scholarly journals Counting on chemistry: laboratory evaluation of seed-material-dependent detection efficiencies of ultrafine condensation particle counters

2020 ◽  
Vol 13 (7) ◽  
pp. 3787-3798
Author(s):  
Peter Josef Wlasits ◽  
Dominik Stolzenburg ◽  
Christian Tauber ◽  
Sophia Brilke ◽  
Sebastian Harald Schmitt ◽  
...  
Keyword(s):  
Chemistry Laboratory ◽  
Laboratory Evaluation ◽  
Working Fluid ◽  
Seed Particle ◽  
Chemical Interactions ◽  
Particle Detectors ◽  
Working Fluids ◽  
Seed Particles ◽  
Materials Used ◽  
Theoretical Simulations

Abstract. Condensation particle counters (CPCs) are crucial instruments for detecting sub-10 nm aerosol particles. Understanding the detection performance of a CPC requires thorough characterization under well-controlled laboratory conditions. Besides the size of the seed particles, chemical interactions between the working fluid and the seed particles also influence the activation efficiencies. However, common seed particle materials used for CPC characterizations are not chosen with respect to chemical interactions with vapor molecules of the working fluid by default. Here, we present experiments on the influence of the seed particle material on the detection efficiencies and the 50 % cutoff diameters of commonly used CPCs for the detection of sub-10 nm particles. A remarkable set consisting of six different and commercially available particle detectors, including the newly developed TSI V-WCPC 3789 and a tuned TSI 3776, was tested. The corresponding working fluids of the instruments are n-butanol, diethylene glycol and water. Among other materials we were able to measure detection efficiencies with nanometer-sized organic seed particles reproducibly generated by the oxidation of β-caryophyllene vapor in a flow tube. Theoretical simulations of supersaturation profiles in the condensers were successfully related to measured detection efficiencies. Our results demonstrate the importance of chemical similarities between seed particles and the working fluids used when CPCs are characterized. We anticipate our study to contribute to a deeper understanding of chemical interactions during heterogeneous nucleation processes.

scholarly journals Counting on Chemistry: Laboratory Evaluation of Seed Material-Dependent Detection Efficiencies of Ultrafine Condensation Particle Counters

2020 ◽  
Author(s):  
Peter Josef Wlasits ◽  
Dominik Stolzenburg ◽  
Christian Tauber ◽  
Sophia Brilke ◽  
Sebastian Harald Schmitt ◽  
...  
Keyword(s):  
Chemistry Laboratory ◽  
Laboratory Evaluation ◽  
Working Fluid ◽  
Seed Particle ◽  
Chemical Interactions ◽  
Particle Detectors ◽  
Working Fluids ◽  
Seed Particles ◽  
Materials Used ◽  
Theoretical Simulations

Abstract. Condensation Particle Counters (CPCs) are crucial instruments for detecting sub-10 nm aerosol particles. Understanding the detection performance of a CPC requires thorough characterization under well-controlled laboratory conditions. Besides the size of the seed particles, chemical interactions between the working fluid and the seed particles also influence the activation efficiencies. However, common seed particle materials used for CPC characterizations are not chosen in respect of chemical interactions with 5 vapor molecules of the working fluid by default. Here, we present experiments on the influence of the seed particle material on the detection efficiencies and the 50 % cut-off diameters of commonly used CPCs for the detection of sub-10 nm particles. A remarkable set consisting of six different and commercially available particle detectors, including the newly-developed TSI V-WCPC 3789 and a tuned TSI 3776, was tested. The corresponding working fluids of the instruments are n-butanol, diethylene glycol and water. Among other materials we were able to measure detection efficiencies with 10 nanometer-sized organic seed particles reproducibly generated by oxidation of β-caryophyllene vapor in a flow tube. Theoretical simulations of supersaturation profiles in the condensers were successfully related to measured detection efficiencies. Our results demonstrate the importance of chemical similarities between seed particles and the used working fluids when CPCs are characterized. We anticipate our study to contribute to a deeper understanding of chemical interactions during heterogeneous nucleation processes.

