scholarly journals Effects of Grog Additions on Some Refractory Properties of Raw (Abusoro) Kaolin Clay Deposit for Furnace Lining

2020 ◽  
pp. 180-191
Author(s):  
A. O. Aluko ◽  
C. O. Ikubuwaje

The influence of the weight of grog on some refractory properties of raw Abusoro clay samples found in Abusoro Village, Ondo State, Nigeria was evaluated. These samples were presented for refractory tests (apparent porosity, linear shrinkage, refractoriness, bulk density and cold crushing strength). The weights of the grog were varied from 20-40 wt. % in the blend. The chemical and microstructural examinations of the untreated alumino-silicate Abusoro clay samples indicated that they are abundant in silica, SiO2 (62.74wt. %) and alumina, Al2O3 (31.42wt. %). Other minor compounds found are Fe2O3 (1.43%), K2O (0.30%) with no trace amounts of MgO (0.00); therefore, they are regarded as alumino-silicate. Particular observation is made on MgO with zero amounts and the total of K2O + Na2O + MgO which are less than 2% in the clay samples. These results signify that the clay possesses high viability for manufacturing of refractory bricks, pulp and paper, ceramics, fertilizers, paint and cement. The performance evaluations of the refractory bricks measured indicated acceptable and satisfactory results vis-à-vis standard refractory properties for refractory fireclay bricks. However, the apparent porosity (43.2%) and CCS (21.21MPa) obtained for Abusoro clay sample at 30% weight of grog may as well be suitable for insulating refractory applications. The high apparent porosity could be an indication of high content of silicon oxide in the raw clay.

2017 ◽  
Vol 888 ◽  
pp. 66-70 ◽  
Author(s):  
Amkpa Job Ajala ◽  
Nur Azam Badarulzaman ◽  
Abu Bakar Aramjat

Riyom clay sample was investigated and have porosity of 18.6 %, firing shrinkage of 7.8 %, bulk density 2.2 g/cm3 and cold crushing strength. Chemical composition was analyzed using the XRF. The refractoriness of the fireclay was 1621 °C. The thermal shock resistance was up to 25 cycles. The apparent porosity fell within the standard value of 10-30 % for refractory fireclay bricks. The investigation proved that the Riyom clay deposit belong to the alumino-silicate group of bricks. The clay is therefore, suitable for production of refractory bricks for furnace lining.


2017 ◽  
Vol 36 (3) ◽  
pp. 844-848
Author(s):  
FA Ovat ◽  
DE Ewa ◽  
EA Egbe

The characterization of some clay as refractory materials for furnace lining has become relevant to find solutions to the cost involved in the purchase and importation of these refractory materials. This work investigated the refractory properties of clay samples for their suitability for use in the industries. Clay samples were collected from Gakem and Abouchiche areas and analysed for physical and chemical properties to determine the suitability of the clays as refractory materials. The results showed cold crushing strength (21.46MN/m2), thermal shock resistance (27 cycles), bulk density (3.52g/cm3), linear shrinkage(3.80%), apparent porosity (28.84%) and permeability (80%) for Gakem; and cold cold crushing strength (18.40MN/m2), thermal shock resistance (25 cycles), bulk density(2.81g/cm3), linear shrinkage (3.70%), apparent porosity (25.86%) and permeability (77%) for Abouchiche respectively. The chemical compositions of these clay samples were also investigated. The results showed that the samples fall under Aluminosilicate type of clay because of their high values of Aluminium Oxide and Silicon Oxide. Tests showed that clay from these areas can be used to produce refractory materials that can withstand a furnace temperature of about 1600°C. http://dx.doi.org/10.4314/njt.v36i3.26


2018 ◽  
Vol 3 (2) ◽  
Author(s):  
Yusuf L Shuaib-Babata ◽  
Abdulhafeez N Abdulrahaman

