scholarly journals Characteristics of PM<sub>2.5</sub> speciation in representative megacities and across China

2011 ◽  
Vol 11 (1) ◽  
pp. 1025-1051 ◽  
Author(s):  
F. Yang ◽  
J. Tan ◽  
Q. Zhao ◽  
Z. Du ◽  
K. He ◽  
...  

Abstract. Based on PM2.5 chemical database from literature and our observations, chemical species and reconstructed speciation of PM2.5 in several representative Chinese megacities and across China were compared to draw insights into the characteristics of PM2.5 speciation. PM2.5 mass and speciation varied substantially over geographical regions in China. Near six-fold variations in average PM2.5 concentrations (34.0–193.4 μg m−3) across China were found with high PM2.5 levels (>100 μg m−3) appearing along northern region and in western urban areas. At both urban and rural sites in eastern region, sum of sulfate, nitrate, and ammonia (SNA) typically constituted 40–57% of PM2.5 mass, indicative of the regional characteristics of fine particulate pollution and more intensive "complex atmospheric pollution" compared to western region. Particulate organic matter (POM) had constant and significant contribution to PM2.5 mass. POM plus SNA accounted for 62–90% of PM2.5 mass at most of the sites. PM2.5 speciation in China was also characterized by high content of mineral dust. In four representative megacities (i.e. Beijing, Chongqing, Shanghai, and Guangzhou) with substantially higher levels of all the species except that NO3−, NH4+, and EC in PM2.5 than those in Los Angeles, distinct differences in nitrate and sulfate levels and their mass ratio [NO3−]/[SO42−] imply that mobile source is likely more important than stationary (coal combustion) source in Guangzhou whereas in Chongqing the situation is contrary. The observed intra-city variations in PM2.5 mass and speciation indicate that local emissions and regional transportation both contributed significantly to high fine particles levels in Beijing, while local contribution likely played a predominant role in Chongqing. During the ten-year period from 1999 through 2008 in urban Beijing, both SNA and [NO3−]/[SO42−] exhibited steadily increasing trends, implying that the characteristic of "complex atmospheric pollution" and the contribution from mobile sources were both being enhanced.

2011 ◽  
Vol 11 (11) ◽  
pp. 5207-5219 ◽  
Author(s):  
F. Yang ◽  
J. Tan ◽  
Q. Zhao ◽  
Z. Du ◽  
K. He ◽  
...  

Abstract. Based on PM2.5 chemical data sets from literature and from our surface observations, chemical species and reconstructed speciation of PM2.5 in representative Chinese megacities and across China were compared to draw insights into the characteristics of PM2.5 speciation. PM2.5 mass concentrations and speciation compositions varied substantially over geographical regions in China. Near six-fold variations in average PM2.5 concentrations (34.0–193.4 μg m−3) across China were found with high PM2.5 levels (>100 μg m−3) appearing in the cities in the northern and western regions and low levels (<40 μg m−3) in the remote forest area (Changbai Mountain) and in Hong Kong. The percentages of the sum of sulfate, nitrate and ammonium, organic matter, crustal material, and elemental carbon in PM2.5 mass ranged 7.1–57 %, 17.7–53 %, 7.1–43 %, and 1.3–12.8 %, respectively. At both urban and rural sites in the eastern region, the sum of sulfate, nitrate and ammonia typically constituted much higher fractions (40–57 %) of PM2.5 mass, indicative of more local formation/production and regional transport of the secondary aerosols, thus more intensive characteristic of "complex atmospheric pollution" compared to the western region. Organic matter had significant contribution to PM2.5 over all the sites. Organic matter plus sulfate, nitrate, and ammonia accounted for 53–90 % of PM2.5 mass across China. PM2.5 speciation across China was also characterized by high content of crustal material, which was usually at more than ~10 μg m−3 level or shared ~10 % of PM2.5 mass in urban areas, due to transported desert dust and locally induced dust. In four representative megacities (i.e. Beijing, Chongqing, Shanghai, and Guangzhou), PM2.5 mass and major components (except sulfate) were at higher levels than those in US continental east by one order of magnitude. Distinct differences in nitrate and sulfate levels and their mass ratio [NO3−]/[SO42−] imply that mobile sources are likely more important in Guangzhou, whereas in Chongqing it is stationary (coal combustion) sources. The observed intra-city variations in PM2.5 mass and speciation indicate that both local emissions and regional transportation contributed significantly to high fine particle loadings in Beijing, while local contribution likely played a predominant role in Chongqing. During the ten-year period from 1999 through 2008 in urban Beijing, both the sum of sulfate, nitrate, and ammonia and [NO3−]/[SO42−] ratio exhibited steadily increasing trends, implying that the characteristic of "complex atmospheric pollution" and the contribution from mobile sources were being enhanced.


