scholarly journals Seasonal Variation of Metallic Contamination of Water and Sediments in Navigation Canal and Industrial Zone South Port Said, Egypt

2018 ◽  
pp. 1-12
Author(s):  
Nabil, A. E. Azzaz ◽  
Mokhtar, S. Beheary ◽  
Mohamed, N. Raslan ◽  
Hazem T. Abd El Hamid
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Winter Season ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Industrial Zone ◽  
Sediment Samples ◽  
Accumulation Index ◽  
Port Said ◽  
Mean Concentration

In the present study, water and sediment samples were collected from Navigation Canal and from Industrial Zone South Port Said to assess heavy metals contamination. It was shown that, the highest mean concentration of heavy metals in water samples was observed in summer, and the lowest mean was observed in winter. It has been made evident that the industrialization in Industrial Zone South Port Said was responsible for the present deteriorating conditions. However, it was shown that, the highest mean concentration of heavy metals in sediment samples was observed in winter, and the lowest mean was observed in summer. Pollution status was evaluated using some indices: geo-accumulation index (Igeo), contamination factor (CF), pollution load index (PLI) and ecological risk index (RI). Based on Igeo, all metal values were unpolluted. On the basis of the values of CF, sediments are high in winter and low in summer. Metals concentrations were in the following order: Ni > Fe > Mn > Pb > Cu > Zn > Co > Cd. According to CF classification, Ni contamination was considerable. RI of winter season can be classified as moderate pollution. No pollution was classified for PLI in all seasons. The decrease in PLI and RI values were indicated dilution and dispersion of metal content with increasing distance from source areas. It is suggested that PLI can give an indication about the trend spatially and temporarily. In addition, it also provides significant data and advice to the policy and decision makers on the contamination degree of the area.

scholarly journals Study of potential availability of heavy metals to phytoremediation to use of ash from biomass combustion

2018 ◽  
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Biomass Combustion ◽  
Multivariate Statistical ◽  
New Class ◽  
Accumulation Index ◽  
Potential Availability ◽  
Test Soil

<p>Ashes, formed as a result of combustion of biomass are a new class of by-products of combustion and due to the large variety of these materials their chemical composition has not been fully determined. Their use is limited, despite the fact that their production has increased. This work presents the results of studies on the possibility of limiting the potential availability of Cu, Mn, Pb and Zn for plants by use of an inorganic stabilizer - ash from biomass combustion. In this study the usefulness of ash from biomass for binding mobile fractions of heavy metals (Cu, Mn, Pb and Zn) was evaluated. The investigations were executed using three extraction tests with the use of the following extraction solutions: 1 M HNO3 – acid soluble forms (As), 0.05 M EDTA – bioavailable forms (Bio), 2.5% CH3COOH – exchangeable forms (Ex). The values of the following parameters: Mobility Index (MI), Contamination Factor (CF), Pollution Load Index (PLI), Geo – accumulation Index (Igeo) and Ecological Risk Index (RI) were defined and determined for their suitability as a test soil stabilizer. Furthermore, a multivariate statistical analysis was carried out. It was found, that a phytoremediation process using investigated ash from biomass combustion can be applied to soil contaminated by heavy metals.</p>

scholarly journals Heavy Metals Contamination of Soil in the Vicinity of Hawassa Industrial Zone, Ethiopia

2020 ◽  
Vol 24 (8) ◽  
pp. 1447-1454
Author(s):  
B. Samuel ◽  
S. Solomon ◽  
F. Daniel ◽  
G.M. Zinabu ◽  
G. Riise
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Human Impacts ◽  
Risk Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Water Sources ◽  
Industrial Zone ◽  
Pollution Load ◽  
Degree Of Contamination

