Melt inclusions in metamorphic rocks: how localized melting promoted the formation of the Gore Mountains mega garnets (Adirondacks, US)

Author(s):  
Silvio Ferrero ◽  
Iris Wannhoff ◽  
Robert Darling ◽  
Bernd Wunder ◽  
Laurent Oscar ◽  
...  

<p>Melt inclusions have been for almost 150 years an exclusive feature of magmatic rocks. However, intensive research activity in the last decade has shown that melt inclusions, or nanogranitoids, are also a widespread feature of high grade metamorphic rocks. Such inclusions rapidly became fundamental tools to unravel partial melting and melt-related processes taking place during orogenesis.</p><p>One of the latest discoveries in this field has been the identification of nanogranitoids and glass inside the mega almandine-pyrope garnets of Barton Mine (Gore Mountain, NY State, US). These crystals are arguably the world’s largest garnets and occur within garnet hornblendite. Their size is ca. 35 cm in average, while garnet diameters up to 1 m were reported in historical record. Fluid is often invoked in the formation of large crystals, but so far no study has identified clear witnesses for the presence of fluid during garnet formation, e.g. primary fluid inclusions.</p><p>Polycrystalline inclusions of primary nature were instead reported by Darling et al. (1997) to occur inside the garnet: such inclusions are the main target of our study. Their shape ranges from tubular (2-100 µm in length) to negative crystal shape (2-50 µm). They mainly contain cristobalite/quartz, kumdykolite and amphibole. Minor phases such as biotite/phlogopite, enstatite, rutile, ilmenite and a second, Ca-richer plagioclase (or its rare polymorphs dmisteinbergite and svyatoslavite) may be also present. The inclusions were re-homogenized to a silicate-rich glass via piston cylinder experiments at 1.0-1.5 GPa and 925-940°C. Experimental results prove that such inclusions are former droplets of melt, in agreement with the finding of preserved residual glass in one single inclusion before the experimental runs. The melt composition measured in situ via electron microprobe is tonalitic-trondhjemitic with 5-6 wt% H<sub>2</sub>O.</p><p>The identification of melt inclusions points toward a melt rather than a fluid as the medium which favored extreme garnet growth under low nucleation rate conditions. The elements necessary to grow garnets – mainly Fe, Al, Si, Mg- are indeed far more effectively transported by a silicate melt rather than simple aqueous fluid, at least at the limited depth envisioned for this process. In conclusion, the finding of melt inclusions in metamorphic rocks brought us forward along the path toward the solution of the enigma represented by the formation of these giant garnets.</p><p>References<br>Darling, R.S., Chou, I.M., Bodnar, R.J., 1997. An Occurrence of Metastable Cristobalite in High-Pressure Garnet Granulite. Science 276, 91.</p>

2020 ◽  
Author(s):  
Anna Redina ◽  
Cora Wohlgemuth-Ueberwasser ◽  
Julia Mikhailova ◽  
Gregory Ivanyuk

