Influence of dispersed particles of tungsten carbide on the microstructure of 12Kh18N10T steel obtained by centrifugal casting

2020 ◽  
pp. 68-73
Author(s):  
I. V. Chumanov ◽  
◽  
A. N. Anikeev ◽  
D. A. Zherebtsov ◽  
◽  
...  

The development of new technologies in various industries, such as fast neuron reactors, require a new level of operational properties from steels and raise the issues of resistance to neutron radiation, radiation swelling, embrittlement and creep, and the level of residual activation. The principal way to increase these properties is to adjust the chemical composition, and rearrange the crystal structure of the metal. The authors propose to achieve this by introducing finely dispersed particles into the melt and controlled by them to “reinforce” the crystal lattice, grinding the metal structure. During the work, using the FactSage software package, thermodynamic modeling of the interaction of dispersed particles with a 18Х18Н10T steel melt was carried out, showing that the particles will interact with the metal melt, which can lead to their complete dissociation, and at the next stage of crystallization, regardless of the degree of dissolution of tungsten carbide, the formation of carbide phases based on titanium carbide with an FSS structure, as well as a carbide phase based on chromium carbide with the formula M23C3, will become. According to the simulation parameters, experiments were conducted, experimental blanks with different contents of the introduced tungsten carbide were obtained, and heat treatment was carried out. The study of microstructures showed that the introduced particles of tungsten carbide completely dissociate when interacting with a metal melt and contribute to an increase in ferrite in the microstructure of the workpiece. Studies of microhardness confi rmed the significant effect of the introduced carbide on the properties of the material: the maximum values of microhardness are achieved at a high concentration of refractory particles in the areas of their maximum concentration (outer edge of the workpieces). Carrying out heat treatment reduces microhardness, while aligning the gradient of properties with the volume of castings. This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the federal target program under Agreement No. 075-15-2019-1711 (internal number 05.608.21.0276) dated December 04, 2019 (unique project identifier RFMEFI60819X0276).

2020 ◽  
Vol 986 ◽  
pp. 3-8
Author(s):  
Andrey N. Anikeev ◽  
Ilia V. Chumanov ◽  
Vadim Sedukhin

Creating a gradient of properties in a single material is challenging for scientists and engineers. For this purpose, such methods are used as: welding of steels of different chemical compositions, joint rolling of steel sheets, sealing and surfacing of various kinds. All of these methods have a big disadvantage: under load, the material is destroyed in the weakest place - the place where the layers join. In this article, the authors proposed to obtain a gradient of properties in steel castings due to the introduction of dispersed particles of tungsten carbide into the crystallizing melt during centrifugal casting. The particles introduced serve as crystallization centers, accelerate the crystallization process and increase certain types of mechanical properties (hardness, microhardness, tensile strength). In addition, the particles of tungsten carbide have high hardness; therefore, in the structure of the workpieces they serve as reinforcing elements that strengthen the structure. The uneven distribution of particles in the preform being formed is possible for two reasons: tungsten carbide has a density greater than the melt, and besides, centrifugal force acts on them. The article describes the experiment and its results on the production of metal preforms with a gradient of properties. The introduced particles significantly influenced the macro-structure of the prepared castings. The article also presents the results of a study of the effect of particles on the hardness and micro-hardness of the resulting blanks.


Author(s):  
Marios Kazasidis ◽  
Elisa Verna ◽  
Shuo Yin ◽  
Rocco Lupoi

AbstractThis study elucidates the performance of cold-sprayed tungsten carbide-nickel coating against solid particle impingement erosion using alumina (corundum) particles. After the coating fabrication, part of the specimens followed two different annealing heat treatment cycles with peak temperatures of 600 °C and 800 °C. The coatings were examined in terms of microstructure in the as-sprayed (AS) and the two heat-treated conditions (HT1, HT2). Subsequently, the erosion tests were carried out using design of experiments with two control factors and two replicate measurements in each case. The effect of the heat treatment on the mass loss of the coatings was investigated at the three levels (AS, HT1, HT2), as well as the impact angle of the erodents (30°, 60°, 90°). Finally, the response surface methodology (RSM) was applied to analyze and optimize the results, building the mathematical models that relate the significant variables and their interactions to the output response (mass loss) for each coating condition. The obtained results demonstrated that erosion minimization was achieved when the coating was heat treated at 600 °C and the angle was 90°.


Author(s):  
Williams S. Ebhota ◽  
Akhil S. Karun ◽  
Freddie L. Inambao

The study investigates the application of centrifugal casting process in the production of a complex shape component, Pelton turbine bucket. The bucket materials examined were functionally graded aluminium A356 alloy and A356-10%SiCp composite. A permanent mould for the casting of the bucket was designed with a Solidworks software and fabricated by the combination of CNC machining and welding. Oil hardening non-shrinking die steel (OHNS) was chosen for the mould material. The OHNS was heat treated and a hardness of 432 BHN was obtained. The mould was put into use, the buckets of A356 Alloy and A356-10%SiCp composite were cast, cut and machined into specimens. Some of the specimens were given T6 heat treatment and the specimens were prepared according to the designed investigations. The micrographs of A356-10%SiCp composite shows more concentration of SiCp particles at the inner periphery of the bucket. The maximum hardness of As-Cast A356 and A356-10%SiCp composite were 60 BRN and 95BRN respectively, recorded at the inner periphery of the bucket. And these values appreciated to 98BRN and 122BRN for A356 alloy and A356-10%SiCp composite respectively after heat treatment. The prediction curves of the ultimate tensile stress and yield tensile stress show the same trend as the hardness curves.


