Nitriding Effect on Corrosion Fatigue Strength of Low Alloy Steel in 1% HCl Aqueous Solution

In this paper the emphasis is focused upon nitriding effect on corrosion fatigue strength of Cr-Mo low alloy steel in 1% HCl aqueous solution.Corrosion fatigue strength enhancement of Cr-Mo low alloy steel by nitriding is discussed on the basis of the corrosion fatigue testing results on gas and ion nitrided Cr-Mo low alloy steel plate specimen with 3.5mm thickness in 1%HCl aqueous solution. It can be concluded that residual compressive stress distributed on the nitrided specimen surface caused improvement of corrosion fatigue strength of Cr-Mo low alloy steel.

Evaluation of the Corrosion Behavior of the Laser Gas Nitrided Ti-6Al-4V

Laser gas nitriding of Ti-6Al-4V alloy was carried out using a Nd:YAG pulsed laser under pure nitrogen environment at a flow rate of 30 l/min. The microstructure and corrosion behavior of the nitrided samples were examined using scanning electron microscopy, XRD, XPS, and anodic polarization tests in 2M HCl solution. For comparison, untreated samples were tested under the same conditions. After laser treatment, samples showed a relative flat surface with no problems of cracks or delamination of the alloyed tracks. Laser nitriding produced dendritic structures. The microstructure of the laser melted zone consisted of a thin continuous layer followed by a nearly perpendicular growth of dendrites. Below this a mixture of small dendrites and large needles with random orientation was produced. X-ray spectrum and XPS analyses from the surface of the laser nitrided specimen at different depth, confirmed that the thin top layer and large dendrites close to the surface corresponded to TiN. It can be also seen that the strong TiN peaks on the top surface gradually decrease with depth which suggests that the structure beneath the top surface is likely TiN0.3 and ά-Ti mixtures. In general, the corrosion potential of laser gas nitrided specimens was relatively nobler than the untreated sample. Furthermore, the proper laser nitrided specimen exhibited less corrosion current density, passivated more readily and also maintained a lower current density over the duration of the experiment. This was correlated with the formation of very thin, continuous TiNxOy film in an oxidation state that was confirmed by XPS analyses of the passive layers.

Effects of Nitriding Processes on the Mechanical Properties of SACM 645 Steel

In this project, the alternating torsion fatigue test was carried out to investigate the effect of the nitrided case produced by gas and plasma nitriding processes on the fatigue endurance of the JIS SACM 645 steel. The surface layers of the nitrided specimens exhibited hardness profiles in the range between 1000–1100HV0.1, and the white layer of the nitrided specimen was consisted of Fe3N and Fe4N. Wear test result indicated that the mass loss of JIS SACM 645 steel was greatly improved by nitriding processes. From the mass loss data, the wear resistance of the steel was significantly influenced by nitriding time. The fatigue strength of the 35C-GN48 nitrided specimen rose 51.9% to 632 MPa, which was the maximum fatigue strength in this study.

Thermal Crack Propagation Behavior on Nitrided H13 Hot Work Die Steel

The influence of nitriding type and condition on the thermal crack propagation behavior of hot work die steel was investigated. Thermal fatigue tests were carried out using a special apparatus, which is consisted of induction heating and water spray cooling unit. The sum of crack length per unit specimen length, Lm is proposed as an index representing the susceptibility to crack propagation. The Lm values of the gas and ion nitrided specimens were lower than that of as-heat treated specimen. But in the case of maximum and average crack length of nitrided specimen was higher than those of as-heat treated specimen. The nitrogen diffusion layer still remained although the oxide scale was formed and fell off during thermal fatigue test. After 1000 cycles of the thermal fatigue test, the interior region of nitrided specimen showed lower hardness by softening. In particular, ion nitrided specimens of relatively less softening condition showed reduction both the depth and number of cracks compared with the other surface conditions.

Influence of Plasma Radical Nitriding on Fatigue Properties of SCM435 Steel

The effect of plasma radical nitriding treatment on fatigue properties of SCM435 steel in super long life region was investigated. Fatigue tests were carried out using a dual-spindle rotating bending fatigue-testing machine at room temperature in air for the specimens nitrided at 773 K and 823 K for 3 hrs. The fatigue strength of nitrided specimen was greater than that of un-nitrided specimen and the crack initiation mode changed from the surface cracking of un-nitrided specimen to the subsurface cracking of nitrided specimen. Hardening layer and compressive residual stress were formed by nitriding, which resulted in the improvement of the fatigue strength. The stress intensity factor was calculated using facet area in Fish-eye fracture mode. As a result, the stress intensity factor indicated almost constant value, ~ 3-4 MPa·m1/2, regardless of the number of cycles to failure.

Microstructure Control of High Nitrogen Alpha + Beta Type Titanium Alloy

Solution nitriding and aging treatment were applied to Ti-4mass%Cr alloy in order to fabricate a ductile high-nitrogen titanium alloy with fine (α + β) structure. The solution-nitrided specimen withα’ martensitic structure was significantly hardened by solid solution strengthening by the absorbed nitrogen. During the aging treatment, fine β grains with a size of 1 microns in thickness precipitated along the martensite-plate boundaries. Although the specimen was softened to some extent after the aging treatment, the hardness is kept much higher than that of the aged Ti-4mass%Cr alloy without solution nitriding. This indicates that the nitrogen is still in solid solution of α phase even after the aging treatment, and contributes to strengthening of the fine-structured Ti-4mass%Cr-N alloy.

Water Vapor Oxidation Behavior under High-Temperature and Pressure Conditions of the Nitrided Alloys for Steam Turbine Valve System Parts

Mechanical and corrosion properties were evaluated in the nitrided and non-nitrided specimens of ASTM 355 and SUS422 steels. The oxides formed on the specimen were analyzed using by XRD and the weight change was measured after oxidation test at high temperature, high pressure, and steam conditions. The oxidation behaviors and rates between two alloys and nitrided/non-nitrided specimens were clearly different. XRD analysis showed that the nitrides formed on the nitrided specimen were composed of CrN, Fe4N, and Fe2-3N. Also, it was found that the hardness on the nitrided specimen at 283°C decreased from Hv 1150 of room temperature to Hv 425.

High-Temperature Wear Properties of the Nitrided Alloys for Steam Turbine Valve System Parts

ASTM A355, SUS422 and Nimonic 901 steel were nitrided and their wear characteristics such as the wear coefficient, amount of wear, shape and composition of wear debris were evaluated. Fe3N and Fe4N were observed in the nitrided layer of ASTM A355. Fe3N, Fe4N and CrN were appeared in the nitride of SUS422. However, only CrN phase was observed in the layer of Nimonic 901. The amount of wear and wear coefficient for the nitride specimen decreased remarkably compared with non-nitrided specimens. Also, the surface hardness and ductility increased and small debris was formed in the nitrided specimen.

Thermal Fatigue Behavior of the Surface Treated Hot Die Steel Depending on Test Temperature

The influence of thermal fatigue test temperature on crack propagation behavior of the surface treated tool steel for die-casting was investigated. For this purpose, thermal fatigue system consisted of induction heating and water spray quenching unit was constructed to simulate the service condition and Lm is proposed as the index representing the susceptibility to crack initiation and propagation. The thermal fatigue tests were conducted at the maximum temperature of 600°C, 700°C and 720°C using as-heat treated or nitrided specimens. The ion nitrided specimen showed lower Lm value than as-heat treated at all test temperature. But in the case of maximum and average crack length, the ion nitrided specimen exhibited higher value than those of as-heat treated specimen.