Effects of Substrate Bias Voltage on Structure of Diamond-Like Carbon Films on AISI 316L Stainless Steel: A Molecular Dynamics Simulation Study

With the recent significant advances in micro- and nanoscale fabrication techniques, deposition of diamond-like carbon films on stainless steel substrates has been experimentally achieved. However, the underlying mechanism for the formation of film microstructures has remained elusive. In this study, the growth processes of diamond-like carbon films on AISI 316L substrate are studied via the molecular dynamics method. Effects of substrate bias voltage on the structure properties and sp3 hybridization ratio are investigated. A diamond-like carbon film with a compact structure and smooth surface is obtained at 120 V bias voltage. Looser structures with high surface roughness are observed in films deposited under bias voltages of 0 V or 300 V. In addition, sp3 fraction increases with increasing substrate bias voltage from 0 V to 120 V, while an opposite trend is obtained when the bias voltage is further increased from 120 V to 300 V. The highest magnitude of sp3 fraction was about 48.5% at 120 V bias voltage. The dependence of sp3 fraction in carbon films on the substrate bias voltage achieves a high consistency within the experiment results. The mechanism for the dependence of diamond-like carbon structures on the substrate bias voltage is discussed as well.

Effect of Ion Energy on the Microstructure and Properties of Titanium Nitride Thin Films Deposited by High Power Pulsed Magnetron Sputtering

Titanium nitride (Ti-N) thin films are electrically and thermally conductive and have high hardness and corrosion resistance. Dense and defect-free Ti-N thin films have been widely used in the surface modification of cutting tools, wear resistance components, medical implantation devices, and microelectronics. In this study, Ti-N thin films were deposited by high power pulsed magnetron sputtering (HPPMS) and their plasma characteristics were analyzed. The ion energy of Ti species was varied by adjusting the substrate bias voltage, and its effect on the microstructure, residual stress, and adhesion of the thin films were studied. The results show that after the introduction of nitrogen gas, a Ti-N compound layer was formed on the surface of the Ti target, which resulted in an increase in the Ti target discharge peak power. In addition, the total flux of the Ti species decreased, and the ratio of the Ti ions increased. The Ti-N thin film deposited by HPPMS was dense and defect-free. When the energy of the Ti ions was increased, the grain size and surface roughness of the Ti-N film decreased, the residual stress increased, and the adhesion strength of the Ti-N thin film decreased.

Robust low friction performance of graphene sheets embedded carbon films coated orthodontic stainless steel archwires

Reducing the friction force between the commercial archwire and bracket during the orthodontic treatment in general dental practice has attracted worldwide interest. An investigation on the friction and wear behaviors of the uncoated and carbon film coated stainless steel archwires running against stainless steel brackets was systematically conducted. The carbon films were prepared at substrate bias voltages from +5 to +50 V using an electron cyclotron resonance plasma sputtering system. With increasing substrate bias voltage, local microstructures of the carbon films evolved from amorphous carbon to graphene nanocrystallites. Both static and stable friction coefficients of the archwire-bracket contacts sliding in dry and wet (artificial saliva) conditions decreased with the deposition of carbon films on the archwires. Low friction coefficient of 0.12 was achieved in artificial saliva environment for the graphene sheets embedded carbon (GSEC) film coated archwire. Deterioration of the friction behavior of the GSEC film coated archwire occurred after immersion of the archwire in artificial saliva solution for different periods before friction test. However, moderate friction coefficient of less than 0.30 sustained after 30 days immersion periods. The low friction mechanism is clarified to be the formation of salivary adsorbed layer and graphene sheets containing tribofilm on the contact interfaces. The robust low friction and low wear performances of the GSEC film coated archwires make them good candidates for clinical orthodontic treatment applications.

Зависимость механических и трибологических свойств a-C : H : SiO-=SUB=-x-=/SUB=--пленок от амплитуды напряжения смещения подложки

The paper presents the AISI 316L stainless steel surface modification by plasma-assisted chemical vapor deposition of a-C:H:SiOx film using the pulsed bipolar substrate bias voltage. The mechanical and tribological properties of the a-C:H:SiOx film and the steel surface are examined using the nanoindentation method and the pin-on-disk tribometer, respectively. The optimum value is obtained for the amplitude of the negative pulse of the bipolar bias voltage, when the hardness of the a-C:H:SiOx film is high (19±2 GPa). This hardness value is 3.5 times greater, than the hardness of the AISI 316L steel surface (5.5±0.1 GPa). At the same time, the coefficient of friction of the film is low (0.08), which is 9 times lower than that of the steel (0.72). The wear rate values are found to be 8.5×10-7 and 3.7×10-5 mm3N-1m-1 for the coated and uncoated steel, respectively. The structure and composition of the obtained films are studied by Raman spectroscopy and scanning electron microscopy.