<p>The Kovdor massif is a part of the Paleozoic Kola alkaline province and located in the eastern part of the Baltic Shield. Kovdor carbonatites host a unique complex baddeleyite-apatite-magnetite deposit from which iron ores and zirconium have been mined. New data on melt inclusions in olivine crystals from phoscorites and olivinites of the ore complex are presented in this contribution. Daughter minerals in crystallized melt inclusions were identified by Raman spectroscopy and scanning electron microscopy. The trace element composition of inclusions was determined using LA-ICP-MS.</p><p>Melt inclusions in olivine from Kovdor phoscorites are negative crystal or round in shape, with sizes ranging from 5 to 50 microns. They form groups or line up. According to the mineral composition, two types of melt inclusions can be distinguished: carbonate and silicate-carbonate. In the first type, Ca-Na-Mg- (Sr?) - REE carbonates are dominant among daughter phases. In the second one, silicate phases (phlogopite, monticellite, diopside), Ca-Na-Mg carbonates and magnetite are found together. Melt inclusions in olivine from olivinites are isometric or elongated, 5–25 μm in size. They form groups or occur as isolated inclusions. Benstoneite, geylussit, ankerite, calcite and hydroxyl-bastnesite along with phyllosilicates (phlogopite, paragonite?) were identified among daughter minerals.</p><p>The rare earth elements composition of melt inclusions from both types of rocks is characterized by the predominance of light REE. The content of REE, especially light ones, in inclusions from phoscorites is higher. Strontium and barium contents in most melt inclusions have negative correlations with niobium and zirconium concentrations.</p><p>Melt inclusions from phoscorites and olivinites contain carbonate and silicate mineral phases in various proportions, which may imply heterogeneous trapping of crystalline phases and two immiscible melts, silicate and carbonatite. Inclusions from phoscorite represent a more evolved magma with higher concentrations of rare metals.</p><p>This work was supported by the Russian Science Foundation, grant No 19-17-00013.</p>


2019 ◽  
Vol 27 (5) ◽  
pp. 503-524
Author(s):  
A. L. Perchuk ◽  
A A. Serdyuk ◽  
N. G. Zinovievа

We present the results of analogue experiments carried out in a piston–cylinder apparatus at 750–900°C and 2.9 GPa aimed to simulate metasomatic transformation of the fertile mantle caused by fluids and melts released from the subducting sediment. A synthetic H2O- and CO2-bearing mixture that corresponds to the average subducting sediment (GLOSS, Plank, Langmuir, 1998) and mineral fractions of natural lherzolite (analogue of a mantle wedge) were used as starting materials. Experiments demonstrate that the mineral growth in capsules is controlled by ascending fluid and hydrous melt (from 850°C) flows. Migration of the liquids and dissolved components develops three horizontal zones in the sedimentary layer with different mineral parageneses that slightly changed from run to run. In the general case, however, the contents of omphacite and garnet increase towards the upper boundary of the layer. Magnesite and omphacite (± garnet ± melt ± kyanite ± phengite) are widespread in the central zone of the sedimentary layer, whereas SiO2 polymorph (± kyanite ± phengite ± biotite ± omphacite ± melt) occurs in the lower zone. Clinopyroxene disappears at the base of lherzolite layer and the initial olivine is partially replaced by orthopyroxene (± magnesite) in all experiments. In addition, talc is formed in this zone at 750°C, whereas melt appears at 850°C. In the remaining volume of the lherzolite layer, metasomatic transformations affect only grain boundaries where orthopyroxene (± melt ± carbonate) is developed. The described transformations are mainly related to a pervasive flow of liquids. Mineral growth in the narrow wall sides of the capsules is probably caused by a focused flow: omphacite grows up in the sedimentary layer, and talc or omphacite with the melt grow up in the lherzolite layer. Experiments show that metasomatism of peridotite related to a subducting sediment, unlike the metasomatism related to metabasites, does not lead to the formation of garnet-bearing paragenesis. In addition, uprising liquid flows (fluid, melt) do not remove significant amounts of carbon from the metasedimentary layer to the peridotite layer. It is assumed that either more powerful fluxes of aqueous fluid or migration of carbonate-bearing rocks in subduction melanges are necessary for more efficient transfer of crustal carbon from metasediments to a mantle in subduction zones.


2020 ◽  
Vol 105 (4) ◽  
pp. 569-582 ◽  
Author(s):  
Tingting Shen ◽  
Cong Zhang ◽  
Jing Chen ◽  
Jörg Hermann ◽  
Lifei Zhang ◽  
...  

