The effects of hydrodynamic sorting on the Ti isotope composition of sediments

2020 ◽  
Author(s):  
Martijn Klaver ◽  
Pieter Vroon ◽  
Marc-Alban Millet
Keyword(s):  
Chemical Weathering ◽  
Isotope Composition ◽  
Eastern Mediterranean ◽  
Hf Isotope ◽  
Passive Margin ◽  
Coarse Grained ◽  
Fine Grained ◽  
Crustal Composition ◽  
Mass Dependent ◽  
Physical And Chemical

<p>Detrital sediments provide a useful tool to investigate the composition of the continental crust through time. Mass-dependent (“stable”) isotope variations in Archaean to present-day sediments (shales, diamictites) have recently received much attention and Ti, in particular, holds significant promise as a novel tracer of crustal composition [1, 2, 3]. This approach is based on i) the contrasting Ti isotope composition of mafic versus felsic rocks as a result of the removal of isotopically light oxides during igneous differentiation; and ii) the chemical behaviour of Ti, a refractory and biologically inert element that should not fractionate during weathering and sedimentation. Hence, current interpretations of the Ti isotope detrital sediment record rely heavily on the assumption that it reflects the integrated composition of the source(s), and thus provides a record of the proportion of felsic to mafic rocks in that source.</p><p>A potential caveat, however, is the hydrodynamic sorting of dense minerals in coarse, more proximal sediments [4]. This effect is well-known for zircon; coarser sediments tend to have higher Zr/Al<sub>2</sub>O<sub>3</sub> and a less radiogenic Hf isotope composition due to the concentration of zircon grains [e.g., 5, 6]. Shales form the complementary zircon-depleted reservoir characterised by lower Zr/Al<sub>2</sub>O<sub>3</sub> and a more radiogenic Hf isotope composition relative to the source. Common Ti-rich phases such as ilmenite and rutile are also resistant against physical and chemical weathering and could be concentrated together with zircon in coarse sediments.</p><p>We examined a suite of Eastern Mediterranean passive margin sediments with well-constrained provenance [7] and found that Ti indeed behaves like Zr. Fine-grained samples have lower TiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> compared to coarser, proximal deposits of identical provenance. The removal of Ti-rich phases with a light Ti isotope composition into coarse-grained sediments could thus bias the Ti isotope composition of shales towards isotopically heavier values. We will report on the δ<sup>49/47</sup>Ti isotope composition of these sediment samples, but a TiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> mass balance suggests that a bias of more than 0.05 ‰ in the δ<sup>49/47</sup>Ti of shales is possible. Understanding the consequences of hydrodynamic sorting for Ti isotopes in sediments is crucial for their use as a quantitative proxy of crustal composition and for reconciling the shale and diamictite Ti isotope records.</p><p>[1] Greber <em>et al.</em> (2017) <em>Science</em> <strong>357</strong> 1271-1274; [2] Deng <em>et al.</em> (2019) <em>PNAS</em> <strong>116-4</strong> 1132-1135; [3] Saji <em>et al.</em> (2019) <em>Goldschmidt abstract</em> <strong>2929</strong>; [4] Greber & Dauphas (2019) <em>GCA</em> <strong>255</strong> 247-264; [5] Patchett <em>et al.</em> (1984) <em>EPSL</em> <strong>69</strong> 365-378; [6] Carpentier <em>et al.</em> (2009) <em>EPSL</em> <strong>287</strong> 86-99; [7] Klaver <em>et al.</em> (2015) <em>GCA</em> <strong>153</strong> 149-168.</p>

Origin and physical and chemical characteristics of glacial overburden in Essex and Kent counties, southwestern Ontario

1997 ◽  
Vol 34 (3) ◽  
pp. 233-246 ◽  
Author(s):  
T. F. Morris ◽  
R. I. Kelly
Keyword(s):  
Coarse Grained ◽  
Glacial Lake ◽  
Silty Clay ◽  
Fine Grained ◽  
The North ◽  
Geochemical Properties ◽  
Clayey Silt ◽  
Kent County ◽  
Stratigraphic Position ◽  
Physical And Chemical

The overburden of Essex and Kent counties, southwestern Ontario, has been described as consisting of a clayey silt to silty clay till overlying a gravelly unit resting on bedrock. Recent Quaternary geology mapping has identified additional materials and redefined the origin of others by determining the stratigraphic position and physical and geochemical properties of materials encountered in a sonic drilling program and field mapping. Catfish Creek Till was deposited on the bedrock surface during the Nissouri Stadial as ice advanced south over the area. As ice retreated during the Erie Interstade, fine-grained glaciolacustrine material was deposited in glacial Lake Leverett and overlay Catfish Creek Till. Tavistock Till was deposited over glacial Lake Leverett material as the Huron lobe readvanced south during the Port Bruce Stadial. As the Huron lobe retreated north, coarse-grained glaciolacustrine materials were deposited in the Leamington area. Ice from the Erie lobe deposited the Port Stanley Till along the north shore of Lake Erie in Kent County and deflected meltwater southward from the Huron lobe in the Blenheim area. A series of recessional moraines were deposited by the Huron lobe as it retreated north. The area is capped by a fine-grained glaciolacustrine deposit.

