Mathematical models for thermionic emission current density of graphene emitter

In this study, five mathematical models were fitted in the absence of space charge with experimental data to find a more appropriate model and predict the emission current density of the graphene-based thermionic energy converter accurately. Modified Richardson Dushman model (MRDE) shows that TEC's electron emission depends on temperature, Fermi energy, work function, and coefficient of thermal expansion. Lowest Least square value of $$S=\sum {\left({J}_{th}-{J}_{exp}\right)}^{2}=0.0002 \,\text{A}^{2}/\text{m}^{4}$$ S = ∑ J th - J exp 2 = 0.0002 A 2 / m 4 makes MRDE most suitable in modelling the emission current density of the graphene-based TEC over the other four tested models. The developed MRDE can be adopted in predicting the current emission density of two-dimensional materials and also future graphene-based TEC response.

Stable Field Emission from Vertically Oriented SiC Nanoarrays

Silicon carbide (SiC) nanostructure is a type of promising field emitter due to high breakdown field strength, high thermal conductivity, low electron affinity, and high electron mobility. However, the fabrication of the SiC nanotips array is difficult due to its chemical inertness. Here we report a simple, industry-familiar reactive ion etching to fabricate well-aligned, vertically orientated SiC nanoarrays on 4H-SiC wafers. The as-synthesized nanoarrays had tapered base angles >60°, and were vertically oriented with a high packing density >107 mm−2 and high-aspect ratios of approximately 35. As a result of its high geometry uniformity—5% length variation and 10% diameter variation, the field emitter array showed typical turn-on fields of 4.3 V μm−1 and a high field-enhancement factor of ~1260. The 8 h current emission stability displayed a mean current fluctuation of 1.9 ± 1%, revealing excellent current emission stability. The as-synthesized emitters demonstrate competitive emission performance that highlights their potential in a variety of vacuum electronics applications. This study provides a new route to realizing scalable field electron emitter production.

Review of Greenhouse Gas Emissions from Rewetted Agricultural Soils

Climate policies encourage the search for greenhouse gas (GHG) mitigation options in all economic sectors and peatland rewetting is one of the most efficient mitigation measures in agriculture and land use. The benefits shown in the national GHG inventories, however, depend not only on the actual mitigation actions on the ground but also how well the effects can be reported. Currently there are no specific emission factors for reporting GHG emissions from rewetted agricultural soils as the current emission factors are aggregated for several pre-rewetting land use types. Also, rewetting can aim at either restoration or different forms of paludiculture which may differ in their GHG profile and thus demand disaggregated emission factors. We compiled the current knowledge on GHG emissions on sites where rewetting has occurred on former agricultural peatland in temperate or boreal climate zones. The recent data suggest that on average the current emission factors for rewetting nutrient-rich sites published by the Intergovernmental Panel for Climate Change (IPCC) provide a good estimate for reporting emissions from rewetting in the temperate zone. However, the total GHG balances differed widely in restoration, Sphagnum farming and production of emergent plants in paludiculture and it is evident that disaggregated emission factors will be needed to improve the accuracy of reporting the effects of mitigation measures in the GHG inventories.

Research on the Monitoring Methods of VOCs Leak of Open Circulating Water System in Refineries

Open circulating water heat exchangers are widely used in refineries. According to the current emission standards, whether a circulating water system is leaking is determined by total organic carbon (TOC) concentration at the inlets and outlets of circulating water heat exchangers. However, this method is rough with low compatibility, making it hard to judge the actual leak of a circulating water heat exchanger. Taking a typical refinery with a yearly output of five million tons of oil as an example, we established a ledger of an open circulating water system and optimized the method to judge whether the system is leaking in this paper. The results show that there are 63% of the circulating water heat exchangers can be decided by monitoring the quality of circulating water. Among all, the leak of only 18.81% of the circulating water heat exchangers can be decided by monitoring the amount of TOC.

The Future

This chapter draws together information to discuss a vision for the future, including emissions reduction and avoidance, implementation of negative emissions technologies, solar radiation management, adaptation, and the human dimension of how to drive change. Previous chapters have shown that the current trajectory, if unchanged, will result in global temperatures far exceeding the recommended 1.5–2°C maximum increase recommended in the Paris Agreement and that current emission levels are more likely to continue than not. This chapter summarizes this information, linking it to the important role of NETs in managing future climate change and the need for investment in new technologies. The chapter then introduces Integrated Assessment Models, which are helpful in assessing the various approaches to meeting emissions targets. Finally, the chapter considers the importance of slow response and feedback processes and tipping points.

Thermal Analysis and Testing of Different Designs of LaB6 Hollow Cathodes to Be Used in Electric Propulsion Applications

LaB6 emitters are commonly used in hollow cathodes that are utilized in electric space propulsion systems. In order to obtain necessary surface current emission densities of 1–10 A/cm2 for cathode operations, LaB6 emitters require temperatures above 1500 °C. Hence, the design for LaB6 cathodes presents thermal and mechanical challenges. In this paper, several design iterations for LaB6 hollow cathodes are presented and thermal analyses are conducted for each design. Temperature and heat flux distributions that are obtained from thermal analyses are investigated. The designs are evaluated according to the required heat input to the emitter, and the radiative and conductive heat loss mechanisms. In addition to the thermal analyses, experimental tests are conducted for different cathode designs and, based on these tests, various modes of failure are determined. Revising the cathode design and the material selection iteratively to eliminate the encountered failure mechanisms, a novel cathode design is achieved. Experimental tests of this novel cathode are conducted and current-voltage characteristics are presented for different mass flow rates and for discharge currents between 0.5 and 12 A. Tests and analysis results show that the selection of materials and design are crucial for a sturdy and long lifetime cathode.