Industrial effluents, containing heavy metals, drain directly into downstream water sources within the Hawassa Industrial Zone. These, water  sources are used for irrigation, drinking water and other domestic purposes. The load of pollutants, environmental risks and potential human impacts are generally, unknown for soil in Ethiopia. Therefore, the aim of this study was to determine the extent of heavy metal pollution of soil within the Hawassa Industrial Zone and to evaluate environmental impacts using contamination factor (CF), degree of contamination (Cd), modified degree of contamination (mCd), ecological risk factor (Er), ecological risk index (ERI) and pollution load index (PLI) analyses. Seven heavy metals: Cr, Ni, Cu, Zn, As, Cd and Pb were determined in soil samples from three different sites by inductively coupled plasma mass spectrometry (ICP-MS). Average concentration of metals decreased in the order of Zn>Cu>Cr>Ni>Pb>As>Cd consistent with the normal order of abundance in non-polluted soils. One way ANOVA revealed significant differences (P<0.05) in the concentrations of Cu, As, Cd and Pb among the sampling sites. Pearson’s correlation, principal component and cluster analyses revealed that heavy metals are originating from different sources. Within the industrial area,  the CF increased in the order of Pb<Cd<Zn<As<Cu<Cr<Ni. The result of Cd revealed that there was considerable to very high contamination of the soil. The mCd index showed moderate contamination of the soils. The Er increased in the order of Zn<Cr<Pb<Cu<Ni<As<Cd and the result of the ERI value revealed considerable ecological risk for the soils. Overall, the study showed that the soils within the Hawassa Industrial Zone are highly contaminated with heavy metals. Therefore, regular monitoring of heavy metals concentration in soil and policy interventions with respect to waste disposal are recommended. Keywords: Heavy metals, potential ecological risks, pollution load index, soil

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals Environmental Geochemical Assessment of Heavy Metals in Soil and Sediment of (Shatt-Al-Hilla) Babil Governorate, Central Iraq

2019 ◽  
Vol 60 (5) ◽  
pp. 1055-1068
Author(s):  
Mansour Hussain Manea ◽  
Balsam Salim. Al-Tawash ◽  
Younus I. Al-Saady
Keyword(s):  
Heavy Metals ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Exchange Capacity ◽  
Geochemical Background ◽  
Degree Of Contamination ◽  
Sediment Samples ◽  
Low Degree ◽  
Soils And Sediments ◽  
Soil And Sediment

Heavy metals concentration in the soils and sediments has increased worldwide during the last century as a result of the rapid increase in population which combined by an increase in human activity as agriculture,  industrial and many other activities. Ten soil and three river sediment samples were collected from 10 main sampling stations at Shatt Al-Hilla River from Sada area to Dora Bridge in Babylon province. The chemical analysis of the sedimentation sample in the laboratory included pH calculation, electrical conductivity (EC) (Cation Exchange Capacity (CEC), organic matter (OM), and heavy metals as (Mn, Ni, Cr, Zn, Cu, Co, Pb, Cd, As and Fe). Indirect geochemical background (IGB) of heavy metal was calculated by the iterative 2 standard deviations (SD) method. The results of enrichment factor for heavy metals of the soil and sediment show that the all heavy metals in the studied samples were within Ef<2 indicate to depletion to minimal enrichment (i.e. no or minimal pollution). While Cd in the sample (5), Co in the sample (7), Cr in the sample (8) and Mn in the sample (1S) are within 2 ≤ EF < 5 indicate to Moderate enrichment. Contamination factor (Cf) for heavy metals of soil and sediment show that the all heavy metals in the studied samples were within Cf < 1 -Low contamination. While Sample "2" (Cd, Fe), sample "3" (Ni, Cr, Pb, and Cd), sample "4" (Mn, Fe) and sample "8" (Cr) are within 1 ≤ Cf < 3 moderate contamination. Pollution load index result of all the soil and sediment samples are less than one indicate that  "no pollution" are present, except sample 3 where the PLI value higher than 1 indicates the samples have been "polluted ". The modified degree of contamination (mCd) data indicate nil to a low degree of contamination for all of the soil and sediments samples.

scholarly journals Analysis of Heavy Metals in Surface Sediments from Agh Gel Wetland, Iran