scholarly journals Elucidating Pathfinding Elements from the Kubi Gold Mine in Ghana

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 912
Author(s):  
Gabriel K. Nzulu ◽  
Babak Bakhit ◽  
Hans Högberg ◽  
Lars Hultman ◽  
Martin Magnuson
Keyword(s):  
Photoelectron Spectroscopy ◽  
Chemical Weathering ◽  
Gold Mining ◽  
Coarse Grained ◽  
Small Scale ◽  
X Ray ◽  
Mining Sites ◽  
Fine Grained ◽  
Exploration Area ◽  
Indicator Minerals

X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX) are applied to investigate the properties of fine-grained concentrates on artisanal, small-scale gold mining samples from the Kubi Gold Project of the Asante Gold Corporation near Dunwka-on-Offin in the Central Region of Ghana. Both techniques show that the Au-containing residual sediments are dominated by the host elements Fe, Ag, Al, N, O, Si, Hg, and Ti that either form alloys with gold or with inherent elements in the sediments. For comparison, a bulk nugget sample mainly consisting of Au forms an electrum, i.e., a solid solution with Ag. Untreated (impure) sediments, fine-grained Au concentrate, coarse-grained Au concentrate, and processed ore (Au bulk/nugget) samples were found to contain clusters of O, C, N, and Ag, with Au concentrations significantly lower than that of the related elements. This finding can be attributed to primary geochemical dispersion, which evolved from the crystallization of magma and hydrothermal liquids as well as the migration of metasomatic elements and the rapid rate of chemical weathering of lateralization in secondary processes. The results indicate that Si and Ag are strongly concomitant with Au because of their eutectic characteristics, while N, C, and O follow alongside because of their affinity to Si. These non-noble elements thus act as pathfinders for Au ores in the exploration area. This paper further discusses relationships between gold and sediments of auriferous lodes as key to determining indicator minerals of gold in mining sites.

scholarly journals Loess in eastern equatorial Pangea archives a dusty atmosphere and possible upland glaciation

2020 ◽  
Vol 133 (1-2) ◽  
pp. 379-392 ◽  
Author(s):  
Lily S. Pfeifer ◽  
Gerilyn S. Soreghan ◽  
Stéphane Pochat ◽  
Jean Van Den Driessche
Keyword(s):  
Chemical Weathering ◽  
Ice Age ◽  
Coarse Grained ◽  
Mean Annual Temperature ◽  
Fine Grained ◽  
Chemical Index ◽  
Low Degree ◽  
Low Latitudes ◽  
Chemical Index Of Alteration ◽  
Unique Distribution

Abstract Carboniferous–Permian strata in basins within the Central Pangean Mountains in France archive regional paleoequatorial climate during a unique interval in geological history (Pangea assembly, ice-age collapse, megamonsoon inception). The voluminous (∼1.5 km) succession of exclusively fine-grained red beds that comprises the Permian Salagou Formation (Lodève Basin, France) has long been interpreted to record either lacustrine or fluvial deposition, primarily based on a local emphasis of subaqueous features in the upper ∼25% of the section. In contrast, data presented here indicate that the lower-middle Salagou Formation is dominated by up to 15-m-thick beds of internally massive red mudstone with abundant pedogenic features (microscale) and no evidence of channeling. Up-section, limited occurrences of ripple and hummocky cross-stratification, and mudcracks record the intermittent influence of shallow water, but with no channeling nor units with grain sizes exceeding coarse silt. These data suggest that the most parsimonious interpretation for the Salagou Formation involves eolian transport of the sediment and ultimate deposition as loess in shallow, ephemeral lacustrine environments. Provenance analyses of the Salagou Formation indicate coarse-grained protoliths and, together with geochemical proxies (chemical index of alteration [CIA] and τNa) that correspond respectively to a low degree of chemical weathering and a mean annual temperature of ∼4 °C, suggest that silt generation in this case is most consistent with cold-weathering (glacial and associated periglacial) processes in the Variscan highlands. Together with previous studies that detailed voluminous Permian loess in western equatorial Pangea, this work shows a globally unique distribution of dust at low latitudes that can be linked either directly to glaciated alpine terranes or to reworked and deflated deposits of other types (e.g., fluvial outwash) where fine-grained material was originally generated from glacial grinding in alpine systems. These results further support a revised model for early Permian climate, in which extratropical ice sheets coexisted with a semiarid tropics that may have hosted significant ice at moderate elevation.

