Interfacial interaction induced OER activity of MOF derived superhydrophilic Co3O4-NiO hybrid nanostructures

Electrocatalytic water splitting is one of the key technology for the future energy systems envisioned for the storage of energy obtained from variable renewables and green fuels. The development of...

Achieving Net Zero Emissions in Italy by 2050: Challenges and Opportunities

This paper contributes to the climate policy discussion by focusing on the challenges and opportunities of reaching net zero emissions by 2050 in Italy. To support Italian energy planning, we developed energy roadmaps towards national climate neutrality, consistent with the Paris Agreement objectives and the IPCC goal of limiting the increase in global surface temperature to 1.5 °C. Starting from the Italian framework, these scenarios identify the correlations among the main pillars for the change of the energy paradigm towards net emissions by 2050. The energy scenarios were developed using TIMES-RSE, a partial equilibrium and technology-rich optimization model of the entire Italian energy system. Subsequently, an in-depth analysis was developed with the sMTISIM, a long-term simulator of power system and electricity markets. The results show that, to achieve climate neutrality by 2050, the Italian energy system will have to experience profound transformations on multiple and strongly related dimensions. A predominantly renewable-based energy mix (at least 80–90% by 2050) is essential to decarbonize most of the final energy consumption. However, the strong increase of non-programmable renewable sources requires particular attention to new flexibility resources needed for the power system, such as Power-to-X. The green fuels produced from renewables via Power-to-X will be a vital energy source for those sectors where electrification faces technical and economic barriers. The paper’s findings also confirm that the European “energy efficiency first” principle represents the very first step on the road to climate neutrality.

Design, Production Cost, and Air Flow Distribution of Biomass Pellet Furnace

Biomass attracts a great deal of attention to be converted into green fuels in the form of pellets. The furnace is needed to burn pellets to generate heat up to 300 kW. In addition to meeting the heat capacity needs of the small and medium-sized industries, furnaces must also be competitive in terms of price. The purpose of this study is therefore to obtain details of the cost of manufacturing the furnace and the model of air flow that occurs in the furnace. The cost of production of the furnace includes manufacturing costs, assembly costs, machining and repair costs. The findings revealed that the key portion of the cost of the furnace was a material cost of 77%. The findings of the simulation showed that the total pressure difference of up to 850 Pa and had to be resolved by air-supplying blowers. The gas velocity ranges from 2 to 10 m/s and rises significantly near the exit to 42 m/s.

Assessment of Renewable Natural Gas Refuelling Stations for Heavy-Duty Vehicles

With environmental concerns and limited natural resources, there is a need for cleaner resources of energy in the transportation sector. Renewable natural gas (RNG) is being considered as a potential fuel for heavy-duty applications due to its comparable usage to diesel and gasoline in vehicles. The idea of compressed RNG vehicles is being proposed especially because it will significantly reduce harmful emissions into the environment. This study examines the feasibility of implementing a nationwide network of compressed RNG refueling infrastructure in order to accommodate a conversion of long-haul, heavy-duty (LHHD) truck fleet from diesel fuel to RNG. Two methods, Constant Traffic and Variable Traffic, along with data about compressed RNG infrastructure and vehicles, were developed and used to predict fuelling requirements for LHHD truck fleet. Then, a detailed economic analysis was conducted on various test cases to estimate how different variables impact the final selling price of RNG. This provided insight with the understanding of what factors go into pricing RNG and if it can compete against diesel in the trucking market. Results disclosed that the cost to purchase RNG is the greatest factor in the final selling price of compressed RNG. Due to the variability in RNG production however, there is no precise cost, which makes predictions challenging. However, results revealed that it is possible for compressed RNG to be competitive with diesel, with the mean compressed RNG price being 16.5% cheaper than diesel, before being taxed. Future studies should focus on the feasibility of the production of RNG and the associated costs. An in-depth analysis on operational and maintenance costs for compressed RNG refuelling stations may also provide predictions that are more accurate. The methodology developed in this feasibility analysis may serve as a useful tool for future techno-economics of RNG refuelling stations for other types of ICE fleets or those powered with alternative green fuels.

Influence of Combustion Chamber Shapes and Nozzle Geometry on Performance, Emission, and Combustion Characteristics of CRDI Engine Powered with Biodiesel Blends

Environmentally friendly, renewable, and green fuels have many benefits over fossil fuels, particularly regarding energy efficiency, in addition to addressing environmental and socioeconomic problems. As a result, green fuels can be used in transportation and power generating applications. Furthermore, being green can ably address the emission-related issues of global warming. In view of the advantages of renewable fuels, two B20 fuel blends obtained from methyl esters of cashew nutshell (CHNOB), jackfruit seed (JACKFSNOB), and jamun seed oils (JAMSOB) were selected to evaluate the performance of a common rail direct injection (CRDI) engine. Compatibility of the nozzle geometry (NG) and combustion chamber shape (CCS) were optimized for increased engine performance. The optimized CCS matched with an increased number of injector nozzle holes in NG showed reasonably improved brake thermal efficiency (BTE), reduced emissions of smoke, HC, and CO, respectively, while NOx increased. Further combustion parameters, such as ignition delay (ID) and combustion duration (CD) reduced, while peak pressure (PP) and heat release rates (HRR) increased at the optimized injection parameters. The CRDI engine powered with JAMSOB B20 showed an increase in BTE of 4–5%, while a significant reduction in HC and CO emissions was obtained compared to JACKFSNOB B20 and CHNOB B20, with increased NOx.

Hydrodeoxygenation of Xylose Isopropylidene Ketal Over Pd/HBEA Catalyst for the Production of Green Fuels

1,2:3,5-Di-O-isopropylidene-α-D-xylofuranose (DX) is a major component of a new bio-crude: a viscous oil presenting petroleum-friendly properties produced by the ketalization of sugarcane bagasse. This article studies DX HDO (hydrodeoxygenation) over a Pd/HBEA catalyst in a batch reactor at 250°C. The effects of hydrogen pressure from 10 to 40 bar, catalyst/DX ratio from ½ to 2, and reaction time 0–24 h were investigated. A range of conditions for complete hydrodeoxygenated DX into alkanes with a Pd/HBEA catalyst was found. In these conditions, a low coke yield with water as the principal deoxygenated product was obtained. Further, higher amounts of alkanes containing seven or more carbons (A7+) were favored at 30 bar of hydrogen pressure, Cat/DX ratio = 2, and short reaction time. Products analysis that accompanied the above variations during reaction time led to general insights into reaction pathways. First, in the presence of DX, an effective n-hexane conversion was not observed on experiments of low catalyst/DX ratio (½) or in the initial period of high Cat/DX ratio, suggesting DX is much more successful than n-hexane to compete for active sites. Then, the formation of a pool of oxygenated compounds, such as furans, ketones, and carboxylic acids, along with lighter and heavier alkanes was observed. Hence, the aforementioned oxygenates may undergo reactions, such as aldol condensation with subsequent hydrodeoxygenation reaction, generating heavier alkanes.