Reduced light absorption of black carbon (BC) and its influence on BC-boundary-layer interactions during “APEC Blue”

Light absorption and radiative forcing of black carbon (BC) is influenced by both BC itself and its interactions with other aerosol chemical compositions. Although the changes in BC concentrations in response to emission reduction measures have been well documented, the influence of emission reductions on the light absorption properties of BC and its influence on BC-boundary-layer interactions has been less explored. In this study, we used the online coupled WRF-Chem model to examine how emission control measures during the Asia-Pacific Economic Cooperation (APEC) summit affect the mixing state and light absorption of BC, and the associated implications for BC-PBL interactions. We found that both the mass concentration of BC and the BC coating materials declined during the APEC week, which reduced the light absorption and light absorption enhancement (Eab) of BC. The reduced absorption aerosol optical depth (AAOD) during APEC was caused by both the decline in the mass concentration of BC itself (52.0 %), and the lensing effect of BC (48.0 %). The reduction in coating materials (39.4 %) contributed the most to the influence of the lensing effect, and the reduced light absorption capability (Eab) contributed 3.2 % to the total reduction in AAOD. Reduced light absorption of BC due to emission control during APEC enhanced planetary boundary layer height (PBLH) by 8.2 m. PM2.5 and O3 were found to have different responses to the changes in the light absorption of BC. Reduced light absorption of BC due to emission reductions decreased near-surface PM2.5 concentrations but near-surface O3 concentrations were enhanced in the North China Plain. These results suggest that current measures to control SO2, NOx, etc. would be effective in reducing the absorption enhancement of BC and in inhibiting the feedback of BC on the boundary layer. However, enhanced ground O3 might be a side effect of current emission control strategies. How to control emissions to offset this side effect of current emission control measures on O3 should be an area of further focus.

Cleaner burning aviation fuels can reduce contrail cloudiness

Contrail cirrus account for the major share of aviation’s climate impact. Yet, the links between jet fuel composition, contrail microphysics and climate impact remain unresolved. Here we present unique observations from two DLR-NASA aircraft campaigns that measured exhaust and contrail characteristics of an Airbus A320 burning either standard jet fuels or low aromatic sustainable aviation fuel blends. Our results show that soot particles can regulate the number of contrail cirrus ice crystals for current emission levels. We provide experimental evidence that burning low aromatic sustainable aviation fuel can result in a 50 to 70% reduction in soot and ice number concentrations and an increase in ice crystal size. Reduced contrail ice numbers cause less energy deposition in the atmosphere and less warming. Meaningful reductions in aviation’s climate impact could therefore be obtained from the widespread adoptation of low aromatic fuels, and from regulations to lower the maximum aromatic fuel content.

Marine ice-cliff instability modeling shows mixed-mode ice-cliff failure and yields calving rate parameterization

Marine ice-cliff instability could accelerate ice loss from Antarctica, and according to some model predictions could potentially contribute >1 m of global mean sea level rise by 2100 at current emission rates. Regions with over-deepening basins >1 km in depth (e.g., the West Antarctic Ice Sheet) are particularly susceptible to this instability, as retreat could expose increasingly tall cliffs that could exceed ice stability thresholds. Here, we use a suite of high-fidelity glacier models to improve understanding of the modes through which ice cliffs can structurally fail and derive a conservative ice-cliff failure retreat rate parameterization for ice-sheet models. Our results highlight the respective roles of viscous deformation, shear-band formation, and brittle-tensile failure within marine ice-cliff instability. Calving rates increase non-linearly with cliff height, but runaway ice-cliff retreat can be inhibited by viscous flow and back force from iceberg mélange.

The role of termite CH₄ emissions on the ecosystem scale: a case study in the Amazon rainforest

The magnitude of termite methane (CH4) emissions is still an uncertain part of the global CH4 budget and current emission estimates are based on limited field studies. We present in situ CH4 emission measurements of termite mounds and termite mound subsamples performed in the Amazon rainforest. Emissions from five termite mounds of the species Neocapritermes brasiliensis were measured by use of a large flux chamber connected to a portable gas analyser measuring CH4 and CO2. In addition, the emissions of mound subsamples were measured, after which the termites were counted so that a termite CH4 and CO2 emission factor could be determined. Mound emissions were found to range between 17.0 and 34.8 nmol mound−1 s−1 for CH4 and between 1.1 and 13.0 µmol mound−1 s−1 for CO2. A termite emission factor of 0.35 µmol CH4 gtermite-1 h−1 was found, which is almost twice as high as the only other reported value for the Amazon. By combining mound emission measurements with the termite emission factor, colony sizes could be estimated, which were found to range between 55–125 thousand individuals. Estimates were similar to literature values, and we therefore propose that this method can be used as a quick non-intrusive method to estimate termite colony size in the field. The role of termites in the ecosystem's CH4 budget was evaluated by use of two approaches. Termite mound emission values were combined with local mound density numbers, leading to an estimate of 0.15–0.71 nmol CH4 m−2 s−1, on average, emitted by termite mounds. In addition, the termite CH4 emission factor from this study was combined with termite biomass numbers, resulting in an estimate of termite-emitted CH4 of ∼1.0 nmol m−2 s−1. Considering the relatively low net CH4 emissions previously measured at this ecosystem, we expect that termites play an important role in the CH4 budget of this terra firme ecosystem.