scholarly journals Diversity of microbes colonizing forages of varying lignocellulose properties in the sheep rumen

PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e10463
Author(s):  
Mohammad Farhad Vahidi ◽  
Javad Gharechahi ◽  
Mehrdad Behmanesh ◽  
Xue-Zhi Ding ◽  
Jian-Lin Han ◽  
...  
Keyword(s):  
Community Structure ◽  
Chemical Properties ◽  
Microbial Colonization ◽  
Chemical Compositions ◽  
Plant Materials ◽  
Rumen Microbiota ◽  
Rumen Degradation ◽  
Fiber Degradation ◽  
Sheep Rumen

Background The rumen microbiota contributes strongly to the degradation of ingested plant materials. There is limited knowledge about the diversity of taxa involved in the breakdown of lignocellulosic biomasses with varying chemical compositions in the rumen. Method We aimed to assess how and to what extent the physicochemical properties of forages influence the colonization and digestion by rumen microbiota. This was achieved by placing nylon bags filled with candidate materials in the rumen of fistulated sheep for a period of up to 96 h, followed by measuring forage’s chemical characteristics and community structure of biofilm-embedded microbiota. Results Rumen degradation for all forages appeared to have occurred mainly during the first 24 h of their incubation, which significantly slowed down after 48 h of rumen incubation, depending on their chemical properties. Random Forest analysis predicted the predominant role of Treponema and Butyrivibrio in shaping microbial diversity attached to the forages during the course of rumen incubation. Exploring community structure and composition of fiber-attached microbiota revealed significant differential colonization rates of forages depending on their contents for NDF and cellulose. The correlation analysis highlighted the significant contribution of Lachnospiraceae and Veillonellaceae to fiber degradation in the sheep rumen. Conclusion Our findings suggested that forage cellulose components are critical in shaping the pattern of microbial colonization and thus their final digestibility in the rumen.

scholarly journals The role of VOC oxidation products in continental new particle formation

2008 ◽  
Vol 8 (10) ◽  
pp. 2657-2665 ◽  
Author(s):  
A. Laaksonen ◽  
M. Kulmala ◽  
C. D. O'Dowd ◽  
J. Joutsensaari ◽  
P. Vaattovaara ◽  
...  
Keyword(s):  
Gas Phase ◽  
Chemical Properties ◽  
High Volume ◽  
Particle Growth ◽  
Particle Formation ◽  
Oxidation Products ◽  
Chemical Compositions ◽  
New Particle Formation ◽  
Voc Oxidation

Abstract. Aerosol physical and chemical properties and trace gas concentrations were measured during the QUEST field campaign in March–April 2003, in Hyytiälä, Finland. Our aim was to understand the role of oxidation products of VOC's such as mono- and sesquiterpenes in atmospheric nucleation events. Particle chemical compositions were measured using the Aerodyne Aerosol Mass Spectrometer, and chemical compositions of aerosol samples collected with low-pressure impactors and a high volume sampler were analysed using a number of techniques. The results indicate that during and after new particle formation, all particles larger than 50 nm in diameter contained similar organic substances that are likely to be mono- and sesquiterpene oxidation products. The oxidation products identified in the high volume samples were shown to be mostly aldehydes. In order to study the composition of particles in the 10–50 nm range, we made use of Tandem Differential Mobility Analyzer results. We found that during nucleation events, both 10 and 50 nm particle growth factors due to uptake of ethanol vapour correlate strongly with gas-phase monoterpene oxidation product (MTOP) concentrations, indicating that the organic constituents of particles smaller than 50 nm in diameter are at least partly similar to those of larger particles. We furthermore showed that particle growth rates during the nucleation events are correlated with the gas-phase MTOP concentrations. This indicates that VOC oxidation products may have a key role in determining the spatial and temporal features of the nucleation events. This conclusion was supported by our aircraft measurements of new 3–10 nm particle concentrations, which showed that the nucleation event on 28 March 2003, started at the ground layer, i.e. near the VOC source, and evolved together with the mixed layer. Furthermore, no new particle formation was detected upwind away from the forest, above the frozen Gulf of Bothnia.

scholarly journals The role of VOC oxidation products in continental new particle formation

