scholarly journals Electro-Kinetic Degradation of Diesel Originated from a Costal Crude Oil Terminal

2021 ◽  
Vol In Press (In Press) ◽  
Author(s):  
Babak Darabi ◽  
Tayyebeh Tabatabaei ◽  
Fazel Amiri ◽  
Sahand Jorfi
Keyword(s):  
Petroleum Hydrocarbon ◽  
Removal Rate ◽  
Total Petroleum Hydrocarbon ◽  
Order Kinetic ◽  
Operational Parameters ◽  
Efficient Technology ◽  
First Order ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Pseudo First Order

: The present study evaluated the effect of the integration of electro-kinetic (EK) oxidation with sonication degradation of diesel in a hydrocarbon contaminated wastewater. The effect of operational parameters including initial pH (3 - 9), sonication (100 - 300 W), voltage (0.5 - 3 V/cm), and reaction time (60 - 150 min) were studied consecutively. The highest total petroleum hydrocarbon (TPH) destruction rate of 40% was achieved at pH 5. Also, increasing the sonication intensity up to 300 W improved the removal rate to 70%. The pseudo-first-order kinetic model was selected due to higher correlation coefficient. Considering the obtained integration of EK oxidation with sonication is a viable and efficient technology for treatment of diesel contaminated wastewaters.

scholarly journals Decolorization Kinetics of Acid Azo Dye and Basic Thiazine Dye in Aqueous Solution by UV/H2O2 and UV/Fenton: Effects of Operational Parameters

2017 ◽  
Vol 17 (1) ◽  
pp. 85-94
Author(s):  
Ayda Baffoun ◽  
Amel El Ghali ◽  
Imen Hachani
Keyword(s):  
Order Kinetic ◽  
Operational Parameters ◽  
Operational Conditions ◽  
First Order ◽  
Aqueous Effluents ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Thiazine Dye ◽  
Kinetics Of ◽  
Decolorization Kinetics

AbstractThe photochemical decolorization of two dyes, namely Acid Yellow 54 and Basic Blue 9, was studied using the UV/H2O2and UV/Fenton processes. The effects of the amount of H2O2and FeSO4as well as the initial pH solution on decolorization kinetics of both the dyes were investigated. The pseudo-first order kinetic model was applied to predict the decolorization of the selected dyes at the different operational conditions and results showed that this model fitted very well with the experimental data. The obtained results also showed the efficiency of UV/Fenton process to quickly degrade aqueous effluents polluted by Acid Yellow 54 and Basic Blue 9 compared to the UV/H2O2process.

scholarly journals Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates

2018 ◽  
Vol 38 ◽  
pp. 02014
Author(s):  
Yu Zhang ◽  
Jian Gu ◽  
Mengqi Zhang
Keyword(s):  
Hydrothermal Method ◽  
Order Kinetic ◽  
Carbon Fabric ◽  
Facile Hydrothermal Method ◽  
Sem Images ◽  
First Order ◽  
Good Crystallinity ◽  
Degradation Rate Constant ◽  
Order Kinetic Model ◽  
Pseudo First Order

The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.

Characteristics and kinetics of hexavalent chromium reduction by gallic acid in aqueous solutions

2015 ◽  
Vol 71 (11) ◽  
pp. 1694-1700 ◽  
Author(s):  
ZiFang Chen ◽  
YongSheng Zhao ◽  
Qin Li
Keyword(s):  
Kinetic Model ◽  
Gallic Acid ◽  
Hexavalent Chromium ◽  
Ph Value ◽  
Order Kinetic ◽  
First Order ◽  
Molar Ratios ◽  
Wide Range ◽  
Order Kinetic Model ◽  
Pseudo First Order

