scholarly journals Reliability of foraminiferal Na/Ca as a direct paleo-salinity proxy in various planktonic species from the eastern tropical North Atlantic

2020 ◽  
Author(s):  
Jacqueline Bertlich ◽  
Dirk Nürnberg ◽  
Ed Hathorne ◽  
Michael Siccha ◽  
Jeroen Groeneveld ◽  
...  
Keyword(s):  
North Atlantic ◽  
Influencing Factor ◽  
Life Time ◽  
Total Alkalinity ◽  
Icp Ms ◽  
Tropical North Atlantic ◽  
Neogloboquadrina Dutertrei ◽  
Planktonic And Benthic Foraminifers ◽  
Species Specific ◽  
Relationship Of

<p><span>Foraminiferal Na/Ca in planktonic and benthic foraminifers is a promising new method to assess directly past seawater salinities, which complements existing approaches (e.g., paired shell Mg/Ca and δ</span><sup><span>18</span></sup><span>O, shell Ba/Ca). Recent culture and field calibration studies have shown a significant positive relationship of Na incorporation into foraminiferal calcite shells with increasing salinity [1, 2], as confirmed by our culture study of <em>Trilobatus sacculifer </em>[3]. However, we note that the sensitivity of Na/Ca in response to salinity changes is species-specific and regional dependent, whereas temperature could be excluded as a secondary influencing factor [2, 3, 5]. Na/Ca values vary from 1–3 mmol/mol for the same salinity within and between foraminiferal species, suggesting a dominant biological control. </span></p><p><span>To further evaluate the robustness of Na/Ca for its application as a reliable proxy, we here examine possible secondary controls on foraminiferal Na/Ca with new data for commonly used species for paleoreconstructions (<em>Globigerinoides elongatus</em>, <em>G. ruber </em>(pink), <em>Orbulina universa</em>, <em>Globigerina bulloides</em>, <em>Neogloboquadrina dutertrei</em>) collected by plankton tows in the eastern tropical North Atlantic during R/V Meteor cruise M140. We performed laser ablation ICP-MS measurements on single foraminiferal shells from depth-resolved plankton tows in 20 m net-intervals from locations where salinity was essentially constant, </span>while seawater <span>pH and total alkalinity differed</span> by ~0.5 and 100 µmol/kg, respectively. Plankton tow samples <span>provide new insights </span>in<span>to </span>the <span>possible effects of </span>natural variations in <span>carbonate system parameters on Na incorporation into calcite tests with increasing water depth. The comparison of living foraminifers to sedimentary shells gives further information about the preservation state of Na/Ca in calcite shells over time, whereas fossil shells have mostly undergone gametogenesis during their life-time, or were affected post mortem by early diagenesis (sedimentation) processes. Those foraminifers were collected from surface sediments (M65-1) located in proximity to plankton tows. Our results show that all measured species, either from plankton tows or buried in the sediment, are within the Na/Ca range of previous studies [1-5], which increases the confidence for a robust Na/Ca to salinity proxy. However, the offset of ~2-5 mmol/mol between living foraminifers collected in surface waters (0-20 m) and fossil assemblages of the same species could be related to spine loss at the end of a foraminiferal life cycle [4]. In addition, the usage of inconsistent test sizes could further influence the foraminiferal Na/Ca signal. Our results reveal significant (R = </span><span>-</span><span>0.97, <em>p</em><0.03</span><span>) decreasing Na/Ca values with increasing test sizes between </span><span>180-250 µm </span><span>for <em>G. ruber </em>(pink, white), <em>N. dutertei </em>and <em>T. sacculifer</em>, whereas values increase again with larger size classes >355 µm (R = 0.87, <em>p</em><0.02).</span><span> </span></p><p><span>[1] Wit et al. (2013) Biogeosciences <strong>10</strong>, 6375-6387. [2] Mezger et al. (2016) Paleoceanography <strong>31</strong>, 1562-1582. [3] Bertlich et al. (2018) Biogeosciences </span><strong>15</strong>, 5991–6018.<span>[4] Mezger et al. (2019) Biogeosciences <strong>16</strong>, 1147-1165, 2019. [5] Allen et al. (2016) Geochim. Cosmochim. Acta <strong>193</strong>, 197-221.</span></p>

scholarly journals Geochemical signatures of mineralizing events in the Juomasuo Au–Co deposit, Kuusamo belt, northeastern Finland

