scholarly journals Pemanfaatan kulit singkong sebagai bahan baku pembuatan Natrium Karbosimetil Selulosa

2018 ◽  
Vol 11 (3) ◽  
pp. 124
Author(s):  
Shella Permatasari Santoso ◽  
Niko Sanjaya ◽  
Aning Ayucitra
Keyword(s):  
Sodium Hydroxide ◽  
Carboxymethyl Cellulose ◽  
Isopropyl Alcohol ◽  
Degree Of Substitution ◽  
Raw Material ◽  
Sodium Carboxymethyl Cellulose ◽  
Carboxymethyl Cellulose Sodium ◽  
Alcohol Solvent ◽  
Cassava Peels ◽  
Cassava Peel

The use of cassava peels as raw material for Sodium Carboxymethyl Cellulose productionCassava peels are abundantly available and may be used as an lowcost cellulose source (80-85% cellulose per weight cassava peel). the study was to evaluate the effect of the concentration of sodium hydroxide, sodium chloroacetate, and temperature reaction on the sodium carboxymethyl cellulose (sodium-CMC) characteristics i.e. yield, purity, and degree of substitution in sodium-CMC preparation.  Sodium-CMC functional group was determined using FTIR spectrophotometer. Cassava peels was dried and grounded to 50 mesh. Lignin was eliminated from cassava peel by extraction of grounded cassava peel with 10% NaOH at 35 °C for 5 h. Cassava peel free lignin was then re-extracted using 10% of acetic acid and sodium chloride at 75 °C for 1 h, thus cellulose free hemicellulose was obtained. Alkalization at 30 °C for 90 min was performed by adding sodium hydroxyde at 10-40% to cellulose using isopropyl alcohol solvent. Following this, etherification was conducted by adding sodium chloroacetate of 1-5 g at 50-80 °C for 6 h. As result, the highest purity of sodium-CMC (96.20%) was obtained from alkalization using 20% of sodium hydroxide and etherification using 3 g sodium chloroacetate at 70 °C. Sodium-CMC yield was 22% and degree of substitution 0.705.Keywords: cassava peel, carboxymethyl cellulose, sodium-CMC, etherification AbstrakKulit singkong merupakan sumber selulosa yang berlimpah dan murah, dengan kadar selulosa 80-85% dari berat kulit singkong. Tujuan penelitian ini adalah memanfaatkan selulosa dalam kulit singkong sebagai bahan baku pembuatan natrium karboksimetil selulosa (Na-CMC), mempelajari pengaruh natrium hidroksida, natrium kloroasetat serta suhu pada karakteristik Na-CMC seperti perolehan, kemurnian, dan derajat substitusi, serta menentukan kondisi operasi optimum untuk pembuatan Na-CMC berdasarkan kemurnian Na-CMC terbesar. Gugus fungsi Na-CMC ditentukan menggunakan Fourier Transform Infrared Spectra. Mula-mula, kulit singkong dikeringkan dan dihancurkan sehingga berukuran 50 mesh. Kulit singkong diekstraksi dengan NaOH 10% di suhu 35 °C selama 5 jam, untuk melarutkan lignin. Kulit singkong bebas lignin diekstrak dengan asam asetat 10% dan natrium klorida dengan pemanasan 750 °C selama 1 jam untuk melarutkan hemiselulosa sehingga didapatkan selulosa. Alkalisasi dilakukan dengan mereaksikan selulosa dengan NaOH 10-40% dengan pelarut isopropil alkohol pada suhu 30 °C selama 90 menit, dilanjutkan eterifikasi dengan natrium kloroasetat 1-5 g pada suhu 50-80 °C selama 6 jam. Berdasarkan hasil penelitian, karakteristik Na-CMC terbaik didapatkan dari alkalisasi selulosa menggunakan NaOH 20% serta eterifikasi menggunakan 3 g natrium kloroasetat pada suhu 70 °C. Perolehan Na-CMC yang didapat adalah sebesar 22%, kemurnian 96,20%, derajat substitusi 0,705; termasuk dalam grade kedua menurut SNI 06-3736-1995.Kata kunci: kulit singkong, karboksimetil selulosa, Na-CMC, eterifikasi

Synthesis of Sodium Carboxymethyl Cellulose Based on Pretreated Bamboo Shaving

2014 ◽  
Vol 997 ◽  
pp. 169-172 ◽  
Author(s):  
Wei Qing Chen ◽  
Dong Ping Lou
Keyword(s):  
Aqueous Solution ◽  
Carboxymethyl Cellulose ◽  
Degree Of Substitution ◽  
Raw Material ◽  
Sodium Carboxymethyl Cellulose ◽  
Main Reaction ◽  
Reaction Conditions