2016 ◽  
Vol 10 (3) ◽  
pp. 41-46
Author(s):  
Soheil Sobhanardakani ◽  
◽  
Mehrnaz Ghoochian ◽  
Keyword(s):  
Heavy Metals ◽  
Surface Sediments ◽  
Contamination Factor ◽  
Dry Weight ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Chemical Pollutants ◽  
Accumulation Index ◽  
The Mean ◽  
Geo Accumulation Index

Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo), Contamination factor (CF) and Pollution load index (PLI) were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight) ranged within 0.20-0.29 (Cd), 58-71 (Cr) and 23-36 (Cu). According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.

scholarly journals Estimation of Risk to the Eco-Environment and Human Health of Using Heavy Metals in the Uttarakhand Himalaya, India

2020 ◽  
Vol 10 (20) ◽  
pp. 7078 ◽  
Author(s):  
Amit Kumar ◽  
Marina Cabral-Pinto ◽  
Amit Kumar ◽  
Munesh Kumar ◽  
Pedro A. Dinis
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Ecological Risk ◽  
Risk Index ◽  
Hazard Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Mitigation Measures ◽  
Sampling Locations ◽  
Modern Era

In the modern era, due to the rapid increase in urbanization and industrialization in the vicinity of the Himalayas, heavy metals contamination in soil has become a key priority for researchers working globally; however, evaluation of the human and ecological risks mainly in hilly areas remains limited. In this study, we analyzed indices like the contamination factor (CF), degree of contamination (DC), enrichment factor (EF), geochemical index (Igeo), pollution ecological risk index (PERI), and pollution load index (PLI), along with cancer risk (CR) and hazard indices (HI), to ascertain the eco-environmental and human risks of using heavy metals in datasets collected from 168 sampling locations in Uttarakhand, India. The evaluation calculated of Igeo, EF, and CF suggests that represented soil samples were moderately contaminated and highly augmented with Rb, while PERI (75.56) advocates a low ecological risk. Further, PLI and DC (PLI: 1.26; DC: 36.66) show a possible health risk for the native population in the vicinity of the studied catchment. The hazard index (HI) is estimated greater than 1 (HI > 1) for Cr and Mn, representing a possible risk for cancer. However, adults are free from cancer risk, and other studied elements have been reported as noncarcinogenic. This assessment gives important information to policymakers, environmentalists, and foresters for taking mitigation measures in advance to mitigate the potential future risk of soil pollution on humans, ecology, and the environment.

scholarly journals Assessment of Heavy Metals in the Sediments of Chalan Beel Wetland Area in Bangladesh

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 410
Author(s):  
Mohammad Abdus Salam ◽  
Mohammad Ashraful Alam ◽  
Sulav Indra Paul ◽  
Fatama Islam ◽  
Dinesh Chandra Shaha ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Anthropogenic Activities ◽  
Risk Index ◽  
Contamination Factor ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
Northwestern Part ◽  
Accumulation Index ◽  
Significant Enrichment ◽  
The Mean

This study aimed to determine the levels and possible sources of heavy metals (HMs) in the sediments of Chalan beel (a large lake-like aquatic ecosystem) area located in the northwestern part of Bangladesh. The mean concentrations (mg kg−1) of two HMs, Cd (6.22) and Pb (51.39) exceeded the world normal averages (WNA), whereas the mean concentrations (mg kg−1) of Ni (60.46), Zn (10.75), Mn (8.64) and Cu (4.71) were below the WNA. The sediments showed significant enrichment with Cd, Pb and Ni in the studied area. The geo-accumulation index values of Cd (3.72) and Pb (0.76) were significantly higher in the sediments. The contamination factor and potential ecological risk index values of Cd and Pb revealed that Chalan beel was extremely and moderately contaminated by these heavy metals, respectively. Analysis of dye complexes used in handlooms around the Chalan beel areas revealed that mean concentrations of Cd and Pb exceeded the WNA. Furthermore, analyses of principal component, cluster and correlation matrix indicated that the presence of the higher levels of Cd and Pb in the sediments might be linked to various anthropogenic activities like discharged dyes into the beel water from the nearby handloom dyeing factories.

