scholarly journals Winter climate affects long-term trends in stream water nitrate in acid-sensitive catchments in southern Norway

2007 ◽  
Vol 4 (5) ◽  
pp. 3055-3085 ◽  
Author(s):  
H. A. de Wit ◽  
A. Hindar ◽  
L. Hole

Abstract. Controls of stream water NO3 in mountainous and forested catchments are not thoroughly understood. Long-term trends in stream water NO3 are positive, neutral and negative, often apparently independent of trends in N deposition. Here, time series of NO3 in four small acid-sensitive catchments in southern Norway were analysed in order to identify likely drivers of long-term changes in NO3. In two sites, stream water NO3 export declined ca 50% over a period of 25 years while in the other sites NO3 export increased with roughly 20%. Discharge and N deposition alone were poor predictors of these trends. The most distinct trends in NO3 were found in winter and spring. Empirical models explained between 45% and 61% of the variation in weekly concentrations of NO3, and described both upward and downward seasonal trends tolerably well. Key explaining variables were snow depth, discharge, temperature and N deposition. All catchments showed reductions in snow depth and increases in winter discharge. In two inland catchments, located in moderate N deposition areas, these climatic changes appeared to drive the distinct decreases in winter and spring concentrations and fluxes of NO3. In a coast-near mountainous catchment in a low N deposition area, these climatic changes appeared to have the opposite effect, i.e. lead to increases in especially winter NO3. This suggests that the effect of a reduced snow pack may result in both decreased and increased catchment N leaching depending on interactions with N deposition, soil temperature regime and winter discharge.

2008 ◽  
Vol 12 (2) ◽  
pp. 393-403 ◽  
Author(s):  
H. A. de Wit ◽  
A. Hindar ◽  
L. Hole

Abstract. Controls of stream water NO3 in mountainous and forested catchments are not thoroughly understood. Long-term trends in stream water NO3 are positive, neutral and negative, often apparently independent of trends in N deposition. Here, time series of NO3 in four small acid-sensitive catchments in southern Norway were analysed in order to identify likely drivers of long-term changes in NO3. In two sites, stream water NO3 export declined ca 50% over a period of 25 years while in the other sites NO3 export increased with roughly 20%. Discharge and N deposition alone were poor predictors of these trends. The most distinct trends in NO3 were found in winter and spring. Empirical models explained between 45% and 61% of the variation in weekly concentrations of NO3, and described both upward and downward seasonal trends tolerably well. Key explaining variables were snow depth, discharge, temperature and N deposition. All catchments showed reductions in snow depth and increases in winter discharge. In two inland catchments, located in moderate N deposition areas, these climatic changes appeared to drive the distinct decreases in winter and spring concentrations and fluxes of NO3. In a coast-near mountainous catchment in a low N deposition area, these climatic changes appeared to have the opposite effect, i.e. lead to increases in especially winter NO3. This suggests that the effect of a reduced snow pack may result in both decreased and increased catchment N leaching depending on interactions with N deposition, soil temperature regime and winter discharge.


2007 ◽  
Vol 11 (1) ◽  
pp. 614-622 ◽  
Author(s):  
M. Ranzini ◽  
M. C. Forti ◽  
P. G. Whitehead ◽  
F. C. S. Arcova ◽  
V. de Cicco ◽  
...  

Abstract. Stream-water flows and in-stream nitrate and ammonium concentrations in a small (36.7 ha) Atlantic Forest catchment were simulated using the Integrated Nitrogen in CAtchments (INCA) model version 1.9.4. The catchment, at Cunha, is in the Serra do Mar State Park, SE Brazil and is nearly pristine because the nearest major conurbations, São Paulo and Rio, are some 450 km distant. However, intensive farming may increase nitrogen (N) deposition and there are growing pressures for urbanisation. The mean-monthly discharges and NO3-N concentration dynamics were simulated adequately for the calibration and validation periods with (simulated) loss rates of 6.55 kg.ha−1 yr−1 for NO3-N and 3.85 kg.ha−1 yr−1 for NH4-N. To investigate the effects of elevated levels of N deposition in the future, various scenarios for atmospheric deposition were simulated; the highest value corresponded to that in a highly polluted area of Atlantic Forest in Sao Paulo City. It was found that doubling the atmospheric deposition generated a 25% increase in the N leaching rate, while at levels approaching the highly polluted São Paulo deposition rate, five times higher than the current rate, leaching increased by 240%, which would create highly eutrophic conditions, detrimental to downstream water quality. The results indicate that the INCA model can be useful for estimating N concentration and fluxes for different atmospheric deposition rates and hydrological conditions.


