Two-Dimensional Soil Geometric Tortuosity Model Based on Porosity and Particle Arrangement

Porosity and particle arrangement are important parameters affecting soil tortuosity, so it is of great significance to determine the intrinsic relationship between them when studying soil permeability characteristics. Theoretical derivation and geometric analysis methods are used to derive a two-dimensional geometric tortuosity model. The model is a function of particle arrangement parameters (m and θ) and porosity. An analysis of the model and its parameters shows that: (1) The arrangement of particles is one of the reasons for the different functional relationship between tortuosity and porosity, which proved that the tortuosity is not only related to the porosity but also affected by the particle arrangement. (2) The greater the anisotropy parameter m is, the greater the tortuosity is, indicating m varies when fluid passes through the soil from different sides resulting in different values of permeability. (3) The tortuosity increases with the increase in the blocking parameters θ. (4) With increasing porosity, the influence of the parameters m and θ on the tortuosity gradually decreases, suggesting that the influence of particle arrangement on tortuosity gradually decreases. The results presented here increase the understanding of the physical mechanisms controlling tortuosity and, hence, the process of fluid seepage through soil.

Characterization of gliadin, secalin and hordein fractions using analytical techniques

Prolamins, alcohol soluble storage proteins of the Triticeae tribe of Gramineae family, are known as gliadin, secalin and hordein in wheat, rye and barley respectively. Prolamins were extracted from fifteen cultivars using DuPont protocol to study their physiochemical, morphological and structural characteristics. SDS-PAGE of prolamins showed well resolved low molecular weight proteins with significant amount of albumin and globulin as cross-contaminant. The β-sheet (32.72–37.41%) and β-turn (30.36–37.91%) were found higher in gliadins, while α-helix (20.32–28.95%) and random coil (9.05–10.28%) in hordeins. The high colloidal stability as depicted by zeta-potential was observed in gliadins (23.5–27.0 mV) followed secalins (11.2–16.6 mV) and hordeins (4.1–7.8 mV). Surface morphology by SEM illustrated the globular particle arrangement in gliadins, sheet like arrangement in secalins and stacked flaky particle arrangement in hordeins fraction. TEM studies showed that secalin and hordein fractions were globular in shape while gliadins in addition to globular structure also possessed rod-shaped particle arrangement. XRD pattern of prolamin fractions showed the ordered crystalline domain at 2θ values of 44.1°, 37.8° and 10.4°. The extracted prolamins fractions showed amorphous as well as crystalline structures as revealed by XRD and TEM analysis. Space saving hexagonal molecular symmetry was also observed in TEM molecular arrangement of prolamins which has profound application in development of plant-based polymers and fibres.

Microscopic Mechanism of Cement Improving the Strength of Lime-Fly Ash-Stabilized Yellow River Alluvial Silt

Silt is a kind of soil with poor engineering performance. Lime-fly ash- (LF-) stabilized silt has the problem of low early strength. In this study, it is aimed to investigate the effect of cement on improving the strength of LF-stabilized silt and reveal the microscopic mechanism. A fixed percentage of LF (18%) plus different percentages of cement (0%, 2%, 4%, and 6%) were mixed with Yellow River alluvial silt (YRAS). Soil samples for tests were artificially made by compaction in the laboratory. Unconfined compressive strength (UCS) tests were performed on soil samples cured for 7 d, 28 d, 60 d, and 90 d. Scanning electron microscope (SEM) tests, energy dispersive X-ray spectroscopy (EDS) tests, and mercury intrusion porosimetry (MIP) tests were performed on soil samples cured for 7 d and 28 d. UCS results showed that the early strength of LF-stabilized YRAS developed significantly after adding cement. UCS also increased with the increase in cement content and curing time. SEM results revealed the differences in microstructure of LF-stabilized YRAS before and after adding cement. Before adding cement, the main microstructure characteristics included small soil particles, large number of pores, and loose particle arrangement. After adding cement, the main microstructure characteristics included large bonded particles, small number of pores, and dense particle arrangement. The EDS results showed that, after curing for 28 d, the elements of gels in stabilized YRAS had changed, mainly including appearance of C and a significant increase of Ca. MIP results showed that the pores with a size of 1 μm∼10 μm accounted for the largest proportion in stabilized YRAS. The product (mainly C-S-H) of cement hydration mainly filled the pores with a size larger than 10 μm at the early stage. Combining strength results and microresults, the micromechanism of cement improving the strength of LF-stabilized YRAS was discussed.

Resistance Characteristics and Particle Arrangement of Smart Paint for Surface Temperature Sensor

There are limitations on the shape of models that can be measured with commonly used temperature sensors. These disadvantages are difficult to measure temperatures of the curved surface. To overcome the shortcomings, a smart paint for temperature measurement is proposed in this work. A polymer solution was prepared for viscosity of the paint and dispersion of materials. The BaTiO3 and Ag nanopaste are used for PTC characteristics and conductivity of the paint, respectively. Smart paint were analyzed the arrangement and shape of particles according to the processes and production methods. Also, the change of resistance was measured while increasing the temperature. The results show that resistance increased as the temperature increased. The performance of the manufactured smart paint was confirmed as a surface temperature sensor.