scholarly journals Evaluation of ecological risk, source and spatial distribution of some heavy metals in marine sediments in the Middle and Eastern Black Sea region, Turkey

2021 ◽  
Author(s):  
Aylin Apaydın ◽  
Hatice Kabaoğlu ◽  
Gökhan Apaydın ◽  
Murat Şirin ◽  
Erhan Cengiz ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Black Sea ◽  
Ecological Risk ◽  
Risk Index ◽  
Agricultural Practices ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Black Sea Region ◽  
The Mean

Abstract In the present study, the concentration levels of heavy metals such as Mn, Fe, Ni, Cu, Zn, Cr and Pb in sediment samples collected from 16 sampling locations in the Middle and Eastern Black Sea regions, Turkey was measured using energy dispersive X–ray fluorescence spectroscopy (EDXRF). Various pollution parameters and methods, such as the enrichment factor (EF), geo–accumulation index (Igeo), contamination factor (CF), pollution load index (PLI), ecological risk index (RI), and geo–spatial distribution patterns were used to assess in detail the pollution status, ecological risks and sources of metals in sediment. The mean concentrations of Mn, Fe, Ni, Cu, Zn, Cr and Pb were found to be 565.38, 46,000, 34.38, 104.06, 109.88, 87.31, and 32.31 mg/kg, respectively. Results showed that the mean concentrations of Cu, Zn and Pb exceeded the crustal shale value, with the exception of Mn, Fe, Ni and Cr. According to the calculated pollution parameters, although minimal or moderate pollution was detected in the area investigated, it was determined that there was a very low ecological risk. Multivariate statistical analysis results showed that Cu, Zn, and Pb levels in the investigated region were slightly influenced by anthropogenic inputs such as mining and agricultural practices. In addition, the geo–spatial distributions of Cu, Zn, Fe and Pb were found to be higher in this region due to the mining activities carried out in the Eastern Black Sea region.

scholarly journals Penilaian pencemaran logam berat dalam sedimen di Teluk Jakarta

DEPIK ◽  
2020 ◽  
Vol 9 (3) ◽  
pp. 403-410
Author(s):  
Edward Edward
Keyword(s):  
Heavy Metals ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Index Analysis ◽  
Accumulation Index ◽  
Geo Accumulation Index ◽  
Geo Accumulation ◽  
Total Average

