Filmwise Condensation From Humid Air On a Vertical Superhydrophilic Surface: Explicit Roles of the Humidity Ratio Difference and the Degree of Subcooling

2021 ◽  
Author(s):  
Chayan Das ◽  
Rohit Gupta ◽  
Saikat Halder ◽  
Amitava Datta ◽  
Ranjan Ganguly
Keyword(s):  
Mass Transfer ◽  
Mass Flux ◽  
Mechanistic Model ◽  
Operating Conditions ◽  
Humidity Ratio ◽  
Ratio Difference ◽  
Environment Temperature ◽  
Humidity Chamber ◽  
Superhydrophilic Surface ◽  
Vapor Mass

Abstract The process involving heat and mass transfer during filmwise condensation (FWC) in presence of non-condensable gases (NCG) has great significance in a large variety of engineering applications. The vapor mass flux leading to condensation and the resulting condensation heat transfer coefficient (CHTC) are dependent on the gradients of temperature and vapor mass fraction established near the condenser plate. The effects of the two most influencing thermodynamic parameters, i.e., the degree of subcooling and the difference of humidity ratio (between the free stream environment and on the condenser plate), have been characterized in this work both experimentally and through a mechanistic model. The vapor mass flux during condensation on a subcooled vertical superhydrophilic surface under a free convection regime is experimentally measured in a controlled environment (temperature and humidity) chamber. A mechanistic model, based on the similarity of energy and species transports, is formulated for the thermogravitational boundary layer over the condenser plate and tuned against the experimental results. Further, the model is used to obtain comprehensive data of the condensate mass flux and CHTC as functions of the salient thermal operating conditions over a wide parametric range. Results indicate that humidity ratio difference has a more pronounced influence on the condensation mass transfer rather than the degree of subcooling. The mechanistic model lends to the development of empirical correlations of condensate mass flux and CHTC as explicit functions of these two parameters for easy use in practical FWC configurations.

scholarly journals Integrated Experimental and Theoretical Studies on an Electrochemical Immunosensor

Biosensors ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 144
Author(s):  
Neda Rafat ◽  
Paul Satoh ◽  
Scott Calabrese Barton ◽  
Robert Mark Worden
Keyword(s):  
Mass Transfer ◽  
Mechanistic Model ◽  
Signal Amplitude ◽  
Electrical Signal ◽  
Current Control ◽  
Operating Conditions ◽  
Statistical Design Of Experiments ◽  
Modeling Framework ◽  
Control Coefficients ◽  
Individual Mass

Electrochemical immunosensors (EIs) integrate biorecognition molecules (e.g., antibodies) with redox enzymes (e.g., horseradish peroxidase) to combine the advantages of immunoassays (high sensitivity and selectivity) with those of electrochemical biosensors (quantitative electrical signal). However, the complex network of mass-transfer, catalysis, and electrochemical reaction steps that produce the electrical signal makes the design and optimization of EI systems challenging. This paper presents an integrated experimental and modeling framework to address this challenge. The framework includes (1) a mechanistic mathematical model that describes the rate of key mass-transfer and reaction steps; (2) a statistical-design-of-experiments study to optimize operating conditions and validate the mechanistic model; and (3) a novel dimensional analysis to assess the degree to which individual mass-transfer and reaction steps limit the EI’s signal amplitude and sensitivity. The validated mechanistic model was able to predict the effect of four independent variables (working electrode overpotential, pH, and concentrations of catechol and hydrogen peroxide) on the EI’s signal magnitude. The model was then used to calculate dimensionless groups, including Damkohler numbers, novel current-control coefficients, and sensitivity-control coefficients that indicated the extent to which the individual mass-transfer or reaction steps limited the EI’s signal amplitude and sensitivity.

scholarly journals Modeling Bacterial Regrowth and Trihalomethane Formation in Water Distribution Systems

Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 463
Author(s):  
Gopinathan R. Abhijith ◽  
Leonid Kadinski ◽  
Avi Ostfeld
Keyword(s):  
Distribution Systems ◽  
Water Distribution ◽  
Mechanistic Model ◽  
Water Distribution Systems ◽  
Sensitivity Study ◽  
Operating Conditions ◽  
Growth Rate Constant ◽  
Model Parameters ◽  
Bacterial Regrowth ◽  
The Impact