Forests ◽  
2021 ◽  
Vol 12 (12) ◽  
pp. 1798
Author(s):  
Piaopiao Ke ◽  
Gaoyue Si ◽  
Yao Luo ◽  
Zhenglin Cheng ◽  
Qian Yu ◽  
...  

Anthropogenic emissions of nitrogen- (N) and sulfur (S)-containing pollutants have declined across China in recent years. However, the responses of N and S depositions and dynamics in soil remain unclear in subtropical forests. In this study, the wet and throughfall depositions of dissolved inorganic N (DIN) and SO42− were continuously monitored in a mildly polluted subtropical forest in Southeast China in 2017 and 2018. Moreover, these solutes in soil water along the soil profile were monitored in 2018. Throughfall deposition of DIN and S decreased by 59% and 53% in recent 3 years, respectively, which can be majorly attributed to the decreases in wet depositions of NO3− and SO42−. Meanwhile, NH4+ deposition remained relatively stable at this site. Even though N deposition in 2018 was below the N saturation threshold for subtropical forests, significant N leaching still occurred. Excess export of N occurred in the upper soil layer (0–15 cm), reaching 6.86 ± 1.54 kg N/ha/yr, while the deeper soil (15–30 cm) was net sink of N as 8.29 ± 1.71 kg N/ha/yr. Similarly, S was excessively exported from the upper soil with net flux of 14.7 ± 3.15 kg S/ha/yr, while up to 6.37 ± 3.18 kg S/ha/yr of S was retained in the deeper soil. The significant N and S leaching under declined depositions suggested that this site possibly underwent a transition state, recovering from historically high acid deposition. Furthermore, the rainfall intensity remarkably regulated leaching and retention of SO42− and DIN at this site. The impacts of climate changes on N and S dynamics require further long-term monitoring in subtropical forests.


2002 ◽  
Vol 6 (1) ◽  
pp. 101-112 ◽  
Author(s):  
Ø. Kaste ◽  
A. Henriksen ◽  
M. Posch

Abstract. The steady-state First-order Acidity Balance (FAB) model for calculating critical loads of sulphur (S) and nitrogen (N) is applied to 609 Norwegian soft-water lakes to assess the future nitrate (NO3‾) leaching potential under present (1992-96) S and N deposition. The lakes were separated into five groups receiving increasing levels of N deposition (<25, 25-49, 50-74, 75-99 and 100-125 meq m-2yr-1). Using long-term sustainable N sink rates presently recommended for FAB model applications, N immobilisation, net N uptake in forests, denitrification and in-lake N retention were estimated for each group of lakes. Altogether, the long-term N sinks constituted 9.9 ± 3.2 to 40.5 ± 11.4 meq m-2yr-1 in the lowest and highest N deposition categories, respectively. At most sites, the current N deposition exceeds the amount of N retained by long-term sustainable N sinks plus the NO3‾ loss via the lake outlets. This excess N, which is currently retained within the catchments may, according to the FAB model, leach as acidifying NO3‾ in the future. If these predictions are fulfilled, NO3‾ leaching at sites in the various N deposition categories will increase dramatically from present (1995) mean levels of 1-20 meq m-2yr-1, to mean levels of 7-70 meq m-2yr-1 at future steady state. To illustrate the significance of such an increase in NO3‾ leaching, the mean Acid Neutralising Capacity (ANC) at sites in the highest N deposition category may decrease from -18 ± 15 μeq L-1 at present, to -40 ± 20 μeq L-1. Under present S and N deposition levels, the FAB model predicts that 46% of the Norwegian lakes may experience exceedances of critical loads for acidifying deposition. In comparison, the Steady-State Water Chemistry model (SSWC), which considers only the present N leaching level, estimates critical load exceedances in 37% of the lakes under the same deposition level. Thus far, there are great uncertainties regarding both the time scales and the extent of future N leaching, and it is largely unknown whether the FAB model predictions will ever be fulfilled. Hence, long-term monitoring and further studies on N immobilisation processes under varying N deposition levels and ecosystem types seem necessary to make better predictions of future NO3‾ leaching. Keywords: Lakes, hydrochemistry, nitrogen, nitrate, sinks, leaching, acidification, critical loads, FAB model