Correlation between dislocation, grain boundary and interface of duplex SS in stress corrosion cracking(SCC)

1990 ◽  
Vol 48 (4) ◽  
pp. 928-929
Author(s):  
Wang Zheng-fang ◽  
Z.F. Wang
Keyword(s):  
Stainless Steel ◽  
Thermal Cycle ◽  
Secondary Phase ◽  
Corrosion Cracking ◽  
Coarse Grained ◽  
Test Environment ◽  
Fine Grained ◽  
Evaluation Test ◽  
Welding Thermal Cycle ◽  
Micro Analysis

The main purpose of this study highlights on the evaluation of chloride SCC resistance of the material,duplex stainless steel,OOCr18Ni5Mo3Si2 (18-5Mo) and its welded coarse grained zone(CGZ).18-5Mo is a dual phases (A+F) stainless steel with yield strength:512N/mm2 .The proportion of secondary Phase(A phase) accounts for 30-35% of the total with fine grained and homogeneously distributed A and F phases(Fig.1).After being welded by a specific welding thermal cycle to the material,i.e. Tmax=1350°C and t8/5=20s,microstructure may change from fine grained morphology to coarse grained morphology and from homogeneously distributed of A phase to a concentration of A phase(Fig.2).Meanwhile,the proportion of A phase reduced from 35% to 5-10°o.For this reason it is known as welded coarse grained zone(CGZ).In association with difference of microstructure between base metal and welded CGZ,so chloride SCC resistance also differ from each other.Test procedures:Constant load tensile test(CLTT) were performed for recording Esce-t curve by which corrosion cracking growth can be described, tf,fractured time,can also be recorded by the test which is taken as a electrochemical behavior and mechanical property for SCC resistance evaluation. Test environment:143°C boiling 42%MgCl2 solution is used.Besides, micro analysis were conducted with light microscopy(LM),SEM,TEM,and Auger energy spectrum(AES) so as to reveal the correlation between the data generated by the CLTT results and micro analysis.

THE IMPACT OF PHYSICAL AND CHEMICAL WEATHERING ON IRON SLAG FROM STANDISH, NY

2019 ◽  
Author(s):  
Maria L. Leonard ◽  
◽  
Rachel M. Kelk ◽  
Dori J. Farthing
Keyword(s):  
Chemical Weathering ◽  
Iron Slag ◽  
Physical And Chemical ◽  
The Impact

scholarly journals Balanced Sparsity for Efficient DNN Inference on GPU

2019 ◽  
Vol 33 ◽  
pp. 5676-5683 ◽  
Author(s):  
Zhuliang Yao ◽  
Shijie Cao ◽  
Wencong Xiao ◽  
Chen Zhang ◽  
Lanshun Nie
Keyword(s):  
Deep Neural Networks ◽  
General Purpose ◽  
Coarse Grained ◽  
Efficient Computation ◽  
Model Accuracy ◽  
Sparse Model ◽  
Model Inference ◽  
Fine Grained ◽  
Practical Inference ◽  
Speed Up

In trained deep neural networks, unstructured pruning can reduce redundant weights to lower storage cost. However, it requires the customization of hardwares to speed up practical inference. Another trend accelerates sparse model inference on general-purpose hardwares by adopting coarse-grained sparsity to prune or regularize consecutive weights for efficient computation. But this method often sacrifices model accuracy. In this paper, we propose a novel fine-grained sparsity approach, Balanced Sparsity, to achieve high model accuracy with commercial hardwares efficiently. Our approach adapts to high parallelism property of GPU, showing incredible potential for sparsity in the widely deployment of deep learning services. Experiment results show that Balanced Sparsity achieves up to 3.1x practical speedup for model inference on GPU, while retains the same high model accuracy as finegrained sparsity.

scholarly journals Submarine lava deltas of the 2018 eruption of Kīlauea volcano

2021 ◽  
Vol 83 (4) ◽  
Author(s):  
S. Adam Soule ◽  
Michael Zoeller ◽  
Carolyn Parcheta
Keyword(s):  
Grain Size ◽  
Pore Pressure ◽  
Mechanistic Model ◽  
Large Fraction ◽  
Volcanic Hazards ◽  
Lava Flows ◽  
Coarse Grained ◽  
Fine Grained ◽  
Fine Grain ◽  
Delta Formation