Performance Analysis and Comparison Study of Transcritical Power Cycles Using CO2-Based Mixtures as Working Fluids

2016 ◽  
Author(s):  
Jiaxi Xia ◽  
Jiangfeng Wang ◽  
Pan Zhao ◽  
Dai Yiping
Keyword(s):  
Critical Temperature ◽  
Parametric Optimization ◽  
Design Parameters ◽  
Working Fluid ◽  
Comparison Study ◽  
Software Environment ◽  
Working Fluids ◽  
Power Cycles ◽  
Power Cycle ◽  
Thermodynamic Performance

CO2 in a transcritical CO2 cycle can not easily be condensed due to its low critical temperature (304.15K). In order to increase the critical temperature of working fluid, an effective method is to blend CO2 with other refrigerants to achieve a higher critical temperature. In this study, a transcritical power cycle using CO2-based mixtures which blend CO2 with other refrigerants as working fluids is investigated under heat source. Mathematical models are established to simulate the transcritical power cycle using different CO2-based mixtures under MATLAB® software environment. A parametric analysis is conducted under steady-state conditions for different CO2-based mixtures. In addition, a parametric optimization is carried out to obtain the optimal design parameters, and the comparisons of the transcritical power cycle using different CO2-based mixtures and pure CO2 are conducted. The results show that a raise in critical temperature can be achieved by using CO2-based mixtures, and CO2-based mixtures with R32 and R22 can also obtain better thermodynamic performance than pure CO2 in transcritical power cycle. What’s more, the condenser area needed by CO2-based mixture is smaller than pure CO2.

Multi-Fluid Gas Turbine Components Scaling for a Generation IV Nuclear Power Plant Performance Simulation

2018 ◽  
Author(s):  
Emmanuel O. Osigwe ◽  
Arnold Gad-Briggs ◽  
Theoklis Nikolaidis ◽  
Pericles Pilidis ◽  
Suresh Sampath
Keyword(s):  
Power Plant ◽  
Nuclear Power Plant ◽  
Gas Turbine ◽  
Nuclear Power ◽  
Working Fluid ◽  
Simulation Tool ◽  
Closed Cycle ◽  
Performance Simulation ◽  
Working Fluids ◽  
Component Map

One major challenge to the accurate development of performance simulation tool for component-based nuclear power plant engine models is the difficulty in accessing component performance maps; hence, researchers or engineers often rely on estimation approach using various scaling techniques. This paper describes a multi-fluid scaling approach used to determine the component characteristics of a closed-cycle gas turbine plant from an existing component map with their design data, which can be applied for different working fluids as may be required in closed-cycle gas turbine operations to adapt data from one component map into a new component map. Each component operation is defined by an appropriate change of state equations which describes its thermodynamic behavior, thus, a consideration of the working fluid properties is of high relevance to the scaling approach. The multi-fluid scaling technique described in this paper was used to develop a computer simulation tool called GT-ACYSS, which can be valuable for analyzing the performance of closed-cycle gas turbine operations with different working fluids. This approach makes it easy to theoretically scale existing map using similar or different working fluids without carrying out a full experimental test or repeating the whole design and development process. The results of selected case studies show a reasonable agreement with available data.

An experimental evaluation of R11 as a heat pump working fluid in comparison with some other working fluids

1983 ◽  
Vol 7 (2) ◽  
pp. 129-135
Author(s):  
S. E. Ogbeide ◽  
S. A. K. El-Meniawy ◽  
S. Devotta ◽  
F. A. Watson ◽  
F. A. Holland
Keyword(s):  
Heat Pump ◽  
Experimental Evaluation ◽  
Working Fluid ◽  
Working Fluids

scholarly journals The Influence of Loop Heat Pipe Evaporator Porous Structure Parameters and Charge on Its Effectiveness for Ethanol and Water as Working Fluids