Contamination and pollution of heavy metals in the bottom sediment can pose serious issues to marine organisms and human health. Jakarta Bay which is located adjacent to the capital city of Indonesia is notorious for its pollution problems. The purpose of this research was to assest the contamination levels of heavy metals Hg, Pb, and Cd in sea-bottom sediments based on an index analysis approach (contamination factors, geo accumulation index, pollution load index). Sediment samples were collected from 31 stations in Jakarta Bay. Heavy metal concentration was measured using Atomic Absorption Spectrophotometer (AAS). The results showed that an average mercury (Hg) concentration ranged from 0.150 to 0.530 µg.g-1 with an total average of 0.362 µg.g-1, Lead (Pb) from 14.870 to 35.650 µg.g-1 with an total average of 21.774 µg.g-1, Cadmium (Cd) 0.110-0.280 µg.g-1 with an total average of 0.190 µg.g-1.The average concentration of Hg, Pb, and Cd is still lower than the sediment quality threshold values set by the Office of the State Minister of Environment of Indonesia  2010. The results of the index analysis showed that the average value of contamination factor (CF) are Hg 0.685, Pb 0.558, and Cd 0.380 respectively (low contamination) and geo accumulation index values are Hg 0.237, Pb -1.655, and Cd 0.069 respectively (unpolluted to moderate polluted). Overall, based on the pollution load index value is -0,511 (PLI 1), sediments in these waters are categorized as not yet polluted by Hg, Pb and Cd. This situation  is so necessary to be maintained, that in order for the preservation of marine resources will remain.Keywords: Jakarta Bay, sediment, pollution, heavy metals, assessmentABSTRAKKontaminasi dan pencemaran logam berat pada sedimen dasar dapat menimbulkan masalah yang serius bagi biota laut dan kesehatan manusia. Teluk Jakarta yang terletak berdekatan dengan ibu kota Indonesia terkenal karena masalah pencemarannya yang parah. Tujuan penelitian ini adalah untuk menilai tingkat kontaminasi logam berat Hg, Pb dan Cd dalam sedimen dasar laut berdasarkan pendekatan analisis indeks. Contoh sedimen diambil dari 31 stasiun penelitian di Teluk Jakarta. Kadar logam berat diukur dengan alat Spektrofometer Penyerapan Atom. Hasil penelitian menunjukkan kadar Hg rerata berkisar 0,150-0,530 µg. g-1 dengan rerata total 0,362 µg. g-1, Timbal (Pb) 14,870-35,650 µg. g-1 dengan rerata total 21,774 µg. g-1, Kadmium (Cd) 0,110-0,280 µg. g-1 dengan rerata total 0,190 µg.g-1. Kadar rerata Hg, Pb dan Cd masih lebih rendah dari nilai ambang batas kualitas sedimen yang ditetapkan oleh Kantor Menteri Negara Lingkungan Hidup Indonesia 2010. Hasil analisis indeks menunjukkan nilai rerata faktor kontaminasi (CF) berturut-turut adalah Hg 0,685, Pb 0,352 dan Cd 0,380 (kontaminasi rendah) dan nilai indeks geo akumulasi berturut-turut adalah Hg 0,227, Pb 1,098 dan Cd 0,633 (tidak tercemar sampai tercemar sedang). Secara keseluruhan, berdasarkan nilai indeks beban pencemaran yakni -3.772 (PLI 1), sedimen di perairan ini termasuk kategori belum tercemar oleh Hg, Pb dan Cd. Keadaan ini perlu dipertahankan, agar kelestarian sumberdaya laut tetap terjaga.Kata kunci: Teluk Jakarta, sedimen, pencemaran, logam berat, penilaian

scholarly journals “Assessment of Heavy Metal Pollution in Soil of Chattogram Hill Tracts, Bangladesh and Concomitant Health Risk”

2021 ◽  
Author(s):  
Troyee Barua ◽  
AKM Saiful Islam Bhuian ◽  
Mayeen Uddin Khandaker ◽  
Nipa Deb ◽  
Shahadat Hossain ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Hazard Index ◽  
Significant Risk ◽  
Contamination Factor ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Potential Ecological Risk ◽  
Pollution Load Index ◽  
Toxic Heavy Metals

Abstract The increased human population and associated activities may create a risk in the ecological balance of Chattogram Hill Tracts (CHT), Bangladesh via contamination of soil with toxic heavy metals. Thus, the present study was conducted to assess the concentration of heavy metals (Lead, Cadmium, Copper, Zinc, Iron, Manganese, Chromium and Nickel) in forest soils of the CHT area by using an atomic absorption spectrometer. The degree of contamination of soil was evaluated by five indices: geo-accumulation index (I geo ), enrichment factor (EF), contamination factor (CF), pollution load index (PLI) and potential ecological risk index (PERI). According to these criteria, these soils can be classified as moderately contaminated with some metals. Furthermore, the identification of pollution sources based on principal component analysis and hierarchical cluster analysis have revealed that all analyzed metals are anthropogenic except Fe. Calculated hazard index>1 indicates the possibility of noncarcinogenic effect due to higher value of Fe. Carcinogenic risks through the ingestion, inhalation and dermal pathway for carcinogenic elements (Pb, Cd, Cr, and Ni) shows a non-significant risk (CR<10 -6 ) for both children and adults living in the studied area. Measured data may help the policymakers to reduce the potential effects of soil contamination on eco-environment and human health.

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