Podiform and stratiform chromitite with PGE in Paleoproterozoic (2.1 Ga) Pados-Tundra ultramafic (ophiolite) complex (N-E part of the Fennoscandian Shield, Arctic region)

2020 ◽  
Author(s):  
Tamara Bayanova ◽  
Serov Pavel ◽  
Kunakkuzin Evgeniy ◽  
Steshenko Ekaterina ◽  
Borisenko Elena
Keyword(s):  
Arctic Region ◽  
Fennoscandian Shield ◽  
Ultramafic Rocks ◽  
Chromian Spinel ◽  
Ophiolite Complex ◽  
Enriched Mantle ◽  
Ultramafic Complex ◽  
Magma Sources ◽  
Podiform Chromitites ◽  
Research Contract

<p>Pados-Tundra ultramafic complex belong to Serpentinite belt in the northern Fennoscandian Shield and composed of dunite-harzburgite-orthopyroxenite with 7 rhythms and 4 Cr layers. The associated massif named as Malyi Pados are considered as a satellite intrusion (Mamontov, Dokuchaeva, 2005) or dislocated block detached according by (Barkov et al., 2016). Nevertheless the complex includes of Dunite Zone with podiform and stratiform chromitite with Ir subgroup PGE (Ru, Os, Ir – IPGE) and associated with chromian spinel in ophiolite (Joban, 2006). Fiestly unusual microtextures and mineralogical features with clinochlore, laurite and native Ru was found (Barkov et al., 2017).</p><p>Isotope U-Pb data on baddeleyite in core of zircon from mafic gabbronorite rocks of the Malyi Pados gave 2083±7 Ma and are coeval to ages of Cu-Ni Pechenga (1980 Ma) and PGE Bushveld deposits. Notably are measured new U-Pb ages with 2087±3 Ma for baddeleyite and metamorphic rutile with 1804±10 Ma from hornblendite dyke which are cutted ultramafic rocks of the Pados-Tundra complex.</p><p>New Sm-Nd mapping data for the main rocks of the complex are reflected model T<sub>DM</sub> ages of primary protolith from 2.78 Ga to 2.36 Ga and 3.13 Ga for host rock with positive εNd values from +2.7 to +2.1. New Sm-Nd investigations to podiform chromitites of the Pados-Tundra complex are similar to Sopcheozerskoe Cr-deposit (Dunite Block) of the Monchegorsk ore region with positive εNd and young protolith ages about 2.7 Ga for primary magma sources instead of Paleoproterozoic Co-Cu-Ni and PGE layered intrusions of the Fennoscandian Shield with 2.4 Ga to 2.5 Ga for origin and 3.2 - 3.5 Ga of the protolith EM-1 enriched mantle plume reservoir (Bayanova et al., 2009, 2014, 2018). All new U-Pb on baddeleyite and Sm-Nd studies to whole rocks of the Pados-Tundra complex infer about ophiolite (spreading or oceanization of the crust) and presence diamond in podiform chromitites according to new highlights of (Ballhause et al., 2017).</p><p>All investigations are supported by RFBR 18-05-70082 (Arctic resources), 18-35-00152, 18-35-00246, Scientific Research Contract N0.0226-2019-0053 and Program of Presidium RAS 8.48.</p>

Sources of placer platinum in Yukon: provenance study from detrital minerals

2008 ◽  
Vol 45 (8) ◽  
pp. 879-896 ◽  
Author(s):  
Yana Fedortchouk ◽  
William LeBarge
Keyword(s):  
Unknown Origin ◽  
Heavy Mineral ◽  
Source Rocks ◽  
Ultramafic Rocks ◽  
Chromian Spinel ◽  
Mafic Intrusions ◽  
Platinum Group Minerals ◽  
Mineral Sample ◽  
Back Arc ◽  
Ocean Ridge