Gallic acid (GA) is a naturally occurring plant polyphenol compound. Experiments were conducted to study the kinetics and effects of pH, temperature, irradiation, and initial hexavalent chromium (Cr(VI)) concentration on Cr(VI) reduction by GA. Results indicated that Cr(VI) could be reduced to chromium oxide (Cr(III)) with GA in a wide range of pH values from 2.0 to 8.5. The reaction followed a pseudo-first-order kinetic model with respect to Cr(VI) and GA in acid conditions (pH 2.0–5.0). However, the reaction did not follow the pseudo-first-order kinetic model at pH 6.5 and 8.5. Removal efficiencies and reaction rate constants of Cr(VI) significantly increased with decreasing pH value and increasing temperature. The effect of irradiation on Cr(VI) reduction increased with increasing pH, and irradiation improved the removal efficiency of Cr(VI) by 11.29% at pH 6.5. At pH 2.0, nearly all molar ratios of GA required for the reduction of Cr(VI) were 1:2 (±0.1) under different initial Cr(VI) concentrations; however, the molar ratios of GA required for the reduction of Cr(VI) were 1:1.29, 1:1.43, and 1:1.69, respectively, when the initial Cr(VI) concentrations were 10, 25, and 50 mg/L at pH 5.5.

Sorption of Pb2+ on Mg-Al-Fe Hydrotalcite-Like Compounds

2012 ◽  
Vol 573-574 ◽  
pp. 86-91
Author(s):  
Xue Feng Liang ◽  
Wan Guo Hou ◽  
Ying Ming Xu ◽  
Lin Wang ◽  
Yue Bing Sun
Keyword(s):  
Kinetic Model ◽  
Rate Increase ◽  
Freundlich Isotherm ◽  
Order Kinetic ◽  
Sorption Mechanism ◽  
Chemical Binding ◽  
First Order ◽  
Maximum Sorption ◽  
Order Kinetic Model ◽  
Pseudo First Order

Hydrotalcite-like compounds containing Mg2+, Al3+ and Fe3+ with a constant M2+/M3+ ratio but varying Al3+/Fe3+ ratios have been prepared. The effects of iron contents on the structural and sorption of Pb2+ by Mg-Al-Fe HTlc samples were investigated. The maximum sorption amounts were about 88-201 mg/g for Mg-Al-Fe HTlc samples. The sorption isotherm and kinetic processes can be described with Freundlich isotherm and pseudo first order kinetic model, respectively. The sorption amounts and rate increase with the increase of iron contents in HTlc samples. The sorption mechanism of Pb2+ on Mg-Al-Fe HTlcs may be the surface-induced precipitation and chemical binding adsorption.

scholarly journals A study of photocatalytic degradation of textile dye CI basic yellow 28 in water using P160 TiO2 based catalyst

2012 ◽  
Vol 77 (12) ◽  
pp. 1747-1757 ◽  
Author(s):  
Veljko Djokic ◽  
Jelena Vujovic ◽  
Aleksandar Marinkovic ◽  
Rada Petrovic ◽  
Djordje Janackovic ◽  
...  
Keyword(s):  
Photocatalytic Degradation ◽  
Textile Dye ◽  
Order Kinetic ◽  
Operational Parameters ◽  
First Order ◽  
Photodegradation Rate ◽  
Vis Spectroscopy ◽  
Langmuir Hinshelwood Mechanism ◽  
Order Kinetic Model ◽  
Alkaline Conditions

The photocatalytic degradation of synthetic textile dye CI Basic Yellow 28 (BY28) in water, using recently synthesized P160 TiO2 based catalyst, under Osram ultra-vitalux? lamp (300 W) light, was studied. The effect of the operational parameters such as initial concentration of catalyst, initial dye concentration and pH was studied. Salt effect was also investigated (NaCl, Na2CO3, Na2SO4, NaNO3). It was found that the optimal concentration of catalyst is 2.0 g L-1. A pseudo first-order kinetic model was illustrated using the Langmuir-Hinshelwood mechanism, and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (KBY = 6.126 L mg-1 and kC = 0.272 mg L-1 min-1, respectively). The photodegradation rate was higher in weak acidic than in high acidic and alkaline conditions. The presence of CO32- ions increases the photodegradation rate while Cl-, SO42- and NO3-ions decreases the reaction rate. The rate of photodegradation of BY28 was measured using UV-Vis spectroscopy.

