in 2010/11), the chlorine activation is nearly complete. In this case addition of water vapour to the stratosphere increased the formation of ICE clouds, but did not increase the chlorine activation and ozone destruction significantly. In the warm winter 2012/13 the impact of water vapour concentration on ozone loss was small, because the ozone loss was mainly NOx induced. In intermediately cold conditions, e.g. 2013/14, the effect of added water vapour was more prominent than in the other studied winters. The results show that the simulated water vapour concentration in the tropical tropopause has a significant impact on the Arctic ozone loss and deserves attention in order to improve future projections of ozone layer recovery.

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The use of SMILES data to study ozone loss in the Arctic winter 2009/2010 and comparison with Odin/SMR data using assimilation techniques

Atmospheric Chemistry and Physics ◽

10.5194/acp-14-12855-2014 ◽

2014 ◽

Vol 14 (23) ◽

pp. 12855-12869 ◽

Cited By ~ 5

Author(s):

K. Sagi ◽

D. Murtagh ◽

J. Urban ◽

H. Sagawa ◽

Y. Kasai

Keyword(s):

Ozone Depletion ◽

Transport Model ◽

Space Station ◽

Polar Vortex ◽

The Arctic ◽

Mixing Ratio ◽

Weather Forecasts ◽

Ozone Loss ◽

Medium Range ◽

Assimilation Model

Abstract. The Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on board the International Space Station observed ozone in the stratosphere with high precision from October 2009 to April 2010. Although SMILES measurements only cover latitudes from 38° S to 65° N, the combination of data assimilation methods and an isentropic advection model allows us to quantify the ozone depletion in the 2009/2010 Arctic polar winter by making use of the instability of the polar vortex in the northern hemisphere. Ozone data from both SMILES and Odin/SMR (Sub-Millimetre Radiometer) for the winter were assimilated into the Dynamical Isentropic Assimilation Model for OdiN Data (DIAMOND). DIAMOND is an off-line wind-driven transport model on isentropic surfaces. Wind data from the operational analyses of the European Centre for Medium- Range Weather Forecasts (ECMWF) were used to drive the model. In this study, particular attention is paid to the cross isentropic transport of the tracer in order to accurately assess the ozone loss. The assimilated SMILES ozone fields agree well with the limitation of noise induced variability within the SMR fields despite the limited latitude coverage of the SMILES observations. Ozone depletion has been derived by comparing the ozone field acquired by sequential assimilation with a passively transported ozone field initialized on 1 December 2009. Significant ozone loss was found in different periods and altitudes from using both SMILES and SMR data: The initial depletion occurred at the end of January below 550 K with an accumulated loss of 0.6–1.0 ppmv (approximately 20%) by 1 April. The ensuing loss started from the end of February between 575 K and 650 K. Our estimation shows that 0.8–1.3 ppmv (20–25 %) of O3 has been removed at the 600 K isentropic level by 1 April in volume mixing ratio (VMR).

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Nitrification of the lowermost stratosphere during the exceptionally cold Arctic winter 2015/16

10.5194/acp-2019-108 ◽

2019 ◽

Cited By ~ 1

Author(s):

Marleen Braun ◽

Jens-Uwe Grooß ◽

Wolfgang Woiwode ◽

Sören Johansson ◽

Michael Höpfner ◽

...

Keyword(s):

Cross Sections ◽

Large Scale ◽

Potential Temperature ◽

Lagrangian Model ◽

The Arctic ◽

Small Scale ◽

Mountain Waves ◽

Mixing Ratios ◽

Fine Structures ◽

The Impact

Abstract. The Arctic winter 2015/16 was characterized by exceptionally cold stratospheric temperatures, favouring the formation of polar stratospheric clouds (PSCs) from mid-December until the end of February down to low stratospheric altitudes. Observations by GLORIA (Gimballed Limb Observer for Radiance Imaging of the Atmosphere) on HALO (High Altitude and LOng range research aircraft) during the PGS (POLSTRACC/GW-LCYLCE II/SALSA) campaign from December 2015 to March 2016 allow an investigation of the influence of denitrification on the lowermost stratosphere (LMS) with a high spatial resolution. For the first time vertical cross-sections of nitric acid (HNO3) along the flight track and tracer-tracer correlations derived from the GLORIA observations document detailed pictures of wide-spread nitrification of the Arctic LMS during the course of an entire winter. GLORIA observations show large-scale structures and local fine structures with strongly enhanced absolute HNO3 volume mixing ratios reaching up to 11 ppbv at altitudes of 11 km in January and nitrified filaments persisting until the middle of March. Narrow streaks of enhanced HNO3, observed in mid-January, are interpreted as regions recently nitrified by sublimating HNO3-containing particles. Overall, a nitrification of the LMS between 5.0 ppbv and 7.0 ppbv at potential temperature levels between 350 and 380 K is estimated. This extent of nitrification has never been observed before in the Arctic lowermost stratosphere. The GLORIA observations are compared with CLaMS (Chemical Lagrangian Model of the Stratosphere) simulations. The fundamental structures observed by GLORIA are well reproduced, but differences in the fine structures are diagnosed. Further, CLaMS predominantly underestimates the spatial extent of maximum HNO3 mixing ratios derived from the GLORIA observations as well as the enhancement at lower altitudes. Sensitivity simulations with CLaMS including (i) enhanced sedimentation rates in case of ice supersaturation (to resemble ice nucleation on NAT), (ii) a global temperature offset, (iii) modified growth rates (to resemble aspherical particles with larger surfaces) and (iv) temperature fluctuations (to resemble the impact of small-scale mountain waves) mostly improve the agreement with the GLORIA observations. The sensitivity simulations suggest that details of particle microphysics play a significant role for simulated LMS nitrification in January, while air subsidence, transport and mixing become increasingly important towards the end of the winter.