2021 ◽  
Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  
Keyword(s):  
Trace Element ◽  
Sulfur Isotope ◽  
Mineral Chemistry ◽  
Chemical Compositions ◽  
Metasedimentary Rocks ◽  
Metavolcanic Rocks ◽  
Icp Ms ◽  
Stage 1 ◽  
Host Rocks ◽  
Relationship Of

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.

scholarly journals Particle export fluxes to the oxygen minimum zone of the eastern tropical North Atlantic

2017 ◽  
Vol 14 (7) ◽  
pp. 1825-1838 ◽  
Author(s):  
Anja Engel ◽  
Hannes Wagner ◽  
Frédéric A. C. Le Moigne ◽  
Samuel T. Wilson
Keyword(s):  
Organic Matter ◽  
North Atlantic ◽  
Organic Phosphorus ◽  
Euphotic Zone ◽  
Carbon Export ◽  
Organic Matter Quality ◽  
B Values ◽  
Chl A ◽  
Tropical North Atlantic ◽  
Particle Export

Abstract. In the ocean, sinking of particulate organic matter (POM) drives carbon export from the euphotic zone and supplies nutrition to mesopelagic communities, the feeding and degradation activities of which in turn lead to export flux attenuation. Oxygen (O2) minimum zones (OMZs) with suboxic water layers (< 5 µmol O2 kg−1) show a lower carbon flux attenuation compared to well-oxygenated waters (> 100 µmol O2 kg−1), supposedly due to reduced heterotrophic activity. This study focuses on sinking particle fluxes through hypoxic mesopelagic waters (< 60 µmol O2 kg−1); these represent  ∼  100 times more ocean volume globally compared to suboxic waters, but they have less been studied. Particle export fluxes and attenuation coefficients were determined in the eastern tropical North Atlantic (ETNA) using two surface-tethered drifting sediment trap arrays with seven trapping depths located between 100 and 600 m. Data on particulate matter fluxes were fitted to the normalized power function Fz =  F100 (z∕100)−b, with F100 being the flux at a depth (z) of 100 m and b being the attenuation coefficient. Higher b values suggest stronger flux attenuation and are influenced by factors such as faster degradation at higher temperatures. In this study, b values of organic carbon fluxes varied between 0.74 and 0.80 and were in the intermediate range of previous reports, but lower than expected from seawater temperatures within the upper 500 m. During this study, highest b values were determined for fluxes of particulate hydrolyzable amino acids (PHAA), followed by particulate organic phosphorus (POP), nitrogen (PN), carbon (POC), chlorophyll a (Chl a) and transparent exopolymer particles (TEP), pointing to a sequential degradation of organic matter components during sinking. Our study suggests that in addition to O2 concentration, organic matter composition co-determines transfer efficiency through the mesopelagic. The magnitude of future carbon export fluxes may therefore also depend on how organic matter quality in the surface ocean changes under influence of warming, acidification and enhanced stratification.

scholarly journals Preparation and characterisation of an 57Fe enriched haemoglobin spike material for species-specific isotope dilution mass spectrometry

2016 ◽  
Vol 31 (9) ◽  
pp. 1846-1857 ◽  
Author(s):  
C. Brauckmann ◽  
C. Frank ◽  
D. Schulze ◽  
P. Kaiser ◽  
R. Stosch ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Isotope Dilution ◽  
Isotope Dilution Mass Spectrometry ◽  
Icp Ms ◽  
Species Specific

A species-specific ID-ICP-MS method for intact haemoglobin was developed applying an 57Fe enriched haemoglobin spike, which was prepared and characterised carefully.

scholarly journals Open ocean dead zones in the tropical North Atlantic Ocean

2015 ◽  
Vol 12 (8) ◽  
pp. 2597-2605 ◽  
Author(s):  
J. Karstensen ◽  
B. Fiedler ◽  
F. Schütte ◽  
P. Brandt ◽  
A. Körtzinger ◽  
...  
Keyword(s):  
North Atlantic ◽  
North Atlantic Ocean ◽  
Dead Zone ◽  
Marine Ecosystem ◽  
High Surface ◽  
Open Ocean ◽  
Depth Range ◽  
Low Oxygen ◽  
Dead Zones ◽  
Tropical North Atlantic