Abstract The unit-cell parameter a of antigorite (usually expressed as the polysome m value) has been determined as a function of temperature (T) and pressure (P) in the range of 600–650 °C, 25–45 kbar in weeklong piston-cylinder experiments. A well-characterized natural antigorite (with m = 16 and less abundant m = 15) was used as a starting material that coexisted with olivine, chlorite, Ti-humite, and aqueous fluid at run conditions. Transmission electron microscope (TEM) measurements on selected focused ion beam (FIB) wafers showed that antigorite m values after the experiments varied between 14 and 22. More than 40 punctual analyses for each run condition were acquired to determine the range and the primary m value. The most frequent antigorite m-value decreased systematically from 17–19 at 600 °C to 15–16 at 650 °C. The spacing of the m-isolines is getting narrower as the antigorite breakdown reaction is approached. The topology of the m-isolines is similar to that previously characterized for the simple MgO-SiO2-H2O (MSH) system. However, the isolines are shifted to about 50–100 °C higher temperatures due to the incorporation of Al into antigorite. Powder samples and FIB wafers of natural antigorite from the Tianshan UHP belt (China) with peak metamorphic conditions of ~35 kbar, ~520 °C were also investigated with TEM. Low Al-antigorite formed at peak metamorphic conditions displays a peak m value of 20–21, whereas high-Al antigorite formed during isothermal decompression displays a lower m value of 19. Combination of our results with the published data of m values from metamorphic antigorite that experienced various conditions allowed construction of a P-T-m diagram that can be used in future studies to better constrain formation conditions of serpentinites. The decrease of m values and the increase of Al in antigorite with increasing temperature result in small, continuous dehydration whereby the H2O content of antigorite changes from 12.4 to 12.1 wt%. Therefore, it is expected that a pore fluid is present during the prograde deformation of serpentinites. TEM observations showed that antigorite adjusted its Al content by segregation of chlorite at the nanoscale. Together with the observation that multiple m values are always present in a single sample, this result indicates that full equilibration of antigorite at the micrometer-scale is rare, with important implications for the interpretation of geochemical signatures obtained by in situ techniques.


2021 ◽  
Author(s):  
Bruna B. Carvalho ◽  
Omar Bartoli ◽  
Madhusoodhan Satish-Kumar ◽  
Tetsuo Kawakami ◽  
Tomokazu Hokada ◽  
...  