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7029
Author(s):  
Krzysztof Blauciak ◽  
Pawel Szymanski ◽  
Dariusz Mikielewicz
Keyword(s):  
Porous Structure ◽  
Pore Size ◽  
Heat Pipe ◽  
Capillary Pressure ◽  
Pressure Difference ◽  
Working Fluid ◽  
Loop Heat Pipe ◽  
Working Fluids ◽  
Integral Characteristics ◽  
Sintered Stainless Steel

This paper presents the results of experiments carried out on a specially designed experimental rig designed for the study of capillary pressure generated in the Loop Heat Pipe (LHP) evaporator. The commercially available porous structure made of sintered stainless steel constitutes the wick. Three different geometries of the porous wicks were tested, featuring the pore radius of 1, 3 and 7 µm. Ethanol and water as two different working fluids were tested at three different evaporator temperatures and three different installation charges. The paper firstly presents distributions of generated pressure in the LHP, indicating that the capillary pressure difference is generated in the porous structure. When installing with a wick that has a pore size of 1 μm and water as a working fluid, the pressure difference can reach up to 2.5 kPa at the installation charge of 65 mL. When installing with a wick that has a pore size of 1 μm and ethanol as a working fluid, the pressure difference can reach up to 2.1 kPa at the installation charge of 65 mL. The integral characteristics of the LHP were developed, namely, the mass flow rate vs. applied heat flux for both fluids. The results show that water offers larger pressure differences for developing the capillary pressure effect in the installation in comparison to ethanol. Additionally, this research presents the feasibility of manufacturing inexpensive LHPs with filter medium as a wick material and its influence on the LHP’s thermal performance.

Converting Low-Grade Heat Into Power Using a Supercritical Rankine Cycle With Zeotropic Mixture Working Fluid

2010 ◽  
Author(s):  
Huijuan Chen ◽  
D. Yogi Goswami ◽  
Muhammad M. Rahman ◽  
Elias K. Stefanakos
Keyword(s):  
Rankine Cycle ◽  
Phase Region ◽  
Working Fluid ◽  
Condensation Process ◽  
Heating Process ◽  
Low Grade ◽  
Two Phase ◽  
Working Fluids ◽  
Zeotropic Mixture ◽  
Low Grade Heat

A supercritical Rankine cycle using zeotropic mixture working fluids for the conversion of low-grade heat into power is proposed and analyzed in this paper. A supercritical Rankine cycle does not go through two-phase region during the heating process. By adopting zeotropic mixtures as the working fluids, the condensation process happens non-isothermally. Both of the features create a potential in reducing the irreversibility and improving the system efficiency. A comparative study between an organic Rankine cycle and the proposed supercritical Rankine cycle shows that the proposed cycle improves the cycle thermal efficiency, exergy efficiency of the heating and the condensation processes, and the system overall efficiency.

Three Dimensional Dynamic Analysis of a Piezoelectric Valveless Micropump: Effects of Working Fluid

2012 ◽  
Author(s):  
Ersin Sayar ◽  
Bakhtier Farouk
Keyword(s):  
Fluid Flow ◽  
Flow Analysis ◽  
Three Dimensional ◽  
Piezoelectric Element ◽  
Working Fluid ◽  
Working Fluids ◽  
Valveless Micropump ◽  
Velocity Flow ◽  
Layer Membrane ◽  
Fluid Flow Analysis

Coupled structural and fluid flow analysis of a piezoelectric valveless micropump is carried out for liquid transport applications. The valveless micropump consists of trapezoidal prism inlet/outlet elements; the pump chamber, a thin structural layer (Pyrex glass) and a piezoelectric element (PZT-5A), as the actuator. Two-way coupling of forces and displacements between the solid and the liquid domains in the systems are considered where actuator deflection and motion causes fluid flow and vice-versa. Flow contraction and expansion (through the trapezoidal prism inlet and outlet respectively) generates net fluid flow. The pressure, velocity, flow rate and pump membrane deflections of the micropump are investigated for six different working fluids (acetone, methanol, ethanol, water, and two hypothetical fluids). For the compressible flow formulation, an isothermal equation of state for the working fluid is employed. Three-dimensional governing equations for the flow fields and the structural-piezoelectric bi-layer membrane motions are considered. Comparison of the pumping characteristics of the micropumps operating with different working fluids can be utilized to optimize the design of MEMS based micropumps in drug delivery and biomedical applications.