Abstract. Here we present first observations, from instrumentation installed on moorings and a float, of unexpectedly low (<2 μmol kg−1) oxygen environments in the open waters of the tropical North Atlantic, a region where oxygen concentration does normally not fall much below 40 μmol kg−1. The low-oxygen zones are created at shallow depth, just below the mixed layer, in the euphotic zone of cyclonic eddies and anticyclonic-modewater eddies. Both types of eddies are prone to high surface productivity. Net respiration rates for the eddies are found to be 3 to 5 times higher when compared with surrounding waters. Oxygen is lowest in the centre of the eddies, in a depth range where the swirl velocity, defining the transition between eddy and surroundings, has its maximum. It is assumed that the strong velocity at the outer rim of the eddies hampers the transport of properties across the eddies boundary and as such isolates their cores. This is supported by a remarkably stable hydrographic structure of the eddies core over periods of several months. The eddies propagate westward, at about 4 to 5 km day−1, from their generation region off the West African coast into the open ocean. High productivity and accompanying respiration, paired with sluggish exchange across the eddy boundary, create the "dead zone" inside the eddies, so far only reported for coastal areas or lakes. We observe a direct impact of the open ocean dead zones on the marine ecosystem as such that the diurnal vertical migration of zooplankton is suppressed inside the eddies.

Failure Analysis of High Pressure Rupture Discs and Effective Counter Measures

2016 ◽  
Author(s):  
Stefan Rüsenberg ◽  
Georg Vonnahme
Keyword(s):  
High Pressure ◽  
High Pressures ◽  
Influencing Factor ◽  
Applied Pressure ◽  
Life Time ◽  
Burst Pressure ◽  
Counter Measures ◽  
Welding Joint ◽  
Rupture Disc ◽  
Geometrical Change

For the production of LDPE, high process pressures (>1000 bar up to 3500 bar and above) as well as high temperatures (>100 °C up to 300 °C and above) are required. In order to ensure a safe production process the autoclaves and compressors have to be protected against dangerous overpressure. Rupture discs are typically used to protect this high pressure process itself, as well as the employees, and the environment. Traditionally rupture discs for high pressure applications are manufactured by a weld seam which has an influence on the burst pressure. After installation the applied pressure is nearly fully-loaded on the welding joint. Additionally, the welding joint is another unwanted influencing factor. This increases the possibility of an unexpected failure which leads to an unwanted rupture disc response or, in critical cases, to a rupture disc failure recently after initial operation of the process even at lower pressures than the defined burst pressure. This, in turn, leads to a reduced life time of the disc. A special version of a rupture disc, a High Pressure Rupture Disc (HPRD) is developed specifically for this application. This long life version for high pressure applications has a lifetime which is 5–10 times higher than that of a standard rupture disc, that saves money and installation time. The differences are explained in some minor geometrical changes. This safety device allows a protection of high pressures up to 4000 bar and beyond. The HPRD is a forward acting rupture disc and the burst pressure is adjusted by a combination of material thickness, the height of the dome, and, of course, of the chosen material. An easy and simple geometrical change eliminates the welding joint as an influencing factor, thus eliminating any unwanted responding of the rupture disc. The tolerances for high pressure rupture discs are +/−3% and lower and the HPRD can be used for all kind of different high pressure applications.

scholarly journals A quest for the biological sources of long chain alkyl diols in the western tropical North Atlantic Ocean

2018 ◽  
Vol 15 (19) ◽  
pp. 5951-5968 ◽  
Author(s):  
Sergio Balzano ◽  
Julie Lattaud ◽  
Laura Villanueva ◽  
Sebastiaan W. Rampen ◽  
Corina P. D. Brussaard ◽  
...  
Keyword(s):  
Atlantic Ocean ◽  
Water Column ◽  
North Atlantic ◽  
18S Rrna ◽  
North Atlantic Ocean ◽  
18S Rrna Gene ◽  
Rrna Gene ◽  
Tropical North Atlantic ◽  
Biological Sources ◽  
Long Chain

