scholarly journals Impact of snow deposition on major and trace element concentrations and fluxes in surface waters of Western Siberian Lowland

Author(s):  
Vladimir P. Shevchenko ◽  
Oleg S. Pokrovsky ◽  
Sergey N. Vorobyev ◽  
Ivan V. Krickov ◽  
Rinat M. Manasypov ◽  
...  

Abstract. Towards a better understanding of chemical composition of snow and its impact on surface water hydrochemistry in poorly studied Western Siberia Lowland (WSL), dissolved (melted snow) and particulate (> 0.45 μm) fractions of snow were sampled in February 2014 across a 1700-km latitudinal gradient (c.a. 56.5 to 68° N) in essentially pristine regions. Concentration of dissolved Fe, Co, Cu, As, La, increased by a factor of 2 to 5 north of 63° N. The pH, Ca, Mg, Sr, Mo and U dissolved concentration in snow water increased with the increase in concentration of particulate fraction (PF), which was also correlated with the increase in calcite and dolomite proportion in the mineral fraction, suggesting an enrichment of meltwater by these elements during dissolution of carbonate minerals. The concentrations of Al, Fe, Pb, La and other insoluble elements in

2017 ◽  
Vol 21 (11) ◽  
pp. 5725-5746 ◽  
Author(s):  
Vladimir P. Shevchenko ◽  
Oleg S. Pokrovsky ◽  
Sergey N. Vorobyev ◽  
Ivan V. Krickov ◽  
Rinat M. Manasypov ◽  
...  

Abstract. In order to better understand the chemical composition of snow and its impact on surface water hydrochemistry in the poorly studied Western Siberia Lowland (WSL), the surface layer of snow was sampled in February 2014 across a 1700 km latitudinal gradient (ca. 56.5 to 68° N). We aimed at assessing the latitudinal effect on both dissolved and particulate forms of elements in snow and quantifying the impact of atmospheric input to element storage and export fluxes in inland waters of the WSL. The concentration of dissolved+colloidal (< 0.45 µm) Fe, Co, Cu, As and La increased by a factor of 2 to 5 north of 63° N compared to southern regions. The pH and dissolved Ca, Mg, Sr, Mo and U in snow water increased with the rise in concentrations of particulate fraction (PF). Principal component analyses of major and trace element concentrations in both dissolved and particulate fractions revealed two factors not linked to the latitude. A hierarchical cluster analysis yielded several groups of elements that originated from alumino-silicate mineral matrix, carbonate minerals and marine aerosols or belonging to volatile atmospheric heavy metals, labile elements from weatherable minerals and nutrients. The main sources of mineral components in PF are desert and semi-desert regions of central Asia. The snow water concentrations of DIC, Cl, SO4, Mg, Ca, Cr, Co, Ni, Cu, Mo, Cd, Sb, Cs, W, Pb and U exceeded or were comparable with springtime concentrations in thermokarst lakes of the permafrost-affected WSL zone. The springtime river fluxes of DIC, Cl, SO4, Na, Mg, Ca, Rb, Cs, metals (Cr, Co, Ni, Cu, Zn, Cd, Pb), metalloids (As, Sb), Mo and U in the discontinuous to continuous permafrost zone (64–68° N) can be explained solely by melting of accumulated snow. The impact of snow deposition on riverine fluxes of elements strongly increased northward, in discontinuous and continuous permafrost zones of frozen peat bogs. This was consistent with the decrease in the impact of rock lithology on river chemical composition in the permafrost zone of the WSL, relative to the permafrost-free regions. Therefore, the present study demonstrates significant and previously underestimated atmospheric input of many major and trace elements to their riverine fluxes during spring floods. A broader impact of this result is that current estimations of river water fluxes response to climate warming in high latitudes may be unwarranted without detailed analysis of winter precipitation.


Author(s):  
Ketevan Kupatadze

The article reviews the chemical composition of borehole and surface waters in three villages of one of the regions of Georgia - Kakheti, Gurjaani Municipality. The study was specifically focused on iodine content in waters. It turned out that certain amount of iodine really existed in borehole waters, which means that by everyday drinking of water, the human body gets maybe not the complete required amount of iodine, but at least some part of it. It was also discovered, that according to certain parameters, waters are clean, do not contain heavy metals and can be freely used for drinking and cooking. The chemical composition of the Alazani River was also examined according to all four seasons. This river is interesting because of being used for irrigation of vineyards and fruit gardens.


Author(s):  
Ketevan KUPATADZE

The article reviews the chemical composition of borehole and surface waters in three villages of one of the regions of Georgia - Kakheti, Gurjaani Municipality. The study was specifically focused on iodine content in waters. It turned out that certain amount of iodine really existed in borehole waters, which means that by everyday drinking of water, the human body gets maybe not the complete required amount of iodine, but at least some part of it. It was also discovered, that according to certain parameters, waters are clean, do not contain heavy metals and can be freely used for drinking and cooking. The chemical composition of the Alazani River was also examined according to all four seasons. This river is interesting because of being used for irrigation of vineyards and fruit gardens.


Author(s):  
Vladimir P. Shevchenko ◽  
Oleg S. Pokrovsky ◽  
Sergey N. Vorobyev ◽  
Ivan V. Krickov ◽  
Rinat M. Manasypov ◽  
...  

2021 ◽  
Vol 6 (2(35)) ◽  
pp. 5-10
Author(s):  
Liliya Zuberovna Zhinzhakova ◽  
Elena Alexandrovna Cherednik

The assessment of the chemical composition and quality of glacial waters for the period 2017-2018 was carried out according to the maximum permissible concentrations. The results of the study of the content of the trace element Mn and mineral nitrogen compounds in the waters of glacial rivers are presented. According to observations during this period, the features of the waters of the studied rivers and their difference in the level of pollution were revealed. An ecological assessment of the pollution of water bodies is given according to the classification of the quality of surface waters of the land. The data are presented in tables.