Bamboo shaving is a by-product of bamboo industry, often be discarded or incinerated. In this work, sodium carboxymethyl cellulose (CMC) was prepared from pretreated bamboo shaving as raw material, while the main reaction conditions affecting product properties such as pretreated method, alkalization temperature and time, etherified temperature and time were studied. The results showed that the optimized pretreated conditions for bamboo cellulose were soaked in 15% NaOH at 1:8 (w/v) ratio of cellulose to solvent for 1 h at 95°C, The content of α-cellulose reach to 94.25%. The optimized reaction conditions for CMC synthesis were alkalified at 30°C for 70 min and etherified at 55°C for 90min; afterwards, temperature was kept at 70°C for 10min. Under these conditions, viscosity of 1% CMC aqueous solution was above 260 mPa·s, degree of substitution (DS)≥0.8, and content of chloride and moisture were less than 1.2 % and 10 % respectively.

scholarly journals PENGARUH PENAMBAHAN KARBON AKTIF DARI KULIT SINGKONG TERHADAP PENURUNAN KADAR MANGAN (Mn) DALAM AIR DENGAN BEBERAPA VARIASI KONSENTRASI

2019 ◽  
Vol 7 (2) ◽  
pp. 96
Author(s):  
Darmawati Darmawati ◽  
Syarifah Maulidar ◽  
Khairun Nisa
Keyword(s):  
Activated Carbon ◽  
Spectrophotometric Method ◽  
Carbon Concentration ◽  
Raw Material ◽  
Manganese Concentration ◽  
Manganese Reduction ◽  
Cassava Peels ◽  
Cassava Peel ◽  
Banda Aceh

The study aims to find out about the possibility of utilizing cassava peel waste as raw material for making activated carbon to reduce levels of Manganese in water. This study also wants to see the effect of variations in the concentration of activated carbon from cassava peels on decreasing levels of Manganese in water. This research was conducted at the Laboratory of the Akademi Analis Kesehatan Pemerintah Aceh and at the UPTD Laboratorium Kesehatan Banda Aceh on 3-11 March 2016. Manganese was analysed using the persulfate method while the Manganese was examinated by the spectrophotometric method. The sample used is an artificial sample by adding MnSO4 to water. The variation of activated carbon concentration added is 2 gr, 3 gr, and 4 gr. The results are that with the addition of 2 grams of activated carbon the percentage of Manganese reduction was 70.37%, the addition of 3 grams of activated carbon decreased Manganese concentration by 86.59%, while the addition of 4 grams of activated carbon reduced the percentage of Manganese to 92.33%. It can be concluded that the higher the concentration of activated carbon added, the higher the decrease in levels of Manganese in the water.

Evaluation of Yam (Dioscorea sp.) Starch and Arrowroot (Maranta arundinacea) Starch as Suspending Agent in Suspension

2010 ◽  
Vol 93-94 ◽  
pp. 362-365 ◽  
Author(s):  
Suchada Piriyaprasarth ◽  
Vipaluk Patomchaiviwat ◽  
Pornsak Sriamornsak ◽  
Nate Seangpongchawal ◽  
Prachya Katewongsa ◽  
...  
Keyword(s):  
Carboxymethyl Cellulose ◽  
Optimal Concentration ◽  
Sodium Carboxymethyl Cellulose ◽  
Carboxymethyl Cellulose Sodium ◽  
Model Drug ◽  
Suspending Agents ◽  
Low Solubility ◽  
Arrowroot Starch

The aim of our study was to evaluate the applicability of yam (Dioscorea sp.) starch and arrowroot (Maranta arundinacea) starch as suspending agents in suspension. Paracetamol was used as a model drug because of its low solubility. It was found that the optimal concentration as suspending agent in paracetamol suspension was in the range of 7-8% for yam starch and 5-6% for arrowroot starch. All formulations were stable within the period of study with pH of 5.4-6.9. These results were comparable to those obtained from the sodium carboxymethyl cellulose (sodium CMC) which is a common suspending agent. It could be concluded that yam starch and arrowroot starch showed suspending activity in paracetamol suspension and could be applied as commercial suspending agent.

scholarly journals Preparation and Properties of Sodium Carboxymethyl Cellulose/Sodium Alginate/Chitosan Composite Film