Author(s):  
Ming Li ◽  
Guojun Zhang ◽  
Ying Liu ◽  
Yongwang Cao ◽  
Chunshan Zhou

China is the world’s largest developing country and its regions vary considerably. However, spatial heterogeneity in determinants of urban expansion in prefecture-level cities have not been identified. The present study explored the spatiotemporal characteristics of Chinese urban expansion and adopted a geographically weighted regression (GWR) method to determine this spatial heterogeneity. The results indicated that China experienced massive urban expansion during 1990–2015, with urban areas growing from 4.88 × 104 km2 to 1.06 × 105 km2, 46.42% of which was distributed in the eastern region. The results of the GWR model revealed the spatial heterogeneity in the determinants of urban expansion. Marketization was vital for urban expansion and had a stronger impact in the developed eastern and southern regions than in the less-developed northern and western regions. Globalization and decentralization bi-directionally affected urban expansion. The constraining effects of physical factors were limited and stronger in the developing northern region than in the developed southern region. Identifying the varying determinants of urban expansion is essential for policy-making in various regions.


Author(s):  
Irina Glinyanova ◽  
Valery Azarov ◽  
Valery Fomichev

Fine dust: (PM2.5, PM10) is a priority pollutant that contributes to the development of numerous dis-eases in urban areas. The purpose of this scientific work is to study the dispersed composition of dust parti-cles on the leaves of apricot trees (Prúnus armeníaca) in the residential zone of Volgograd. The novelty of the work lies in the study of the dispersed composition of dust particles on the leaves of apricot trees (Prúnus armeníaca) in the residential zone in the city of Volgograd near the construction industry enterprise, me-chanical engineering, leather production and railway transport line in comparison with the conditionally clean (control) zone of the SNT “Orocenets” ”(Sovetsky District, Volgograd) from the standpoint of random functions expressed by integral distribution curves of the mass of particles over their equivalent diameters. As a result of the research, the dispersed composition of dust on the leaves of apricot trees (Prúnus ar-meníaca) in the residential area of Volgograd was revealed. Fine particles were found: PM2.5, PM10 in each of the studied points, which by their values, both in their number and mass fraction, significantly exceed the data on fine dust in a conditionally clean area (control) in the SNT “Oroshanets” (Sovetsky district Volgo-grad), which creates certain environmental risks for local residents. The dispersed analysis of particles from the standpoint of random functions in the future will allow with a sufficiently high degree of accuracy to pre-dict the dust content of urban atmospheric air in the range of monthly and / or seasonal average values compared to the traditional measurement of fine dust concentration in atmospheric air of the urban environ-ment as the maximum single or daily average. At the same time, further studies of dust on the leaves of plants in an urban environment, namely, the study of the density of its sedimentation, will also reveal a group of ur-ban plants that are best suited to retain PM2.5 and PM10 on leaf plates in this region, which can significantly increase the quality of the atmospheric air of the urban environment and be of a recommendatory nature for the state-owned landscaping services of the city of Volgograd when improving the green areas of a megacity.


2020 ◽  
Vol 4 (Supplement_1) ◽  
pp. 823-824
Author(s):  
Mark Brennan-Ing ◽  
Michael Plankey ◽  
Deborah Gustafson

Abstract In 1984, the Multicenter AIDS Cohort Study (MACS) was started to identify factors in the HIV epidemic related to disease risk and treatment progression among gay, bisexual, and other men who have sex with men (MSM) in four urban areas in the US: Baltimore, MD/Washington, D.C.; Chicago, IL; Pittsburgh, PA, and Los Angeles, CA. MACS participants complete biannual study visits involving HIV testing, biometric screenings, and psychosocial data collection. In 2015 a MACS sub-study, the Understanding Patterns of Healthy Aging among MSM Project (HAMSM), was started to better understand resiliencies promoting well-being among MSM age 40 and older, including those with HIV. HAMSM has helped us to understand aging trajectories among MSM, and provides a unique combination of physiological and psychosocial data that can inform efforts to support MSM in healthy aging. This symposium will present emerging findings from the HAMSM study. Our first paper examines the relationships between psychological connection to the gay community (PSOC) and developmental regulatory strategies associated with health behaviors and more positive self-appraisals. The second paper examines how PSOC is related to HIV risk reduction behaviors, and if there are differences in such behaviors based on HIV status. Our third paper considers how self-perceptions of aging (age discrepancy, aging satisfaction) are related to frailty and frailty transitions, and if these relationships differ by HIV status. The final paper examines the relationship of social support to frailty among MSM by HIV status. Implications of these findings for research, policy, and programs targeting MSM will be discussed.


