scholarly journals Local artifacts in ice core methane records caused by layered bubble trapping and in-situ production: a multi-site investigation

2016 ◽  
Author(s):  
R. H. Rhodes ◽  
X. Faïn ◽  
E. J. Brook ◽  
J. R. McConnell ◽  
O. J. Maselli ◽  
...  
Keyword(s):  
Transport Model ◽  
Accumulation Rate ◽  
Ice Core ◽  
Ice Cores ◽  
Analytical Techniques ◽  
Site Investigation ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Bubble Trapping

Abstract. Superimposed on the coherent and major atmospheric changes in trace gases revealed by ice core records, local high frequency, non-atmospheric features can now be resolved due to improvement s in resolution and precision of analytical techniques. These are signals that could not have survived the low-pass filter effect that firn diffusion exerts on the atmospheric history and therefore do not result from changes in the composition of the atmosphere at the surface of the ice sheet. Using continuous methane (CH4) records obtained from five polar ice cores, we characterize these non-atmospheric signals and explore their origin. Isolated samples, enriched in CH4 in the Tunu13 (Greenland) record are linked to the presence of melt layers. Melting can enrich the methane concentration due to preferential dissolution of methane relative to nitrogen, but we find that an additional in-situ process is required to generate the full magnitude of these anomalies. Furthermore, in the all ice cores studied there is evidence of reproducible, decimetre-scale CH4 variability. Through a series of tests, we demonstrate that this sign al is an artifact of layered bubble trapping in a heterogeneous-density firn column; we term this phenomenon ‘trapping noise’. The magnitude of CH4 trapping noise increases with atmospheric CH4 growth rate and seasonality of density contrasts, and decreases with accumulation rate. Firn air transport model simulations, accounting for layered bubble trapping, are in agreement with our empirical data. Significant annual periodicity is present in the CH4 variability of two Greenland ice cores, suggesting that layered gas trapping at these sites is controlled by regular, seasonal variations in the physical properties of the firn.

scholarly journals Local artifacts in ice core methane records caused by layered bubble trapping and in situ production: a multi-site investigation

2016 ◽  
Vol 12 (4) ◽  
pp. 1061-1077 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xavier Faïn ◽  
Edward J. Brook ◽  
Joseph R. McConnell ◽  
Olivia J. Maselli ◽  
...  
Keyword(s):  
Growth Rate ◽  
High Frequency ◽  
Ice Core ◽  
Ice Cores ◽  
Gas Diffusion ◽  
Atmospheric Composition ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Bubble Trapping

Abstract. Advances in trace gas analysis allow localised, non-atmospheric features to be resolved in ice cores, superimposed on the coherent atmospheric signal. These high-frequency signals could not have survived the low-pass filter effect that gas diffusion in the firn exerts on the atmospheric history and therefore do not result from changes in the atmospheric composition at the ice sheet surface. Using continuous methane (CH4) records obtained from five polar ice cores, we characterise these non-atmospheric signals and explore their origin. Isolated samples, enriched in CH4 in the Tunu13 (Greenland) record are linked to the presence of melt layers. Melting can enrich the methane concentration due to a solubility effect, but we find that an additional in situ process is required to generate the full magnitude of these anomalies. Furthermore, in all the ice cores studied there is evidence of reproducible, decimetre-scale CH4 variability. Through a series of tests, we demonstrate that this is an artifact of layered bubble trapping in a heterogeneous-density firn column; we use the term “trapping signal” for this phenomenon. The peak-to-peak amplitude of the trapping signal is typically 5 ppb, but may exceed 40 ppb. Signal magnitude increases with atmospheric CH4 growth rate and seasonal density contrast, and decreases with accumulation rate. Significant annual periodicity is present in the CH4 variability of two Greenland ice cores, suggesting that layered gas trapping at these sites is controlled by regular, seasonal variations in the physical properties of the firn. Future analytical campaigns should anticipate high-frequency artifacts at high-melt ice core sites or during time periods with high atmospheric CH4 growth rate in order to avoid misinterpretation of such features as past changes in atmospheric composition.

scholarly journals Isotope Climatic Record Over The Last 2.5 KA from Dome C, Antarctica, Ice cores

1982 ◽  
Vol 3 ◽  
pp. 17-22 ◽  
Author(s):  
J. P. Benoist ◽  
J. Jouzel ◽  
C. Lorius ◽  
L. Merlivat ◽  
M. Pourchet
Keyword(s):  
Isotope Composition ◽  
Accumulation Rate ◽  
Maximum Amplitude ◽  
Ice Cores ◽  
Ice Age ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Temperature Changes ◽  
Low Pass ◽  
Climatic Record