2007 ◽  
Vol 7 (3) ◽  
pp. 7819-7841 ◽  
Author(s):  
A. Laaksonen ◽  
M. Kulmala ◽  
C. D. O'Dowd ◽  
J. Joutsensaari ◽  
P. Vaattovaara ◽  
...  
Keyword(s):  
Gas Phase ◽  
Chemical Properties ◽  
High Volume ◽  
Particle Growth ◽  
Particle Formation ◽  
Oxidation Products ◽  
Chemical Compositions ◽  
New Particle Formation ◽  
Voc Oxidation

Abstract. Aerosol physical and chemical properties and trace gas concentrations were measured during the QUEST field campaign in March–April, 2003, in Hyytiälä, Finland. Our aim was to understand the role of oxidation products of VOC's such as mono- and sesquiterpenes in atmospheric nucleation events. Particle chemical compositions were measured using the Aerodyne Aerosol Mass Spectrometer, and chemical compositions of aerosol samples collected with low-pressure impactors and a high volume sampler were analysed using a number of techniques. The results indicate that during and after new particle formation, all particles larger than 50 nm in diameter contained similar organic substances that are likely to be mono- and sesquiterpene oxidation products. The oxidation products identified in the high volume samples were shown to be mostly aldehydes. In order to study the composition of particles in the 10–50 nm range, we made use of Tandem Differential Mobility Analyzer results. We found that during nucleation events, both 10 and 50 nm particle growth factors due to uptake of ethanol vapour correlate strongly with gas-phase monoterpene oxidation product (MTOP) concentrations, indicating that the organic constituents of particles smaller than 50 nm in diameter are at least partly similar to those of larger particles. We furthermore showed that particle growth rates during the nucleation events are correlated with the gas-phase MTOP concentrations. This indicates that VOC oxidation products may have a key role in determining the spatial and temporal features of the nucleation events. This conclusion was supported by our aircraft measurements of new 3–10 nm particle concentrations, which showed that the nucleation event on 28 March 2003, started at the ground layer, i.e. near the VOC source, and evolved together with the mixed layer. Furthermore, no new particle formation was detected upwind away from the forest, above the frozen Gulf of Bothnia.

Characteristics Of The Structure Formation Of Gypsum Binder Modified With Zinc Hydrosilicates

2020 ◽  
pp. 40-46
Keyword(s):  
Synergistic Effect ◽  
Physicochemical Properties ◽  
Structure Formation ◽  
Silicic Acid ◽  
Chemical Properties ◽  
Crystal Formation ◽  
Ability To Act ◽  
Chemical Factors ◽  
Sorption Characteristics

The authors' methodic for assessing the role of chemical and physic-chemical factors during the structure formation of gypsum stone is presented in the article. The methodic is also makes it possible to reveal the synergistic effect and to determine the ranges of variation of controls factors that ensure maximum values of such effect. The effect of a micro-sized modifier based on zinc hydro-silicates on the structure formation of building gypsum is analyzed and corresponding dependencies are found. It is shown that effects of influence of modifier on the properties of gypsum compositions are determined by chemical properties of modifier. Among the mentioned properties are sorption characteristics (which depend on the amount of silicic acid and its state) and physicochemical properties - the ability to act as a substrate during crystal formation. The proposed method can also be extended to other binding substances and materials. This article contributes to the understanding of the processes that occur during the structure formation of composites, which will make it possible to control the structure formation in the future, obtaining materials with a given set of properties.

The Nature of S-N Bonding in Sulfonamides and Related Compounds: Insights into π-Bonding Contributions from Sulfur K-Edge XAS

2020 ◽  
Author(s):  
Tulin Okbinoglu ◽  
Pierre Kennepohl
Keyword(s):  
Density Functional ◽  
Chemical Properties ◽  
Functional Theory ◽  
Rotational Barriers ◽  
Td Dft ◽  
Nitrogen Bonds ◽  
X Ray Absorption ◽  
Related Compounds ◽  
And Chemical Properties

Molecules containing sulfur-nitrogen bonds, like sulfonamides, have long been of interest due to their many uses and chemical properties. Understanding the factors that cause sulfonamide reactivity is important, yet their continues to be controversy regarding the relevance of S-N π bonding in describing these species. In this paper, we use sulfur K-edge x-ray absorption spectroscopy (XAS) in conjunction with density functional theory (DFT) to explore the role of S<sub>3p</sub> contributions to π-bonding in sulfonamides, sulfinamides and sulfenamides. We explore the nature of electron distribution of the sulfur atom and its nearest neighbors and extend the scope to explore the effects on rotational barriers along the sulfur-nitrogen axis. The experimental XAS data together with TD-DFT calculations confirm that sulfonamides, and the other sulfinated amides in this series, have essentially no S-N π bonding involving S<sub>3p</sub> contributions and that electron repulsion and is the dominant force that affect rotational barriers.

scholarly journals Neonatal Immune System Ontogeny: The Role of Maternal Microbiota and Associated Factors. How Might the Non-Human Primate Model Enlighten the Path?

