Ice Growth and Platelet Crystals in Antarctica

<p>First-year land-fast sea ice growth in both the Arctic and the Antarctic is characterised by the formation of an initial ice cover, followed by the direct freezing of seawater at the ice-water interface. Such growth usually results, through geometric selection, in congelation ice. This is, in general, the typical crystal structure observed in first-year ice growth in the Arctic. However, in certain regions of the Antarctic, platelet crystals are observed to contribute significantly to the ice growth, beyond a depth of 1 m. This thesis will investigate a number of ideas as to why the platelet crystals only appear in the ice after a significant amount of congelation growth has occurred. One of the key premises will be that platelet ice forms when smaller frazil crystals, beneath the ice, rise up and attach to the interface. They are then incorporated into the ice cover and become the platelets seen in ice cores. The Shields criterion is used to find the strength of turbulence, associated with tidal flow, required to keep a frazil crystal from adhering to the interface. It is shown that the sub-ice flow is sufficient to keep most crystals in motion. However, this turbulence may weaken or dissipate completely as the tide turns. The velocity associated with brine rejection is suggested as an alternative to keep the crystals in suspension during these periods of low shear turbulence. Brine rejection occurs as the sea ice grows, rejecting salt into the seawater below. By comparing this velocity with a model for the frazil rise velocity it is shown that brine rejection has sufficient strength to keep crystals in suspension. This effect weakens as the ice gets thicker, allowing larger frazil crystals to rise to the interface. The early work in this thesis shows that a flow can keep a single crystal from adhering to the interface. This can be regarded as the competence of a flow to keep a crystal in suspension. However, of equal importance is the capacity of a flow to keep a mass of crystals in suspension. It is shown that, given a sufficiently large mass of crystals beneath the ice, the same flow that can hold a single crystal in suspension will not be able to keep all the crystals in motion. The deposition of crystals is predicted to occur in a gradual manner if there is a steady build-up of crystals beneath the ice. The largest crystals, close to the interface, will settle against the ice as the flow is unable to support the entire mass of crystals Also considered is whether frazil crystals may be similar to cohesive sediments. If this is the case, a sudden influx of crystals from outside of the system may lead to the formation of a layer of unattached crystals beside the ice-water interface. This can cause a critical collapse of the turbulent field, resulting in the settling of a large quantity of frazil crystals. Though the emphasis of much of this thesis is on the effect of the flow on the crystals, it is also found that a mass of crystals can have a stabilising effect on the flow. The change in the density profile induced by an increase in the frazil concentration towards the ice-water interface (and hence a decrease in the density of the ice-water mixture) damps the turbulence produced by shear. The mass and size of crystals in suspension play major roles in the strength of stabilisation. Measurements of turbulence and the suspension of frazil crystals beneath sea ice are difficult to make. This thesis aims to present and analyse a number of models which may explain the platelet puzzle - the delayed appearance of the platelet crystals in ice cores. These are compared with the observations which are available, and conclusions made on the validity of the theories presented.</p>