Kinetic Study of the Adsorption of Dye onto Cotton in SDS-CTAB Reverse Micelles

2015 ◽  
Vol 723 ◽  
pp. 591-595
Author(s):  
Zu Lan Liu ◽  
Lan Qian Li ◽  
Yi Ping Liu ◽  
Ming Lu
Keyword(s):  
Kinetic Study ◽  
Adsorption Kinetics ◽  
Reverse Micelles ◽  
Adsorption Kinetic ◽  
Order Kinetic ◽  
First Order ◽  
Reactive Blue 19 ◽  
Order Kinetic Model ◽  
Pseudo First Order ◽  
Kinetics Of

Adsorption kinetic study of C.I. reactive blue 19 onto cotton was carried out in SDS-CTAB reverse micelles. The data of adsorption kinetics were examined using pseudo first-and second-order kinetic models. It was found that the adsorption kinetics of dye on cotton with diffusion controlling follows the pseudo first-order kinetic model.

Effects of ultraviolet intensity and wavelength on the photolysis of triclosan

2007 ◽  
Vol 55 (1-2) ◽  
pp. 209-216 ◽  
Author(s):  
H.-S. Son ◽  
S.-B. Choi ◽  
K.-D. Zoh ◽  
E. Khan
Keyword(s):  
Kinetic Model ◽  
Hydroxyl Radicals ◽  
Direct Photon ◽  
Order Kinetic ◽  
First Order ◽  
Photodegradation Rate ◽  
Order Kinetic Model ◽  
Pseudo First Order ◽  
First Time ◽  
Subordinate Role

The effects of ultraviolet (UV) intensity and wavelength on triclosan (TCS) photodegradation kinetic, efficiency, mechanisms and pathway were studied. The TCS photodegradation followed the pseudo-first order kinetic model at all UV intensities examined at the wavelengths of 254 and 365 nm and the photodegradation rate increased with increasing UV intensity. TCS photodegradation efficiencies of 90 to 98% and 79 to 90% were obtained at the wavelengths of 254 and 365 nm, respectively. TCS was degraded mainly by photon induced hydroxyl radicals while the direct photon reaction with TCS played a subordinate role. Chlorophenol, dichlorophenol and phenol were the intermediates detected in all experiments conducted. Dibenzodichloro-p-dioxin and dibenzo-p-dioxin were observed as the intermediates only at lower UV intensities investigated at the wavelength of 365 nm. Based on these intermediates, a complete TCS photolysis pathway was proposed for the first time.

Fabrication and Photocatalytic Decolorization Performance of ZnO

2011 ◽  
Vol 396-398 ◽  
pp. 823-826
Author(s):  
Jie Cheng ◽  
Jian Zhang Li ◽  
Jun Bo Zhong ◽  
Wei Hu
Keyword(s):  
Methyl Orange ◽  
Kinetic Model ◽  
Uv Irradiation ◽  
Precipitation Method ◽  
Order Kinetic ◽  
First Order ◽  
Photocatalytic Decolorization ◽  
Langmuir Hinshelwood Mechanism ◽  
Order Kinetic Model ◽  
Pseudo First Order

Paralled flaw precipitation method has been employed to synthesize nanostructured ZnO. The prepared photocatalyst was characterized by BET, XRD. The paper reveals that Methyl Orange (MO) can be decolorized effectively in ZnO suspension system under UV irradiation. The optimal loading of photocatalyst in our experimental condition for the decolorization of MO is 1g/L. The present study, on the base of Langmuir-Hinshelwood mechanism, illustrates that the decolorization reaction is a pseudo first order kinetic model with the limiting rate constant of 8.48×10-2 mgL-1min-1 and equilibrium adsorption constant 0.335 L/mg, respectively.

scholarly journals Kinetics and reaction mechanism of photochemical degradation of diclofenac by UV-activated peroxymonosulfate

RSC Advances ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 6804-6817
Author(s):  
Yunlan Peng ◽  
Hongle Shi ◽  
Zhenran Wang ◽  
Yongsheng Fu ◽  
Yiqing Liu
Keyword(s):  
Reaction Mechanism ◽  
Kinetic Model ◽  
Order Kinetic ◽  
Photochemical Degradation ◽  
First Order ◽  
Order Kinetic Model ◽  
Pseudo First Order

Compared to UV alone and PMS alone systems, diclofenac was removed more efficiently in UV/PMS system at pH 7.0 due to the contribution of SO4˙− and HO˙ and its degradation followed the pseudo-first order kinetic model.

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