The coupling of dehydration and deformation results in localised fluid flow in the accretionary wedge – a novel study of calcite veins
<p>In plate-convergent settings, fluid-saturated sediments dehydrate during subduction. The sediments are subsequently accreted to the upper plate. Along their dehydration-deformation path, the initial unconsolidated soft marine sediments become thick, foliated, impermeable meta-sedimentary sequences. Fluid flow through such &#8216;non&#8217;-porous low-permeability rocks is concentrated in fracture networks, ranging from the mm- to the km-scale. We study the interplay between ductile and brittle deformation processes and fluid flow by investigating calcite veins in slates from the exhumed European Alpine accretionary wedge across scales (&#181;m to km). These slates experienced peak metamorphic temperatures between 200&#176;C and 330&#176;C and represent the transition between the upper aseismic and seismic zone. With the use of Synchrotron X-ray Fluorescence Microscopy (SXFM), we investigate the slates by visualizing trace-element distributions. This technique shows that alternating cycles of slow pressure-dissolution processes and brittle fracturing persist over long time scales. At the micron-scale, pressure solution of the initial carbonate-rich slates is indicated by an enrichment of newly recrystallized phyllosilicates on cleavage planes and in pressure shadows. These ductile deformation features are mutually overprinted by calcite veins (aperture 10 &#181;m), which are nicely visualized with Sr-SXFM maps. Increasing compaction and recrystallization in the slate-rich matrix leads to progressed dehydration resulting in an increased pore fluid pressure and subsequent hydrofracturing. The micron-sized fractures are immediately filled in with minerals, which are oversaturated at that time in the fluid, resulting in the formation of (i) micron-veinlets. Micron-veinlets collect (ii) into mm-cm sized veins, which themselves form (iii) vein arrays and (iv) mega-arrays, respectively at the 50-100 m and 300-400 m scale. This upscaling of fluid pathways indicates a localised fluid transport through the accretionary wedge, which has important implications for the understanding of the mechanical stability of the accretionary wedge and related seismic activity.</p>