<p>Metamorphism at ultra-high temperature (UHT) conditions (i.e., T >900°C and pressures from 7 to 13 kbar) is now recognized as a fundamental process of Earth’s crust, and although progress has been achieved on its understanding, constraining melt generation and fluid regime at such extreme conditions is still poorly explored.</p><p>In this study we use former melt inclusions found in peritectic garnet to investigate anatexis and fluid regime of metapelitic granulites in samples from the Rundvågshetta area, the thermal axis of the Lützow-Holm Complex (East Antarctica). Peak P-T estimates are 925-1039°C at 11.5-15 kbar. The studied rock is a coarse-grained heterogeneous metapelitic granulite with a predominant mafic residual domain and a relatively more felsic, melt-rich domain. The mineral association in the mafic domain typically contains orthopyroxene (Al<sub>2</sub>O<sub>3</sub>6-8.1 wt.%) + sillimanite + quartz + garnet (Prp<sub>42-55</sub>Alm<sub>40-52</sub>Grs<sub>3-4</sub>Sps<sub>0.2-1</sub>; X<sub>Mg</sub>0.5) + K-feldspar (Kfs) + cordierite (X<sub>Mg</sub>0.86) + rutile ± sapphirine ±biotite (X<sub>Mg</sub>0.75; TiO<sub>2</sub>3.7-5.8 wt.%) ±plagioclase (An<sub>35-46</sub>). Interstitial Kfs and quartz with low dihedral angles are often present, in particular as thin films between sillimanite and quartz; these features are interpreted as evidence for the presence of former melt along the grain boundaries. In contrast, the more felsic, melt-rich domain is composed of mesoperthite + quartz + garnet + sillimanite + brown biotite (X<sub>Mg</sub>0.7; TiO<sub>2</sub>3.7-5.4 wt.%) + rutile, but is free of orthopyroxene. Cores of garnet porphyroblasts (0.2-0.8 cm, Prp<sub>54-57</sub>Alm<sub>39-42</sub>Grs<sub>3-4</sub>Sps<sub>0.2-0.6</sub>, X<sub>Mg</sub>0.57) in the melt-rich domains contain clusters of primary glassy inclusions (GI) and crystallized melt inclusions (nanogranitoids; NI) together with multiphase fluid inclusions (MFI) and accessory phases (mainly rutile and apatite).</p><p>The GI (5-20 µm) have negative crystal shapes and contain shrinkage bubbles with or without CO<sub>2</sub>and N<sub>2</sub>. In some cases, GI may have trapped apatite and rutile. Micro-Raman investigation suggest that the H<sub>2</sub>O contents of these glasses range from 0 to 3.4 wt.%. Glasses are weakly peraluminous (ASI=1-1.1), have high SiO<sub>2</sub>(76-78 wt.%), very high K<sub>2</sub>O (6.5-10 wt.%) and extremely low CaO and FeO+MgO contents.</p><p>The NI have variable sizes (10-150 µm) and often contains intergrowth of plagioclase + quartz, K-feldspar (Kfs) and biotite (Bt). Less frequently NI may have euhedral to subhedral grains of Kfs and Bt. Trapped phases are apatite and rutile, except for one inclusion that contains the sapphirine + quartz pair indicating that melt inclusions were trapped at UHT conditions.</p><p>The MFI are composed of CO<sub>2</sub>(with densities from 0.23 to 0.93 g/cm<sup>3</sup>) and step-daughter magnesite, pyrophyllite. Methane, N<sub>2</sub>or H<sub>2</sub>O were not detected.</p><p>Our results show that anatexis of metapelites at extremely hot conditions occurred in the presence of COHfluids and generated highly silicic, weakly peraluminous, mildly to strongly potassic magmas with low H<sub>2</sub>O contents. Additional trace element data will be acquired to shed light on further geochemical fingerprints of these peculiar magmas.</p>


2021 ◽  
Author(s):  
Alessia Borghini ◽  
Silvio Ferrero ◽  
Patrick J. O'Brien ◽  
Bernd Wunder ◽  
Oscar Laurent

<p>Melt inclusions of very unusual nature occur in garnets of eclogites of the Granulitgebirge, Bohemian Massif. This is one of the first direct characterization of a preserved metasomatic melt responsible for the formation of eclogites enclosed in garnet peridotites. The inclusions are micrometric, from glassy to fully crystalized as nanogranitoids and randomly distributed in the garnet core. Nanogranitoids contain kumdykolite/albite, phlogopite, osumilite and kokchetavite with a variable amount of quartz, pyroxene, carbonate and rare white mica. The melt has a granitic composition rather than basaltic or tonalitic/trondhjemitic as would be expected from the partial melting of ultramafic or mafic rocks and it is as well hydrous and peraluminous. The trace elements composition is also unusual for melts in mantle rocks with elements typical of continental crust (Cs, Li, B, Pb and Rb) and subduction zone (Th and U). Similar signatures, i.e. continental crust and subduction, are visible also in the whole rock trace elements in the form of high amounts of LILE and U. The eclogite major elements composition is similar to a Ca- and Fe - rich mafic rock akin more to the crust than to the mantle.</p><p>The peculiar melt composition and the lack of a clear residue of a melting reaction in the eclogites suggest that this melt is external, i.e. metasomatic. It infiltered the peridotites during subduction of the continental crust at mantle depth and aided the transformation of basic layers, already in the peridotite, to eclogite. In addition, similar trace elements patterns to the melt reported here can be found in the so-called durbachite -ultrapotassic melanosyenite present in the high-grade Variscan basement- and in the garnet peridotites and garnet pyroxenites of the T-7 borehole. In both case metasomatism was suggested but the agent was just inferred based on the geochemical signature. All these occurrences suggest that mantle contaminated by melts from deeply subducted continental crust is widespread beneath the Bohemian Massif.</p>


