Assessment of the Feedstock Availability for Covering EU Alternative Fuels Demand

Modern economies rely on the efficiency of their transportation sector; however, the environmental impact of the sector remains a growing concern. Among the various proposed solutions, the production and deployment of alternative fuels is a major option. However, concerns exist that the actual availability of sustainable feedstock might lower the current level of ambition. This paper addresses this issue by reviewing recent studies and policy targets, to match forecasts for expected demand and feedstock availability for road, aviation, and maritime sectors in the EU in 2030. The existing literature is fragmented and based on a variety of different approaches, and a consistent assessment of the potential overall demand for transport is still missing. In spite of the challenges posed by the numerous uncertainties, this research provides an estimate of potential European demand for alternative fuels that ranges between 20 and 33 Mtoe. We aimed to answer the question about the availability of sustainable feedstock to cover this potential demand. The analysis confirmed, even under very conservative assumptions, that feedstock may not be the major barrier today. Other issues, such as the feedstock costs, the price volatilities, the existing logistical infrastructures, etc., are relevant aspects contributing to the puzzle. Whilst feedstock is present across European regions, a critical element which requires detailed analysis at the implementation value chain level is the effectiveness of its sustainable mobilisation alongside the synergies and trade-offs that may arise.

Potential Impacts of Water Stress on Rice Biomass Composition and Feedstock Availability for Bioenergy Production

Bioenergy from rice biomass feedstock is considered one of the potential clean energy resources and several small biomass-based powerplants have been established in rice–growing areas of Thailand. Rice production is significantly affected by drought occurrence which results in declined biomass production and quality. The impact of water stress (WS) was evaluated on six rice cultivars for biomass quality, production and bioenergy potential. Rice cultivars were experimented on in the field under well–watered (WW) and WS conditions. Data for biomass contributing parameters were collected at harvest whereas rice biomass samples were analyzed for proximate and lignocellulosic contents. Results indicated that WS negatively influenced crop performance resulting in 11–41% declined biomass yield (BY). Stability assessment indicated that cultivars Hom Pathum and Dum Ja were stress–tolerant as they exhibited smaller reductions by 11% in their BY under WS. Statistics for proximate components indicated a significant negative impact influencing biomass quality as ash contents of Hom Chan, Dum Ja and RD-15 were increased by 4–29%. Lignocellulosic analysis indicated, an increase in lignin contents of Hom Nang Kaew, Hom Pathum, Dum Ja and RD–15 ranging 7–39%. Reduced biomass production resulted in a 10–42% reduction in bioenergy potential (E). Results proved that cultivation of stress-susceptible cultivars or farmer’s choice and occurrence of WS during crop growth will reduce biomass production, biomass feedstock availability to biomass-based powerplants and affect powerplant’s conversion efficiency resulting in declined bioenergy production.

Hollow Nanostructures for Application in Solar Cells

Hollow nanostructures are nanoscale materials with interior cavities, high volumetric load capacity ratio and high porosity. This new generation structure has gained huge momentum in the field of energy storage and photovoltaics due to such promising physical and chemical features. This chapter highlights contributions of various works where hollow nanostructures of metals and carbonaceous materials had been used in solar cell over the last few years. The harnessing of efficiency with structural modifications in the hollow structures over the years was shown in various works. The effect of structure engineering on the performance of solar cell has been explained in detail where voids in metallic hollow nanostructure enhance light scattering and high charge recombination. Simultaneously, carbonaceous hollow nanostructured materials are considered to be the latest photoelectrode materials and designated to be alternatives for metallic hollow nanostructures counterpart due to their high feedstock availability and fabrication charges.

Magnesium Leachability of Mg-Silicate Peridotites: The Effect on Magnesite Yield of a Mineral Carbonation Process

The aim of this study was to increase feedstock availability for mineral carbonation. Acid dissolution and carbonic acid dissolution approaches were used to achieve higher Mg extractions from peridotites. Acid dissolution studies of raw dunite, heat-activated dunite, heat-transformed dunite, and twin sister dunite have not been reported in the literature. Heat-activated dunite is more reactive as compared to heat-transformed dunite, raw dunite, and twin sister dunite. The fraction of magnesium extracted from heat-activated dunite was 57% as compared to 18% from heat-transformed dunite, 14% from raw dunite, and 11% from twin sister dunite. Similarly, silicon and iron extractions were higher for heat-activated dunite compared to that of heat-transformed dunite, raw dunite, and twin sister dunite. Materials rich in forsterite (twin sister dunite and heat-transformed dunite) showed preferential Mg release and exhibited incongruent dissolution similar to that of forsterite. Heat-activated dunite (amorphous magnesium silicate rich) on the other hand behaved differently and showed congruent dissolution. Olivine did not dissolve under carbonic acid dissolution (with concurrent grinding) and acidic conditions. Under carbonic acid dissolution with concurrent grinding conditions, olivine was partially converted into nanometer sized particles (d10 = 0.08 µm) but still provided 16% Mg extraction during 4 h of dissolution.

