Mechanical Property Comparison of Ni–Cr–Mo Alloys Fabricated via One Conventional and Two New Digital Manufacturing Techniques

This study compared the microstructures and mechanical properties of nickel–chromium–molybdenum (Ni–Cr–Mo) alloys prepared from a single alloy with an identical composition using two new digital processes (selective laser melting (SLM) and soft metal milling (SMM)) and conventional lost-wax casting (LWC). Disc specimens were used to study the microstructures via various analytical methods, while dumbbell-shaped specimens were subjected to tension to determine the mechanical properties (n = 6). The SLM and SMM alloys showed a higher number of large and small pores, respectively, than the LWC alloy. A face-centered cubic (γ)-phased matrix was indexed for all three resultant alloys. The SLM and SMM alloys also showed more homogeneously distributed elements and finer grains (in particular, ultrafine grains in the SLM alloy) when compared to the LWC alloy. Meanwhile, the LWC alloy showed a statistically higher yield strength than the other two alloys (p < 0.001). Notwithstanding, all three resultant Ni–Cr–Mo alloys satisfied the ISO 22674 standard criteria for type 5 materials (yield strength: >500 MPa; percentage elongation: >2%; and elastic modulus: >150 GPa).

Mathematical and Computer Simulation of Hex Head Screws for Implementation on a 3D Printer

In this paper, based on the R-functions theory, methods have been developed and equations have been constructed for the 3D printing of hex-head screws with Bristol, Pentalobe, Polydrive and other types of screw slots. Such screws are used both in personal computers and other high-end equipment. The Bristol slot has four or six radial grooved beams. The advantage of the design of this slot is the correct perpendicular, rather than tangential, vector of force application when the slot is rotated by a tool, which minimizes the risk of stripping out the slot. For this reason, the Bristol slot is used in soft metal screws. Compared to the internal hex, the Bristol slot allows a noticeably higher torque, only slightly higher than that of the Torx slot. This type of slot is used in aviation, high-end telecommunications equipment, cameras, air brakes, agricultural equipment, astronomical equipment, and foreign military equipment. Variations with a pin in the center are found in game consoles to prevent the use of a flat-blade screwdriver as an improvised key. The Pentalobe slot is a five-point slot designed by Apple and used in its products to limit unauthorized disassembly. It was first used in mid 2009 to mount MacBook Pro batteries. Its miniature version was used in the iPhone 4 and later models, in the MacBook Air (available since late 2010 models), and the MacBook Pro with Retina screens. The Polydrive slot is a starlike slot with rounded star points, used in the automotive industry for applications requiring high tightening torque. The Torq-set slot is a cross slot for fasteners requiring high tightening torque. The grooves are slightly offset, not intersecting at one point. Fasteners with this type of slot are used in military aviation, for example, in E-3, P-3, F-16, Airbus, Embraer, and Bombardier Inc. The Phillips Screw Company owns the trademark and manufactures fasteners with this type of slot. The slot design standards are National Aerospace Standard NASM 3781 and NASM 4191 for the ribbed version. The resulting equations for the surfaces of screws were checked during the modeling of the screws before 3D printing. The 3D printing technology allows us to reduce the cost and labor intensity of manufacturing products, including complex slot screws. The analytical recording of designed objects makes it possible to use alphabetic geometric parameters, complex superposition of functions, which, in turn, allows us to quickly change their design elements. The positivity property of the constructed functions at the internal points of an object is very convenient for the implementation of 3D printing.

Quantitative evaluation of the feasibility of sampling the ice plumes at Enceladus for biomarkers of extraterrestrial life

Enceladus, an icy moon of Saturn, is a compelling destination for a probe seeking biosignatures of extraterrestrial life because its subsurface ocean exhibits significant organic chemistry that is directly accessible by sampling cryovolcanic plumes. State-of-the-art organic chemical analysis instruments can perform valuable science measurements at Enceladus provided they receive sufficient plume material in a fly-by or orbiter plume transit. To explore the feasibility of plume sampling, we performed light gas gun experiments impacting micrometer-sized ice particles containing a fluorescent dye biosignature simulant into a variety of soft metal capture surfaces at velocities from 800 m ⋅ s−1 up to 3 km ⋅ s−1. Quantitative fluorescence microscopy of the capture surfaces demonstrates organic capture efficiencies of up to 80 to 90% for isolated impact craters and of at least 17% on average on indium and aluminum capture surfaces at velocities up to 2.2 km ⋅ s−1. Our results reveal the relationships between impact velocity, particle size, capture surface, and capture efficiency for a variety of possible plume transit scenarios. Combined with sensitive microfluidic chemical analysis instruments, we predict that our capture system can be used to detect organic molecules in Enceladus plume ice at the 1 nM level—a sensitivity thought to be meaningful and informative for probing habitability and biosignatures.

Novel Bifunctional [16]aneS4-Derived Chelators for Soft Radiometals

The field of targeted radionuclide therapy is rapidly growing, highlighting the need for wider radionuclide availability. Soft Lewis acid ions, such as radioisotopes of platinum, rhodium and palladium, are particularly underdeveloped. This is due in part to a lack of compatible bifunctional chelators. These allow for the practical bioconjugation to targeting vectors, in turn enabling radiolabeling. The [16]andS4 macrocycle has been reported to chelate a number of relevant soft metal ions. In this work, we present a procedure for synthesizing [16]andS4 in 45% yield (five steps, 12% overall yield), together with a selection of strategies for preparing bifunctional derivatives. An ester-linked N-hydroxysuccimide ester (NHS, seven steps, 4% overall yield), an ether-linked isothiocyanate (NCS, eight steps, 5% overall yield) and an azide derivative were prepared. In addition, a new route to a carbon-carbon linked carboxylic acid functionalized derivative is presented. Finally, a general method for conjugating the NHS and NCS derivatives to a polar peptide (octreotide) is presented, by dissolution in water:acetonitrile (1:1), buffered to pH 9.4 using borate. The reported compounds will be readily applicable in radiopharmaceutical chemistry, by facilitating the labeling of a range of molecules, including peptides, with relevant soft radiometal ions.

STUDY OF WEAR RESISTANCE OF THE CU-AL SYSTEM LAYERED METAL-INTERMETALLIDE COMPOSITES

The results of wear testing of the SMIC of the copper-aluminum system at the angle of action of the abrasive relative to the metal-intermetallic layers - 0, 45 and 90º are given. It is shown that the wear resistance of SMIC is 3.2 ÷ 3.3 times higher than that of AD1 aluminum. At the same time, the samples showed the best indicators of wear resistance when the abrasive was applied to the layered structure of the tested SMIC at an angle of 45º. Analysis of the wear surfaces obtained by friction in all directions with respect to the layers of the SMIC made it possible to identify all the main morphological types of wear particles in the conglomerate. It is shown that additional saturation of the hard phases (intermetallic or abrasive) with pressed particles of soft metal layers contributes to the implementation of the Charpy principle.