1990 ◽  
Vol 54 (375) ◽  
pp. 195-205 ◽  
Author(s):  
T. H. Hansteen ◽  
W. J. Lustenhouwer

AbstractThe mildy peralkaline Eikeren-Skrim granite belongs to the Permian magmatic province of the Oslo rift, south-east Norway. Euhedral quartz crystals from the abundant miarolitic cavities contain primary inclusions of partly crytallized silicate melts and coexisting primary, aqueous fluid inclusions. Micro-thermometric measurements give maximum estimates for the granite solidus of 685–705°C. Quenched silicate melt inclusions are not peralkaline, have normative Or/Ab weight ratios of 1.15–1.44 (compared to 0.49–0.80 in whole-rock samples) and F and Cl contents of 0.1 and 0.21–0.65 wt. %, respectively. Coexisting magmatic fluid inclusions are highly enriched in Na, Cl, S and to some extent K. These chemical characteristics are the results of late-magmatic melt-mineral-fluid interaction in the miarolitic cavities.


2020 ◽  
Author(s):  
Christoph Hauzenberger ◽  
Philip Schantl ◽  
Elena Sizova ◽  
Harald Fritz ◽  
Fritz Finger ◽  
...  

<p><span><span>The granulite occurrences from the Moldanubian zone were extensively studied in the last three decades and their metamorphic overprint at high pressures and at UHT conditions are well constrained. However, there are still some discrepancies regarding the prograde PT-path evolution, the genesis of the granulites and the tectonic processes required to produce the proposed PT-paths. Here we present a comprehensive petrological study where we have investigated more than 300 granulite samples from one of the largest occurrences, the Poechlarn-Wieselburg area - Dunkelsteinerwald. C</span><span>onventional geothermobarometry, garnet zoning pattern, thermodynamic modelling and Zr-in-rutile thermometry on rutile grains enclosed in garnets in felsic and mafic granulites allowed to constrain the prograde as well as the retrograde segments of the PT path. Polycrystalline melt inclusions and high-Ti biotite relics as well as a uniform temperature of approximately 800°C obtained from rutile inclusions (Zr-in-rutile thermometry) in garnet cores disagree with a continuous prograde garnet growth but favour a metastable overstepping of the garnet-in reaction and growth by the peritectic biotite breakdown reaction to garnet and melt within a very narrow PT interval. Subsequent heating to T>1000°C initiated a second stage of garnet growth with a very distinct chemical composition. The preservation of the zoning pattern at these metamorphic conditions clearly document a very short lived process. Diffusion models predict a time span of <5 Ma and cooling rates of 50-60°C/my.</span><span> Zircon U-Pb ages usually cluster around 340 Ma representing the metamorphic peak. However, in mafic granulites zircon ages from approximately 410 Ma to 340 Ma are obtained indicating either an older formation age for the precursor rock of the mafic granulites or just documenting the occurrence of xenocrysts. We applied a series of coupled petrological–thermomechanical tectono-magmatic numerical model to reproduce our deduced PTt-path that evolved from exhumation of subducted lower crust followed by intense heating at the crust-mantle boundary.</span></span></p>