Source rocks for the platinum group minerals (PGM), historically reported in a number of Yukon placers, remain either unknown or poorly understood. A study of heavy-mineral samples from five creeks draining bedrock in west and central Yukon was undertaken to confirm the presence of placer platinum, to determine which mafic–ultramafic rock is the source of PGM in Kluane area, southern Yukon, and to explain platinum occurrences in Canadian and Florence creeks, central Yukon, where no known mafic–ultramafic rocks are present. Diverse composition of chromian spinel and clinopyroxenes from three creeks in the Kluane area indicate several sources of ultramafic rocks, including fragments of Alpine-type peridotites formed in back-arc basin and mid-ocean-ridge settings, and a source rock for zoned zinc-rich chromites of unknown origin. The Kluane ultramafic sills are the most likely source of PGM in this area. The heavy-mineral sample from Canadian Creek returned one PGM grain, no chromite, and abundant ilmenite and titanomagnetite. A group of chromium-rich magnesian ilmenites (∼4 wt.% MgO) closely match the composition of ilmenites from continental mafic intrusions produced during continental rift magmatism. This supports the continental rifting event recently proposed for this part of Yukon and indicates the economic potential of the Canadian Creek platinum occurrence. Composition of spinel from Florence Creek sample indicates an Alaskan-type intrusion as the source of PGM.

scholarly journals Exsolution Lamellae in Orthopyroxene of Lherzolite from the Pauza Ultramafic Rocks, Ne Iraq: Evidence of Deep Mantle Signature in the Zagros Suture Zone

2013 ◽  
Vol 2 (9) ◽  
pp. 102-115
Author(s):  
Yousif Osman Mohammad ◽  
Nabaz Rashid Hama Aziz
Keyword(s):  
High Pressure ◽  
Upper Cretaceous ◽  
Suture Zone ◽  
Ultramafic Rocks ◽  
Chromian Spinel ◽  
Spinel Peridotite ◽  
Incongruent Melting ◽  
Fine Grained ◽  
Ultra High Pressure ◽  
Deep Mantle

The Pauza ultramafic body is part of Upper Cretaceous Ophiolitic massifs of the Zagros Suture Zone, NE Iraq. The present study reveals evidence of Ultra-high pressure (UHP), and deep mantle signature of these peridotites in the Zagros Suture Zone throughout the observation of backscattered images and micro analyses which have been performed on orthopyroxen crystals in lherzolite of Pauza ultramafic rocks.Theorthopyroxen shows abundant exsolution lamellae of coarse unevenly distributed clinopyroxene coupled with the submicron uniformly distributed needles of Cr-spinel. The observed clusters of Opx–Cpx–Spl represent the decompression products of pyrope-rich garnet produced as a result of the transition from ultra-high pressure garnet peridotite to low-pressure spinel peridotite (LP). Neoblastic olivine (Fo92 – 93) with abundant multi-form Cr- spinel inclusions occurs as a fine-grained aggregate around orthopyroxene, whereas coarse olivine (Fo90-91) free from chromian-spinel is found in matrix. The similarity of the Cr-spinel lamellae orientations in both olivine and orthopyroxene, moreover, the enrichments of both Cr and Fe3+ in the Cr-spinel inclusions in neoblastic olivine relative to Cr-spinel lamellae in orthopyroxene, suggest that spinel inclusions in olivine have been derived from former Cr-spinel lamellae in orthopyroxene. Neoblastic olivine is formed by reaction of silica-poor ascending melt and orthopyroxene. It is inferred that the olivines with multi-form spinel inclusions has been formed by incongruent melting of pre-existing spinel lamellae-rich orthopyroxene.

scholarly journals Geochemistry of the Madawara Igneous Complex, Bundelkhand Craton, Central India: Implications for PGE Metallogeny

2015 ◽  
Vol 7 (1) ◽  
Author(s):  
Satyanarayanan Manavalan ◽  
Surya Prakash Singh ◽  
Vysetti Balaram ◽  
Mohanty Niranjan
Keyword(s):  
Central India ◽  
Shear Zones ◽  
Ultramafic Rocks ◽  
Spinel Peridotite ◽  
Igneous Complex ◽  
Total Platinum ◽  
Group I ◽  
Ultramafic Complex ◽  
Group Ii ◽  
High Degree