Abstract. Long chain alkyl diols (LCDs) are widespread in the marine water column and sediments, but their biological sources are mostly unknown. Here we combine lipid analyses with 18S rRNA gene amplicon sequencing on suspended particulate matter (SPM) collected in the photic zone of the western tropical North Atlantic Ocean at 24 stations to infer relationships between LCDs and potential LCD producers. The C30 1,15-diol was detected in all SPM samples and accounted for >95 % of the total LCDs, while minor proportions of C28 and C30 1,13-diols, C28 and C30 1,14-diols, as well as C32 1,15-diol were found. The concentration of the C30 and C32 diols was higher in the mixed layer of the water column compared to the deep chlorophyll maximum (DCM), whereas concentrations of C28 diols were comparable. Sequencing analyses revealed extremely low contributions (≈0.1 % of the 18S rRNA gene reads) of known LCD producers, but the contributions from two taxonomic classes with which known producers are affiliated, i.e. Dictyochophyceae and Chrysophyceae, followed a trend similar to that of the concentrations of C30 and C32 diols. Statistical analyses indicated that the abundance of 4 operational taxonomic units (OTUs) of the Chrysophyceae and Dictyochophyceae, along with 23 OTUs falling into other phylogenetic groups, were weakly (r≤0.6) but significantly (p value <0.01) correlated with C30 diol concentrations. It is not clear whether some of these OTUs might indeed correspond to C28−32 diol producers or whether these correlations are just indirect and the occurrence of C30 diols and specific OTUs in the same samples might be driven by other environmental conditions. Moreover, primer mismatches were unlikely, but cannot be excluded, and the variable number of rRNA gene copies within eukaryotes might have affected the analyses leading to LCD producers being undetected or undersampled. Furthermore, based on the average LCD content measured in cultivated LCD-producing algae, the detected concentrations of LCDs in SPM are too high to be explained by the abundances of the suspected LCD-producing OTUs. This is likely explained by the slower degradation of LCDs compared to DNA in the oxic water column and suggests that some of the LCDs found here were likely to be associated with suspended debris, while the DNA from the related LCD producers had been already fully degraded. This suggests that care should be taken in constraining biological sources of relatively stable biomarker lipids by quantitative comparisons of DNA and lipid abundances.

scholarly journals The distribution of neodymium isotopes and concentrations in the eastern tropical North Atlantic

2019 ◽  
Vol 511 ◽  
pp. 265-278 ◽  
Author(s):  
Moritz Zieringer ◽  
Martin Frank ◽  
Roland Stumpf ◽  
Ed C. Hathorne
Keyword(s):  
North Atlantic ◽  
Neodymium Isotopes ◽  
Tropical North Atlantic

scholarly journals Diapycnal oxygen supply to the tropical North Atlantic oxygen minimum zone

2012 ◽  
Vol 9 (10) ◽  
pp. 14291-14325 ◽  
Author(s):  
T. Fischer ◽  
D. Banyte ◽  
P. Brandt ◽  
M. Dengler ◽  
G. Krahmann ◽  
...  
Keyword(s):  
North Atlantic ◽  
Large Scale ◽  
Oxygen Supply ◽  
Water Layer ◽  
Oxygen Minimum Zone ◽  
Depth Interval ◽  
Diapycnal Mixing ◽  
Tropical North Atlantic ◽  
Minimum Zone ◽  
Oxygen Minimum

Abstract. The replenishment of consumed oxygen in the open ocean oxygen minimum zone (OMZ) off West Africa in the tropical North Atlantic Ocean is studied, with a focus on oxygen transport across density surfaces (diapycnal flux). The latter is obtained from a large observational set of oxygen profiles and diapycnal mixing data from years 2008 to 2010. Diapycnal mixing is inferred from different sources: a large scale tracer release experiment, microstructure profiles, and shipboard acoustic current measurements plus density profiles. The average diapycnal diffusivity in the study area is 1 × 10−5 m2 s−1. No significant vertical gradient of average diapycnal diffusivities exists in the depth interval from 150 to 500 m. The diapycnal flux is found to contribute substantially to the oxygen supply of the OMZ. Within the OMZ core, 1.5 µmol kg−1 a−1 of oxygen is supplied via diapycnal mixing, contributing about a third of the total demand. The oxygen that is contributed via diapycnal mixing originates from oxygen that has been laterally supplied within the overlying Central Water layer by advective and eddy fluxes. Due to the existence of a separate shallow oxygen minimum at about 100 m depth throughout most of the study area, there is no direct net vertical oxygen flux from the surface layer of the study area into the Central Water layer. Thus all oxygen supply of the OMZ is associated with remote pathways.

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