The formation of bacterial regrowth and disinfection by-products is ubiquitous in chlorinated water distribution systems (WDSs) operated with organic loads. A generic, easy-to-use mechanistic model describing the fundamental processes governing the interrelationship between chlorine, total organic carbon (TOC), and bacteria to analyze the spatiotemporal water quality variations in WDSs was developed using EPANET-MSX. The representation of multispecies reactions was simplified to minimize the interdependent model parameters. The physicochemical/biological processes that cannot be experimentally determined were neglected. The effects of source water characteristics and water residence time on controlling bacterial regrowth and Trihalomethane (THM) formation in two well-tested systems under chlorinated and non-chlorinated conditions were analyzed by applying the model. The results established that a 100% increase in the free chlorine concentration and a 50% reduction in the TOC at the source effectuated a 5.87 log scale decrement in the bacteriological activity at the expense of a 60% increase in THM formation. The sensitivity study showed the impact of the operating conditions and the network characteristics in determining parameter sensitivities to model outputs. The maximum specific growth rate constant for bulk phase bacteria was found to be the most sensitive parameter to the predicted bacterial regrowth.

scholarly journals Dynamics with Cattaneo–Christov heat and mass flux theory of bioconvection Oldroyd-B nanofluid

2020 ◽  
Vol 12 (8) ◽  
pp. 168781402093046 ◽  
Author(s):  
Noor Saeed Khan ◽  
Qayyum Shah ◽  
Arif Sohail
Keyword(s):  
Mass Transfer ◽  
Porous Media ◽  
Differential Equations ◽  
Mass Flux ◽  
Homotopy Analysis Method ◽  
Two Dimensional ◽  
Analysis Method ◽  
Homotopy Analysis ◽  
Transfer Flow ◽  
Insight Into

Entropy generation in bioconvection two-dimensional steady incompressible non-Newtonian Oldroyd-B nanofluid with Cattaneo–Christov heat and mass flux theory is investigated. The Darcy–Forchheimer law is used to study heat and mass transfer flow and microorganisms motion in porous media. Using appropriate similarity variables, the partial differential equations are transformed into ordinary differential equations which are then solved by homotopy analysis method. For an insight into the problem, the effects of various parameters on different profiles are shown in different graphs.

Analysis of Vapor Evaporation Loss in Filling Gasoline into Tank

2011 ◽  
Vol 347-353 ◽  
pp. 372-375 ◽  
Author(s):  
Wei Qiu Huang ◽  
Feng Li ◽  
Shu Hua Zhao ◽  
Jing Zhong
Keyword(s):  
Mass Transfer ◽  
Experimental System ◽  
Pilot Scale ◽  
Convective Transport ◽  
Operating Conditions ◽  
Vapor Concentration ◽  
Air Mass ◽  
Evaporation Loss ◽  
Gas Space ◽  
Gasoline Evaporation

A pilot-scale experimental system of filling gasoline into a tank was built to investigate gasoline vapor-air mass transfer in the tank gas space and the vapor evaporation loss from the tank in different operating conditions. The results showed that the higher the location of filling pipe exit inside the tank, the quicker the speed of the filling gasoline, and the higher the initial vapor concentration in the tank gas space, then the more severe the vapor-air convective transport and the larger the gasoline evaporation loss rates.

Numerical Analysis of the Heat and Mass Transfer Characteristics in an Autothermal Methane Reformer

2010 ◽  
Vol 7 (5) ◽  
Author(s):  
Joonguen Park ◽  
Shinku Lee ◽  
Sunyoung Kim ◽  
Joongmyeon Bae
Keyword(s):  
Mass Transfer ◽  
Numerical Analysis ◽  
Heat And Mass Transfer ◽  
Steam Reforming ◽  
Space Velocity ◽  
Reaction Model ◽  
Operating Conditions ◽  
Local Thermal Equilibrium ◽  
Inlet Temperature ◽  
Transfer Characteristics

This paper discusses a numerical analysis of the heat and mass transfer characteristics in an autothermal methane reformer. Assuming local thermal equilibrium between the bulk gas and the surface of the catalyst, a one-medium approach for the porous medium analysis was incorporated. Also, the mass transfer between the bulk gas and the catalyst’s surface was neglected due to the relatively low gas velocity. For the catalytic surface reaction, the Langmuir–Hinshelwood model was incorporated in which methane (CH4) is reformed to hydrogen-rich gases by the autothermal reforming (ATR) reaction. Full combustion, steam reforming, water-gas shift, and direct steam reforming reactions were included in the chemical reaction model. Mass, momentum, energy, and species balance equations were simultaneously calculated with the chemical reactions for the multiphysics analysis. By varying the four operating conditions (inlet temperature, oxygen to carbon ratio (OCR), steam to carbon ratio, and gas hourly space velocity (GHSV)), the performance of the ATR reactor was estimated by the numerical calculations. The SR reaction rate was improved by an increased inlet temperature. The reforming efficiency and the fuel conversion reached their maximum values at an OCR of 0.7. When the GHSV was increased, the reforming efficiency increased but the large pressure drop may decrease the system efficiency. From these results, we can estimate the optimal operating conditions for the production of large amounts of hydrogen from methane.