1986 ◽  
Vol 50 (357) ◽  
pp. 399-415 ◽  
Author(s):  
David C. Rubie

AbstractThe problems of characterizing inter-granular regions and of estimating rates of intergranular diffusion in metamorphic rocks are discussed. Inter-granular regions can be anhydrous, hydrated but under-saturated with H2O, or saturated with H2O, but only in the latter case can a free aqueous fluid phase be present. Estimates of intergranular diffusion coefficients (DIGR) at 550°C derived from a variety of published experimental work, vary from ∼ 10−8 m2 s−1 for diffusion of species through an intergranular fluid film to ⩽ 4 × 10−24 m2 s−1 for diffusion of SiO2 or O in anhydrous grain boundaries in quartzite. Estimates of DIGR for hydrated grain boundaries vary from ∼ 10−13 m2 s−1 to ∼ 10−21 m2 s−1; the concentration of H2O in the grain boundaries and the identity of the diffusing species (generally unknown) may be important controlling factors, and there exists the possibility of a spectrum of values between these two extremes.Using available kinetic data it is shown that a free aqueous fluid could never have been present in parts of the basement terrane of the Sesia Zone (Western Alps) during uplift from the eclogite facies, except possibly late in the cooling history. The breakdown of sodic pyroxene + quartz occurred in response to the localized infiltration of catalytic aqueous fluid, possibly over a time interval as short as 6–6000 a, and possibly under conditions remote from equilibrium. H2O-present conditions during a dehydration reaction in metapelites of the Adula nappe (central Alps) could also have been of short duration. These examples are consistent with a model in which basement rocks at deep crustal levels are dry for long periods of time and in which the development of equilibrium mineral assemblages and microstructures generally occurs over relatively short periods of time under transitory fluid-present conditions (caused by devolatilization and/or infiltration).


2020 ◽  
Vol 81 (3) ◽  
pp. 84-86
Author(s):  
Lyubomira Macheva

Micro-inclusions in garnet porphyroblasts from high-grade Ograzhden metapelites, SW Bulgaria, have been studied by SEM and micro-Raman Spectroscopy. Micro-inclusions are presented by single grains with facetted outlines parallel to rational crystallographic orientations of the host garnet or by multiphase aggregates with negative crystal shape. Many of studied micro-inclusions can be formed by the presence of melt. The morphology of some of them suggests formation under high pressure metamorphism.


Solid Earth ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 1335-1355
Author(s):  
Miguel Cisneros ◽  
Jaime D. Barnes ◽  
Whitney M. Behr ◽  
Alissa J. Kotowski ◽  
Daniel F. Stockli ◽  
...  

Abstract. Retrograde metamorphic rocks provide key insights into the pressure–temperature (P–T) evolution of exhumed material, and resultant P–T constraints have direct implications for the mechanical and thermal conditions of subduction interfaces. However, constraining P–T conditions of retrograde metamorphic rocks has historically been challenging and has resulted in debate about the conditions experienced by these rocks. In this work, we combine elastic thermobarometry with oxygen isotope thermometry to quantify the P–T evolution of retrograde metamorphic rocks of the Cycladic Blueschist Unit (CBU), an exhumed subduction complex exposed on Syros, Greece. We employ quartz-in-garnet and quartz-in-epidote barometry to constrain pressures of garnet and epidote growth near peak subduction conditions and during exhumation, respectively. Oxygen isotope thermometry of quartz and calcite within boudin necks was used to estimate temperatures during exhumation and to refine pressure estimates. Three distinct pressure groups are related to different metamorphic events and fabrics: high-pressure garnet growth at ∼1.4–1.7 GPa between 500–550 ∘C, retrograde epidote growth at ∼1.3–1.5 GPa between 400–500 ∘C, and a second stage of retrograde epidote growth at ∼1.0 GPa and 400 ∘C. These results are consistent with different stages of deformation inferred from field and microstructural observations, recording prograde subduction to blueschist–eclogite facies and subsequent retrogression under blueschist–greenschist facies conditions. Our new results indicate that the CBU experienced cooling during decompression after reaching maximum high-pressure–low-temperature conditions. These P–T conditions and structural observations are consistent with exhumation and cooling within the subduction channel in proximity to the refrigerating subducting plate, prior to Miocene core-complex formation. This study also illustrates the potential of using elastic thermobarometry in combination with structural and microstructural constraints, to better understand the P–T-deformation conditions of retrograde mineral growth in high-pressure–low-temperature (HP/LT) metamorphic terranes.


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