AbstractHawaiian and other ocean island lava flows that reach the coastline can deposit significant volumes of lava in submarine deltas. The catastrophic collapse of these deltas represents one of the most significant, but least predictable, volcanic hazards at ocean islands. The volume of lava deposited below sea level in delta-forming eruptions and the mechanisms of delta construction and destruction are rarely documented. Here, we report on bathymetric surveys and ROV observations following the Kīlauea 2018 eruption that, along with a comparison to the deltas formed at Pu‘u ‘Ō‘ō over the past decade, provide new insight into delta formation. Bathymetric differencing reveals that the 2018 deltas contain more than half of the total volume of lava erupted. In addition, we find that the 2018 deltas are comprised largely of coarse-grained volcanic breccias and intact lava flows, which contrast with those at Pu‘u ‘Ō‘ō that contain a large fraction of fine-grained hyaloclastite. We attribute this difference to less efficient fragmentation of the 2018 ‘a‘ā flows leading to fragmentation by collapse rather than hydrovolcanic explosion. We suggest a mechanistic model where the characteristic grain size influences the form and stability of the delta with fine grain size deltas (Pu‘u ‘Ō‘ō) experiencing larger landslides with greater run-out supported by increased pore pressure and with coarse grain size deltas (Kīlauea 2018) experiencing smaller landslides that quickly stop as the pore pressure rapidly dissipates. This difference, if validated for other lava deltas, would provide a means to assess potential delta stability in future eruptions.

scholarly journals A cooperative DDoS attack detection scheme based on entropy and ensemble learning in SDN

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Shanshan Yu ◽  
Jicheng Zhang ◽  
Ju Liu ◽  
Xiaoqing Zhang ◽  
Yafeng Li ◽  
...  
Keyword(s):  
Ensemble Learning ◽  
Denial Of Service ◽  
Attack Detection ◽  
Coarse Grained ◽  
Communication Overhead ◽  
Detection Scheme ◽  
Fine Grained ◽  
Ddos Attack ◽  
Network Status ◽  
Ddos Attack Detection

AbstractIn order to solve the problem of distributed denial of service (DDoS) attack detection in software-defined network, we proposed a cooperative DDoS attack detection scheme based on entropy and ensemble learning. This method sets up a coarse-grained preliminary detection module based on entropy in the edge switch to monitor the network status in real time and report to the controller if any abnormality is found. Simultaneously, a fine-grained precise attack detection module is designed in the controller, and a ensemble learning-based algorithm is utilized to further identify abnormal traffic accurately. In this framework, the idle computing capability of edge switches is fully utilized with the design idea of edge computing to offload part of the detection task from the control plane to the data plane innovatively. Simulation results of two common DDoS attack methods, ICMP and SYN, show that the system can effectively detect DDoS attacks and greatly reduce the southbound communication overhead and the burden of the controller as well as the detection delay of the attacks.

Russellite: a second occurrence

1970 ◽  
Vol 37 (290) ◽  
pp. 705-707 ◽  
Author(s):  
L. C. Hodge
Keyword(s):  
Powder Diffraction ◽  
Western Australia ◽  
Original Description ◽  
Chemical Data ◽  
Green Material ◽  
X Ray ◽  
Fine Grained ◽  
Physical And Chemical ◽  
Pale Green

SummaryRussellite Bi2O3. WO3 occurs in a small pegmatite near Poona, Western Australia. The fine-grained yellow to pale green material is an inseparable mixture of russellite, bismite, koechlinite, and bismutite. X-ray powder diffraction, physical, and chemical data agree in general with the original description of the mineral from Cornwall, England. The original analyses made on micro quantities are now supplemented by analyses on macro quantities.

Rheology of hydrocarbon gels

1950 ◽  
Vol 200 (1061) ◽  
pp. 183-188 ◽  
Keyword(s):  
Mechanical Properties ◽  
Experimental Measurement ◽  
Theoretical Basis ◽  
Continuous Media ◽  
Point Of View ◽  
Coarse Grained ◽  
Testing Instrument ◽  
Fine Grained ◽  
Mineral Oils ◽  
Space And Time

Hydrocarbon gels contain a number of materials, such as rubber, greases, saponified mineral oils, etc., of great interest for various engineering purposes. Specific requirements in mechanical properties have been met by producing gels in appropriately chosen patterns of constituent components of visible, colloidal, molecular and atomic sizes, ranging from coarse-grained aggregates, represented by sponges, foams, emulsions, etc.; to fine-grained and apparently homogeneous ones, represented by optically clear compounds. The engineer who has to deal with the whole range of such materials will adopt a macroscopic point of view, based on an apparent continuity of all the material structures and of the distributions in space and time of the displacements and forces occurring under mechanical actions. It has been possible to determine these distributions in the framework of a comprehensive scheme in which the fundamental principles of the mechanics of continuous media provide the theoretical basis, and a testing instrument of new design, termed Rheogoniometer, the means of experimental measurement (Weissenberg 1931, 1934, 1946, 1947, 1948).

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