Heat Transport Characteristics in Closed Loop Oscillating Heat Pipes

2005 ◽  
Author(s):  
Shuangfeng Wang ◽  
Shigefumi Nishio
Keyword(s):  
Heat Pipe ◽  
Heat Transport ◽  
Closed Loop ◽  
Flow Behavior ◽  
Working Fluid ◽  
Liquid Volume ◽  
High Heat Flux ◽  
Two Phase ◽  
Working Fluids ◽  
Inner Diameter

Heat transport rates of micro scale SEMOS (Self-Exciting Mode Oscillating) heat pipe with inner diameter of 1.5mm, 1.2mm and 0.9mm, were investigated by using R141b, ethanol and water as working fluids. The effects of inner diameter, liquid volume faction, and material properties of the working fluids are examined. It shows that the smaller the inner diameter, the higher the thermal transport density is. For removing high heat flux, the water is the most promising working fluid as it has the largest critical heat transfer rate and the widest operating range among the three kinds of working fluids. A one-dimensional numerical simulation is carried out to describe the heat transport characteristics and the two-phase flow behavior in the closed loop SEMOS heat pipe. The numerical prediction agrees with the experimental results fairly well, when the input heat through was not very high and the flow pattern was slug flow.   This paper was also originally published as part of the Proceedings of the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems.

Power Recovery From Gas Turbines: A Review of the Limitations, and an Evaluation of the Use of “Organic” Working Fluids

1970 ◽  
Author(s):  
Stephen Luchter
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Waste Heat ◽  
Power Level ◽  
Working Fluid ◽  
Working Fluids ◽  
Valuable Source ◽  
Power Recovery

Gas-turbine waste heat appears to be a valuable source of energy, yet the number of installations in which this energy is utilized is minimal. The reasons for this are reviewed and a typical nonafterburning cycle is examined for both steam and an “organic” working fluid. The power level range over which each is attractive is obtained, and the costs of each are compared on a relative basis.

Heat Transfer Analysis of Regenerative Thermo-Mechanical Refrigeration System

2020 ◽  
Author(s):  
Ahmad K. Sleiti ◽  
Mohammed Al-Khawaja
Keyword(s):  
Environmental Effects ◽  
Power Efficiency ◽  
Power Plants ◽  
Internal Combustion Engines ◽  
Waste Heat ◽  
Heat Transfer Analysis ◽  
Working Fluid ◽  
Refrigeration System ◽  
Renewable Energy Resources ◽  
Working Fluids

Abstract Refrigeration systems contribute to the critical environmental concerns including global warming and ozone depletion. It is necessary to develop new systems that use renewable energy resources and waste heat to perform the cooling function with eco-friendly working fluids. This improves the energy efficiency of the power systems and minimizes the harmful effects of conventional refrigeration systems. This paper introduces an analysis of a regenerative thermo-mechanical refrigeration system that is powered with renewable heat sources (solar, geothermal) or waste heat (from internal combustion engines, gas power plants, and steam power plants). The system operates at the supercritical conditions of the working fluids. The performance of the system is evaluated based on power efficiency, the COP, and the expander-compressor diameters. Also, a number of working fluids were compared with each other based on their performance and environmental effects. There is a trade-off between high-performance fluids and their environmental effects. Using R32 as a working fluid at Th = 150 °C and Tc1 = 40 °C, the system produces a cooling capacity of 1 kW with power efficiency of 10.23%, expander diameter of 53.12 mm and compressor diameter of 75.4mm. The regenerator increases the power efficiency by about 1%. However, the size of the regenerator is small (Dr = 6.5 mm, Lr = 142 mm].

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