Data on climatic changes over thousands of years is needed for a better understanding of the shorter term variations which are of interest to man. For this purpose we measured the isotope composition (δD‰) of two adjacent ice cores drilled in the Dome C area. The time scale was established using the remarkably constant mean annual accumulation rate (37 kg m−2) determined by various techniques. The detailed isotope records were smoothed to filter out the δ value fluctuations not directly related to local temperature changes. With respect to conditions over the last 2.5 ka, the combined smoothed δ curve indicates a cooler climate from about 1800 to 1200 AD and a slightly warmer period from about 1200 to 700 AD. These periods may well correspond to the suggested world-wide Little Ice Age and medieval warm phase. Using the present δD‰/T°C measured at the surface, the maximum amplitude for these two periods, after smoothing with a low pass filter of 512 a, is approximately -0.35 and +0.3°C, respectively.

scholarly journals Climatic information archived in ice cores: impact of intermittency and diffusion on the recorded isotopic signal in Antarctica

2019 ◽  
Author(s):  
Mathieu Casado ◽  
Thomas Münch ◽  
Thomas Laepple
Keyword(s):  
Time Scales ◽  
Signal To Noise Ratio ◽  
Ice Core ◽  
Ice Cores ◽  
Reanalysis Data ◽  
Climatic Conditions ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Frequency Changes ◽  
Isotopic Signal

Abstract. The isotopic signal (δ18O and δD) imprinted in ice cores from Antarctica is not solely generated by the temperature sensitivity of the isotopic composition of precipitation but also contains the signature of the intermittency of precipitation patterns as well as of post-deposition processes occurring at the surface and in the firn. This leads to a proxy signal recorded by the ice cores that may not be representative of the local climatic variations. Due to precipitation intermittency, the ice cores only record brief snapshots of the climatic conditions, resulting in aliasing of the climatic signal, and thus a large amount of noise which reduces the minimum temporal resolution at which a meaningful signal can be retrieved. The analyses are further complicated by isotopic diffusion which acts as a low pass filter that dampens any high frequency changes. Here, we use reanalysis data (ERA-Interim) combined with satellite products of accumulation to evaluate the spatial distribution of the transfer function that describes the formation of the isotopic signal across Antarctica. The minimum time scales at which the signal-to-noise ratio exceeds unity range from less than a year at the coast to a thousand years further inland. Based on solely physical processes, we were thus able to define a lower bound for the time scales at which climate variability can be reconstructed from ice core water isotopic compositions.

scholarly journals Isotope Climatic Record Over The Last 2.5 KA from Dome C, Antarctica, Ice cores

1982 ◽  
Vol 3 ◽  
pp. 17-22 ◽  
Author(s):  
J. P. Benoist ◽  
J. Jouzel ◽  
C. Lorius ◽  
L. Merlivat ◽  
M. Pourchet
Keyword(s):  
Isotope Composition ◽  
Accumulation Rate ◽  
Maximum Amplitude ◽  
Ice Cores ◽  
Ice Age ◽  
Pass Filter ◽  
Low Pass Filter ◽  
Temperature Changes ◽  
Low Pass ◽  
Climatic Record

Data on climatic changes over thousands of years is needed for a better understanding of the shorter term variations which are of interest to man. For this purpose we measured the isotope composition (δD‰) of two adjacent ice cores drilled in the Dome C area. The time scale was established using the remarkably constant mean annual accumulation rate (37 kg m−2) determined by various techniques. The detailed isotope records were smoothed to filter out the δ value fluctuations not directly related to local temperature changes. With respect to conditions over the last 2.5 ka, the combined smoothed δ curve indicates a cooler climate from about 1800 to 1200 AD and a slightly warmer period from about 1200 to 700 AD. These periods may well correspond to the suggested world-wide Little Ice Age and medieval warm phase. Using the present δD‰/T°C measured at the surface, the maximum amplitude for these two periods, after smoothing with a low pass filter of 512 a, is approximately -0.35 and +0.3°C, respectively.

scholarly journals Glacial–interglacial dynamics of Antarctic firn columns: comparison between simulations and ice core air-δ<sup>15</sup>N measurements

2013 ◽  
Vol 9 (3) ◽  
pp. 983-999 ◽  
Author(s):  
E. Capron ◽  
A. Landais ◽  
D. Buiron ◽  
A. Cauquoin ◽  
J. Chappellaz ◽  
...  
Keyword(s):  
Accumulation Rate ◽  
Ice Core ◽  
Ice Cores ◽  
Detailed Comparison ◽  
Last Deglaciation ◽  
Depth Study ◽  
Dronning Maud Land ◽  
The Last Deglaciation ◽  
Correct Estimation ◽  
Lock In