1995 ◽  
Vol 26 (4-5) ◽  
pp. 369-388 ◽  
Author(s):  
Espen Lydersen ◽  
Arne Henriksen

Input of neutral salt, primarily NaCl, from sea spray is an important factor for short-term acidification of surface water, primarily in already acidified areas, because Na may substitute for H+ and cationic aluminium by cation-exchange reactions in the soil. By evaluating the variation of non-marine sodium (Na*) separately it is possible to estimate the major effect of seasalt episodes on the neutralizing capacity (ANC) of stream water. At four long-term monitored Norwegian catchments, the Na* in stream water on average explained 28 ± 4% of the monthly variations of ANC in stream water at Birkenes, and 27 ± 3%, 20 ± 2% and 56 ± 5% of the correspondent variations at Storgama, Langtjern and Kaarvatn, during the respective monitoring periods. The remaining variations in acid neutralizing capacity are explained by the difference between non-marine base cations (ΣCa*,Mg*,K*) and non-marine sulphate (SO4*) and NO3. This paper also indicates that seasalt episodes are probably of greater importance for the periodic variations in ANC of stream water than commonly recognized. During the last years, extreme seasalt episodes have occurred in southern Norway, and more frequently at winter-time, which means that seasalt inputs have played a more important role for the short-term variations of ANC in stream water the last years. This tendency is also strengthened by the fact that there has been a significant decline in the input of acidic sulphur compounds and non-marine base cations in stream water during the last 10-15 years. Because the decline in soil-derived base cations in stream water is somewhat lower than the correspondent decline of sulphate, a slowly improving ANC of stream water should be expected on long-term basis. Seasalt episodes of the same magnitude as those present during the last years, will therefore most likely cause less extreme water-chemical conditions in the years to come. Because the seasalt effect seems to be a short-term effect, there is no reason to claim that these effects may cause long-term acidification, a conclusion earlier drawn from several correspondent studies.


2012 ◽  
Vol 42 (3) ◽  
pp. 437-450 ◽  
Author(s):  
Juan A. Blanco ◽  
Xiaohua Wei ◽  
Hong Jiang ◽  
Cheng-Yue Jie ◽  
Zan-Hong Xin

Atmospheric pollution levels in China are increasing quickly. Experience from other polluted regions shows that tree growth could be affected, but long-term effects of N deposition and soil acidification on Chinese forests remain mostly unknown. Soil acidification and N deposition were simulated for Chinese fir ( Cunninghamia lanceolata (Lamb.) Hook.) plantations managed for three consecutive 20-year rotations in southeastern China. A factorial experiment combined four rain pH levels (2.5, 4.0, 5.6, and 7.0), four N deposition rates (1, 7.5, 15, and 30 kg N·ha–1·year–1), and two site qualities (poor and rich). Results indicate that atmospheric pollution effects are not immediate, but after one to two rotations, soil acidification effects could reduce ecosystem C pools significantly (–25% and –11% in poor and rich sites, respectively). N deposition rates above 15 kg N·ha–1·year–1 could offset some of the negative effects of soil acidification and lead to more ecosystem C (19 and 28 Mg C·ha–1 more in poor and rich sites, respectively, than in low N deposition). However, at high N deposition rates (>15 kg N·ha–1·year–1), N leaching losses could greatly increase, reaching 75 kg N·ha–1·year–1. Moderate N deposition could increase tree biomass production and soil organic mass, resulting in increased ecosystem C, but these gains could be associated with important N leaching. Atmospheric pollution could also result in the long term in nutrient imbalances and additional ecological issues (i.e., biodiversity loss, eutrophication, etc.) not studied here.


2001 ◽  
Vol 5 (3) ◽  
pp. 299-310 ◽  
Author(s):  
R. F. Wright ◽  
C. Alewell ◽  
J. M. Cullen ◽  
C. D. Evans ◽  
A. Marchetto ◽  
...  