Mass Transfer Enhancement for CO2 Absorption in Structured Packed Absorption Column

2019 ◽  
Vol 41 (5) ◽  
pp. 820-820
Author(s):  
Pongayi Ponnusamy Selvi and Rajoo Baskar Pongayi Ponnusamy Selvi and Rajoo Baskar
Keyword(s):  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Gas Flow ◽  
Aqueous Ammonia ◽  
Volume Flow Rate ◽  
Packed Column ◽  
Operating Conditions ◽  
Co2 Absorption ◽  
Absorption Column

The acidic gas, Carbon dioxide (CO2) absorption in aqueous ammonia solvent was carried as an example for industrial gaseous treatment. The packed column was provided with a novel structured BX-DX packing material. The overall mass transfer coefficient was calculated from the absorption efficiency of the various runs. Due to the high solubility of CO2, mass transfer was shown to be mainly controlled by gas side transfer rates. The effects of different operating parameters on KGav including CO2 partial pressure, total gas flow rates, volume flow rate of aqueous ammonia solution, aqueous ammonia concentration, and reaction temperature were investigated. For a particular system and operating conditions structured packing provides higher mass transfer coefficient than that of commercial random packing.

Modeling Heat and Mass Transfer Correlations for Flow Through Micro Channels in Monolith Honeycomb Catalytic Combustor

2009 ◽  
Author(s):  
Juan Yin ◽  
Yi-wu Weng
Keyword(s):  
Mass Transfer ◽  
Heat And Mass Transfer ◽  
Catalytic Combustion ◽  
Operating Conditions ◽  
Performance Characteristics ◽  
Predicting Performance ◽  
Micro Channels ◽  
Characteristics Analysis ◽  
Flow Through ◽  
Catalytic Combustor

This paper investigated performance characteristics analysis of catalytic combustion by utilizing 1-D models incorporated heat and mass transfer correlations. The 1-D numerical results were compared with 2-D models studies and experimental data. The performance characteristics were mainly the effects of operating conditions on methane conversion rate. The comparable analysis confirmed that 1-D model can success in predicting performance of catalytic combustion when empiric inter-phase heat and mass transfer correlations are used and appropriate operating conditions are chosen.

Mechanistic model of iodine mass transfer at pool surfaces

2014 ◽  
Vol 278 ◽  
pp. 627-631
Author(s):  
K. Fischer ◽  
M. Freitag ◽  
H.S. Kang
Keyword(s):  
Mass Transfer ◽  
Mechanistic Model

scholarly journals The Effect of Surface Roughness on Diffusion and Chemical Reaction Controlled Limiting Currents on a Rotating Cylinder Electrode in Deaerated Solutions with and Without CO2

CORROSION ◽  
10.5006/2552 ◽  
2018 ◽  
Vol 74 (9) ◽  
pp. 971-983 ◽  
Author(s):  
M. Al-Khateeb ◽  
R. Barker ◽  
A. Neville ◽  
H.M. Thompson
Keyword(s):  
Mass Transfer ◽  
Surface Roughness ◽  
Sherwood Number ◽  
Schmidt Number ◽  
Rotating Cylinder ◽  
Operating Conditions ◽  
Limiting Current ◽  
Surface Roughening ◽  
Rotating Cylinder Electrode ◽  
Effect Of Surface

The influence of surface roughness on mass transfer on a rotating cylinder electrode apparatus is investigated experimentally for a roughness pattern consisting of grooves parallel to the direction of fluid flow. Mass transfer from four different samples, with roughness values of 0.5 μm, 6 μm, 20 μm, and 34 μm, is measured using the limiting current technique for a range of rotational speeds in NaCl solutions saturated with N2 at pH = 3 and 4. Comparison with available correlations for the Sherwood number in literature (which are independent of surface roughness and are either for specific or arbitrary roughness patterns) shows that H+ mass transfer only correlates well for particular levels of roughness and that their accuracy can be increased if a correlation is utilized which is a function of surface roughening. A new correlation for Sherwood number as a function of the Reynolds number, Schmidt number, and surface roughness is proposed which agrees well with the mass transfer observed from all of the rough surface cases considered for this particular roughness pattern. Complementary experiments in CO2 environments were used to assess the combined limiting current associated with H+ and H2CO3 reduction (with the latter occurring via the buffering effect and being associated with the slow CO2 hydration step). Although the increase in sample roughness clearly leads to an increase in the rate of H+ mass transfer, in the CO2 environments considered, surface roughness is found to have no significant influence on the limiting current contribution from H2CO3, which can therefore be determined from Vetter’s equation across this range of operating conditions.

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