Diastereoselective Formation of Trans-HC(O)SH through Hydrogenation of OCS on Interstellar Dust Grains

With the presence of evermore complex S-bearing molecules being detected lately, studies of their chemical formation routes need to keep up the pace to rationalize observations, suggest new candidates for detection, and provide input for chemical evolution models. In this paper, we theoretically characterize the hydrogenation channels of OCS on top of amorphous solid water (ASW) as an interstellar dust grain analog in molecular clouds. Our results show that the significant reaction outcome is trans-HC(O)SH, a recently detected prebiotic molecule toward G+0.693. The reaction is diastereoselective, explaining the apparent absence of the cis isomer in astronomical observations. We found that the reaction proceeds through a highly localized radical intermediate (cis-OCSH), which could be essential in the formation of other sulfur-bearing complex organic molecules due to its slow isomerization dynamics on top of ASW.

The Role of Terahertz and Far-IR Spectroscopy in Understanding the Formation and Evolution of Interstellar Prebiotic Molecules

Stellar systems are often formed through the collapse of dense molecular clouds which, in turn, return copious amounts of atomic and molecular material to the interstellar medium. An in-depth understanding of chemical evolution during this cyclic interaction between the stars and the interstellar medium is at the heart of astrochemistry. Systematic chemical composition changes as interstellar clouds evolve from the diffuse stage to dense, quiescent molecular clouds to star-forming regions and proto-planetary disks further enrich the molecular diversity leading to the evolution of ever more complex molecules. In particular, the icy mantles formed on interstellar dust grains and their irradiation are thought to be the origin of many of the observed molecules, including those that are deemed to be “prebiotic”; that is those molecules necessary for the origin of life. This review will discuss both observational (e.g., ALMA, SOFIA, Herschel) and laboratory investigations using terahertz and far-IR (THz/F-IR) spectroscopy, as well as centimeter and millimeter spectroscopies, and the role that they play in contributing to our understanding of the formation of prebiotic molecules. Mid-IR spectroscopy has typically been the primary tool used in laboratory studies, particularly those concerned with interstellar ice analogues. However, THz/F-IR spectroscopy offers an additional and complementary approach in that it provides the ability to investigate intermolecular interactions compared to the intramolecular modes available in the mid-IR. THz/F-IR spectroscopy is still somewhat under-utilized, but with the additional capability it brings, its popularity is likely to significantly increase in the near future. This review will discuss the strengths and limitations of such methods, and will also provide some suggestions on future research areas that should be pursued in the coming decade exploiting both space-borne and laboratory facilities.

Optical properties and dust temperatures in clumpy diffuse medium

ABSTRACT In this study, we explore the impact of inhomogeneities in the spatial distribution of interstellar dust on spatial scales of ≤1 au caused by ion shadowing forces on the optical properties of diffuse interstellar medium (ISM) as well as on the dust temperature. We show that recently proposed possibility that interstellar dust grains in the diffuse ISM are grouped in spherical cloudlets (clumps) may significantly affect the observed optical properties of the diffuse ISM in comparison to that calculated under the commonly accepted assumption on the uniform dust/gas mixture if the size of clumps ≳0.1 au. We found that opacity of an arbitrary region of diffuse ISM quickly decreases with growth of dusty clumps. We also studied the dependence of opacity and dust temperature inside the dusty clumps on their size. We show that the clumps larger than 0.1 au are opaque for far-ultraviolet radiation. Dust temperature exhibits a gradient inside a clump, decreasing from the edge to the centre by several degrees for a clump of a size of 0.1 au and larger. We argue that dust temperatures and high opacity within clumps larger than 0.1 au may facilitate somewhat more efficient synthesis of molecules on surfaces of interstellar grains in the diffuse ISM than it was anticipated previously. On the other hand, the presence of clumps with sizes below 0.1 au makes small or negligible influence on the optical properties of the diffuse ISM in comparison to the case with uniform dust/gas mixture.

Origin and evolution of the Galactic inventories of interstellar dust and its composition

ABSTRACT Interstellar dust is a significant component of matter in the galaxies. The dust owns its origin and reprocessing in a wide range of astrophysical environments. In order to understand the origin and evolution of the distinct types of interstellar dust grains, we have attempted a comprehensive correlated study of the thermodynamics condensation of dust grains in distinct stellar environments with the Galactic chemical evolution of the Milky Way Galaxy. The Galaxy is evolved in terms of elemental evolution resulting from stellar nucleosynthetic contributions of several generations of stars. Based on the elemental composition of the evolving Galaxy, the relative abundances of the major constituents of interstellar dust are assessed. The major aim is to redistribute the various condensable elements at any epoch during the evolution of the Galaxy into various grain constituents and understand their abundance evolution based on a mass-balance formalism. We also performed thermodynamical equilibrium condensation calculations to understand the stellar origin of various grain constituents that could carry the isotopic signatures of the various stellar nucleosynthetic sources. This is perhaps a novel attempt to estimate the bulk dust mass budget in the evolving Galaxy. The normalized mass of the Galactic dust is predicted to decrease with the increase in distance from the Galactic centre. It increases over time. The supernovae SNe Ia are predicted as the most prominent sources of Fe-dust mass, the supernova SN II+Ib/c produces oxides- and silicate-dust mass, and the AGB stars contribute to carbonaceous dust mass.