Abstract. Long-term records of nitrogen in deposition and streamwater were analysed at 30 sites covering major acid sensitive regions in Europe. Large regions of Europe have received high inputs of inorganic nitrogen for the past 20 - 30 years, with an approximate 20% decline in central and northern Europe during the late 1990s. Nitrate concentrations in streamwaters are related to the amount of N deposition. All sites with less than 10 kgN ha-1 yr-1 deposition have low concentrations of nitrate in streamwater, whereas all sites receiving > 25 kgN ha-1 yr-1 have elevated concentrations. Very few of the sites exhibit significant trends in nitrate concentrations; similar analyses on other datasets also show few significant trends. Nitrogen saturation is thus a process requiring many decades, at least at levels of N deposition typical for Europe. Declines in nitrate concentrations at a few sites may reflect recent declines in N deposition. The overall lack of significant trends in nitrate concentrations in streams in Europe may be the result of two opposing factors. Continued high deposition of nitrogen (above the 10 kgN ha-1 yr-1 threshold) should tend to increase N saturation and give increased nitrate concentrations in run-off, whereas the decline in N deposition over the past 5 – 10 years in large parts of Europe should give decreased nitrate concentrations in run-off. Short and long-term variations in climate affect nitrate concentrations in streamwater and, thus, contribute "noise" which masks long-term trends. Empirical data for geographic pattern and long-term trends in response of surface waters to changes in N deposition set the premises for predicting future contributions of nitrate to acidification of soils and surface waters. Quantification of processes governing nitrogen retention and loss in semi-natural terrestrial ecosystems is a scientific challenge of increasing importance. Keywords: Europe, acid deposition, nitrogen, saturation, recovery, water


2012 ◽  
Vol 44 (1) ◽  
pp. 169-179 ◽  
Author(s):  
Anita Verpe Dyrrdal ◽  
Tuomo Saloranta ◽  
Thomas Skaugen ◽  
Heidi Bache Stranden

Observed trends in annual maximum snow depth (SD) in Norway are analyzed and examined in the context of changes in winter climate from 1961 until today. Trends are evaluated for the 50-year period (1961–2010) and for three 30-year periods (1961–1990, 1971–2000, 1981–2010). The analyzed dataset is the most extensive and geographically representative for the country so far, and the analysis gives an up-to-date picture of the recent development in snow accumulation. In regions characterized by colder winter climate long-term trends are found to be positive in general, while short-term trends shift from strongly positive in the first period to predominantly negative in the last period. Variation in SD is here mainly linked to variation in precipitation. In regions of warmer winter climate variation in SD is dominated by temperature, and long-term trends are mainly negative. Short-term trends start out weak overall in the first period but become strongly negative most places in the last period. It is likely that, although more and more regions in Norway will experience declining maximum annual SD in a projected wetter and warmer future climate, some inland and higher mountain regions may still accumulate more snow in the coming decades.


2016 ◽  
Vol 13 (19) ◽  
pp. 5567-5585 ◽  
Author(s):  
Marta Camino-Serrano ◽  
Elisabeth Graf Pannatier ◽  
Sara Vicca ◽  
Sebastiaan Luyssaert ◽  
Mathieu Jonard ◽  
...  

Abstract. Dissolved organic carbon (DOC) in surface waters is connected to DOC in soil solution through hydrological pathways. Therefore, it is expected that long-term dynamics of DOC in surface waters reflect DOC trends in soil solution. However, a multitude of site studies have failed so far to establish consistent trends in soil solution DOC, whereas increasing concentrations in European surface waters over the past decades appear to be the norm, possibly as a result of recovery from acidification. The objectives of this study were therefore to understand the long-term trends of soil solution DOC from a large number of European forests (ICP Forests Level II plots) and determine their main physico-chemical and biological controls. We applied trend analysis at two levels: (1) to the entire European dataset and (2) to the individual time series and related trends with plot characteristics, i.e., soil and vegetation properties, soil solution chemistry and atmospheric deposition loads. Analyses of the entire dataset showed an overall increasing trend in DOC concentrations in the organic layers, but, at individual plots and depths, there was no clear overall trend in soil solution DOC. The rate change in soil solution DOC ranged between −16.8 and +23 % yr−1 (median  = +0.4 % yr−1) across Europe. The non-significant trends (40 %) outnumbered the increasing (35 %) and decreasing trends (25 %) across the 97 ICP Forests Level II sites. By means of multivariate statistics, we found increasing trends in DOC concentrations with increasing mean nitrate (NO3−) deposition and increasing trends in DOC concentrations with decreasing mean sulfate (SO42−) deposition, with the magnitude of these relationships depending on plot deposition history. While the attribution of increasing trends in DOC to the reduction of SO42− deposition could be confirmed in low to medium N deposition areas, in agreement with observations in surface waters, this was not the case in high N deposition areas. In conclusion, long-term trends of soil solution DOC reflected the interactions between controls acting at local (soil and vegetation properties) and regional (atmospheric deposition of SO42− and inorganic N) scales.


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