The study aims at finding the impact of leadership roles, achievement motivation in achieving career excellence for employees in the Ministry of Education in the UAE. To achieve the objectives of the study, the researcher used the quantitative and descriptive approach. The questionnaire was designed as a study tool. It was formulated in (5) axes, (10) paragraphs and (55) phrases, the source of which is: the model of government leadership in the UAE, the criteria for job excellence adopted in government excellence, the EFQM Model, and the achievement motivation for Mwary and McClelland. The study population consists of distinguished employees in the ministry who won three awards: Khalifa Education Award 2007, Hamdan bin Rashid Al Maktoum for Distinguished Academic Performance in 1998, and Sharjah Award for Excellence 1995. The total population is (944) distinguished employees, and the sample represented (283) employees at a rate of (30%) of the study population. They were chosen in a random stratified method to ensure a fair and varied representation in the sample size. The results of the study showed a moderate effect closer to the high in the influence of leadership on enhancing job excellence, a higher effect of achievement and self-fulfillment motives among distinguished employees, and a high impact of the distinguished employee practices. In addition, a moderate influence of competition standards, which is attributed to the need for more realism and suitability for government work conditions in the Ministry of Education. Based on the results of the study, the researcher had a number of recommendations directed to the Ministry of Education, leaders, award departments, and distinguished winners in various categories.