2021 ◽  
Author(s):  
Benedikt Hemmer ◽  
Christin Proß ◽  
Stanley P. Sander ◽  
Thomas J. Pongetti ◽  
Zhao-Cheng Zeng ◽  
...  

&lt;div&gt; &lt;div&gt;Precise knowledge of sources and sinks in the carbon cycle is desired to understand its sensitivity to climate change and to account and verify man-made emissions. In this context, extended sources like urban areas play an important role. While in-situ measurements of carbon dioxide (CO&lt;sub&gt;2&lt;/sub&gt;) and methane (CH&lt;sub&gt;4&lt;/sub&gt;) are highly accurate but localized, satellites measure column-integrated concentrations over an extended footprint. The CLARS-FTS [1, 2] stationed at the Mt. Wilson observatory looking downward into the Los Angeles basin has pioneered an innovative measurement technique that fills the sensitivity gap between in-situ and satellite measurements. The technique enables mapping the urban greenhouse gas concentration fields by collecting spectra of ground scattered sunlight and scanning through the region.&lt;/div&gt; &lt;div&gt;&amp;#160;&lt;/div&gt; &lt;div&gt;Here, we report on progress developing a portable setup for a CLARS-FTS-like measurement geometry. The instrument is based on the EM27/SUN FTS with a modified pointing technique and a more sensitive detector. The retrieval algorithm is based on the RemoTeC software, previously employed for solar backscatter satellite measurements. We discuss first steps in terms of instrument performance and retrieval exercises. For the latter, we have carried out simulations on how the neglect of scattering by the retrieval affects the retrieved boundary layer concentrations of CO&lt;sub&gt;2&lt;/sub&gt; and CH&lt;sub&gt;4&lt;/sub&gt; for an ensemble of hypothetical scenes with variable complexity in aeorsol loadings and viewing geometry. We also report on a test to apply RemoTeC to a small set of CLARS-FTS spectra collected throughout the Los Angeles basin.&lt;/div&gt; &lt;div&gt;&amp;#160;&lt;/div&gt; &lt;div&gt;&lt;em&gt;References&lt;/em&gt;&lt;/div&gt; &lt;div&gt;[1] Fu, D. et al., 2014: Near-infrared remote sensing of Los Angeles trace gas distributions from a mountaintop site, Atmos. Meas. Tech., 7, 713&amp;#8211;729, https://doi.org/10.5194/amt-7-713-2014&lt;/div&gt; [2] Wong, K. W. et al., 2015: Mapping CH4 : CO2 ratios in Los Angeles with CLARS-FTS from Mount Wilson, California, Atmos. Chem. Phys., 15, 241&amp;#8211;252, https://doi.org/10.5194/acp-15-241-2015&lt;/div&gt;


2016 ◽  
Vol 44 (6) ◽  
pp. 1036-1055 ◽  
Author(s):  
Andrew M Fraser ◽  
Mikhail V Chester ◽  
David Eisenman ◽  
David M Hondula ◽  
Stephanie S Pincetl ◽  
...  

Access to air conditioned space is critical for protecting urban populations from the adverse effects of heat exposure. Yet there remains fairly limited knowledge of the penetration of private (home air conditioning) and distribution of public (cooling centers and commercial space) cooled space across cities. Furthermore, the deployment of government-sponsored cooling centers is likely to be inadequately informed with respect to the location of existing cooling resources (residential air conditioning and air conditioned public space), raising questions of the equitability of access to heat refuges. We explore the distribution of private and public cooling resources and access inequities at the household level in two major US urban areas: Los Angeles County, California and Maricopa County, Arizona (whose county seat is Phoenix). We evaluate the presence of in-home air conditioning and develop a walking-based accessibility measure to air conditioned public space using a combined cumulative opportunities-gravity approach. We find significant variations in the distribution of residential air conditioning across both regions which are largely attributable to building age and inter/intra-regional climate differences. There are also regional disparities in walkable access to public cooled space. At average walking speeds, we find that official cooling centers are only accessible to a small fraction of households (3% in Los Angeles, 2% in Maricopa) while a significantly higher number of households (80% in Los Angeles, 39% in Maricopa) have access to at least one other type of public cooling resource such as a library or commercial establishment. Aggregated to a neighborhood level, we find that there are areas within each region where access to cooled space (either public or private) is limited which may increase heat-related health risks.