Abstract The southern part of the Bundelkhand craton contains a series of a E-W trending mafic and ultramafic rocks, about 40 km in length and 2–4 km wide, that occur as intrusions within the Bundelkhand Gneissic Complex (BnGC). They are confined between the Madawara- Karitoran and Sonrai-Girar shear zones. Dunite, harzburgite, lherzolite and websterite are the commonly occurring ultramafic rocks that have high MgO, Ni, Cr, PGE and low Al2O3, CaO, K2O, TiO2 and V contents, and shows peridotitic affinity. A distinct trend of crystallization from peridotite to komatiitic basalt has been inferred from geochemical plots, which also indicates the occurrence of at least two varieties among the ultramafic suite of the Madawara ultramafic complex, namely, Group I comprising dunite, spinel peridotite, harzburgite and lherzolite, and Group II consisting of pyroxenite, websterite and olivine websterite. In several places, the rocks of Group II have an intrusive relationship with Group I, and are relatively enriched in total platinum group elements (PGE ~ 300 ppb). The discrimination diagrams suggest that the PGE are enriched in low sulphur-fugacity source magma at moderate to deeper depths by high degree of partial melting of the mantle.

Leka Ophiolite Complex as analogy to the serpentinization-carbonation system on Mars.

2021 ◽  
Author(s):  
benjamin bultel ◽  
Agata M. Krzesinska ◽  
Damien Loizeau ◽  
François Poulet ◽  
Håkon O. Astrheim ◽  
...  
Keyword(s):  
Near Infrared ◽  
Nir Spectroscopy ◽  
Ground Truth ◽  
Ultramafic Rocks ◽  
Ophiolite Complex ◽  
Spectral Parameters ◽  
Thin Sections ◽  
Accessory Minerals ◽  
Mineral Assemblages ◽  
Alteration Minerals

<p>Serpentinization and carbonation have affected ultramafic rocks on Noachian Mars in several places called here serpentinization-carbonation systems (SCS). Among the most prominent SCS revealing mineral assemblages characteristic of serpentinization/carbonation is the Nili Fossae region [1]. Jezero crater – the target of the Mars 2020 rover –hosted a paleolake which constitutes a sink for sediments from Nili Fossae [1]. Thanks to the near infrared spectrometer onboard Mars2020 [2], the mission has the potential to offer ground truth measurement for other putative serpentinization/carbonation system documented on Mars. Several important aspects that may be addressed are: Do carbonates result from primary alteration of olivine-rich lithologies or are they derived by reprocessing of previous alteration minerals [3]? What is the composition? and nature of the protolith, which appear to be constituted of considerable amounts of olivine [4]? To reveal critical information regarding the conditions of serpentinization/carbonation, accessory minerals need detailed studies [1; 5]. In case of Jezero Crater, and serpentinization on Mars in general, the main alteration minerals are identified, but little is known about the accessory minerals.</p> <p>The Nili Fossae-Jezero system has potential analogues in terrestrial serpentinized and carbonated rocks, such as the Leka Ophiolite Complex, Norway (PTAL collection, https://www.ptal.eu). Here, distinct mineral assemblages record different stages of hydration and carbonation of ultramafic rocks [6].</p> <p>We perform petrological and mineralogical analyses on thin sections to characterize the major and trace minerals and combine with Near Infrared (NIR) spectroscopy measurements. A set of spectral parameters are defined and compare to spectral parameters previously used on CRISM and OMEGA data [1, 4, 7, 8]. We study the significance of the mineralogical assemblages including nature of accessory minerals. Effect of the presence of accessory minerals on the NIR signal is investigated and their potential incidence on the amount of H<sub>2</sub>/CH<sub>4</sub> production in mafic or ultramafic system is discussed [5].</p> <p>We started to apply the newly defined spectral parameters on several SCS on Mars. Results confirm local carbonation of earlier serpentinized rocks and suggest that different protoliths could have led to diversity of mineralogical associations in SCS on Mars. Multiple detection of brucite are also suggested for the first time on Mars. Altogether our results help to better describe key geochemical conditions of the SCS on Mars for habitability potential of the martian crust and Mars’s evolution.</p> <p><strong> </strong></p> <p>References:</p> <ul> <li>Brown, A. J., et al. <em>EPSL</em>1-2 (2010): 174-182.</li> <li>Wiens, R.C., et al.  <em>Space Sci Rev</em><strong>217, </strong>4 (2021).</li> <li>Horgan, B., et al. <em>Second International Mars Sample Return</em>. Vol. 2071. 2018.</li> <li>Ody, A., et al. <em>JGR: Planets</em>2 (2013): 234-262.</li> <li>Klein, F., et al. <em>Lithos</em>178 (2013): 55-69.</li> <li>Bjerga, A., et al. <em>Lithos</em>227 (2015): 21-36.</li> <li>Viviano-Beck et al, <em>JGR: Planets 11</em>8.9 (2013)</li> <li>Viviano-Beck et al, <em>JGR: Planets 119.6</em> (2014)</li> </ul>