Ice Growth and Platelet Crystals in Antarctica

<p>First-year land-fast sea ice growth in both the Arctic and the Antarctic is characterised by the formation of an initial ice cover, followed by the direct freezing of seawater at the ice-water interface. Such growth usually results, through geometric selection, in congelation ice. This is, in general, the typical crystal structure observed in first-year ice growth in the Arctic. However, in certain regions of the Antarctic, platelet crystals are observed to contribute significantly to the ice growth, beyond a depth of 1 m. This thesis will investigate a number of ideas as to why the platelet crystals only appear in the ice after a significant amount of congelation growth has occurred. One of the key premises will be that platelet ice forms when smaller frazil crystals, beneath the ice, rise up and attach to the interface. They are then incorporated into the ice cover and become the platelets seen in ice cores. The Shields criterion is used to find the strength of turbulence, associated with tidal flow, required to keep a frazil crystal from adhering to the interface. It is shown that the sub-ice flow is sufficient to keep most crystals in motion. However, this turbulence may weaken or dissipate completely as the tide turns. The velocity associated with brine rejection is suggested as an alternative to keep the crystals in suspension during these periods of low shear turbulence. Brine rejection occurs as the sea ice grows, rejecting salt into the seawater below. By comparing this velocity with a model for the frazil rise velocity it is shown that brine rejection has sufficient strength to keep crystals in suspension. This effect weakens as the ice gets thicker, allowing larger frazil crystals to rise to the interface. The early work in this thesis shows that a flow can keep a single crystal from adhering to the interface. This can be regarded as the competence of a flow to keep a crystal in suspension. However, of equal importance is the capacity of a flow to keep a mass of crystals in suspension. It is shown that, given a sufficiently large mass of crystals beneath the ice, the same flow that can hold a single crystal in suspension will not be able to keep all the crystals in motion. The deposition of crystals is predicted to occur in a gradual manner if there is a steady build-up of crystals beneath the ice. The largest crystals, close to the interface, will settle against the ice as the flow is unable to support the entire mass of crystals Also considered is whether frazil crystals may be similar to cohesive sediments. If this is the case, a sudden influx of crystals from outside of the system may lead to the formation of a layer of unattached crystals beside the ice-water interface. This can cause a critical collapse of the turbulent field, resulting in the settling of a large quantity of frazil crystals. Though the emphasis of much of this thesis is on the effect of the flow on the crystals, it is also found that a mass of crystals can have a stabilising effect on the flow. The change in the density profile induced by an increase in the frazil concentration towards the ice-water interface (and hence a decrease in the density of the ice-water mixture) damps the turbulence produced by shear. The mass and size of crystals in suspension play major roles in the strength of stabilisation. Measurements of turbulence and the suspension of frazil crystals beneath sea ice are difficult to make. This thesis aims to present and analyse a number of models which may explain the platelet puzzle - the delayed appearance of the platelet crystals in ice cores. These are compared with the observations which are available, and conclusions made on the validity of the theories presented.</p>

Dynamics of Eddies Generated by Sea Ice Leads

Interaction between the atmosphere and ocean in sea ice-covered regions is largely concentrated in leads, which are long, narrow openings between sea ice floes. Refreezing and brine rejection in these leads injects salt that plays a key role in maintaining the polar halocline. The injected salt forms dense plumes that subsequently become baroclinically unstable, producing submesoscale eddies that facilitate horizontal spreading of the salt anomalies. However, it remains unclear which properties of the stratification and leads most strongly influence the vertical and horizontal spreading of lead-input salt anomalies. In this study, the spread of lead-injected buoyancy anomalies by mixed layer and eddy processes are investigated using a suite of idealized numerical simulations. The simulations are complemented by dynamical theories that predict the plume convection depth, horizontal eddy transfer coefficient and eddy kinetic energy as functions of the ambient stratification and lead properties. It is shown that vertical penetration of buoyancy anomalies is accurately predicted by a mixed layer temperature and salinity budget until the onset of baroclinic instability (~3 days). Subsequently, these buoyancy anomalies are spread horizontally by eddies. The horizontal eddy diffusivity is accurately predicted by a mixing length scaling, with a velocity scale set by the potential energy released by the sinking salt plume and a length scale set by the deformation radius of the ambient stratification. These findings indicate that the intermittent opening of leads can efficiently populate the polar halocline with submesoscale coherent vortices with diameters of around 10 km, and provide a step toward parameterizing their effect on the horizontal redistribution of salinity anomalies.

Cascading and the pathways of the key biogeochemical tracers in the Canadian Basin: from models and observations.

&lt;p&gt;We explore dense water cascading (DWC; a type of bottom-trapped gravity current) on multi-decadal time scales using a pan-Arctic regional ocean-ice model. DWC is particularly important in the Arctic Ocean as the main mechanism of ventilation of interior waters when open ocean convection is blocked by strong density stratification. We identify the locations where the most intense DWC events occur and evaluate the associated cross-shelf mass, heat and salt fluxes.&amp;#160;&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;A detailed analysis of specific cascading sites around the Beaufort Gyre and adjacent regions is performed. We find that autumn upwelling of warm and saltier Atlantic waters on the shelf and subsequent cooling and mixing of uplifted waters trigger the cascading on the West Chukchi Sea shelf break. We also perform Lagragian particle tacking of low salinity Pacific waters originating at the surface in the Bering Strait; these waters are shown to be modified by brine rejection and cooling, and through subsequent mixing become dense enough to reach depths of 160-200m and below. We examine the role of cascading and shelf upwelling on the shelf waters transformation, pathways and spread of the biological important tracers (O18, Si., DIC snd DIN).&lt;/p&gt;