Studies have shown that Nigerian clays have not been fully utilized for foundry applications, either as refractories or even bonding clays, and are still being imported into the country. There is need to effectively exploit and adequately utilize the available natural resources to improve Nigeria economic activities, most especially during the present economic recession. Samples of clays were obtained from Auchi, Dada-Okelele (Ilorin), Kaba, Maraba-Rido, Mokwa and New-Bussa in Nigeria. The samples’ physico-mechanical properties were examined for its suitability for foundry/refractory applications. The results of the chemical analysis revealed that the samples belong to Alumino-Silicate refractories. The samples exhibited 35.3-96.2%, 17.1-28.7%, 1.72-2.34 g/cm3, 2.2-10.1%, 73-86 and >1300oC as values for percentage clay contents, apparent porosity, bulk density, permeability, linear shrinkage and refractoriness respectively. These values were within the standard range values of >35%, 22-30%, 17-2.4%, 2.0-10.1% and 25-90 required as percentage clay contents, apparent porosity, bulk density, permeability and linear shrinkage values respectively, for refractory clays/brick lining or alumina-silicates, kaolin and fireclays. Hence, the clays could suitably replace imported clays / ceramics in refractory applications, such as in production of earthen wares, chalk; as insulating refractories for casting and melting of low and medium temperature iron and steel. Appropriate utilization of these clays for local foundry applications will assist in addressing the problem of inadequate job, and over dependence on foreign goods.Keywords— Alumino-Silicate, Clay, Foundry, Moisture and Refractoriness


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7803
Author(s):  
Nan Su ◽  
Zishen Li ◽  
Youdong Ding ◽  
Hongliang Yang ◽  
Jingzhou Zhang ◽  
...  

Aluminum dross is a well-known industrial waste generated in the aluminium industry, and its recycling and reuse is still a worldwide issue. Herein, aluminum dross waste (ADW) was recycled to progressively replace the aggregate fraction of clay at 70, 75, 80, 85, and 90 wt% for the fabrication of Al2O3-SiO2-rich porous castable refractories. Their physical properties and mechanical behavior were assessed by the measurement of linear shrinkage rate, bulk density, apparent porosity, cold crushing strength, and thermal conductivity. The microstructure and phase evolutions were analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The incorporation of 85 wt% of ADW allowed the development of a waste-containing conventional refractory castable with improved properties as compared to those of the other samples. The sustainable refractory castable exhibited decent thermal conductivity and physical and mechanical characteristics, and is suitable for application as reheating furnace lining. It is a “green” practice to partially replace the traditional raw materials with industrial waste in the manufacture of conventional refractory castables and provides environmental and economic benefits.


2020 ◽  
Vol 17 (2) ◽  
pp. 113-119
Author(s):  
H.E. Mgbemere ◽  
E.O. Obidiegwu ◽  
A.U. Ubong

In this research, kaolin, ball clay, sawdust and rice husk were used to produce insulation bricks through the solid state synthesis method. Two temperatures, 1100oC and 1200oC were used to sinter the green samples. X-ray fluorescence, scanning electron microscopy, compressive strength tests etc. were used to analyse the properties of the produced bricks. Chemical composition analysis on the starting raw materials showed that SiO2 and Al2O3 were the major constituents while Fe2O3, Na2O, K2O and TiO2 were the minor constituents. As the amounts of kaolin used in preparing the samples decrease, the bulk density, modulus of rupture and cold crushing strength of the bricks decreases while the water absorption capacity, linear shrinkage increases. The thermal analysis showed that on heating the samples, the reactions were mainly exothermic with between 8 to 10 mW/mg of heat released. The morphology of the samples showed that the pores began to collapse when the amount of kaolin present is below 70 wt. %. Sintering the samples at 1100oC and 1200oC led to slightly different values in the results and is therefore very significant. Keywords: Insulation bricks, Kaolin, sawdust, rice husk, temperature effects


2013 ◽  
Vol 315 ◽  
pp. 477-481 ◽  
Author(s):  
I.A. Rafukka ◽  
B. Onyekpe ◽  
Y. Tijjani

The physical properties of some materials used by local foundries were investigated with a view to assessing their suitability for use as low heat duty refractory bricks. The samples were collected from Malamai village, Gezawa Local Government, Kano state; they are Gezawa clay and Burji (Clay). The samples were crushed, ground, sieved and the chemical compositions were determined. The clay samples were treated separately as well as blended with Gezawa clay in different proportions and molded in to bricks. The bricks were dried and fired to 1100. Test for refractoriness, thermal shock resistance, linear shrinkage; bulk density, porosity and compressive strength were carried out on each of the specimen. Burji blended with 50% to 90% Gezawa clay gave improved thermal shock resistance with a refractoriness of 1300 and hence could be used for non ferrous melting cupolas.