Vaccines ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 584
Author(s):  
Natalia Nunez ◽  
Louis Réot ◽  
Elisabeth Menu
Keyword(s):  
Immune System ◽  
Mode Of Delivery ◽  
Microbial Colonization ◽  
Therapeutic Interventions ◽  
Primate Model ◽  
Neonatal Immune System ◽  
Gastrointestinal Colonization ◽  
The Impact ◽  
Human Primate

Interactions between the immune system and the microbiome play a crucial role on the human health. These interactions start in the prenatal period and are critical for the maturation of the immune system in newborns and infants. Several factors influence the composition of the infant’s microbiota and subsequently the development of the immune system. They include maternal infection, antibiotic treatment, environmental exposure, mode of delivery, breastfeeding, and food introduction. In this review, we focus on the ontogeny of the immune system and its association to microbial colonization from conception to food diversification. In this context, we give an overview of the mother–fetus interactions during pregnancy, the impact of the time of birth and the mode of delivery, the neonate gastrointestinal colonization and the role of breastfeeding, weaning, and food diversification. We further review the impact of the vaccination on the infant’s microbiota and the reciprocal case. Finally, we discuss several potential therapeutic interventions that might help to improve the newborn and infant’s health and their responses to vaccination. Throughout the review, we underline the main scientific questions that are left to be answered and how the non-human primate model could help enlighten the path.

scholarly journals Occurrence of drug target residues within decantation tank sediments: a good clue to assess their historical excretion?

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Thomas Thiebault ◽  
Laëtitia Fougère ◽  
Anaëlle Simonneau ◽  
Emilie Destandau ◽  
Claude Le Milbeau ◽  
...  
Keyword(s):  
Drug Target ◽  
Chemical Properties ◽  
Deposition Process ◽  
Drug Consumption ◽  
Organic Layers ◽  
Sewer Systems ◽  
Physico Chemical ◽  
Deep Underground ◽  
Deposition Processes

AbstractThis study investigated the potential of sediments accumulated in sewer systems to record human activities through the occurrence of drug target residues (DTR). The installation studied is 17 m deep underground decantation tank that traps the coarse fractions of a unitary sewer system (northern part of Orléans, France), collecting both stormwater and wastewater. The sediments deposited in this tank could constitute a nonesuch opportunity to study the historical evolution of illicit and licit drug consumption in the catchment, however, the deposition processes and the record of DTRs remain largely unknown at present. Five cores were acquired from 2015 to 2017. One hundred fifty-two sediment samples were extracted using a mixture of ultra-pure water:methanol (1:1) prior to analysis of the extracts by high-pressure liquid chromatography coupled to tandem mass spectrometry. Several classical sedimentological analyses such as total organic carbon, facies description and granulometry were also performed on these samples, in order to understand the most important factors (e.g., physico-chemical properties of the DTRs, solid type, assumed load in wastewater) impacting their deposition.The key role of the speciation of DTRs was highlighted by the higher contents in neutral and anionic DTRs in organic layers, whereas only cationic DTRs were found in mineral layers. The considerable modifications in the sediments’ properties, generated by distinct origins (i.e., stormwater or wastewater), are therefore the most important drivers that must be taken into account when back-calculating the historical patterns of drug consumption from their DTR concentrations in decantation tank sediments. Further research remains necessary to fully understand the deposition process, but this study provides new clues explaining these temporal evolutions.

scholarly journals A 3D study on the amplification of regional haze and particle growth by local emissions

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Wei Du ◽  
Lubna Dada ◽  
Jian Zhao ◽  
Xueshun Chen ◽  
Kaspar R. Daellenbach ◽  
...  
Keyword(s):  
Atmospheric Stability ◽  
Ground Level ◽  
Particle Growth ◽  
Chemical Compositions ◽  
Size Distributions ◽  
Aerosol Composition ◽  
Regional Haze ◽  
Haze Formation ◽  
Beijing China