Abstract. Correct estimation of the firn lock-in depth is essential for correctly linking gas and ice chronologies in ice core studies. Here, two approaches to constrain the firn depth evolution in Antarctica are presented over the last deglaciation: outputs of a firn densification model, and measurements of δ15N of N2 in air trapped in ice core, assuming that δ15N is only affected by gravitational fractionation in the firn column. Since the firn densification process is largely governed by surface temperature and accumulation rate, we have investigated four ice cores drilled in coastal (Berkner Island, BI, and James Ross Island, JRI) and semi-coastal (TALDICE and EPICA Dronning Maud Land, EDML) Antarctic regions. Combined with available ice core air-δ15N measurements from the EPICA Dome C (EDC) site, the studied regions encompass a large range of surface accumulation rates and temperature conditions. Our δ15N profiles reveal a heterogeneous response of the firn structure to glacial–interglacial climatic changes. While firn densification simulations correctly predict TALDICE δ15N variations, they systematically fail to capture the large millennial-scale δ15N variations measured at BI and the δ15N glacial levels measured at JRI and EDML – a mismatch previously reported for central East Antarctic ice cores. New constraints of the EDML gas–ice depth offset during the Laschamp event (~41 ka) and the last deglaciation do not favour the hypothesis of a large convective zone within the firn as the explanation of the glacial firn model–δ15N data mismatch for this site. While we could not conduct an in-depth study of the influence of impurities in snow for firnification from the existing datasets, our detailed comparison between the δ15N profiles and firn model simulations under different temperature and accumulation rate scenarios suggests that the role of accumulation rate may have been underestimated in the current description of firnification models.

scholarly journals High-resolution mineral dust and sea ice proxy records from the Talos Dome ice core

2013 ◽  
Vol 9 (6) ◽  
pp. 2789-2807 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
P. R. Kaufmann ◽  
S. Albani ◽  
C. Barbante ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Sea Ice ◽  
Ross Sea ◽  
Transport Model ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
Last Interglacial ◽  
The Holocene ◽  
Proxy Records

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

scholarly journals What could have caused pre-industrial biomass burning emissions to exceed current rates?

2013 ◽  
Vol 9 (1) ◽  
pp. 289-306 ◽  
Author(s):  
G. R. van der Werf ◽  
W. Peters ◽  
T. T. van Leeuwen ◽  
L. Giglio
Keyword(s):  
Population Density ◽  
Biomass Burning ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Fire Emissions ◽  
Core Data ◽  
Mixing Ratios ◽  
The Past ◽  
Co Concentrations

Abstract. Recent studies based on trace gas mixing ratios in ice cores and charcoal data indicate that biomass burning emissions over the past millennium exceeded contemporary emissions by up to a factor of 4 for certain time periods. This is surprising because various sources of biomass burning are linked with population density, which has increased over the past centuries. We have analysed how emissions from several landscape biomass burning sources could have fluctuated to yield emissions that are in correspondence with recent results based on ice core mixing ratios of carbon monoxide (CO) and its isotopic signature measured at South Pole station (SPO). Based on estimates of contemporary landscape fire emissions and the TM5 chemical transport model driven by present-day atmospheric transport and OH concentrations, we found that CO mixing ratios at SPO are more sensitive to emissions from South America and Australia than from Africa, and are relatively insensitive to emissions from the Northern Hemisphere. We then explored how various landscape biomass burning sources may have varied over the past centuries and what the resulting emissions and corresponding CO mixing ratio at SPO would be, using population density variations to reconstruct sources driven by humans (e.g., fuelwood burning) and a new model to relate savanna emissions to changes in fire return times. We found that to match the observed ice core CO data, all savannas in the Southern Hemisphere had to burn annually, or bi-annually in combination with deforestation and slash and burn agriculture exceeding current levels, despite much lower population densities and lack of machinery to aid the deforestation process. While possible, these scenarios are unlikely and in conflict with current literature. However, we do show the large potential for increased emissions from savannas in a pre-industrial world. This is mainly because in the past, fuel beds were probably less fragmented compared to the current situation; satellite data indicates that the majority of savannas have not burned in the past 10 yr, even in Africa, which is considered "the burning continent". Although we have not considered increased charcoal burning or changes in OH concentrations as potential causes for the elevated CO concentrations found at SPO, it is unlikely they can explain the large increase found in the CO concentrations in ice core data. Confirmation of the CO ice core data would therefore call for radical new thinking about causes of variable global fire rates over recent centuries.

scholarly journals New evidence for enhanced cosmogenic isotope production rate in the atmosphere ∼37 ka BP

1999 ◽  
Vol 29 ◽  
pp. 136-140
Author(s):  
Wang Ninglian ◽  
Yao Tandong ◽  
Qin Dahe ◽  
L. G. Thompson ◽  
E. Mosley-Thompson ◽  
...  
Keyword(s):  
Accumulation Rate ◽  
Ice Core ◽  
Ice Cores ◽  
Isotope Production ◽  
Cosmogenic Isotopes ◽  
Cosmogenic Isotope ◽  
Global Event ◽  
Guliya Ice Core ◽  
New Evidence ◽  
Rate Comparison

AbstractA 36C1 peak has been found at about 37 ka BP in the Guliya ice core, drilled from the Qinghai-Tibetan Plateau. This peak is indicative of enhanced cosmogenic isotope production in the atmosphere, rather than a change in accumulation rate. Comparison with the records of 10Be and 36C1 in ice cores from Antarctica and Greenland indicates that peaks of the cosmogenic isotopes are global, and that they can be used as time markers for dating ice cores. Interestingly, the 37 ka BP global event coincided with a cold period.

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