2011 ◽  
Vol 399-401 ◽  
pp. 834-837
Author(s):  
Chun Hui Cao ◽  
Jun Cong Wei ◽  
Jian Kun Huang ◽  
Jun Bo Tu

MgAl2O4-SiC composites were prepared by using MgAl2O4 and SiC powder as main starting materials, being pressed to cylindrical specimens of Φ30mm×30mm at 200 MPa and heated respectively at 1400°C and 1500°C for 3 hours in air atmosphere. The room temperature physical properties of sintered samples were tested according to related national standards. The phase compositions were analyzed by XRD. The microstructure of the fracture of the samples was observed by SEM. The results showed that MgAl2O4-SiC materials could sintered well in air atmosphere. The mechanism is that SiC was oxidized to form active SiO2, which reacted with MgAl2O4 to produce liquid cordierite promoting the sintering of the materials. The sinterability of MgAl2O4-SiC materials was overall improved with increasing the sintering temperature. When the content of SiC of MgAl2O4-SiC materials was 10%, the cold crushing strength and bulk density of the samples reached maximums and apparent porosity reached a minimum; the content of SiC was more than 10%, the sinterability of samples deteriorated.


Author(s):  
Z Elakhame ◽  
S. A. Bello ◽  
J. O. Agunsoye ◽  
I. Patric ◽  
O. Otitoju

 Ujogba clay deposits in Esan Land, Edo State of Nigeria were characterized for refractory and other applications. The characteristics investigated were mineralogical composition, chemical composition, linear shrinkage, apparent porosity, bulk density, cold crushing strength and density. The physical property tests were carried out in accordance with ASTM C71. Results obtained showed that the Ujogba clays are largely kaolinite and chemically composed of mainly silica (68.93 %) and alumina (24.61 %). These oxides appreciated to 71.04 % (silica) and 19.63 % (alumina) in the fired product; yet the ratio of alumina to silica remained unchanged. The physical property such as refractory property examination confirmed that the clays belong to the fireclay class and are useful for refractory and ceramic applications. Kathmandu UniversityJournal of Science, Engineering and TechnologyVol. 12, No. 2, 2016, page: 71-82  


2018 ◽  
Vol 15 (1) ◽  
pp. 59-69
Author(s):  
K.G. Akpomie ◽  
C.C. Ezeofor ◽  
O.L. Alum ◽  
U.A. Augustine ◽  
F.N. Ibeanu

The effect of Dioscorea rotundata peel environmental waste as an insulating additive for local clay was studied. The potential of a low cost indigenous clay mineral obtained from Akpugu-Ezedike in Nigeria for industrial application was also evaluated. The clay was characterized by the Fourier transform infrared spectroscopy, X-ray diffraction and Scanning electron microscopy (SEM). Prepared slurry mixture of the clay and peels were shaped, dried and fired. The chemical composition of the clay was determined by classical methods. Physical properties such as linear shrinkage, total shrinkage, modulus of rupture, apparent density, bulk density, apparent porosity,s welling index and water absorption, modulus of plasticity and refractoriness of the fired samples were determined. The clay was found to have a refractoriness of 12000C. SEM analysis revealed an increase in porosity of the fired clay bodies with increase in dosage of Dioscorea rotundata added. This result was corroborated by the high apparent porosity 49.67 – 60.02% and water absorption recorded 30.92 – 48.44% for the mixed fired samples. The result of this study clearly indicated the potential of Dioscorea rotundata peel as additive in enhancing insulating properties of fired clay as well as the usefulness of the local clay mineral for industrial purposes.


2013 ◽  
Vol 315 ◽  
pp. 11-14 ◽  
Author(s):  
I.A. Rafukka ◽  
B. Onyekpe ◽  
Y. Tijjani

The investigations centered on how addition of Gezawa clay (GC) affects the refractory properties of the Gezawa stone (GS) (Silica Stone) with a view to finding the optimum percentage of the blend that will give good refractory properties. The samples were crushed, ground, sieved and the chemical compositions were determined. Test samples were produced by blending the Gezawa stone with various proportions of Gezawa clay. The refractoriness of the samples was measured, and the samples were then fired to 1100and standard properties such as thermal shock resistance, cold crushing strength and apparent porosity were determined. The result shows that addition of Gezawa clay to Gezawa stone improves its thermal shock resistance but reduces the refractoriness, while the porosity was found to be within the specified range for fire clay and the cold crushing strength of the samples was high. Compromise could be made in selecting the percentage that would suit certain application.


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