AbstractThe role of new particle formation (NPF) events and their contribution to haze formation through subsequent growth in polluted megacities is still controversial. To improve the understanding of the sources, meteorological conditions, and chemistry behind air pollution, we performed simultaneous measurements of aerosol composition and particle number size distributions at ground level and at 260 m in central Beijing, China, during a total of 4 months in 2015–2017. Our measurements show a pronounced decoupling of gas-to-particle conversion between the two heights, leading to different haze processes in terms of particle size distributions and chemical compositions. The development of haze was initiated by the growth of freshly formed particles at both heights, whereas the more severe haze at ground level was connected directly to local primary particles and gaseous precursors leading to higher particle growth rates. The particle growth creates a feedback loop, in which a further development of haze increases the atmospheric stability, which in turn strengthens the persisting apparent decoupling between the two heights and increases the severity of haze at ground level. Moreover, we complemented our field observations with model analyses, which suggest that the growth of NPF-originated particles accounted up to ∼60% of the accumulation mode particles in the Beijing–Tianjin–Hebei area during haze conditions. The results suggest that a reduction in anthropogenic gaseous precursors, suppressing particle growth, is a critical step for alleviating haze although the number concentration of freshly formed particles (3–40 nm) via NPF does not reduce after emission controls.

scholarly journals Mineralogical and chemical properties inversed from 21-lunar-day VNIS observations taken during the Chang’E-4 mission

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Qinghong Zeng ◽  
Shengbo Chen ◽  
Yuanzhi Zhang ◽  
Yongling Mu ◽  
Rui Dai ◽  
...  
Keyword(s):  
Impact Crater ◽  
Near Infrared ◽  
Infrared Imaging ◽  
Chemical Properties ◽  
Landing Site ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Chemical Compositions ◽  
Impact Melt ◽  
And Chemical Properties

AbstractWe report on the mineralogical and chemical properties of materials investigated by the lunar rover Yutu-2, which landed on the Von Kármán crater in the pre-Nectarian South Pole–Aitken (SPA) basin. Yutu-2 carried several scientific payloads, including the Visible and Near-infrared Imaging Spectrometer (VNIS), which is used for mineral identification, offering insights into lunar evolution. We used 86 valid VNIS data for 21 lunar days, with mineral abundance obtained using the Hapke radiative transfer model and sparse unmixing algorithm and chemical compositions empirically estimated. The mineralogical properties of the materials at the Chang’E-4 (CE-4) site referred to as norite/gabbro, based on findings of mineral abundance, indicate that they may be SPA impact melt components excavated by a surrounding impact crater. We find that CE-4 materials are dominated by plagioclase and pyroxene and feature little olivine, with 50 of 86 observations showing higher LCP than HCP in pyroxene. In view of the effects of space weathering, olivine content may be underestimated, with FeO and TiO2 content estimated using the maturity-corrected method. Estimates of chemical content are 7.42–18.82 wt% FeO and 1.48–2.1 wt% TiO2, with a low-medium Mg number (Mg # ~ 55). Olivine-rich materials are not present at the CE-4 landing site, based on the low-medium Mg #. Multi-origin materials at the CE-4 landing site were analyzed with regard to concentrations of FeO and TiO2 content, supporting our conclusion that the materials at CE-4 do not have a single source but rather are likely a mixture of SPA impact melt components excavated by surrounding impact crater and volcanic product ejecta.

The Extraction of Main Chemical Compositions in Rumex Root

2011 ◽  
Vol 382 ◽  
pp. 372-374
Author(s):  
Yong Jiang ◽  
Zhi Bin Jiang ◽  
Guo Jie Shao ◽  
Dong Cheng Guo ◽  
Yu Tian ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Chemical Properties ◽  
Ethanol Extract ◽  
Chemical Compositions ◽  
Physical And Chemical Properties ◽  
Experimental Basis ◽  
Development And Utilization ◽  
Physical And Chemical ◽  
Root Methods ◽  
And Chemical Properties

Purpose: The purpose of this study was to study the compositions of the polygonaceae medicinal plants called rumex root. Methods: Solvent method and chromatography was used to purificate the chemical compositions of Rumex, and the molecular structure of the compound was identified by physical and chemical properties and spectral data. Results: Two compounds were obtained from the ethanol extract of rumex root, which were identified as Chrysophanol and Physcione. Conclusions: Experimental basis was provided for the further study of the active ingredients of rumex root and the development and utilization of medical resources.

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