Three-dimensional convection, phase change, and solute transport in mushy sea ice

&lt;p&gt;Sea ice is a porous mushy layer composed of ice crystals and interstitial brine. The dense brine tends to sink through the ice, driving convection. Downwelling at the edge of convective cells leads to dissolution of the ice matrix and the development of narrow, entirely liquid brine channels. The channels provide an efficient pathway for drainage of the cold, saline brine into the underlying ocean. This brine rejection provides an important buoyancy forcing for the polar oceans, and causes variation of the internal structure and properties of sea ice on seasonal and shorter timescales. This process is inherently multiscale, with simulations requiring resolution from O(mm) brine-channel scales to O(m) mushy-layer dynamic scales.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;We present new, fully 3-dimensional numerical simulations of ice formation and convective brine rejection that model flow through a reactive porous ice matrix with evolving porosity. To accurately resolve the wide range of dynamical scales, our simulations exploit Adaptive Mesh Refinement using the Chombo framework. This allows us to integrate over several months of ice growth, providing insights into mushy-layer dynamics throughout the winter season. The convective desalination of sea ice promotes increased internal solidification, and we find that convective brine drainage is restricted to a narrow porous layer at the ice-ocean interface. This layer evolves as the ice grows thicker over time. Away from this interface, stagnant sea ice consists of a network of previously active brine channels that retain higher solute concentrations than the surrounding ice. We investigate the response of ice growth and brine drainage to varying atmospheric cooling conditions, and consider the potential implications for ice-ocean brine fluxes, nutrient transport, and sea ice ecology.&lt;/p&gt;&lt;p&gt;&lt;br&gt;&lt;br&gt;&lt;/p&gt;

Brine rejection and hydrate formation upon freezing of NaCl aqueous solutions

Studying the freezing of saltwater on a molecular level is of fundamental importance for improving freeze desalination techniques.

Circulation Induced by Isolated Dense Water Formation over Closed Topographic Contours

The problem of localized dense water formation over a sloping bottom is considered for the general case in which the topography forms a closed contour. This class of problems is motivated by topography around islands or shallow shoals in which convection resulting from brine rejection or surface heat loss reaches the bottom. The focus of this study is on the large-scale circulation that is forced far from the region of surface forcing. The authors find that a cyclonic current is generated around the topography, in the opposite sense to the propagation of the dense water plume. In physical terms, this current results from the propagation of low sea surface height from the region of dense water formation anticyclonically along the topographic contours back to the formation region. This pressure gradient is then balanced by a cyclonic geostrophic flow. This basic structure is well predicted by a linear quasigeostrophic theory, a primitive equation model, and in rotating tank experiments. For sufficiently strong forcing, the anticyclonic circulation of the dense plume meets this cyclonic circulation to produce a sharp front and offshore advection of dense water at the bottom and buoyant water at the surface. This nonlinear limit is demonstrated in both the primitive equation model and in the tank experiments.

Sea-ice thermodynamics and brine drainage

Significant changes in the state of the Arctic ice cover are occurring. As the summertime extent of sea ice diminishes, the Arctic is increasingly characterized by first-year rather than multi-year ice. It is during the early stages of ice growth that most brine is injected into the oceans, contributing to the buoyancy flux that mediates the thermo-haline circulation. Current operational sea-ice components of climate models often treat brine rejection between sea ice and the ocean similarly to a thermodynamic segregation process, assigning a fixed salinity to the sea ice, typical of multi-year ice. However, brine rejection is a dynamical, buoyancy-driven process and the salinity of sea ice varies significantly during the first growth season. As a result, current operational models may over predict the early brine fluxes from newly formed sea ice, which may have consequences for coupled simulations of the polar oceans. Improvements both in computational power and our understanding of the processes involved have led to the emergence of a new class of sea-ice models that treat brine rejection dynamically and should enhance predictions of the buoyancy forcing of the oceans.