Ultrafine Ductile and Austempered Ductile Irons by Solidification in Ultrasonic Field

In this research, ultrasonic melt treatment (UST) was used to produce a new ultrafine grade of spheroidal graphite cast iron (SG iron) and austempered ductile iron (ADI) alloys. Ultrasonic treatment was numerically simulated and evaluated based on acoustic wave streaming. The simulation results revealed that the streaming of the acoustic waves propagated as a stream jet in the molten SG iron along the centerline of the ultrasonic source (sonotrode) with a maximum speed of 0.7 m/s and gradually decreased to zero at the bottom of the mold. The metallographic analysis of the newly developed SG iron alloy showed an extremely ultrafine graphite structure. The graphite nodules’ diameter ranging between 6 and 9 µm with total nodule count ranging between 900 to more than 2000 nodules per mm2, this nodule count has never been mentioned in the literature for castings of the same diameter, i.e., 40 mm. In addition, fully ferritic matrix was observed in all UST SG irons. Further austempering heat treatments were performed to produce different austempered ductile iron (ADI) grades with different ausferrite morphologies. The dilatometry studies for the developed ADI alloys showed that the time required for the completion of the ausferrite formation in UST alloys was four times shorter than that required for statically solidified SG irons. SEM micrographs for the ADI alloys showed an extremely fine and short ausferrite structure together with small austenite blocks in the matrix. A dual-phase intercritically austempered ductile iron (IADI) alloy was also produced by applying partial austenitization heat treatment in the intercritical temperature range, where austenite + ferrite + graphite phases coexist. In dual-phase IADI alloy, it was established that introducing free ferrite in the matrix would provide additional refinement for the ausferrite.

The Role of Selenium on the Formation of Spheroidal Graphite in Cast Iron

Sulfur, an element that belongs to group 16 (chalcogens) of the periodic table, is an excellent promoter of nucleation substrates for graphite in cast iron. In ductile iron, sulfur favors a higher nodule count, which inhibits the risk of carbides and of microporosity. It is reasonable to expect that other elements from group 16, such as selenium or tellurium, play similar roles in the nucleation of graphite. The objective of this paper was to investigate the effect of selenium on the process of graphite formation. Thermal analysis cups were poured to evaluate the nodule count and size distribution. Some of the cups were not inoculated, while others were inoculated with a Ce-bearing inoculant, or with the Ce inoculant and additions of Se. Cross-shaped castings were also poured to quantify the microporosity regions by tomography. It appears that selenium additions modify the number and size of graphite particles, as well as the volume of microshrinkage. Direct correlations between these three parameters were found. Advanced Extensive Field Emission Gun Scanning Electron Microscope (FEG-SEM) techniques were used to identify the nature of the main nucleation compounds. Selenides, combined with Mg and rare earths, were observed to serve as nuclei for graphite. Their presence was justified by thermodynamics calculations.

Nodule Count, End of Solidification Cooling Rate, and Shrinkage Porosity Correlations in High Silicon Spheroidal Graphite Iron

High-silicon spheroidal graphite (SG) irons present higher changes of density during the solidification process when compared to normal SG irons. This special behavior is particularly significant in the last stages of solidification, where the graphite expansion may become insufficient to compensate the contraction of the austenite and the risk of microporosity formation increases. The goal of this laboratory research was to establish correlations between the different levels of nodule count obtained using five commercial inoculants, the cooling rate at the end of solidification, and the shrinkage porosity propensity. The analysis was conducted on thermal analysis cups that were sectioned and evaluated for microstructure by optical metallography and by 2D analysis with the Image J software to quantify the size of the microporosity region. It was found that a higher nodule count, associated with higher cooling rate at the end of solidification, generates lower porosity. SEM analysis was conducted to study the nature of nuclei. Complex (MgSiAl)N nitrides were found as the main nucleation sites for graphite.