Oxygen-Hafnium-Neodymium Isotope Constraints on the Origin of the Talnakh Ultramafic-Mafic Intrusion (Norilsk Province, Russia)

2020 ◽  
Vol 115 (6) ◽  
pp. 1195-1212 ◽  
Author(s):  
Kreshimir N. Malitch ◽  
Elena A. Belousova ◽  
William L. Griffin ◽  
Laure Martin ◽  
Inna Yu. Badanina ◽  
...  
Keyword(s):  
Crustal Contamination ◽  
Ultramafic Rocks ◽  
Magma Chambers ◽  
Nd Isotope ◽  
Crustal Component ◽  
Depleted Mantle ◽  
Magma Sources ◽  
A Minor ◽  
T Values

Abstract The ultramafic-mafic Talnakh intrusion in the Norilsk province (Russia) hosts one of the world’s major platinum group element (PGE)-Cu-Ni sulfide deposits. This study employed a multitechnique approach, including in situ Hf-O isotope analyses of zircon combined with whole-rock Nd isotope data, in order to gain new insights into genesis of the Talnakh economic intrusion. Zircons from gabbrodiorite, gabbroic rocks of the layered series, and ultramafic rocks have similar mantle-like mean δ18O values (5.39 ± 0.49‰, n = 27; 5.64 ± 0.48‰, n = 34; and 5.28 ± 0.34‰, n = 7, respectively), consistent with a mantle-derived origin for the primary magma(s) parental to the Talnakh intrusion. In contrast, a sulfide-bearing taxitic-textured troctolite from the basal part of intrusion has high δ18O (mean of 6.50‰, n = 3), indicating the possible involvement of a crustal component during the formation of sulfide-bearing taxitic-textured rocks. The Hf isotope compositions of zircon from different rocks of the Talnakh intrusion show significant variations, with ɛHf(t) values ranging from –3.2 to 9.8 for gabbrodiorite, from –4.3 to 11.6 for unmineralized layered-sequence gabbroic rocks, from 2.3 to 12 for mineralized ultramafic rocks, and from –3.5 to 8.8 for mineralized taxitic-textured rocks at the base of the intrusion. The significant range in the initial 176Hf/177Hf values is ascribed to interaction of distinct magma sources during formation of the Talnakh intrusion. These include (1) a juvenile source equivalent to the depleted mantle, (2) a subcontinental lithospheric source, and (3) a minor crustal component. Initial whole-rock Nd isotope compositions of the mineralized taxitic-textured rocks from the base of the intrusion (mean ɛNd(t) = –1.5 ± 1.8) differ from the other rocks, which have relatively restricted ranges in initial ɛNd (mean ɛNd = 0.9 ± 0.2). The major set of ɛNd values around 1.0 at Talnakh is attributed to limited crustal contamination, presumably in deep magma chambers, whereas the smaller set of negative ɛNd values in taxitic-textured rocks is consistent with greater involvement of a crustal component and reflects an interaction with the wall rocks during emplacement.