Water ◽  
2022 ◽  
Vol 14 (1) ◽  
pp. 94
Author(s):  
Ivan V. Krickov ◽  
Artem G. Lim ◽  
Vladimir P. Shevchenko ◽  
Sergey N. Vorobyev ◽  
Frédéric Candaudap ◽  
...  

Snow cover is known to be an efficient and unique natural archive of atmospheric input and an indicator of ecosystem status. In high latitude regions, thawing of snow provides a sizable contribution of dissolved trace metals to the hydrological network. Towards a better understanding of natural and anthropogenic control on heavy metals and metalloid input from the atmosphere to the inland waters of Siberian arctic and subarctic regions, we measured chemical composition of dissolved (<0.22 µm) fractions of snow across a 2800 km south–north gradient in Western Siberia. Iron, Mn, Co, Ni, and Cd demonstrated sizable (by a factor of 4–7) decrease in concentration northward, which can be explained by a decrease in overall population density and the influence of dry aerosol deposition. Many elements (Mn, Ni, Cu, Cd, Pb, As, and Sb) exhibited a prominent local maximum (a factor of 2–3) in the zone of intensive oil and gas extraction (61–62° N latitudinal belt), which can be linked to gas flaring and fly ash deposition. Overall, the snow water chemical composition reflected both local and global (long-range) atmospheric transfer processes. Based on mass balance calculation, we demonstrate that the winter time atmospheric input represents sizable contribution to the riverine export fluxes of dissolved (<0.45 µm) Mn, Co, Zn, Cd, Pb, and Sb during springtime and can appreciably shape the hydrochemical composition of the Ob River main stem and tributaries.


Author(s):  
A. I. Gavrishin

The regularities in forming chemical composition of mine and surface waters in the Eastern Donbass were studied using the techniques of statistical estimation of component concentration distributions, the methods of assessing environment pollution, and the digital computer technology on multidimensional classification observations AGAT-2. The article shows that the mine water in the Eastern Donbass is a powerful source of polluting environment, causing serious ecological damage to the territory. Coal mine water contain a lot of dissolved substances up to 413 thousand t/year, among which macro components and various metals forming a significant part. The mean concentrations of most components in mine water hundreds times exceed the maximum allowable concentrations (MACs), and they exceed the maximum concentrations in thousands times. The surface water quality was analyzed in the region proceeding from the results of testing small rivers and streams. Using classification technologies, five genetic variants of surface waters were identified by the macrocomponents. The first option characterizes the initial phase of surface water formation outside the pollution impact. Other options reflect the growing degree of water pollution in the region. The distribution of genetic water variants was shown throughout the region. The calculation of surface water pollution by 20 components revealed the cumulative indicator of pollution to be equal to 108 corresponding to the emergency crisis category. About 65% components exceed MAC. Surface water classes uniform in the content of 15 metals were distinguished using the digital computer technology AGAT-2. A cumulative indicator of pollution varies from 27 to 65, which corresponds to a tense and emergency crisis situations. Therefore, mine waters pollute significantly the surface waters in the Eastern Donbass. Conclusion is made about the need for rehabilitation measures in order to improve the quality of surface waters in the region.


2019 ◽  
Vol 46 (6) ◽  
pp. 613-620
Author(s):  
A. P. Chevychelov ◽  
P. I. Sobakin ◽  
L. I. Kuznetsova

Chemical composition of the surface water and the contents of the radionuclides 238U, 226Ra, and 222Rn in water was examined within the natural and man-made landscapes of South Yakutiya. It was demonstrated that intense water migration of these radionuclides from radioactive dump pits of the man-made landscapes of the Elkonsky uranium-ore district, which were created during the process of wide-scale exploration surveys for radioactive raw materials conducted during the last third of the 20th century, had occurred. Currently, the areas of water dissipation of 238U and 226Ra are detected at a distances of 2 km and greater from the source of the radioactive contamination along the outflow vector.


2007 ◽  
Vol 7 (3) ◽  
pp. 103-110
Author(s):  
C. Schilling ◽  
M. Zessner ◽  
A.P. Blaschke ◽  
D. Gutknecht ◽  
H. Kroiss

Two Austrian case study regions within the Danube basin have been selected for detailed investigations of groundwater and surface water quality at the catchment scale. Water balance calculations have been performed using the conceptual continuous time SWAT 2000 model to characterise catchment hydrology and to identify individual runoff components contributing to river discharge. Nitrogen emission calculations have been performed using the empirical emission model MONERIS to relate individual runoff components to specific nitrogen emissions and for the quantification of total nitrogen emissions to surface waters. Calculated total nitrogen emissions to surface waters using the MONERIS model were significantly influenced by hydrological conditions. For both catchments the groundwater could be identified as major emission pathway of nitrogen emissions to the surface waters. Since most of the nitrogen is emitted by groundwater to the surface water, denitrification in groundwater is of considerable importance reducing nitrogen levels in groundwater along the flow path towards the surface water. An approach was adopted for the grid-oriented estimation of diffuse nitrogen emissions based on calculated groundwater residence time distributions. Denitrification in groundwater was considered using a half life time approach. It could be shown that more than 90% of the total diffuse nitrogen emissions were contributed by areas with low groundwater residence times and short distances to the surface water. Thus, managing diffuse nitrogen emissions the location of catchment areas has to be considered as well as hydrological and hydrogeological conditions, which significantly influence denitrification in the groundwater and reduce nitrogen levels in groundwater on the flow path towards the surface water.


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