Microstructural and Mechanical Assessment of Camshafts Produced by Ductile Cast Iron Low Alloyed with Vanadium

In the present study, ductile iron camshafts low alloyed with 0.2 and 0.3 wt % vanadium were produced to study the microstructural and mechanical evaluation of lobes and camshaft. For this purpose, camshafts were produced in one of the largest manufacturers of the ductile iron camshaft in México by the phenolic urethane no-bake sand mold casting method. The microstructure of the lobes was studied in three zones located at the top, middle, and bottom of the lobes by optical microscopy, and mechanical tests were performed on lobes and camshafts. A homogeneous distribution of spheroidal graphite with high nodularity for both castings was obtained from the regions of the lobes analyzed. The high cooling rate on the lobe surfaces enabled us to obtain a high nodule count of a smaller size instead of the middle region where big nodules with a low nodule count are presented. An inverse chill behavior was found in the middle region of the lobes where there is an increase in the concentration of carbide-forming elements, leading to the highest micro-hardness values in this region. The tensile properties were increased when the vanadium contents were increased; however, the toughness and ductility of the as-cast alloys were decreased as a result of the increase of the volume fraction of carbide particles.

Nodule count effect on microstructure and mechanical properties of hypo-eutectic ADI alloyed with nickel

Samples of ductile iron alloyed with 0.88 % Ni with a nodule count of 606, 523, and 290 nod/mm2 were obtained from sand cast plates of different thickness in the range from 8.46 to 25.4 mm. The effect of the nodule count was evaluated during the austempering process held at 285?C and austempering times of 15, 30, 45, 60, 70, and 90 min. The volume fraction of high carbon austenite increased when the nodule count increased, however, the carbon content of the high carbon austenite kept almost constant. The process window was narrow, requiring a lower austempering time when the nodule count increased. The combination of a higher nodule count and low austempering temperature allowed obtaining a fine ausferritic microstructure which led to higher Brinell hardness and tensile strength. The process window was determined by XRD measurements and it was in good agreement with the microstructural and hardness evolution as the austempering time increased.

Effects of aluminum and copper on the graphite morphology, microstructure, and compressive properties of ductile iron

The effect of aluminum (0, 2, 4, and 6 wt. %) and copper (0, 2, 4, and 6 wt. %) on graphite morphology, microstructure and compressive behavior of ductile iron specimens manufactured by sand casting technique were investigated. The graphite morphology and microstructure were evaluated using optical microscopy (OM) and scanning electron microscopy (SEM) equipped image processing software. To study the mechanical properties, the compression test was conducted on the ductile iron specimens. The results indicated that the surface fraction and nodule count of graphite decreased when the amount of aluminum increased from 0 to 2 wt. % and after that from 2 to 6 wt. %. In addition, the nodularity of graphite increased with the increment of the aluminum amounts. By adding the amount of copper, the surface fraction and nodule count of graphite increased and nodularity of graphite decreased. The addition of aluminum and copper decreased the surface fraction of ferrite and increased the surface fraction of pearlite in the microstructure. By increasing the amounts of aluminum and copper, compressive stress vs. strain curves were shifted upwards, and modulus of elasticity, yield strength, maximum compressive stress, and fracture strain improved. In comparison with copper, aluminum had a greater influence on the mechanical properties of ductile iron.

Mechanical Properties of Thin Wall Ductile Iron: Experimental Correlation Using ANOVA and DOE

The present study was undertaken to investigate the effect of different metallurgical parameters such as casting techniques, wall thickness, inoculant technique, carbon equivalent, nodule count, ferrite and pearlite percent on the mechanical properties of thin wall ductile iron castings (TWDI). Understanding of the effect of chemistry, casting techniques, melting and molten treatment on the mechanical properties and microstructural features of TWDI castings would help in selecting conditions required to achieve optimum mechanical properties and alloy high strength to weight ratio. The use of the design of experiment (DOE) and the analysis of variance (ANOVA) can be a useful methodology to reach this objective. The analysis of the effects of each variable and their interaction on the mechanical properties of TWDI castings using green sand, green sand with insulation and investment casting techniques plays a key role in improved materials performance.The results indicate that nodule count, pearlite content and the interaction between carbon equivalent, nodule count and pearlite content have a significant effect on the tensile strength of TWDI castings. The impact toughness values decrease with smaller section thickness and increased nodule count. Using investment casting technique, decreasing the pearlite percent and nodule count, and increasing the wall thickness and ferrite percent reduce the values of ultimate tensile strength and yield strength. The results of percent elongation and impact toughness show a reverse trend compared with those of ultimate tensile strength and yield strength in terms with different metallurgical parameters.