Performance of Fly Ash-Based Inorganic Polymer Mortar with Petroleum Sludge Ash

Petroleum sludge is a waste product resulting from petroleum industries and it is a major source of environmental pollution. Therefore, developing strategies aimed at reducing its environmental impact and enhance cleaner production are crucial for environmental mortar. Response surface methodology (RSM) was used in designing the experimental work. The variables considered were the amount of petroleum sludge ash (PSA) in weight percent and the ratio of sodium silicate to sodium hydroxide, while the concentration of sodium hydroxide was kept constant in the production of geopolymer mortar cured at a temperature of 60 °C for 20 h. The effects of PSA on density, compressive strength, flexural strength, water absorption, drying shrinkage, morphology, and pore size distribution were investigated. The addition of PSA in the mortar enhanced the mechanical properties significantly at an early age and 28 days of curing. Thus, PSA could be used as a precursor material in the production of geopolymer mortar for green construction sustainability. This study aimed to investigate the influence of PSA in geopolymer mortar.

SLUDGE CHARACTERIZATION OF KHARTOUM PETROLEUM REFINING WASTEWATER TREATMENT PLANT- KHARTOUM-SUDAN

Clearance of sludge has made a major task in latest periods. In the current study sludge from KPRWTP were investigated concerning physicochemical characteristics & disposal options. Organic content of petroleum sludge & clay soil was 0.23 ±0.09% and 0.186±0.1%, respectively. Metals average concentration: Chromium: 130.95±27.32 mg/kg Arsenic: 0.899±0.434 mg/kg lead: 47.83±21.44 mg/kg Cadmium: 18.33±9.04 mg/kg Copper: 209±31.18 mg/kg Zinc: 631±159.57 mg/kg Nickel: 6.6±2.44 mg/kg cobalt: 35.54±10.08 mg/kg manganese: 35.54±10.08 mg/kg: iron: 501±5490.04 mg/kg: titanium: 108.3±18.33 mg/kg, and zirconium: 2.54±0.246 mg/kg respectively. Sludge was made up of particles to some extent of bigger portion compared to soil (sludge: clay and silt 58.9%, sand 41.1% soil: clay and silt 76%, sand 34%). Core constituents of petroleum sludge were Fe2O3 (38.45%), SiO2 (8.55%), CaO (30.35%), MgO (0.85%). According to standards of (NJDEPSCC) As, Cd, Cu, Pb, Ni, & Zn have significantly lower concentration in sludge comparing guideline for residential and nonresidential utilization. On the other hand, FDEPSCTL showed Cu and Zn were only metals in sludge significantly have high concentration regarding guideline for residential applications only. The study confirmed that heavy metals under investigation were significantly lesser than quantities controlled by (TCLP) of (RCRA), with exception for chromium content.

A novel biosurfactant producing Kocuria rosea ABR6 as potential strain in oil sludge recovery and lubrication

At various stages of crude oil refining, solid and semi-solid wastes, known as petroleum sludge, are produced. Accumulation of oil waste in the refinery leads to reduced efficiency of oil refining and its release causes environmental pollution Biosurfactant-producing isolates were isolated from the oil reservoirs of the Isfahan refinery, Iran, and screened by oil expansion test, droplet collapse, and surface tension reduction measurement. Oil recovery from oil sludge was measured under constant conditions. The effect of factoring biosource lubrication on crude oil in pipelines was investigated in vitro. Also, the optimization of biosurfactant production in different conditions was measured as a single factor and Response surface Methodology. The best biosurfactant-producing bacterium was identified as Kocuria rosea ABR6, and its sequence was registered in the gene bank with access number of MK100469 registered. Chemical analysis proved that the biosurfactant produced was a lipopeptide. 7% of crude oil was recovered from petroleum sludge by biosurfactant obtained from Kocuria rosea ABR6.Also, the speed of crude oil transfer in pipelines was reduced from 64 seconds to 35 seconds. The highest biosurfactant production was measured at pH 9, aeration rate of 120 rpm and 96 hours after incubation. The use of biosurfactants produced by Kocuria rosea ABR6 is recommended to remove oil sludge and lubricate oil in pipelines recommended in the oil industry

Hazardous Petroleum Sludge-Derived Nitrogen and Oxygen Co-Doped Carbon Material with Hierarchical Porous Structure for High-Performance All-Solid-State Supercapacitors

Rational design and sustainable preparation of high-performance carbonaceous electrode materials are important to the practical application of supercapacitors. In this work, a cost-effective synthesis strategy for nitrogen and oxygen co-doped porous carbon (NOC) from petroleum sludge waste was developed. The hierarchical porous structure and ultra-high surface area (2514.7 m2 g−1) of NOC electrode materials could provide an efficient transport path and capacitance active site for electrolyte ions. The uniform co-doping of N and O heteroatoms brought enhanced wettability, electrical conductivity and probably additional pseudo-capacitance. The as-obtained NOC electrodes exhibited a high specific capacitance (441.2 F g−1 at 0.5 A g−1), outstanding rate capability, and cycling performance with inconspicuous capacitance loss after 10,000 cycles. Further, the assembled all-solid-state MnO2/NOC asymmetrical supercapacitor device (ASC) could deliver an excellent capacitance of 119.3 F g−1 at 0.2 A g−1 under a wide potential operation window of 0–1.8 V with flexible mechanical stability. This ASC device yielded a superior energy density of 53.7 W h kg−1 at a power density of 180 W kg−1 and a reasonable cycling life. Overall, this sustainable, low-cost and waste-derived porous carbon electrode material might be widely used in the field of energy storage, now and into the foreseeable future.

Alternative Remediation for Raw Petroleum Sludge by Using Solidification/stabilization Method

In Malaysia, the current practise in treatment of petroleum sludge (PS) is by using incineration and the ash produce required further treatment for safely disposal into landfill. This process require high cost and treatment of raw sludge by using solidification/stabilization method was introduce. In this study, ordinary Portland cement was used as binder. This study focuses on physical properties (compressive strength, density test and water absorption) of S/S matrices and leaching behaviour (SPLP). Results shows adds up to of 30% PS gives results on strength which comply with minimum landfill dispose limit. Correlation between strength and density in regression coefficient of 80.99% and correlation between strength and water absorption shows strong regression of 93.12%. Leaching behaviours on 28 th day of curing showed the similar trend as on 7th day of curing. All heavy metals concentration in leaching test were below the USEPA standard except for Nickel and Chromium. Even though these two metals were exceeded the standard, Portland cement was capable to encapsulate Ni and Cr in mixture and reduce the concentration of 87% and 69% (PS 40%), respectively, compare to concentration in raw sludge. As, conclusion S/S method can be an alternative disposal method for raw sludge.