Geochemical researches in situ (LA-ICP-MS) of accessory and ore minerals from multimetal (PGE, Cu-Ni) deposits in the Arctic zone (Fennoscandian Shield) of the Russian Federation

2020 ◽  
Author(s):  
Svetlana Drogobuzhskaya ◽  
Tamara Bayanova ◽  
Andrey Novikov
Keyword(s):  
Inductively Coupled Plasma ◽  
Arctic Region ◽  
Sulfide Minerals ◽  
Fennoscandian Shield ◽  
The Arctic ◽  
Local Analysis ◽  
Icp Ms ◽  
Ore Minerals ◽  
Rfbr Grant

<p>The laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) is a unique method for local analysis that allows studying mineral grains in situ. The aims of these geochemical researches are to estimate concentrations and distributions of REE, Hf, U, Th, Y, Ti, PGE and other elements in accessory and ore minerals from complex deposits in the Arctic region (Fennoscandian Shield), using the LA-ICP-MS local analysis of trace elements. Accessory minerals of zircon and baddeleyite are much valued to study distributions of rare and rare earth elements (REE). Besides, pyrite, pentlandite, pyrrhotite and other sulfides are important for determining platinum-group elements (PGE), REE, etc.</p><p>The electron (LEO-1415) and optic (LEICA OM 2500 P, camera DFC 290) spectroscopy have been applied to study the morphology of the samples. Analytical points have been selected on baddeleyite, zircon crystals and sulfide minerals based on analyses of their BSE, CL and optical images. REE, PGE and other elements have been estimated in situ by ICP-MS, using an ELAN 9000 DRC-e (Perkin Elmer) quadrupole mass spectrometer equipped with UP-266 MAСRO laser (New Wave Research).</p><p>More than 19 elements were profiled during each measurement in zircon or baddeleyite. For the first time, LA-ICP-MS techniques have been applied to estimate PGE, REE and other (S, Cr, Fe, Cu, Ni, Co, As, Se, Mo, Cd, Sn, Sb, Re, Te, Tl, Hf, W, Bi, Pb, Th, U) elements in sulfide minerals. NIST 610, NIST 612 and tandem graduation (using solutions), considering sensitivity coefficients of isotopes have been used to check the accuracy of estimations. Fe, Ni and Cu have been used as internal standards, being most evenly distributed elements in minerals, when concentrations of elements in sulphides were calculated. The estimates have been carried out, using inter-laboratory standards of chalcopyrite, pentlandite and pyrrhotite, which had been preliminarily prepared and studied using micro probe analysis (Cameca MS-46).</p><p>These techniques had been used to estimate elements in zircon extracted from basic and acidic rocks of the Lapland belt (1.9 Ga), the Keivy zone (2.7 Ga), the Kandalaksha and Kolvitsa zone (2.45 Ga) and from the Cu-Ni deposit (Terrace, Mt. Nyud, 2.5 Ga). Novel techniques have been used to analyze baddeleyite from rocks of layered PGE intrusions of the Monchegorsk ore area (2.5 Ga) and carbonatites of Kovdor and Vuoriyarvi (380 Ma). Elaborated LA-ICP-MS techniques have been applied to provide in situ measurements of PGE, Au, Ag, siderophile and chalcophile elements in sulphide minerals from the Pechenga and Allarechka Cu-Ni deposits (1.98 Ga), Fedorova Tundra and Severny Kamennik PGE deposits (2.5 Ga).</p><p>The scientific researches are supported by RFBR Grant No 18-05-70082, scientific themes 0226-2019-0032 and 0226-2019-0053.</p>

Talc–carbonate alteration of ultramafic rocks within the Leka Ophiolite Complex, Central Norway

Lithos ◽  
2015 ◽  
Vol 227 ◽  
pp. 21-36 ◽  
Author(s):  
A. Bjerga ◽  
J. Konopásek ◽  
R.B. Pedersen
Keyword(s):  
Ultramafic Rocks ◽  
Ophiolite Complex
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