The role of wind driving in OB star bow nebulae

ABSTRACT Bow-shaped mid-infrared (mid-IR) emission regions have been discovered in satellite observations of numerous late-type O and early-type B stars with moderate velocities relative to the ambient interstellar medium. Previously, hydrodynamical bow shock models have been used to study this emission. It appears that such models are incomplete in that they neglect kinetic effects associated with long mean free paths of stellar wind particles, and the complexity of Weibel instability fronts. Wind ions are scattered in the Weibel instability and mix with the interstellar gas. However, they do not lose their momentum and most ultimately diffuse further into the ambient gas like cosmic rays, and share their energy and momentum. Lacking other coolants, the heated gas transfers energy into interstellar dust grains, which radiate it. This process, in addition to grain photoheating, provides the energy for the emission. A weak R-type ionization front, formed well outside the IR emission region, generally moderates the interstellar gas flow into the emission region. The theory suggests that the IR emission process is limited to cases of moderate stellar peculiar velocities, evidently in accord with the observations.

What can we learn from observations of small dust grains in the interstellar space?

<p>A fraction of the dust that is contained in the local interstellar medium around the Sun can enter the heliosphere and be observed in the solar system. The exception is the small size component of the interstellar dust spectrum, which can be directly observed only beyond the heliopause. </p><p>The charge-to-mass ratio of the interstellar dust grains of nanometer size can be high enough to make their dynamics highly sensitive to the magnetic field and plasma flow. Based on numerical simulations and analytical models, we show how the small interstellar grains entering the transition region between the undisturbed interstellar medium and the outer boundary of the heliosphere respond to plasma and magnetic field structures (in particular the heliospheric bow shock and the heliopause) expected in this region. We also point out which dust impact measurements from a spacecraft in the interstellar space would be most desirable for imaging the structure of the transition region by means of interstellar dust.</p>

Interstellar Carbon Dust

In the ranking of cosmic abundance of the elements, carbon is the second element, after oxygen, able to form multiple bonds propagating the formation of a network, thus playing an essential role in the formation of nanometer- to micrometer-sized interstellar dust grains. Astrophysical spectroscopic observations give us remote access to the composition of carbonaceous and organic interstellar grains. Their presence and abundances from spectroscopic observations and the phases of importance for the Galactic carbon budget are considered in this article.

Signatures of diffuse interstellar gas in the Galaxy Evolution Explorer all-sky survey

Context. The all-sky survey run by the Galaxy Evolution Explorer (GALEX AIS) mapped about 85% of the Galaxy at ultraviolet (UV) wavelengths and detected the diffuse UV background produced by the scattering of the radiation from OBA stars by interstellar dust grains. Against this background, diffuse weak structures were detected as well as the UV counterparts to nebulae and molecular clouds. Aims. To make full profit of the survey, unsupervised and semi-supervised procedures need to be implemented. The main objective of this work is to implement and analyze the results of the method developed by us for the blind detection of ISM features in the GALEX AIS. Methods. Most ISM features are detected at very low signal levels (dark filaments, globules) against the already faint UV background. We have defined an index, the UV background fluctuations index (or UBF index), to identify areas of the sky where these fluctuations are detected. The algorithm is applied to the images obtained in the far-UV (1344–1786 Å) band since this is less polluted by stellar sources, facilitating the automated detection. Results. The UBF index is shown to be sensitive to the main star forming regions within the Gould’s Belt, and to some prominent loops like Loop I or the Eridanus and Monogem areas. The catalog with the UBF index values is made available online to the community.

Silicon and iron dust in gamma-ray burst host galaxy absorbers

ABSTRACT Depletion studies provide a way to understand the chemical composition of interstellar dust grains. We here examine 23 gamma-ray bursts (GRBs) optical afterglow spectra (spanning 0.6 ≤ z ≤ 5.0) and compare their silicon and iron dust-phase column densities with different extinction curve parameters to study the composition of the interstellar dust grains in these high-redshift GRB host galaxies. The majority of our sample (87 per cent) show featureless extinction curves and only vary in shape. We observe strong correlations (with $\gt 96{{\ \rm per\ cent}}$ significance) between the total-to-selective extinction, RV, and the dust-phase column densities of Si and Fe. Since a large fraction of interstellar iron is locked in silicate grains, this indicates that high Si and Fe depletion leads to an increase in the fraction of large silicate grains and vice versa. This suggests that silicates play a vital role to induce the entire extinction at any wavelength. On the other hand, the far-ultraviolet (UV) extinction is usually attributed to the presence of small silicates. However, we find no trend between the far-UV parameter of the extinction curve, c4, and the abundance of Si and Fe in the dust phase. We, therefore, propose that the far-UV extinction could be a combined effect of small (probably nanoparticles) dust grains from various species.