2010 ◽  
Vol 10 (23) ◽  
pp. 11385-11399 ◽  
Author(s):  
N. Hudda ◽  
K. Cheung ◽  
K. F. Moore ◽  
C. Sioutas

Abstract. Ultrafine Particles (UFP) can display sharp gradients in their number concentrations in urban environment due to their transient nature and rapid atmospheric processing. The ability of using air pollution data generated at a central monitoring station to assess exposure relies on our understanding of the spatial variability of a specific pollutant associated with a region. High spatial variation in the concentrations of air pollutants has been reported at scales of 10s of km for areas affected by primary emissions. Spatial variability in particle number concentrations (PNC) and size distributions needs to be investigated, as the representativeness of a monitoring station in a region is premised on the assumption of homogeneity in both of these metrics. This study was conducted at six sites, one in downtown Los Angeles and five located about 40–115 km downwind in the receptor areas of Los Angeles air basin. PNC and size distribution were measured using Condensation Particle Counters (CPC) and Scanning Mobility Particle Sizer (SMPS). The seasonal and diurnal variations of PNC implied that PNC might vary significantly with meteorological conditions, even though the general patterns at the sites may remain generally similar across the year due to consistency of sources around them. Regionally transported particulate matter (PM) from upwind urban areas of Los Angeles lowered spatial variation by acting as a "homogenizing" factor during favorable meteorological conditions. Spatial variability also increased during hours of the day during which the effects of local sources predominate. The spatial variability associated with PNC (quantified using Coefficients of Divergence, CODs), averaged about 0.3, which was generally lower than that based on specific size ranges. Results showed an inverse relationship of COD with particles size, with fairly uniform values in the particle range which is associated with regional transport. Our results suggest that spatial variability, even in the receptor regions of Los Angeles Basin, should be assessed for both PNC and size distributions, and should be interpreted in context of seasonal and diurnal influences, and suitably factored if values for exposure are ascertained using a central monitoring station.


2016 ◽  
Author(s):  
Jia Chen ◽  
Camille Viatte ◽  
Jacob K. Hedelius ◽  
Taylor Jones ◽  
Jonathan E. Franklin ◽  
...  

Abstract. We demonstrate the use of compact solar-tracking Fourier transform spectrometers (Bruker EM27/SUN) for differential measurements of the column-averaged dry-air mole fractions of CH4 and CO2 within urban areas. Using Allan variance analysis, we show that the differential column measurement has a precision of 0.1 ‰ for XCO2 and XCH4 using an optimum integration time of 10 min, which corresponds to standard deviations of 0.04 ppm, and 0.2 ppb, respectively. The sensor system is very stable over time and after relocation across the continent. We report tests of the differential column measurement, and its sensitivity to emission sources, by measuring the downwind minus upwind column gradient ΔXCH4 across dairy farms in the Chino California area and using the data to verify emissions reported in the literature. Spatial column gradient ratios ΔXCH4/ΔXCO2 were observed across Pasadena within the Los Angeles basin, indicating values consistent with regional emission ratios from the literature. Our precise, rapid measurements allow us to determine significant short-term variations (5–10 minutes) of ΔXCO2 and ΔXCH4, and to show that they represent atmospheric phenomena. Overall, this study helps establish a range of new applications for compact solar-viewing Fourier transform spectrometers. By accurately measuring the small differences in integrated column amounts across local and regional sources, we directly observe the mass loading of the atmosphere due to the influence of emissions in the intervening locale. The inference of the source strength is much more direct than inversion modeling using only surface concentrations, and less subject to errors associated with small-scale transport phenomena.


Author(s):  
Mohamed Fazil Mohamed Firdhous ◽  
B. H. Sudantha ◽  
Naseer Ali Hussien

Vehicular traffic has increased across all over the world especially in urban areas due to many reasons including the reduction in the cost of vehicles, degradation of the quality of public transport services and increased wealth of people. The traffic congestion created by these vehicles causes many problems. Increased environment pollution is one of the most serious negative effects of traffic congestion. Noxious gases and fine particles emitted by vehicles affect people in different ways depending on their age and present health conditions. Professionals and policy makers have devised schemes for better managing traffic in congested areas. These schemes suffer from many shortcomings including the inability to adapt to dynamic changes of traffic patterns. With the development of technology, new applications like Google maps help drivers to select less congested routes. But, the identification of the best route takes only the present traffic condition on different road segments presently. In this paper the authors propose a system that helps drivers select routes based on the present and expected environment pollution levels at critical points in a given area.


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