Coatings ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 291 ◽  
Author(s):  
Wenting Lan ◽  
Li He ◽  
Yaowen Liu
Keyword(s):  
Composite Film ◽  
Sodium Alginate ◽  
Carboxymethyl Cellulose ◽  
Test Method ◽  
Sodium Carboxymethyl Cellulose ◽  
Orthogonal Experimental Design ◽  
Cellulose Solution ◽  
Casting Solution ◽  
Carboxymethyl Cellulose Sodium ◽  
Chitosan Composite

A sodium alginate/chitosan solution was prepared by dissolving sodium alginate, chitosan, and glycerol in an acetic acid solution. This solution was then combined with a sodium carboxymethyl cellulose solution and the mixture was cast onto a glass plate and dried at a constant temperature of 60 °C. Then, a carboxymethyl cellulose/sodium alginate/chitosan composite film was obtained by immersing the film in a solution of a cross-linking agent, CaCl2, and air-drying the resulting material. First, the most advantageous contents of the three precursors in the casting solution were determined by a completely random design test method. Thereafter, a comprehensive orthogonal experimental design was applied to select the optimal mass ratio of the three precursors. The composite film obtained with sodium alginate, sodium carboxymethyl cellulose, and chitosan contents of 1.5%, 0.5%, and 1.5%, respectively, in the casting solution displayed excellent tensile strength, water vapor transmission rate, and elongation after fracture. Moreover, the presence of chitosan successfully inhibited the growth and reproduction of microorganisms. The composite film exhibited antibacterial rates of 95.7% ± 5.4% and 93.4% ± 4.7% against Escherichia coli and Staphylococcus aureus, respectively. Therefore, the composite film is promising for antibacterial food packaging applications.

scholarly journals Isopropanol to Hydrocarbons Transformation Particularities on Hybrid Zeolite H-ZSM-5 and H-Beta Systems

2022 ◽  
Vol 8 (1) ◽  
pp. 10-16
Author(s):  
R. Brovko ◽  
L. Mushinskii ◽  
V. Doluda
Keyword(s):  
Ammonium Nitrate ◽  
Sodium Hydroxide ◽  
Isopropyl Alcohol ◽  
Silicon Oxide ◽  
Colloidal Solution ◽  
Raw Material ◽  
Beta Zeolite ◽  
Core Shell ◽  
Distilled Water ◽  
Zeolite Sample

The continuous depletion of hydrocarbon sources contributes to a wide study of the use of biorenewable raw materials to obtain synthetic hydrocarbons from them. Isopropyl alcohol is traditionally produced by chemical hydration of propylene, however, with the development of biotechnology, broad prospects have opened for its production by fermentation of glucose-containing substrates obtained from agricultural and forestry waste. This way, isopropyl alcohol can also be considered as a bio-renewable raw material and it can be widely used for the production of chemical synthesis products, including hydrocarbons. One of the possible ways of processing isopropyl alcohol is the catalytic transformation of alcohols on zeolites and zeotypes of various natures with the formation of hydrocarbons. Currently, zeolite H-ZSM-5 and zeotype SAPO-34 are the most frequently used catalysts for the transformation of alcohols into hydrocarbons, however, their rapid deactivation due to the formation of a carbon residue remains an unresolved problem. The formation of core-shell structures with H-ZSM-5 zeolite in center and an outer shell consist of H-Beta zeolite with large pores can reduce the deactivation of zeolite because of increase in reagents diffusion rate. In this article is devoted to synthesis of ZSM-5/Beta sample with a core-shell structure, as well as a study of its catalytic and physicochemical properties. To form the H-ZSM-5 zeolite, a colloidal solution of tetrapropylammonium hydroxide, a colloidal solution of silicon oxide, aluminum oxide, sodium hydroxide of distilled water was used. The colloidal solution was placed in an autoclave, heated to 140 °C and kept at this temperature for 48 hours, after which the crystals formed were centrifuged, washed with distilled water and kept in a 1M solution of ammonium nitrate for a day. Then, to form the H-Beta layer, H-ZSM-5 was suspended in a colloidal solution consisting of tetraethylammonium hydroxide, tetraethylammonium chloride, a colloidal solution of silicon oxide, sodium hydroxide, sodium chloride and distilled water. The suspension was placed in an autoclave and kept at a temperature of 140 °C for 48 hours, followed by centrifugation, washing in distilled water, suspended in a 1M solution of ammonium nitrate, with repeated washing with distilled water, drying and calcining at 600 °C. Testing of the synthesized of H-ZSM-5/Beta zeolite sample showed a significant decrease in the rate of deactivation compared to the synthesized sample of H-ZSM-5; it is also necessary to note a slight increase in the fraction of liquid hydrocarbons for the sample H-ZSM-5/Beta.

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