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Ozone Chemistry during the 2002 Antarctic Vortex Split

Journal of the Atmospheric Sciences ◽

10.1175/jas-3330.1 ◽

2005 ◽

Vol 62 (3) ◽

pp. 860-870 ◽

Cited By ~ 36

Author(s):

Jens-Uwe Grooß ◽

Paul Konopka ◽

Rolf Müller

Keyword(s):

Ozone Depletion ◽

Polar Region ◽

Polar Vortex ◽

Dilution Effect ◽

Lagrangian Model ◽

Chemical Effect ◽

Small Scale ◽

Air Masses ◽

Antarctic Polar Vortex ◽

The Antarctic

Abstract In September 2002, the Antarctic polar vortex was disturbed, and it split into two parts caused by an unusually early stratospheric major warming. This study discusses the chemical consequences of this event using the Chemical Lagrangian Model of the Stratosphere (CLaMS). The chemical initialization of the simulation is based on Halogen Occultation Experiment (HALOE) measurements. Because of its Lagrangian nature, CLaMS is well suited for simulating the small-scale filaments that evolve during this period. Filaments of vortex origin in the midlatitudes were observed by HALOE several times in October 2002. The results of the simulation agree well with these HALOE observations. The simulation further indicates a very rapid chlorine deactivation that is triggered by the warming associated with the split of the vortex. Correspondingly, the ozone depletion rates in the polar vortex parts rapidly decrease to zero. Outside the polar vortex, where air masses of midlatitude origin were transported to the polar region, the simulation shows high ozone depletion rates at the 700-K level caused mainly by NOx chemistry. Owing to the major warming in September 2002, ozone-poor air masses were transported into the midlatitudes and caused a decrease of midlatitude ozone by 5%–15%, depending on altitude. Besides this dilution effect, there was no significant additional chemical effect. The net chemical ozone depletion in air masses of vortex origin was low and did not differ significantly from that of midlatitude air, in spite of the different chemical composition of the two types of air masses.

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Middle atmospheric water vapour and dynamics in the vicinity of the polar vortex during the Hygrosonde-2 campaign

Atmospheric Chemistry and Physics ◽

10.5194/acp-9-4407-2009 ◽

2009 ◽

Vol 9 (13) ◽

pp. 4407-4417 ◽

Cited By ~ 9

Author(s):

S. Lossow ◽

M. Khaplanov ◽

J. Gumbel ◽

J. Stegman ◽

G. Witt ◽

...

Keyword(s):

Water Vapour ◽

Middle Atmosphere ◽

Polar Vortex ◽

The Arctic ◽

Small Scale ◽

Air Masses ◽

Mixing Ratios ◽

Water Vapour Concentration ◽

Wind Shears

Abstract. The Hygrosonde-2 campaign took place on 16 December 2001 at Esrange/Sweden (68° N, 21° E) with the aim to investigate the small scale distribution of water vapour in the middle atmosphere in the vicinity of the Arctic polar vortex. In situ balloon and rocket-borne measurements of water vapour were performed by means of OH fluorescence hygrometry. The combined measurements yielded a high resolution water vapour profile up to an altitude of 75 km. Using the characteristic of water vapour being a dynamical tracer it was possible to directly relate the water vapour data to the location of the polar vortex edge, which separates air masses of different character inside and outside the polar vortex. The measurements probed extra-vortex air in the altitude range between 45 km and 60 km and vortex air elsewhere. Transitions between vortex and extra-vortex usually coincided with wind shears caused by gravity waves which advect air masses with different water vapour volume mixing ratios. From the combination of the results from the Hygrosonde-2 campaign and the first flight of the optical hygrometer in 1994 (Hygrosonde-1) a clear picture of the characteristic water vapour distribution inside and outside the polar vortex can be drawn. Systematic differences in the water vapour concentration between the inside and outside of the polar vortex can be observed all the way up into the mesosphere. It is also evident that in situ measurements with high spatial resolution are needed to fully account for the small-scale exchange processes in the polar winter middle atmosphere.

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