Mapping and Analysis of Biomass Supply Chains in Andalusia and the Republic of Ireland

The bioeconomy can play a critical role in helping countries to find alternative sustainable sources of products and energy. Countries with diverse terrestrial and marine ecosystems will see diverging feedstock opportunities to develop these new value chains. Understanding the sources, composition, and regional availability of these biomass feedstocks is an essential first step in developing new sustainable bio-based value chains. In this paper, an assessment and analysis of regional biomass availability was conducted in the diverse regions of Andalusia and Ireland using a bioresource mapping model. The model provides regional stakeholders with a first glance at the regional opportunities with regards to feedstock availability and an estimate of the transportation costs associated with moving the feedstock to a different modelled location/region for the envisioned biorefinery plant. The analysis found that there were more than 30 million tonnes of (wet weight) biomass arisings from Ireland (84,000 km2) with only around 4.8 million tonnes from the Andalusian region (87,000 km2). The study found that Cork in Ireland stood out as the main contributor of biomass feedstock in the Irish region, with animal manures making the largest contribution. Meanwhile, the areas of Almería, Jaén, and Córdoba were the main contributors of biomass in the Andalusia region, with olive residues identified as the most abundant biomass resource. This analysis also found that, while considerable feedstock divergence existed within the regions, the mapping model could act as an effective tool for collecting and interpreting the regional data on a transnational basis.

Can Multiple Uses of Biomass Limit the Feedstock Availability for Future Biogas Production? An Overview of Biogas Feedstocks and Their Alternative Uses

Biogas is expected to contribute 10% of the total renewable energy use in Europe in 2030. This expectation largely depends on the use of several biomass byproducts and wastes as feedstocks. However, the current development of a biobased economy requires biomass sources for multiple purposes. If alternative applications also use biogas feedstocks, it becomes doubtful whether they will be available for biogas production. To explore this issue, this paper aims to provide an overview of potential alternative uses of different biogas feedstocks being researched in literature. We conducted a literature review using the machine learning technique “co-occurrence analysis of terms”. This technique reads thousands of abstracts from literature and records when pairs of biogas feedstock-application are co-mentioned. These pairs are assumed to represent the use of a feedstock for an application. We reviewed 109 biogas feedstocks and 217 biomass applications, revealing 1053 connections between them in nearly 55,000 scientific articles. Our results provide two insights. First, a large share of the biomass streams presently considered in the biogas estimates have many alternative uses, which likely limit their contribution to future biogas production. Second, there are streams not being considered in present estimates for biogas production although they have the proper characteristics.

Assessing New Biotechnologies by Combining TEA and TM-LCA for an Efficient Use of Biomass Resources

An efficient use of biomass resources is a key element of the bioeconomy. Ideally, options leading to the highest environmental and economic gains can be singled out for any given region. In this study, to achieve this goal of singling out an ideal technology for a given region, biotechnologies are assessed by a combination of techno-economic assessment (TEA) and territorial metabolism life cycle assessment (TM-LCA). Three technology variations for anaerobic digestion (AD) were assessed at two different scales (200 kW and 1 MW) and for two different regions. First, sustainable feedstock availability for two European regions was quantified. Then, the environmental impact and economic potential of each technology when scaled up to the regional level, considering all of the region’s unique sustainably available feedstock, was investigated. Multiple criteria decision analysis and internalized damage monetization were used to generate single scores for the assessments. Preference for the technology scenario producing the most energy was shown for all regions and scales, while producing bioplastic was less preferable since the value of the produced bioplastic plastic was not great enough to offset the resultant reduction in energy production. Assessing alternatives in a regional context provided valuable information about the influence of different types of feedstock on environmental performance.

Potential of Novel Biochars Produced from Invasive Aquatic Species Outside Food Chain in Removing Ammonium Nitrogen: Comparison with Conventional Biochars and Clinoptilolite

Previous studies for removal of ammonium from wastewater were mainly conducted using biochars produced from agricultural residue. Feedstock type (agricultural residue, wood, animal waste, and aquatic waste), as well as pyrolysis temperature, can significantly influence biochar properties and hence its adsorption capacity. Such studies are useful in decision making for selecting biochar depending on feedstock availability and pyrolysis temperature. This study aims to explore the effects of different types of biochar (laboratory prepared novel water hyacinth and algae biochar, conventional cedar wood, rice straw, and pig manure biochar) on the adsorption kinetics for ammonium removal from wastewater. The adsorption kinetics of biochars were compared to that of commercially available clinoptilolite and interpreted with their respective physicochemical properties (SEM, FTIR, XRD). Batch tests were performed to evaluate the effects of biochars on adsorption of ammonium nitrogen at different concentrations (10 mg/L and 100 mg/L). The tests reveal that clinoptilolite has the highest adsorption capacity. Among biochars, pig manure (animal based) biochar has a higher adsorption capacity in comparison to conventional agricultural residues based biochars. The capacity of pig manure biochar under highly concentrated ammonium solution (100 mg/L) is merely 20% lower than that of clinoptilolite. Both water hyacinth and algae biochar produced at higher temperature (600 °C) show higher sorption rate and capacity (depending on the initial concentration of ammonium) for ammonium in comparison to that produced at a lower temperature (300 °C). This is likely due to an increase in porosity at higher temperatures of pyrolysis.