2020 ◽  
Vol 861 ◽  
pp. 113-121
Author(s):  
Zhao Jun Jiang ◽  
Jun Wang ◽  
Dong Mei Cao

Nickel base single crystal superalloy is widely used in hot end parts of aeroengine because of its excellent creep, fatigue and oxidation resistance. In the face of strong market demand and the emergence of new technologies and methods, in 2019, nickel-based single crystal superalloys have made remarkable achievements in preparation and heat treatment processes, repair techniques, test methods, characterization methods, theoretical simulation analysis and composition design, which continuously promotes the development of nickel base single crystal superalloy to the direction of high performance and low cost. The present work reviews the progresses from preparation and heat treatment process, repair technology of service alloy structure, service evaluation of alloy, high flux composition design. The progress in the design, preparation and engineering application of superalloy materials will eventually promote the development of a new generation of aeroengine.


Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2460 ◽  
Author(s):  
Jelena Horky ◽  
Abdul Ghaffar ◽  
Katharina Werbach ◽  
Bernhard Mingler ◽  
Stefan Pogatscher ◽  
...  

In this study, two biodegradable Mg-Zn-Ca alloys with alloy content of less than 1 wt % were strengthened via high pressure torsion (HPT). A subsequent heat treatment at temperatures of around 0.45 Tm led to an additional, sometimes even larger increase in both hardness and tensile strength. A hardness of more than 110 HV and tensile strength of more than 300 MPa were achieved in Mg-0.2Zn-0.5Ca by this procedure. Microstructural analyses were conducted by scanning and transmission electron microscopy (SEM and TEM, respectively) and atom probe tomography (APT) to reveal the origin of this strength increase. They indicated a grain size in the sub-micron range, Ca-rich precipitates, and segregation of the alloying elements at the grain boundaries after HPT-processing. While the grain size and segregation remained mostly unchanged during the heat treatment, the size and density of the precipitates increased slightly. However, estimates with an Orowan-type equation showed that precipitation hardening cannot account for the strength increase observed. Instead, the high concentration of vacancies after HPT-processing is thought to lead to the formation of vacancy agglomerates and dislocation loops in the basal plane, where they represent particularly strong obstacles to dislocation movement, thus, accounting for the considerable strength increase observed. This idea is substantiated by theoretical considerations and quenching experiments, which also show an increase in hardness when the same heat treatment is applied.


Water ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 2245
Author(s):  
Kateřina Sukačová ◽  
Daniel Vícha ◽  
Jiří Dušek

Phosphorus is one of the non-renewable natural resources. High concentration of phosphorus in surface water leads to undesirable eutrophication of the water ecosystem. It is therefore necessary to develop new technologies not only for capturing phosphorus from wastewater but also for phosphorus recovery. The aim of the study was to propose three different integration scenarios for a microalgal biofilm system for phosphorus removal in medium and small wastewater treatment plants, including a comparison of area requirements, a crucial factor in practical application of microalgal biofilm systems. The area requirements of a microalgal biofilm system range from 2.3 to 3.2 m2 per person equivalent. The total phosphorus uptake seems to be feasible for construction and integration of microalgal biofilm systems into small wastewater treatment plants. Application of a microalgal biofilm for phosphorus recovery can be considered one of the more promising technologies related to capturing CO2 and releasing of O2 into the atmosphere.


2020 ◽  
Vol 991 ◽  
pp. 86-93
Author(s):  
Priyo Tri Iswanto ◽  
Akhyar Hasan ◽  
Aditya Janata ◽  
Luthfi Muhammad Mauludin ◽  
Hizba Muhammad Sadida

Fatigue behavior of A356 aluminum alloy for motorcycle rim was experimentally investigated based on T6 heat treatment and artificial aging. The high speed of 1,100 rpm from centrifugal casting was used in this study. The pouring temperature at 750 °C was employed and the preheated temperature at 250 °C was applied on the mold. The solution heat treatment of the sample was conducted for 4 hours at 540 o C before it immersed into the water for rapid cooling at room temperature. This step followed by natural aging treatment at 30 °C and artificial aging treatment at 150 °C, 175 °C, and 200 °C for 2 hours, respectively. It is found that increasing centrifugal casting speed into 1,100 rpm combined with heat treatment and artificial aging temperature can significantly increase not only its mechanical properties but also the fatigue life of motorcycle wheel made of A356 aluminum alloy. This experiment proved that the lowest fatigue crack growth rate obtained with this method was at temperature of 175°C.


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